CE_2017_94775.xlsm

Transcription

1 頁數 (Page): 1 of 13 以下測試樣品係由申請廠商所提供及確認 (The following sample(s) was/were submitted and identified by/on behalf of the applicant as): 送樣廠商 (Sample Submitted By) 樣品名稱 (Sample Description) 樣品型號 (Style/Item No.) 收件日期 (Sample Receiving Date) 測試期間 (Testing Period) : : : : : () LEAD FRAME C7025+Ag 2017/09/ /09/26 TO 2017/10/06 ============================================================================================================== 測試結果 (Test Results) : 請參閱下一頁 (Please refer to following pages).

2 頁數 (Page): 2 of 13 測試結果 (Test Results) 測試部位 (PART NAME)No.1 : 銅色 / 銀色金屬片 ( 含鍍層 ) (COPPER/SILVER COLORED METAL SHEET (INCLUDING THE PLATING LAYER)) 鎘 / Cadmium (Cd) 測試項目 (Test Items) 單位 (Unit) 測試方法 (Method) 參考 IEC (2013), 以感應耦合電漿原子發射光譜儀檢測. / With reference to IEC (2013) and performed by ICP-AES. 方法偵測極限值 (MDL) 結果 (Result) No.1 2 n.d. 鉛 / Lead (Pb) 參考 IEC (2013), 以感應耦合電漿原子發射光譜儀檢測. / With reference to IEC (2013) and performed by ICP-AES. 2 n.d. 汞 / Mercury (Hg) 參考 IEC (2013), 以感應耦合電漿原子發射光譜儀檢測. / With reference to IEC (2013) and performed by ICP-AES. 2 n.d. 六價鉻 / Hexavalent Chromium Cr(VI)(#2) µg/cm² 參考 IEC (2015), 以 UV-VIS 檢測. / With reference to IEC (2015) and performed by UV-VIS n.d. 鹵素 / Halogen 鹵素 ( 氟 ) / Halogen-Fluorine (F) (CAS No.: ) 鹵素 ( 氯 ) / Halogen-Chlorine (Cl) (CAS No.: ) 鹵素 ( 溴 ) / Halogen-Bromine (Br) (CAS No.: ) 參考 BS EN (2016), 以離子層析儀分析. / With reference to BS EN (2016). Analysis was performed by IC. 鹵素 ( 碘 ) / Halogen-Iodine (I) (CAS No.: )

3 頁數 (Page): 3 of 13 測試項目 (Test Items) 多溴聯苯總和 / Sum of PBBs 一溴聯苯 / Monobromobiphenyl 二溴聯苯 / Dibromobiphenyl 三溴聯苯 / Tribromobiphenyl 四溴聯苯 / Tetrabromobiphenyl 五溴聯苯 / Pentabromobiphenyl 六溴聯苯 / Hexabromobiphenyl 七溴聯苯 / Heptabromobiphenyl 八溴聯苯 / Octabromobiphenyl 九溴聯苯 / Nonabromobiphenyl 十溴聯苯 / Decabromobiphenyl 多溴聯苯醚總和 / Sum of PBDEs 一溴聯苯醚 / Monobromodiphenyl ether 二溴聯苯醚 / Dibromodiphenyl ether 三溴聯苯醚 / Tribromodiphenyl ether 四溴聯苯醚 / Tetrabromodiphenyl ether 五溴聯苯醚 / Pentabromodiphenyl ether 六溴聯苯醚 / Hexabromodiphenyl ether 七溴聯苯醚 / Heptabromodiphenyl ether 八溴聯苯醚 / Octabromodiphenyl ether 九溴聯苯醚 / Nonabromodiphenyl ether 十溴聯苯醚 / Decabromodiphenyl ether 六溴環十二烷及所有主要被辨別出的異構物 / Hexabromocyclododecane (HBCDD) and all major diastereoisomers identified (α- HBCDD, β- HBCDD, γ- HBCDD) (CAS No.: and ( , , )) 單位 (Unit) 測試方法 (Method) 參考 IEC (2015), 以氣相層析 / 質譜儀檢測. / With reference to IEC (2015) and performed by GC/MS. 參考 IEC (2008), 以氣相層析 / 質譜儀檢測. / With reference to IEC (2008). Analysis was performed by GC/MS. 方法偵測極限值 (MDL) 結果 (Result) No.1 - n.d. - n.d.

