Microsoft Word 孙青青二校

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1 8 4 Vol. 8 No Journal of Food Safety and Quality Apr., 2017 孙青青 1, 徐燕英 2, 谢云飞 1, 郭亚辉 1, 成玉梁 1, 钱和 1, 姚卫蓉 (1., ; 2., ) 1* 摘要 : (nuclear magnetic resonance, NMR),,, NMR, 关键词 : ; ; ; ; ; ; Applications of nuclear magnetic resonance in the adulteration detection of food SUN Qing-Qing 1, XU Yan-Ying 2, XIE Yun-Fei 1, GUO Ya-Hui 1, CHEN Yu-Liang 1, QIAN He 1, YAO Wei-Rong 1* (1. College of Food Science, Jiangnan University, Wuxi , China; 2. Suzhou Gusu District Market Supervision and Administration Bureau, Suzhou , China) ABSTRACT: Food adulteration is one of the hottest food problems in today's society, and how to detect the adulteration or adulteration ratio more effectively is critical to solve this problem. Nuclear magnetic resonance (NMR) technology has received great attention in recent years due to the rapid and nondestructive detection of the physical and chemical properties and structure of the samples. In this paper, the applications of NMR in the detection of food adulteration of oil, milk, honey and other food were introduced from the common detection parameters of iodine value, solid fat content, relaxation time, diffusion rate and specific signal. As a new adulteration detection technology, NMR technology is still not widely applied in domestic food adulteration. Compared with other existing food adulteration detection technologies, NMR technology has the advantages of rapid, nondestructive detection and easy operation and so on, and will have great development prospects in food adulteration detection in the future. KEY WORDS: nuclear magnetic resonance; adulterations detection; iodine value; solid fat; relaxation behavior; diffusion coefficients; specific signal 基金项目 : (SS201440) Fund: Supported by Suzhou Science and Technology Support Project (SS201440) and Jiangsu Province Food Safety and Quality Control synergetic innovation Center * 通讯作者 :,,, yaoweirongcn@jiangnan.edu.cn *Corresponding author: YAO Wei-Rong, Professor, Doctoral Supervisor, Jiangnan University, Wuxi , China. yaoweirongcn@jiangnan.edu.cn

2 4, : 核磁共振应用背景,,,,, [1-3] [4] DNA [5] [6] [7],, (nuclear magnetic resonance, NMR),,, [8],, [9],, ( ) (low-field nuclear magnetic resonance, LF-NMR) [10,11] ( ) (high-field nuclear magnetic resonance, HF-NMR) [12], NMR NMR [13], NMR, 1 H- ( 1 H-NMR) 13 C- ( 13 C-NMR) 31 P- ( 31 P-NMR) (magnetic resonance spectroscopy, MRS) (magnetic resonance imaging, MRI) [14],, NMR [15,16] [13], 2 通过碘值来检测掺假 (iodine value, IV), 100 g ( ), [17],, (Wijs) [18], [6] [19] [20] ( ) IV 1 H-NMR 3 min, IV,, Wijs-, 1 H-NMR ±1%, [21], Alexia [22] 500 MHZ 1 H-NMR 1%~95%,,, (canonical discriminant analysis, CDA) (corpus-based translation studies, CBTs) 3 通过 SFC 值来检测掺假 (solid fat content, SFC), -,, (solid fat index, SFI) [23] 20 60, NMR [24] GB/T [25] NMR, 90, 11 μs( ) 70 μs( ) (free induced decay, FID), SFC H, FID,,, 70 μs 70 μs [25], FID,, NMR SFC [26] NMR, [27,28] SFC,,,, SFC [29] AOCS Cd 16b-93, 3 ( ) 10 0 SFC 10 0, SFC 26.51% 43.25%,

3 % 12.60%, SFC 0, SFC, 1%,, SFC 4 通过弛豫特性来检测掺假,,,, [13] T2 (transverse relaxation time), -,, T2 T2 NMR, [30] 1 H-NMR, (principal component analysis, PCA), PCA, PCA Poliana [31] 9 MHz (time-domain nuclear magnetic resonance, TD-NMR) T2,, 2, [32], PCA, [33] PCA, (Carr-Purcell-Meiboom-Gill, CPMG), T2 Roberta [34] 1 H-NMR 0 100% T1 T2, T2,, ph T2, (low-field 1 h nuclear magnetic resonance, LF- 1 H-NMR), T2 [35] 1 H-NMR LF-NMR, PCA,, PCA, Zhang [36] 22 MHz LF-NMR 2 ( ), 0~20% T2,, T2 Zheng [37] NMR, NMR, T2, T2 [38], PCA (partial least squares regression, PLSR) CPMG T2,, [39] PCA 3, PLSR, 2 5 通过扩散率来检测掺假,, (diffusion coefficients), [40] Zheng [37] NMR, T2-D, D Daniela [41] NMR Diff-30, 350 G/cm,, 2, 20% 20% 10% 30%, NMR 6 通过核磁共振图谱来检测掺假, NMR, [42],,,

