CE_2018_10470.xlsm

Transcription

1 頁數 (Page) : 1 of 10 以下測試樣品係由申請廠商所提供及確認 (The following sample(s) was/were submitted and identified by/on behalf of the applicant as): 送樣廠商 (Sample Submitted By) 樣品名稱 (Sample Description) 收件日期 (Sample Receiving Date) 測試期間 (Testing Period) : : : : () LCJ FREMIVM LABELS ( 三用電腦標籤 ) 2018/01/ /01/03 TO 2018/01/10 ============================================================================================================= 測試需求 (Test Requested) : (1) 依據客戶指定, 檢測鎘 鉛 汞 六價鉻 多溴聯苯 多溴聯苯醚, DBP, BBP, DEHP, DIBP. (As specified by client, to test Cadmium, Lead, Mercury, Cr(VI), PBBs, PBDEs, DBP, BBP, DEHP, DIBP contents in the submitted sample(s).) (2) 依據客戶指定, 進行全氟辛酸 全氟辛烷磺酸 鹵素 - 氟 氯 溴 碘測試. (As specified by client, to test PFOA, PFOS, Halogen-Fluorine, Chlorine, Bromine, Iodine contents in the submitted sample(s).) 測試結果 (Test Results) : 請參閱下一頁 (Please refer to following pages).

2 頁數 (Page) : 2 of 10 測試結果 (Test Results) 測試部位 (PART NAME)No.1 : 整體混測 (MIXED ALL PARTS) 鎘 / Cadmium (Cd) 鉛 / Lead (Pb) 汞 / Mercury (Hg) 測試項目 (Test Items) 六價鉻 / Hexavalent Chromium Cr(VI) ( ) 單位 (Unit) 測試方法 (Method) 參考 IEC (2013), 以感應耦合電漿原子發射光譜儀檢測. / With reference to IEC (2013) and performed by ICP-AES. 參考 IEC (2013), 以感應耦合電漿原子發射光譜儀檢測. / With reference to IEC (2013) and performed by ICP-AES. 參考 IEC (2017), 以 UV-VIS 檢測 ; 參考 IEC (2013), 以 ICP-AES 檢測. / With reference to IEC (2017) and performed by UV-VIS.;With reference to IEC (2013) and performed by ICP-AES. 方法偵測極限值 (MDL) 結果 (Result) No.1 2 n.d. 2 n.d. 2 n.d. 8 n.d. 多溴聯苯總和 / Sum of PBBs 一溴聯苯 / Monobromobiphenyl 二溴聯苯 / Dibromobiphenyl 三溴聯苯 / Tribromobiphenyl 四溴聯苯 / Tetrabromobiphenyl 五溴聯苯 / Pentabromobiphenyl 六溴聯苯 / Hexabromobiphenyl 七溴聯苯 / Heptabromobiphenyl 八溴聯苯 / Octabromobiphenyl 九溴聯苯 / Nonabromobiphenyl 十溴聯苯 / Decabromobiphenyl 參考 IEC (2015), 以氣相層析 / 質譜儀檢測. / With reference to IEC (2015) and performed by GC/MS. - n.d.

