號碼 (No.) : CE/2012/10606 日期 (Date) : 2012/01/09 頁數 (Page) : 1 of 10 以下測試樣品係由客戶送樣, 且由客戶聲稱並經客戶確認如下 (The following samples was/were submitted and identified by/on behalf of the client as): 樣品名稱 (Sample Description) 樣品型號 (Style/Item No.) 收件日期 (Sample Receiving Date) 測試期間 (Testing Period) : : : : PA HP250FX/HP200FX/HP1004FR/HP2004FR/HA348FR/HP2330/HP2458/HP230N/MG306/ NF306 全系列 2012/01/03 2012/01/03 TO 2012/01/09 ================================================================================================================ 測試結果 (Test Results) : 結論 (Conclusion) : 請見下一頁 (Please refer to next pages). 根據客戶所提供的樣品, 其鎘 鉛 汞 六價鉻 多溴聯苯及多溴聯苯醚的測試結果符合 RoHS 指令 2002/95/EC 的更新指令 2011/65/EU 之要求 (Based on the performed tests on submitted samples, the test results of Cadmium, Lead, Mercury, Hexavalent Chromium Cr(VI), PBBs and PBDEs comply with the limits as set by RoHS Directive 2011/65/EU Annex II; recasting 2002/95/EC.)
號碼 (No.) : CE/2012/10606 日期 (Date) : 2012/01/09 頁數 (Page) : 2 of 10 測試結果 (Test Results) 測試部位 (PART NAME)No.1 : 黑色塑膠 (BLACK PLASTIC) 測試項目 (Test Items) 鎘 / Cadmium (Cd) 鉛 / Lead (Pb) 汞 / Mercury (Hg) 六價鉻 / Hexavalent Chromium Cr(VI) 全氟辛烷磺酸 / Perfluorooctane sulfonates (PFOS-Acid, Metal Salt, Amide) 全氟辛酸 ( 銨 ) / PFOA (CAS No.: 335-67-1) 單位 (Unit) 測試方法 (Method) 參考 IEC 62321: 2008 方法, 以感應耦合電漿原子發射光譜儀檢測. / With reference to IEC 62321: 2008 and performed by ICP-AES. 參考 IEC 62321: 2008 方法, 以感應耦合電漿原子發射光譜儀檢測. / With reference to IEC 62321: 2008 and performed by ICP-AES. 參考 IEC 62321: 2008 方法, 以感應耦合電漿原子發射光譜儀檢測. / With reference to IEC 62321: 2008 and performed by ICP-AES. 參考 IEC 62321: 2008 方法, 以 UV-VIS 檢測. / With reference to IEC 62321: 2008 and performed by UV-VIS. 參考 US EPA 3540C: 1996 方法, 以液相層析 / 質譜儀檢測全氟辛烷磺酸含量. / With reference to US EPA 3540C: 1996 method for PFOS Content. Analysis was performed by LC/MS. 參考 US EPA 3540C: 1996 方法, 以液相層析 / 質譜儀檢測全氟辛酸 ( 銨 ) 含量. / With reference to US EPA 3540C: 1996 method for PFOA Content. Analysis was performed by LC/MS. 方法偵測極限值 (MDL) 結果 (Result) 法規限值 (Limit) No.1 2 4 100 2 7 1000 2 n.d. 1000 2 n.d. 1000 10 n.d. - 10 n.d. -