4 4, : 1329 NMR, Jafari [43] (gas chromatograph, GC) (differential scanning calorimetry, DSC) NMR, 400 MHz 1 H-NMR, 9~10,, 2, ; 7,, 2, Alexia [22] 1 H, 31 P, 1 H-NMR 1 H-NMR, 31 P-NMR, MHz 31 P-NMR, MHz 31 P-NMR 2, 2 Daniela [41] Differ30 1 4, 1, 4, 1 4 Mannina [44] MEDEO 92, 600 MHz 1 H-NMR 600 MHz NMR, 5, 5 β- PCA,,,, 10%, 500 MHz 400 MHz [45] 1 H-NMR 13 C-NMR,,,, % Giovanna [46] DEPT( ), DEPT, 13 C-NMR, C-9 C-10,,,, [47] 1 H-NMR 180, NMR,, [48],, NMR,, Ferrari [49] 1 H-NMR, 7 总结,,,,,, 10%,, NMR [50],,, 参考文献 [1],,. [J]., 2015, 41(12): Yang J, Gao J, Miao H. Discuss on food fraud and food adulteration [J]. Food Ferment Ind, 2015, 41(12): [2],,,. [J]., 2016, 37(7): Li D, Wang SW, Zang MW, et al. The united states experience in dealing with economically motivated adulteration and food fraud and its enlightenments to China [J]. Food Sci, 2016, 37(7): [3]. [J]., 2016, (13):