3 頁數 (Page) : 3 of 10 測試項目 (Test Items) 多溴聯苯醚總和 / Sum of PBDEs 一溴聯苯醚 / Monobromodiphenyl ether 二溴聯苯醚 / Dibromodiphenyl ether 三溴聯苯醚 / Tribromodiphenyl ether 四溴聯苯醚 / Tetrabromodiphenyl ether 五溴聯苯醚 / Pentabromodiphenyl ether 六溴聯苯醚 / Hexabromodiphenyl ether 七溴聯苯醚 / Heptabromodiphenyl ether 八溴聯苯醚 / Octabromodiphenyl ether 九溴聯苯醚 / Nonabromodiphenyl ether 十溴聯苯醚 / Decabromodiphenyl ether 鄰苯二甲酸丁苯甲酯 / BBP (Butyl Benzyl phthalate) (CAS No.: ) 鄰苯二甲酸二丁酯 / DBP (Dibutyl phthalate) (CAS No.: ) 鄰苯二甲酸二異丁酯 / DIBP (Di-isobutyl phthalate) (CAS No.: ) 鄰苯二甲酸二 (2- 乙基己基 ) 酯 / DEHP (Di- (2-ethylhexyl) phthalate) (CAS No.: ) 鹵素 / Halogen 鹵素 ( 氟 ) / Halogen-Fluorine (F) (CAS No.: ) 鹵素 ( 氯 ) / Halogen-Chlorine (Cl) (CAS No.: ) 鹵素 ( 溴 ) / Halogen-Bromine (Br) (CAS No.: ) 鹵素 ( 碘 ) / Halogen-Iodine (I) (CAS No.: ) 單位 (Unit) 測試方法 (Method) 參考 IEC (2015), 以氣相層析 / 質譜儀檢測. / With reference to IEC (2015) and performed by GC/MS. 參考 IEC (2017), 以氣相層析儀 / 質譜儀檢測. / With reference to IEC (2017). Analysis was performed by GC/MS. 參考 BS EN (2016), 以離子層析儀分析. / With reference to BS EN (2016). Analysis was performed by IC. 方法偵測極限值 (MDL) 結果 (Result) No.1 - n.d

4 頁數 (Page) : 4 of 10 測試項目 (Test Items) 全氟辛烷磺酸 / Perfluorooctane sulfonates (PFOS-Acid, Metal Salt, Amide) 全氟辛酸 / PFOA (CAS No.: ) 單位 (Unit) 測試方法 (Method) 參考 US EPA 3550C (2007), 以液相層析 / 質譜儀檢測. / With reference to US EPA 3550C (2007). Analysis was performed by LC/MS. 方法偵測極限值 (MDL) 結果 (Result) No.1 10 n.d. 10 n.d. 備註 (Note): 1. = ppm;0.1wt% = 1000ppm 2. n.d. = Not Detected ( 未檢出 ) 3. MDL = Method Detection Limit ( 方法偵測極限值 ) 4. "-" = Not Regulated ( 無規格值 ) 5. ( ): 若鉻含量小於六價鉻之方法偵測極限值, 則六價鉻為 n.d., 不須再測試六價鉻 The result of Cr(VI) is "n.d." as the result of Chromium (Cr) is less than the MDL of Cr(VI), and confirmation test of Cr(VI) is not required. 若鉻含量未小於六價鉻之方法偵測極限值, 需進行六價鉻測試 If the Chromium (Cr) content is not less than the MDL of Cr(VI), confirmation test of Cr(VI) is required. 6. 樣品的測試是基於申請人要求混合測試, 報告中的混合測試結果不代表其中個別單一材質的含量. (The samples was/were analyzed on behalf of the applicant as mixing sample in one testing. The above results was/were only given as the informality value.) PFOS 參考資訊 (Reference Information) : 持久性有機污染物 POPs - (EU) 757/2010 PFOS 濃度在物質或製備中不得超過 0.001%(10ppm), 在半成品 成品或零部件中不得超過 0.1%(1000ppm), 在紡織品或塗層材料中不得超過 1µg/m² (Outlawing PFOS as substances or preparations in concentrations above 0.001% (10ppm), in semi-finished products or articles or parts at a level above 0.1%(1000ppm), in textiles or other coated materials above 1µg/m².)

