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1 5 2 Vol. 5 No Journal of Food Safety and Quality Feb., 2014 胡海 1, 李涵 2, 张红菱 1* (1., ; 2., ) 摘要 : (POPs), 关键词 : ; ; ; Progress on persistent organic pollutants accumulated in food and their detection technologies HU Hai 1, LI Han 2, ZHANG Hong-Ling 1* (1. School of Biology and Pharmaceutical Engineering, Wuhan Polytechnic University, Wuhan , China; 2. School of Public Health, Tongji Medical College, Huazhong University of Science and Technology, Wuhan , China) ABSTRACT: Persistent organic pollutants (POPs) can accumulate in environment and human body tissues or organic through atmosphere, water, soil, and other media, threatening the health and life safety. The species, harm and control technology of POPs were summarized in this paper. A detailed specification for the hotspot detection methods was described, and the advantages and disadvantages of each method were also analyzed, so as to provide useful references to detect of persistent organic pollutants. KEY WORDS: persistent organic pollutants; endanger; accumulation; detecting techniques (persistent organic pollutants, POPs) ( ), 2001, : (DDT) 噁, [1] 持久性有机污染物及其在食物中的蓄积过程基金项目 : ( ) Fund: Supported by the National Natural Science Foundation of China ( ) * 通讯作者 :,, zhlwjb@sina.com *Corresponding author: ZHANG Hong-Ling, Professor, School of Biology and Pharmaceutical Engineering, Wuhan Polytechnic University, No. 68, Xuefu south Road, Dongxihu District, Wuhan , China. zhlwjb@sina.com

2 464 5, ; DDT, 1 [2] ; 噁, ; (PCBs), [3] POPs,,,,, POPs POPs, POPs [4] POPs, POPs [5], 2 持久性有机污染物的特性及危害 POPs 2, 6 [6] POPs, POPs [1], 7 POPs [7] 3 持久性有机污染物 (POPs) 的治理相关技术, (POPs) [8] DDT,,, [9] DDT Taya Titan [10],, 100%, DDT 70 POPs, ; POPs, POPs;, POPs [11],, POPs 4 可蓄积到食物中持久性有机污染物 (POPs) 检测相关技术进展 4.1 生物方向 [12] Quantera SXM DNA(dsDNA) (MB), 30 pmol/l, Behnisch [13], 7- 噁 (EROD) PCBs, (surface plasmon resonance, SPR) Rogers [14] SPR PCBs, 2.5 ng/ml, Mauriz [15] SPR, DDT 15 pg/ml DDT Wei [16] WSPR, mol/l Dong [17] MIP-SPR, μg/ml POPs,

3 2, : 465 SPR,,, 4.2 化学方向,, [18,19], (GC-MS) [20], [21,22] (LC-MS) [23,24] [25] QuEChERS [26,27],,, POPs [28] 7 (PCB) [29],,,, 4.3 免疫传感方向 / POPs, POPs Michele [30] ELISA, HRP,, [31],, 6 G, 0.49 ng/ml [32],,, A [33],, ng/ml,, 4.4 其他方向的新方法, POPs [34] a 0.2~2 THz, [35], (CE-MPEF), POPs [36],,, 5 展望,,, (POPs), POPs 参考文献 [1],,,. POPs [J]., 200, 19(8): Ding F, Sheng W, Gu JL. POPs Pollution and Its Treatment [J]. Sci-Tech Inform Dev Econ, 2009, 19(8): [2]. (POPs) [J]., 2006, 29: Mu JP. Progress on persistent organic pollutants accumulated [J].

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[25] Barriada-Pereira M, Serodio P, Gonzalez-Castro MJ, et al.