5 WU J. Application of modern instrumental analysis technology in food adulteration [J]. Heilongjiang Anim Husb Vet Med, 2016, (13): [4],,,. [J]., 2016, 37(1): Ren JA, Huang WS, Ge YQ, et al. Meat products authenticity identification technology research progress [J]. Food Sci, 2016, 37(1): [5],,,. DNA [J]., 2012, (6): , Song J, Lei SR, Guo LG, et al. Application of DNA fingerprinting technique in food adulteration and origin traceability test [J]. J Anhui Agric Sci, 2012, (6): , [6],,,. [J]., 2013, (07): Dong HS, Zang P, Li YP, et al. Research on rapid determination of iodine value in vegetable oil by laser Raman spectroscopy combined with partial least squares [J]. J Opetelectr Laser, 2013, (07): [7],. [J]., 2016, (07): , 386. Wang J, Liu R. Application of near infrared spectroscopy in the detection of liquid food adulteration [J]. Food Ind Sci Technol, 2016, (07): , 386. [8] ThyboA K, BechmannI E, Martens M, et al. Prediction of sensory texture of cooked potatoes usinguniaxial compression, near infrared spectroscopy andlow field 1 H-NMR spectroscopy [J]. Food Sci Technol, 2000, 33: [9],,,. [J]., 2015, (16): Li J, Cui JY, Yang XD, et al. Quantum control in nuclear magnetic resonance [J]. Acta Phys Sin, 2015, (16): [10],,,. [J]., 2014, 45(4): Du GY, Tang Y, Zhang SW, et al. Nuclear magnetic resonance analysis of wheat leaf senescence [J]. J Agric Mech, 2014, 45(4): [11],,,. [J]., 2015, (15): Song P, Yang T, Wang C, et al. Study on water change in rice seed soaking process by low field nuclear magnetic resonance [J]. Chin J Agric Eng, 2015, (15): [12],. [J]. ( ), 2014, 46(1): Lv MX, Zeng HP. Nuclear magnetic resonance (NMR) to detect harmful polycyclic aromatic hydrocarbons in edible vegetable oil anthracene study [J]. J South China Norm Univ (Nat Sci Ed), 2014, 46(1): [13],,,. [J]., 2016, 7(11): Liu W, Liu WL, Wei XX, et al. Application of nuclear magnetic resonance spectroscopy in the identification of food adulteration [J]. J Food Saf Qual, 2016, 7(11): [14],,,. [J]., 2013, (12): , 147. Zhang JF, He Y, Gong XY, et al. Browning detection of fragrant pear using magnetic resonance imaging [J]. J Agric Mech, 2013, 44(12): , 147. [15],,. [J]., 2016, 59(07): Guo JF, Xie RH, Zou YL. Monuclear magnetic resonance response simulation and constrained diffusion in sandstone [J]. Chin J Geophys, 2016, 59(07): [16],,,. [J]., 2015, 40(06): Liu YF, Tang DZ, Xu H, et al. Study on stress and deformation of coal and rock fractures based on nuclear magnetic resonance [J]. J China Coal Soc, 2015, 40(06): [17],,,. [J]., 2014, 22(2): Yang L, Ji DB, Xue DH, et al. Study on rapid determination of iodine value of edible fats [J]. Cere, Oils Foodstuffs, 2014, 22(2): [18] GB/T [S]. GB/T Determination of iodine value of animal and vegetable [S]. [19],,,. [J]. ( ), 2013, 49(12): Cheng YX, Xian Y, Ma TZ, et al. Identification and vegetable oils or animal fat near infrared spectrum method for the determination of iodine value [J]. PTCA (Part B: Chem Anal), 2013, 49(12): [20]. [J]., 2015, 28(04): Zou LM. Direct determination of iodine value of oils by visible spectroscopy [J]. J Food Sci Technol, 2015, 28(04): [21] Yuko M, Kazuhisa Y, Narihide M. Rapid determination of iodine value by 1 H nuclear magnetic resonance spectroscopy [J] J Am Oil Chem Soc, 1998, 75(1): [22] Alexia A. Detection of refined olive oil adulteration with refined hazelnut oil by employing NMR spectroscopy and multivariate statistical analysis [J]. Talanta, 2010, (80): [23],,,. [J]., 2010, (9): Xu AJ, Yu JB, Zhang LP, et al. Effects of influencing factors on the determination of fat in oil [J]. Cere Oils Process, 2010, (9): [24] Duynhoven J, Goudappel GJ, Gribnau MCM, et al. Solid fat content determination by NMR [J]. Int News Fats Oils Relat Mater, 1999, 10(5): [25] GB/T [S]. GB/T Animal and vegetable fats and oils Determination of solid fat content by pulsed NMR direct method [S]. [26] ISO NMR. 2 : [S]. ISO Animal and vegetable fats and oils Determination of solid fat content by pulsed NMR. Part 2: Indirect method [S]. [27] Sabine BD, Claude D. Determination of solid fat content (SFC) of binary fat blends and use of these data to predict SFC of selected ternary fat blends containing low-erucic rapeseed oil [J]. J Am Oil Chem Soc, 2006, 83(7): [28],,,.

4, : 1331 [J]., 2016, 41(09): 55 58. Shi C, Chang M, liu RJ, et al. Study on the application of rice chaff in the combination of fat and palm stearin [J]. China Oil, 2016, 41(09): 55 58. [29],,. [J]., 2008, 33(10): 75 77.