5 頁數 (Page) : 5 of 10 #FLOW 重金屬流程圖 / Analytical flow chart of Heavy Metal 根據以下的流程圖之條件, 樣品已完全溶解 ( 六價鉻測試方法除外 ) These samples were dissolved totally by pre-conditioning method according to below flow chart.(cr 6+ test method excluded) 測試人員 : 王志瑋 / Technician : JR Wang 測試負責人 : 張啟興 / Supervisor: Troy Chang 剪裁 製備樣品 / Cutting Preparation 測試樣品重量 / Sample Measurement 用微波消解儀 / 電熱板進行酸消解 Acid digestion with microwave / hotplate 溶液 / Solution 過濾 / Filtration 鉛 Pb/ 鎘 Cd/ 汞 Hg/ 鉻 Cr 殘渣 / Residue 1) 鹼熔融法 / Alkali fusion 2) 鹽酸溶解 / HCl to dissolve 感應耦合電漿原子發射光譜儀 / ICP-AES ABS / PC / PVC 超音波溶解 / Dissolving by ultrasonication 在 60 條件下超音波消化 / Digesting at 60 by ultrasonication 非金屬 / Non-metal 其他材質 /Others 在 150~160 下消化 / Digesting at 150~160 取水層 / Separating to get aqueous phase 調整 ph / ph adjustment 加入發色劑顯色 / Add diphenylcarbazide for color development 以 UV-VIS, 量測樣品溶液在 540 nm 的吸收度 / Measure the absorbance at 540 nm by UV-VIS 六價鉻 Cr(VI) 金屬 / Metal 沸水萃取 / Boiling water extraction 冷卻後過濾樣品 / Cool, filter digestate through filter 加入發色劑顯色 / Add diphenylcarbazide for color development 以 UV-VIS, 量測樣品溶液在 540 nm 的吸收度 / Measure the absorbance at 540 nm by UV-VIS

6 頁數 (Page) : 6 of 10 多溴聯苯 / 多溴聯苯醚分析流程圖 / Analytical flow chart - PBB/PBDE 測試人員 : 凃雅苓 / Technician: Yaling Tu 測試負責人 : 張啟興 / Supervisor: Troy Chang 初次測試程序 / First testing process 選擇性篩檢程序 / Optional screen process 確認程序 / Confirmation process Sample / 樣品 Sample pretreatment / 樣品前處理 Screen analysis / 初篩分析 Sample extraction 樣品萃取 / Soxhlet method 索式萃取法 Concentrate/Dilute Extracted solution 萃取液濃縮 / 稀釋 Filter / 萃取液過濾 GC/MS / 氣相層析質譜儀

7 頁數 (Page) : 7 of 10 可塑劑分析流程圖 / Analytical flow chart - Phthalate 測試人員 : 徐毓明 / Technician: Andy Hsu 測試負責人 : 張啟興 / Supervisor : Troy Chang 測試方法/Test method: IEC 樣品前處理 / 分樣 / Sample pretreatment/separation 樣品以 THF 四氫呋喃溶解萃取 / Sample dissolved/extracted by THF 萃取液稀釋 / Dilute Extracted solution 氣相層析質譜儀分析 / Analysis was performed by GC/MS

8 頁數 (Page) : 8 of 10 鹵素分析流程圖 / Analytical flow chart - Halogen 測試人員 : 陳恩臻 / Technician: Rita Chen 測試負責人 : 張啟興 / Supervisor: Troy Chang 樣品前處理 / 分樣 / Sample pretreatment/separation 秤重及將樣品放入樣品槽中 / Weighting and putting sample in cell 燃燒彈 / 吸收 Oxygen Bomb Combustion / Absorption 稀釋至固定體積 / Dilution to fixed volume 離子層析儀分析 / Analysis was performed by IC

9 頁數 (Page) : 9 of 10 全氟辛酸 / 全氟辛烷磺酸分析流程圖 / Analytical flow chart - PFOA/PFOS 測試人員 : 凃雅苓 / Technician: Yaling Tu 測試負責人 : 張啟興 / Supervisor: Troy Chang 樣品前處理 / Sample pretreatment 超音波萃取法萃取 / Sample extraction by Ultrasonic extraction ( 參考方法 Reference method: US EPA 3550C) 萃取液稀釋 / 濃縮 / Concentrate/Dilute Extracted solution 以液相層析質譜儀分析萃取液 / Analysis was performed by LC/MS 數據 / Data

10 頁數 (Page) : 10 of 10 #PIC * 照片中如有箭頭標示, 則表示為實際檢測之樣品 / 部位. * (The tested sample / part is marked by an arrow if it's shown on the photo.) ** 報告結尾 (End of Report) **