5 2, : 467 mistry, 2011, 127: [24] Gonzalez-Rodriguez R M, Rial-Otero R, Cancho-Grande B, et a1. Determination of 23 pesticide residues in leafy vegetables using gas chromatography-ion trap mass spectrometry and analyte protectants [J]. J Chromatogr A, 2008, 1196: [25] Barriada-Pereira M, Serodio P, Gonzalez-Castro MJ, et al. Determination of organochlorine pesticides in vegetable matrices by stir bar sorptive extraction with liquid desorptionand large volume injection-gas chromatography mass spectrometry towards compliance with EuropeanUnion directives [J]. J Chromatogr A, 2010, 1217: [26] EPA8270C. Semivolatile Organic Compounds by Gas Chromatography /Mass Spectrometry(GC-MS) [Z] [27] Aaastasslades M, Lehotays J, Stajnbaher D, et al. Fast and easy multiresidue method employing acetonitrile extraction/partitioning and dispersive solid-phase extraction for the determination of pesticide residues in produce [J]. J AOAC Int, 2003, 86(2): [28],,. [J]., 2005, 33( 9 ): Li JG, Zhao YF, Wu YN. Determination of Polycholorinated Biphenyls in Fish by Gas Chromatography-Ion Trap Tandem Mass Spectrometry [J]. J Chin Anal Chem, 2005, 33( 9): [29],,,. - [C]. 2007, Huang SH, Huang CJ, Chang YX, et al. Determination Polycyclic Aromatic Hydrocarbons by High Performance Liquid Chromatography with Fluorescence and Ultraviolet Detection [C]. Bbs of Pops(2007, symposium of the second proseminar on pops), [30] Michele Del Carlo, Marco Mascini. Enzyme immunoassay with amperometric flow-injection analysis using horseradish peroxidase as a label Application to the determination of polychlorinated biphenyls [J]. Anal Chim Acta, 1996, 336(1-3): [31],,,. [C]. 2010, Bao YG, Du LY, Pang YB, et al. A Novel Immunoassay for the Determination of Diethylstilbestrol Based on the Fluorescence Enhancement of Au Nanoparticles [C]. Bbs of Pops(2010, symposium of the fifth proseminar on pops), [32],,. A [J]., 2011, 27( 4): Du LY, Bao YH, Wang SH. Spectrofluorimetric Determination of Bisphenol A with Acridine Orange as Indicator [J]. J Anal Sci, 2011, 27( 4): [33],,,. [C]. 2010, WangSH,Sun MM, Zhang X, et al. Determination of Diethylstilbestrol by fluorescence immunoassay with streptavidin conjugated quantum dots [C]. Bbs of Pops(2010, symposium of the fifth proseminar on pops), [34],,,. [J]., 2012, 32( 5): Hou DB, Yue FH, Kang XS, et al. Terahertz Time-Domain Spectroscopy of Alpha Endosulfan Persistent Organic Pollutant [J]. Spectrosc Spectr Anal, 2012, 32( 5): [35],,,. DNA [J]., 2008, 37( 2): Cheng S, Xu YZ, Du W, et al. New Technology for DNA Analysis Based on Multiphoton Excited Fluorescence-capillary Electrophoresis [J]. Acta Photonica Sin, 2008, 37( 2): [36],,,. [C]. 2010, Liu J, Yin LF, Jang F, et al. Preliminary Study of Immobilized Enzyme Electrode by Electrospinning in Determination of Pollutants in Water [C]. Bbs of Pops(2010, symposium of the fifth proseminar on pops), 作者简介 ( 责任编辑 : 赵静 ) 胡海, 硕士研究生, 主要研究方向为药物分析 hh @sina.com 张红菱, 教授, 主要研究方向为环境污染物及其健康危害 zhlwjb@sina.com

DOI /j.issn Food Research And Development UPLC-MS/MS 5 0.

DOI /j.issn Food Research And Development UPLC-MS/MS 5 0. 118 217 5 38 1 DOI 1.3969/j.issn.5-6521.217.1.28 Food Research And Development 1 2 1 2 1 2 1 2 1 2 1 2 1. 731 2. 731 - UPLC-MS/MS 5. 1 mol/l ProElut PXC 5 % - Thermo Hypersil Gold mm 2.1 mm 1.9 μm ESI