4 頁數 (Page): 4 of 13 測試項目 (Test Items) 鄰苯二甲酸丁苯甲酯 / BBP (Butyl Benzyl phthalate) (CAS No.: ) 單位 (Unit) 測試方法 (Method) 方法偵測極限值 (MDL) 結果 (Result) No.1 鄰苯二甲酸二丁酯 / DBP (Dibutyl phthalate) (CAS No.: ) 鄰苯二甲酸二 (2- 乙基己基 ) 酯 / DEHP (Di- (2-ethylhexyl) phthalate) (CAS No.: ) 鄰苯二甲酸二異丁酯 / DIBP (Di-isobutyl phthalate) (CAS No.: ) 鄰苯二甲酸二異癸酯 / DIDP (Diisodecyl phthalate) (CAS No.: ; ) 鄰苯二甲酸二異壬酯 / DINP (Diisononyl phthalate) (CAS No.: ; ) 參考 IEC (2017), 以氣相層析儀 / 質譜儀檢測. / With reference to IEC (2017). Analysis was performed by GC/MS. 鄰苯二甲酸二正辛酯 / DNOP (Di-noctyl phthalate) (CAS No.: ) 鄰苯二甲酸二正己酯 / DNHP (Di-nhexyl phthalate) (CAS No.: ) 鄰苯二甲酸二 (2- 甲氧基乙基 ) 酯 / DMEP (Bis (2-methoxyethyl) phthalate) (CAS No.: ) 鄰苯二甲酸二戊酯 / Di-n-pentyl phthalate (CAS No.: ) 全氟辛烷磺酸 / Perfluorooctane sulfonates (PFOS-Acid, Metal Salt, Amide) 全氟辛酸 / PFOA (CAS No.: ) 參考 US EPA 3550C (2007), 以液相層析 / 質譜儀檢測. / With reference to US EPA 3550C (2007). Analysis was performed by LC/MS. 10 n.d. 10 n.d.

5 頁數 (Page): 5 of 13 銻 / Antimony (Sb) 測試項目 (Test Items) 鈹 / Beryllium (Be) 單位 (Unit) 測試方法 (Method) 參考 US EPA 3050B (1996), 以感應耦合電漿原子發射光譜儀檢測. / With reference to US EPA 3050B (1996). Analysis was performed by ICP-AES. 方法偵測極限值 (MDL) 結果 (Result) No.1 2 n.d. 2 n.d. 備註 (Note): 1. = ppm;0.1wt% = 1000ppm 2. n.d. = Not Detected ( 未檢出 ) 3. MDL = Method Detection Limit ( 方法偵測極限值 ) 4. "-" = Not Regulated ( 無規格值 ) 5. (#2) = a. 當六價鉻結果大於 0.13 µg/cm², 表示樣品表層含有六價鉻. / The sample is positive for Cr(VI) if the Cr(VI) concentration is greater than 0.13 µg/cm². The sample coating is considered to contain Cr(VI). b. 當六價鉻結果為 n.d. ( 濃度小於 0.10 µg/cm²), 表示表層不含六價鉻. / The sample is negative for Cr(VI) if Cr(VI) is n.d. (concentration less than 0.10 µg/cm²). The coating is considered a non-cr(vi) based coating c. 當六價鉻結果介於 0.10 及 0.13 µg/cm² 時, 無法確定塗層是否含有六價鉻. / The result between 0.10 µg/cm² and 0.13 µg/cm² is considered to be inconclusive - unavoidable coating variations may influence the determination. 6. 樣品的測試是基於申請人要求混合測試, 報告中的混合測試結果不代表其中個別單一材質的含量. (The samples was/were analyzed on behalf of the applicant as mixing sample in one testing. The above results was/were only given as the informality value.) PFOS 參考資訊 (Reference Information) : 持久性有機污染物 POPs - (EU) 757/2010 PFOS 濃度在物質或製備中不得超過 0.001%(10ppm), 在半成品 成品或零部件中不得超過 0.1%(1000ppm), 在紡織品或塗層材料中不得超過 1µg/m² (Outlawing PFOS as substances or preparations in concentrations above 0.001% (10ppm), in semi-finished products or articles or parts at a level above 0.1%(1000ppm), in textiles or other coated materials above 1µg/m².)