號碼 (No.) : CE/2012/10606 日期 (Date) : 2012/01/09 頁數 (Page) : 3 of 10 測試項目 (Test Items) 鄰苯二甲酸甲苯基丁酯 / BBP (Benzyl butyl phthalate) (CAS No.: 85-68-7) 鄰苯二甲酸二 (2- 乙基己基 ) 酯 / DEHP (Di- (2-ethylhexyl) phthalate) (CAS No.: 117-81-7) 鄰苯二甲酸二異癸酯 / DIDP (Diisodecyl phthalate) (CAS No.: 26761-40-0) 鄰苯二甲酸二異壬酯 / DINP (Diisononyl phthalate) (CAS No.: 28553-12-0) 鄰苯二甲酸二正辛酯 / DNOP (Di-noctyl phthalate) (CAS No.: 117-84-0) 鄰苯二甲酸二丁酯 / DBP (Dibutyl phthalate) (CAS No.: 84-74-2) 六溴環十二烷 / Hexabromocyclododecane (HBCDD) (CAS No.: 25637-99-4) 單位 (Unit) 測試方法 (Method) 參考 US EPA 3540C 方法, 以氣相層析 / 質譜儀檢測. / With reference to US EPA 3540C method. Analysis was performed by GC/MS. 方法偵測極限值 (MDL) 結果 (Result) No.1 法規限值 (Limit) 0.003 n.d. - 0.003 n.d. - 0.01 n.d. - 0.01 n.d. - 0.003 n.d. - 0.003 n.d. -
號碼 (No.) : CE/2012/10606 日期 (Date) : 2012/01/09 頁數 (Page) : 4 of 10 測試項目 (Test Items) 多溴聯苯總和 / Sum of PBBs 一溴聯苯 / Monobromobiphenyl 二溴聯苯 / Dibromobiphenyl 三溴聯苯 / Tribromobiphenyl 四溴聯苯 / Tetrabromobiphenyl 五溴聯苯 / Pentabromobiphenyl 六溴聯苯 / Hexabromobiphenyl 七溴聯苯 / Heptabromobiphenyl 八溴聯苯 / Octabromobiphenyl 九溴聯苯 / Nonabromobiphenyl 十溴聯苯 / Decabromobiphenyl 多溴聯苯醚總和 / Sum of PBDEs 一溴聯苯醚 / Monobromodiphenyl ether 二溴聯苯醚 / Dibromodiphenyl ether 三溴聯苯醚 / Tribromodiphenyl ether 四溴聯苯醚 / Tetrabromodiphenyl ether 五溴聯苯醚 / Pentabromodiphenyl ether 六溴聯苯醚 / Hexabromodiphenyl ether 七溴聯苯醚 / Heptabromodiphenyl ether 八溴聯苯醚 / Octabromodiphenyl ether 九溴聯苯醚 / Nonabromodiphenyl ether 十溴聯苯醚 / Decabromodiphenyl ether 單位 (Unit) 測試方法 (Method) 參考 IEC 62321: 2008 方法, 以氣相層析儀 / 質譜儀檢測. / With reference to IEC 62321: 2008 and performed by GC/MS. 方法偵測極限值 (MDL) 結果 (Result) 法規限值 (Limit) No.1 - n.d. 1000 - n.d. 1000 備註 (Note): 1. = ppm;0.1wt = 1000ppm 2. n.d. = Not Detected ( 未檢出 ) 3. MDL = Method Detection Limit ( 方法偵測極限值 ) 4. "-" = Not Regulated ( 無規格值 )
號碼 (No.) : CE/2012/10606 日期 (Date) : 2012/01/09 頁數 (Page) : 5 of 10 PFOS 參考資訊 (Reference Information) : 指令 2006/122/EC (Directive 2006/122/EC) (1) 該物質不可置於市場上或使用於特殊物質或配置成分重量濃度等於或大於 0.005. (May not be placed on the market or used as a substance or constituent of preparations in a concentration equal to or higher than 0.005 by mass.) (2) 該物質不可置於市場上的半成品或商品或其物件 ; 假若零件上明顯地具有 PFOS 並參照結構上及微細構造上計算 PFOS 重量濃度等於或大於 0.1, 而紡織品或其他覆蓋物質, 如果 PFOS 在覆蓋物質中含量等於或大於 1µg/m². (May not be placed on the market in semi-finished products or articles, or parts thereof, if the concentration of PFOS is equal to or higher than 0.1 by mass calculated with reference to the mass of structurally or microstructurally distinct parts that contain PFOS or, for textiles or other coated materials, if the amount of PFOS is equal to or higher than 1µg/m² of the coated material.)
