thermodynamics from the microscopic aspect. Topics include: First, Second, and Third Law of thermodynamics, concepts of systems, Gibbs free energy, eq

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1 材料热力学课程教学大纲课程基本信息 (Course Information) 课程代码 (Course Code) MT350 * 学时 (Credit Hours) 48 * 学分 (Credits) 3 * 课程名称 (Course Name) 课程性质 (Course Type) 授课语言 (Language of Instruction) * 开课院系 (School) 先修课程 (Prerequisite) 授课教师 (Teacher) * 课程简介 (Description) ( 中文 ) 材料热力学 ( 英文 ) of Materials 金学军李伟 ( 中文 ) 必修 / 材料科学与工程专业双语材料科学与工程学院高等数学大学物理大学化学原理课程网址 (Course Webpage) View.aspx?action=view&courseType=0&courseId=5204 课程目标 : 既掌握热力学的基本知识, 又能将这些原理和方法结合材料实践加以应用重点掌握热力学的基本概念原理和方法, 理解相图的构成规则和诠释相图启发学生发现分析和解决问题的能力, 对实验结果进行整理归纳和分析的能力 ; 同时培养刻苦务实精勤进取乐于创新的精神, 使学生具有良好的职业道德和学术道德课程内容 : 掌握热力学三大定律, 掌握熵焓自由能内能的概念以及用于分析一个特定的系统的方法和思路使学生能够用热力学的原理分析和解释日常生活中的一些相关的现象同时熟悉热力学用于分析解决气体循环溶液化学反应化学平衡电化学以及相变中的相关问题的知识以及在这些领域的应用中发现的重要规律或者方程学会应用材料热力学原理用于阐明和预测相图相变以及材料的其他物理现象 ( 英文 )This course introduces the fundamental concepts/theories on the * 课程简介 (Description) thermodynamics of materials, from the basic concepts of enthalpy, entropy, free energy, and the basic laws of thermodynamics, to the behaviors of the systems including equilibrium, phase transformation, chemical reactions, mixing, cooling etc. Statistic mechanics is also introduced to explain the basic rules of

2 thermodynamics from the microscopic aspect. Topics include: First, Second, and Third Law of thermodynamics, concepts of systems, Gibbs free energy, equilibrium, solution, dilute solutions, mixing, phase equilibrium, phase rules, phase diagrams, statistical mechanics, and surface phenomena. Specific applications of these basic concepts in air conditioning, battery electrodes, desalination, and metallurgy etc. are discussed. 课程教学大纲 (course syllabus) 1. 数理化基础扎实, 专业基础知识结构完整合理 (A4 和 B3); 2. 结合授课老师的研究课题, 关注和了解本领域的最新科技进展 (A3 和 B7); 3. 采用英文原版教材, 具有全球前沿视野 (B6 和 B10); 4. 具有较强的交流能力合作精神以及领导能力 (B1 和 B4); * 学习目标 (Learning Outcomes) 5. To understand the fundamental and basic principles of thermodynamics (A5.3). 6. To lean to apply the basic principles and methods of thermodynamics in the study and the R&D of materials(a3). 7. Tounderstand the phase rules and the phase diagrams, as well as the application of the phase diagrams in materialsstudy(a5.3). 8. To cultivate the ability of discovering the potential of existing materials and of developing new materials(b3). 教学内容学时教学作业基本要求考方式及要查求方式 * 教学内容进度安排及要求 Introduction and the First Law of 课后作业理解与运用 To have a general scenario of materials science and thermodynamics. To understand the main contents and the principles of thermodynamics as well as their interaction with materials (Class Schedule science. & Requirements) The Second Law of Tounderstand the derivation and physical meaning of entropy, a state function of system; To understand the importance of the second law of thermodynamics; be able to interpret the heat-engine process and application; be able to understand the

3 principle of idealization in the analysis of a system; to calculate the change of entropy of a system and to understand the third law of thermodynamics. Relationship between the thermodynamic properties of a system 4 讲课实验 Toderive the partial derivation expression of Gibbs free energy; to know the principle of chemical potential and partial molar quantity;to understand the concept of and application of thermodynamic relations. 课后作 To know the conditions of 业理 equilibrium;derive the Clapeyon 综 Equilibrium 2 讲课解与运用自学 equation and understand the application of the Clapeyron equation in real cases; understand the orders of 合评估 transitions. The principle of thermodynamic Chemical Equilibrium 2 讲课 activity; the idea of chemical equilibrium and the calculation of equilibrium constant; the derivation of Ellingham diagram and its application in telling the relative stability ofoxides; the calculation of adiabatic flame temperature using the principle of chemical equilibrium. To understand the fundamentals of electrochemical cell and the calculation of cell voltage; understand the half-cell reaction Electrochemistry 6 讲课 and the direction of electrochemical reaction;know the variation of cell voltage with the change of solution concentration as well as the application of Nernst equation; understand the application of electrochemical potential, e.g. concentration cells, oxygen pressure determination; know the concepts of electrochemical potential. Solution 6 讲课课后作业理解与运 To know concepts of thermodynamic activity/partial molar quantities and relative partial molar quantities; 综合评估