6 頁數 (Page): 6 of 13 #flow 重金屬流程圖 / Analytical flow chart of Heavy Metal 根據以下的流程圖之條件, 樣品已完全溶解 ( 六價鉻測試方法除外 ) These samples were dissolved totally by pre-conditioning method according to below flow chart.(cr 6+ test method excluded) 測試人員 : 王志瑋 / Technician : JR Wang 測試負責人 : 張啟興 / Supervisor: Troy Chang 剪裁 製備樣品 / Cutting Preparation 測試樣品重量 / Sample Measurement 鉛 Pb/ 鎘 Cd/ 汞 Hg/ 鉻 Cr 六價鉻 Cr(VI) 用微波消解儀 / 電熱板進行酸消解 Acid digestion with microwave / hotplate 溶液 / Solution 過濾 / Filtration 殘渣 / Residue 1) 鹼熔融法 / Alkali fusion 2) 鹽酸溶解 / HCl to dissolve 感應耦合電漿原子發射光譜儀 / ICP-AES ABS / PC / PVC 超音波溶解 / Dissolving by ultrasonication 在 60 條件下超音波消化 / Digesting at 60 by ultrasonication 非金屬 / Non-metal 其他材質 /Others 在 150~160 下消化 / Digesting at 150~160 取水層 / Separating to get aqueous phase 調整 ph / ph adjustment 金屬 / Metal 沸水萃取 / Boiling water extraction 冷卻後過濾樣品 / Cool, filter digestate through filter 加入發色劑顯色 / Add diphenylcarbazide for color development 加入發色劑顯色 / Add diphenylcarbazide for color development 以 UV-VIS, 量測樣品溶液在 540 nm 的吸收度 / Measure the absorbance at 540 nm by UV-VIS 以 UV-VIS, 量測樣品溶液在 540 nm 的吸收度 / Measure the absorbance at 540 nm by UV-VIS

7 頁數 (Page): 7 of 13 根據以下的流程圖之條件, 樣品已完全溶解 / These samples were dissolved totally by pre-conditioning method according to below flow chart. 測試人員 : 王志瑋 / Technician: JR Wang 測試負責人 : 張啟興 / Supervisor: Troy Chang 元素以 ICP-AES 分析的消化流程圖 (Flow Chart of digestion for the elements analysis performed by ICP-AES) 剪裁 製備樣品 / Cutting Preparation 測試樣品重量 / Sample Measurement 依據不同樣品的材質而以適當的酸進行消化 ( 如下表所示 ) / Acid digestion by suitable acid depended on different sample material (as below table) 溶液 / Solution 過濾 / Filtration 殘渣 / Residue 感應耦合電漿原子發射光譜儀 / ICP-AES 1) 鹼熔融法 / Alkali Fusion 2) 鹽酸溶解 / HCl to dissolve 鋼, 銅, 鋁, 焊錫 / Steel, copper, aluminum, solder 王水, 硝酸, 鹽酸, 氫氟酸, 雙氧水 / Aqua regia, HNO3, HCl, HF, H2O2 玻璃 / Glass 硝酸, 氫氟酸 / HNO3/HF 金, 鉑, 鈀, 陶瓷 / Gold, platinum, palladium, ceramic 王水 / Aqua regia 銀 / Silver 硝酸 / HNO3 塑膠 / Plastic 硫酸, 雙氧水, 硝酸, 鹽酸 / H2SO4, H2O2, HNO3, HCl 其他 / Others 加入適當的試劑至完全溶解 / Added appropriate reagent to total digestion