號碼 (No.) : CE/2012/10606 日期 (Date) : 2012/01/09 頁數 (Page) : 6 of 10 1) 根據以下的流程圖之條件, 樣品已完全溶解 ( 六價鉻測試方法除外 ) / These samples were dissolved totally by pre-conditioning method according to below flow chart.(cr 6+ test method excluded) 2) 測試人員 : 楊登偉 / Name of the person who made measurement: Climbgreat Yang 3) 測試負責人 : 張啟興 / Name of the person in charge of measurement: Troy Chang 剪裁 製備樣品 / Cutting Preparation 測試樣品重量 / Sample Measurement 鉛 Pb 鎘 Cd 依據不同樣品的材質而以適當的酸進行消化 ( 如下表所示 ) / Acid digestion by suitable acid depended on different sample material (as below table) 汞 Hg 硝酸 / 鹽酸 / 氫氟酸的微波消化 / Microwave digestion with HNO 3/HCl/HF 六價鉻 Cr 6+ 添加適量消化液 / Add appropriate amount of digestion reagent 溶液 / Solution 過濾 / Filtration 殘渣 / Residue 加熱至適當溫度進行消化萃取 / Heat to appropriate temperature to extract 感應耦合電漿原子發射光譜儀 / ICP-AES 1) 鹼熔融法 / Alkali Fusion 2) 鹽酸溶解 / HCl to dissolve 冷卻後過濾樣品 / Cool, filter digestate through filter 樣品材質 / Sample Material 消化酸液種類 / Digestion Acid 鋼, 銅, 鋁, 焊錫 / Steel, copper, aluminum, solder 王水, 硝酸, 鹽酸, 氫氟酸, 雙氧水 / Aqua regia, HNO 3, HCl, HF, H 2O 2 玻璃 / Glass 硝酸, 氫氟酸 / HNO 3/HF 金, 鉑, 鈀, 陶瓷 / 王水 / Aqua regia Gold, platinum, palladium, ceramic 銀 / Silver 硝酸 / HNO 3 塑膠 / Plastic 硫酸, 雙氧水, 硝酸, 鹽酸 / H 2SO 4, H 2O 2, HNO 3, HCl 其他 / Others 加入任何酸至完全溶解 / Any acid to total digestion 加入發色劑顯色 / Add diphenyl-carbazide for color development 以紫外光 - 可見光光譜儀, 量測樣品溶液在 540 nm 的吸收度 / measure the absorbance at 540 nm by UV-VIS
號碼 (No.) : CE/2012/10606 日期 (Date) : 2012/01/09 頁數 (Page) : 7 of 10 索式萃取分析流程圖 / Analytical flow chart of Soxhlet extraction (LC/MS) procedure 測試人員 : 翁賜彬 / Name of the person who made measurement: Roman Wong 測試負責人 : 張啟興 / Name of the person in charge of measurement: Troy Chang 測試項目 : 全氟辛烷磺酸 / 全氟辛酸 ( 銨 ) 苯並三唑類化合物 / Test Items: PFOS/PFOA Benzotriazole 樣品前處理 / 分樣 / Sample pretreatment/separation 樣品萃取採用索式萃取法 / Sample extraction by soxhlet method 萃取液濃縮 / 稀釋 / Concentrate/Dilute Extracted solution 以液相層析質譜儀分析萃取液 / Analysis was performed by LC/MS 數據 / Data
號碼 (No.) : CE/2012/10606 日期 (Date) : 2012/01/09 頁數 (Page) : 8 of 10 索式萃取分析流程圖 / Analytical flow chart of Soxhlet extraction (GC/MS) procedure 測試人員 : 翁賜彬 / Name of the person who made measurement: Roman Wong 測試負責人 : 張啟興 / Name of the person in charge of measurement: Troy Chang 測試項目 : 可塑劑 苯並三唑類化合物 六溴環十二烷 壬酚 單甲基二溴二苯基甲烷 有機磷化合物 / Test Items: Phthalate Benzotriazole HBCDD NP DBBT Organic phosphorus compounds 樣品前處理 / 分樣 / Sample pretreatment/separation 樣品萃取採用索式萃取法 / Sample extraction by soxhlet method 萃取液濃縮 / 稀釋 / Concentrate/Dilute Extracted solution 氣相層析質譜儀分析 / Analysis was performed by GC/MS 數據 / Data
號碼 (No.) : CE/2012/10606 日期 (Date) : 2012/01/09 頁數 (Page) : 9 of 10 分析流程圖 / Analytical flow chart 測試人員 : 翁賜彬 / Name of the person who made measurement: Roman Wong 測試負責人 : 張啟興 / Name of the person in charge of measurement: Troy Chang 測試項目(Test Items): 多溴聯苯 / 多溴聯苯醚 四溴雙酚 -A- 雙 / PBB/PBDE, TBBP-A-bis 初次測試程序 / First testing process 選擇性篩檢程序 / Optional screen process 確認程序 / Confirmation process 樣品 / Sample 樣品前處理 / Sample pretreatment 初篩分析 / Screen analysis 樣品萃取法 / Sample extraction method 萃取液濃縮 / 稀釋 / Concentrate/Dilute Extracted solution 萃取液過濾 / Filter 氣相層析質譜儀分析 / Analysis by GC/MS Issue Report / 撰打報告
號碼 (No.) : CE/2012/10606 日期 (Date) : 2012/01/09 頁數 (Page) : 10 of 10 * 照片中如有箭頭標示, 則表示為實際檢測之樣品 / 部位. * (The tested sample / part is marked by an arrow if it's shown on the photo.) ** 報告結尾 (End of Report) **