4 用自学 understand the calculation of mixing entropy and enthalpy of ideal solution as well as the graphing; understand the Gibbs- Duhem equation, dilute solution and colligative properties of dilute solution; know the principle of regular solution and its microscopic explanation. Phase Rule 2 讲课 To understand the principles of phases, components, degree of freedom; understand the derivation and application of Gibbs phase rules; be familiar with the derivation of onecomponent phase diagram. 课后作 Toknow the lever rule, cooling curves; Phase Diagrams 8 讲课业理解与运用自学 understand the principle of simple Eutectic diagram, completemiscibility, immiscibility, and Peritectic phase diagrams; understand thefundamental of ternary phase diagram. Statistical 2 讲课 To know the principle of macrostate and microstate; understand Hypothesis of Boltzmann and Boltzmann distribution; understand the Statistical explanation of entropy and ideal gas To know the principle of heat Statistic Mechanics capacity of condense matters and some empirical laws of heat capacities; understand the Maxwell distribution for gases; know the concepts of quantum statistics, including Bose-Einstein distribution and Fermi-Diracdistribution. Interface and Surface Toknow the principle of surface energy and the method to measure the surface energy; understandvapor pressure on curved liquid surface, solubility and melting point of small particles; explain the phenomena of wetting, physical andchemical

5 adsorption. ( 成绩构成 ) 1. 课后作业 (20%); * 考核方式 (Grading) 2. 课堂表现 (20%); 3. 期中考试 (20%) 4. 期末考试 (40%). 1. of Materials David V. Rangone John Wiley & Sons, Inc 材料热力学江伯鸿编著上海交通大学出版社 1999 * 教材或参考资料 (Textbooks & Other Materials) 3. 物理化学程兰征, 章燕豪等编上海科学技术出版社物理化学简明教程印永嘉, 奚正楷, 李大珍等编高等教育出版金属材料热力学徐祖耀著科学出版社材料热力学, 徐祖耀主编, 高等教育出版社, 微观组织热力学, 西泽泰二著, 郝士明译, 化学工业出版社, University policy states that cheating, including plagiarism, is a scholastic offence. The commission of a scholastic offence is attended by academic penalties which might include expulsion from the program. If you are caught cheating, there will be no second warning. (see Student Manual for undergraduate students of Shanghai Jiao Tong University.) 其它 (More) 2. Any student who, in the opinion of the instructor, is absent too frequently from class, will be debarred from taking the regular examination in the course. (see Student Manual for undergraduate students of Shanghai Jiao Tong University.) In case of illness or other problems that make your absence inevitable, a written permission by a doctor or by school student affair officer should be handed in before the class. 3. All cell phones that are taken into class should be poweredoff. 4. The tutorial sessions are held to discuss the materials covered in the lectures. Students are advised, but not required, to attend tutorials.

6 5. Advise the instructor if you are having problems completing the assignment on time (prior to the due date of the assignment); penalty might be applied for late assignments. 6. The above topics and outline are subject to adjustments and changes as needed. Students who have failed this course must re-take the course. 备注 (Notes) 备注说明 : 1. 课程大纲一般为教师网上填写, 填写要求会自动提示 ; 对于新开课程, 需要填着纸质大纲, 并经院系教学委员会或专业委员会通过 2. 带 * 内容为必填项 3. 课程简介字数为字 ; 课程大纲以表述清楚教学安排为宜, 字数不限

Theory of Groups is another course for undergraduates; and Module Theory will be a basic course of graduates). The main contents include the basic str

Theory of Groups is another course for undergraduates; and Module Theory will be a basic course of graduates). The main contents include the basic str 抽象代数课程教学大纲课程基本信息 (Course Information) 课程代码 (Course Code) * 学时 MA20 (Credit Hours) 6 * 学分 (Credits) * 课程名称抽象代数 (Course Name) Abstract Algebra 课程性质 (Course Type) 必修课授课对