8 頁數 (Page): 8 of 13 多溴聯苯 / 多溴聯苯醚分析流程圖 / Analytical flow chart - PBB/PBDE 測試人員 : 凃雅苓 / Technician: Yaling Tu 測試負責人 : 張啟興 / Supervisor: Troy Chang 初次測試程序 / First testing process 選擇性篩檢程序 / Optional screen process 確認程序 / Confirmation process Sample / 樣品 Sample pretreatment / 樣品前處理 Screen analysis / 初篩分析 Sample extraction 樣品萃取 / Soxhlet method 索式萃取法 Concentrate/Dilute Extracted solution 萃取液濃縮 / 稀釋 Filter / 萃取液過濾 GC/MS / 氣相層析質譜儀

9 頁數 (Page): 9 of 13 可塑劑分析流程圖 / Analytical flow chart - Phthalate 測試人員 : 徐毓明 / Technician: Andy Hsu 測試負責人 : 張啟興 / Supervisor : Troy Chang 測試方法 /Test method: IEC 樣品前處理 / 分樣 / Sample pretreatment/separation 樣品以 THF 四氫呋喃溶解萃取 / Sample dissolved/extracted by THF 萃取液稀釋 / Dilute Extracted solution 氣相層析質譜儀分析 / Analysis was performed by GC/MS

10 頁數 (Page): 10 of 13 六溴環十二烷分析流程圖 / Analytical flow chart - HBCDD 測試人員 : 凃雅苓 / Technician: Yaling Tu 測試負責人 : 張啟興 / Supervisor: Troy Chang 樣品前處理 / Sample pretreatment 樣品萃取 Sample extraction / 超音波萃取法 Ultrasonic method 萃取液濃縮 / 稀釋 / Concentrate/Dilute Extracted solution 萃取液過濾 / Filter 以氣相層析 / 質譜儀分析 / Analysis was performed by GC/MS 數據 / Data

11 頁數 (Page): 11 of 13 鹵素分析流程圖 / Analytical flow chart - Halogen 測試人員 : 陳恩臻 / Technician: Rita Chen 測試負責人 : 張啟興 / Supervisor: Troy Chang 樣品前處理 / 分樣 / Sample pretreatment/separation 秤重及將樣品放入樣品槽中 / Weighting and putting sample in cell 燃燒彈 / 吸收 Oxygen Bomb Combustion / Absorption 稀釋至固定體積 / Dilution to fixed volume 離子層析儀分析 / Analysis was performed by IC

12 頁數 (Page): 12 of 13 全氟辛酸 / 全氟辛烷磺酸分析流程圖 / Analytical flow chart - PFOA/PFOS 測試人員 : 凃雅苓 / Technician: Yaling Tu 測試負責人 : 張啟興 / Supervisor: Troy Chang 樣品前處理 / Sample pretreatment 超音波萃取法萃取 / Sample extraction by Ultrasonic extraction ( 參考方法 Reference method: US EPA 3550C) 萃取液稀釋 / 濃縮 / Concentrate/Dilute Extracted solution 以液相層析質譜儀分析萃取液 / Analysis was performed by LC/MS 數據 / Data

13 頁數 (Page): 13 of 13 * 照片中如有箭頭標示, 則表示為實際檢測之樣品 / 部位. * (The tested sample / part is marked by an arrow if it's shown on the photo.) ** 報告結尾 (End of Report) **