6 4, : 1331 [J]., 2016, 41(09): Shi C, Chang M, liu RJ, et al. Study on the application of rice chaff in the combination of fat and palm stearin [J]. China Oil, 2016, 41(09): [29],,. [J]., 2008, 33(10): Wang L, Li Y, Hu JH. Evaluation of absorbed vegetable oil by edible vegetable oil by nuclear magnetic resonance [J]. China Oil, 2008, 33(10): [30],,,. [J]., 2010, 26(9): Jiang C, Han JF, Fan JL, et al. Rapid detection of adulteration milk by low field nuclear magnetic resonance (NMR) combined with principal component analysis (PCA) [J] Agric Eng J, 2010, 26 (9): [31] Poliana M, Santos A, Edenir R, et al. Detection and quantification of milk adulteration using time domain nuclear magnetic resonance (TD-NMR)[J]. Microchem J, 2016, (124): [32],,,. [J]., 2016, 32(7): Chen YB, Liu MH, Wang SL, et al. Rapid detection of low field MRI in combination with chemical metrology method adulterated milk [J]. Food Mach, 2016, 32(7): [33]. [D]. :, SRDL. Rapid detection of adulterated camel milk using low-field nuclear magnetic resonance technology [D]. Hohhot: Inner Mongolia Agricultural University, [34] Roberta de ORR, Eliane TM, Carla da SC, et al. Detection of honey adulteration of high fructose corn syrup by low field nuclear magnetic resonance (LF 1H NMR) [J]. J Food Eng, 2014, (135): [35],,,. [J]., 2014, 30(9): Zhao TT, Wang X, Lu HY, et al. Application of low field nuclear magnetic resonance combined with principal component analysis in edible oil quality analysis [J]. Mod Food Sci Technol, 2014, 30(9): [36] Zhang Q, Ahmed S, Saleh M, et al. Discrimination of edible vegetable oil adulteration with used frying oil by low field nuclear magnetic resonance [J] Food Bioprocess Technol, 2013, (6): [37] Zheng X, Robert HM, Martin B, et al. Detection of virgin olive oil adulteration using low field unilateral NMR [J]. Sensors, 2014, 14: [38],,. [J]., 2015, 34(07): Wang XL, Wu J, Tan MQ. Study on rapid detection of adulterated walnut oil by low field nuclear magnetic resonance combined with chemometrics [J]. J Instrum Anal, 2015, 34(07): [39],,. [J]., 2014, 35(20): Shao L, Zhang LY, Feng YL. Detection of sesame oil adulteration by low field nuclear magnetic technique [J]. Food Sci, 2014, 35(20): [40] Rachock A, Tritt-Goc J. Novel application of NMR relaxometry in studies of diffusion in virgin rape oil [J]. Food Chem, 2014, 152(6): [41] Daniela S, Alessandro P. High-power gradient diffusion NMR spectroscopy for the rapid assessment of extra-virgin olive oil adulteration [J] Food Chem, 2010, 118(1): [42]. [M]. :, Zhao TZ. Nuclear magnetic resonance spectroscopy [M]. Beijing: Peking University Press, [43] Jafari M, Kadivar M, Keramat J. Detection of adulteration in iranian olive oils using instrumental (GC, NMR, DSC) methods [J]. Am Oil Chem Soc, 2009, 86(2): [44] Mannina L, Marco D, Capitani D. 1 H NMR-Based Protocol for the detection of adulterations of refined olive oil with refined hazelnut oil[j]. J Agric Food Chem, 2009, 57(24): [45],,,. [J]., 2015, 40(7): Yang Y Yin L, Yin FH, et al. Nuclear magnetic resonance spectroscopy of several edible oils and rapid detection of trench oil [J]. China Oil Ind, 2015, 40(7): [46] Giovanna V. Quantitative 13 C NMR method using the DEPT pulse sequence for the detection of olive oil adulteration with soybean Oil [J]. Magn Resona Chem, 1997, 35(13): [47],,. [J]., 2017, 38(04): Chen L, Liu HB, Luo LT. Determination and analysis of adulteration of fructose and glucose in rape honey by hydrogen nuclear magnetic resonance combined with orthogonal partial least square method [J]. Food Sci, 2017, 38(4): [48],,,. 1 H-NMR [J]., 2016, 37(12): 80 84, 171. He Y, Zheng YJ, Deng XL, et al. Analysis of 1 H-NMR spectrum and adulteration identification of flavors in Wushan rice [J]. Food Ind Technol, 2016, 37(12): 80 84, 171. [49] Ferraria E, GFocab, MVignalic, et al. Adulteration of the anthocyanin content of red wines: Perspectives forauthentication by Fourier transform-near infrared and 1 H NMR spectroscopies [J]. Anal Chim Acta, 2011, 701(2): [50]. FoodScreener TM, [J]., 2017, (C31): Wang CM. FoodScreener TM, so that food adulteration nowhere to hide [J]. China Food Saf Magaz, 2017, (C31): 作者简介 ( 责任编辑 : 姚菲 ) 孙青青, 硕士, 主要研究方向为食品安全与质量控制 @vip.jiangnan.edu.cn 姚卫蓉, 教授, 博士生导师, 主要研究方向为食品安全与质量控制 yaoweirongcn@jiangnan.edu.cn

30期

30期中国农学通报 2014,30(30):285-289 Chinese Agricultural Science Bulletin 傅里叶变换红外光谱法在橄榄油掺假鉴别中的应用黄秀丽, 黄飞, 曾宪远, 宁焕焱, 唐丽娜, 奉夏平 ( 广东省惠州市质量计量监督检测所, 广东惠州 516003)

Microsoft Word 孙青青 二校

Microsoft Word 孙青青二校