Z0602 1 2 1
ISO 1 2 1 2 3 4 5 CO2H2O 2
1 2 3 4 ISO 1. 2002 8 2.. 2002 11 3. 2002 10 4. 2004 6 3
Z0602 2 2 4
mn/m : : P 2 P=4/ R 1Gibbs 2 5
1nm 2 ; 3210-6 mol/l, ; 80010-6 mol/l, ; 60010-6mol/L 1 2 1.. 2002 8 2... 2002 11 3. 2002 10 4. 2004 6 6
Z0602 3 2 + + + 7
Langmuir P43 219 8
PH PH 1 2 3 4 1 2 3 1. 2002 8 2.. 2002 11 3. 2002 10 4. 2004 6 9
Z0602 4 2 : : C Krafft C Krafft Krafft Krafft ( ) 10
CH2 cmc cmc cmc cmc cmc cmc cmc cmc cmc H F H F cmc cmc 11
cmc cmc PH 1 2 3 cmc cmc cmc 1. 2002 8 2.. 2002 11 3. 2002 10 4. 2004 6 12
Z0602 5 2 HLB (HLB ) HLB HLB 140 1 1~20 HLB=0 HLB20 HLB HLB HLB 1~4 3~6 6~8 8~10 10~13 >13 13
HLB HLB HLB 1.53.0 3.06.0 W/ O 7~9.0 8~18 O/ W 13~15 15~18 HLB 1~3 3~6 6~8 8~10 10~13 >13 HLB HLB SO 4 Na SO 3 Na OPO 3 Na COONa OH O cmc 14
cmc 411 1 2 HLB HLB 1.. 2002 8 2... 2002 11 3. 2002 10 4. 2004 6 15
Z0602 6 2 HLB 800 CF3 CH3 CH2 16
HLB HLB cmc 17
1g 1% 50mm 100 1g 10ml 30 1 EO 4-11 4-1718 18
1 2 3 1 2 3 ISO 1. 2002 8 2.. 2002 11 3. 2002 10 4. 2004 6 19
Z0602 7 2 cmc,,, ( ), : LAS 10 4 3 6 20 38 CMC 1.4 0.1 3 20
cmc C12H25OSO3Na cmc cmc cmc 0.4mol / LNaCl cmc 21
cmc cmc cmc CMC cmc cmc cmc N cmc cmc 22
cmc, cmc / 23
OP-8S/C12E C12E9S/OP8C12E9S/C12E cmc 24
LAS C12HAA-2EO LAS PH 1 2 3 4 1. 2. 1. 2002 8 2.. 2002 11 3. 2002 10 4. 2004 6 25
Z0602 8 2 26
20 72.8mN/m 1. 2. 1. BX T TN MP 27
2. Tween-61 HLB 9.6 96% PH PH JFC Tx10 28
O 25% NN OHCOOHSO3H 5~10 C T >90 29
PF AEG CR AC (),, 30
OHCOOH 1 2 3 4 6 1.. 2002 8 2... 2002 11 3. 2002 10 4. 2004 6 31
Z0602 9 2 cmc cmc 32
01m W/O O/W + 40mN/m O 1mN/m 33
2m / O/W W/O O/W 74.02% 25.02% 74.02% O/W W/O W/O 34
W/O O/W W/O W/OO/W W/OO/W O/W W/O O/W 3% 1 PVA 35% HLB HLB HLB 35
HLB 1015 () 36
, 1 2 3 4 2. 3. 1. 2002 8 2.. 2002 11 3. 2002 10 4. 2004 6 37
Z0602 11 2 38
() 39
W1 Wf =W1/Wf 40
, PEO 41
1 2 3 4 1. 2002 8 2.. 2002 11 3. 2002 10 4. 2004 6 42
Z0602 12 2? 12 18 1418 -COO- -SO 4 -SO 3 -CH 2 -CH 2 -O- -NH 2 43
-NH-CO- 10 18 44
45
cmc 9-10 PH PH 46
CH2COONa ABS LAS RSO3Na ABS LAS ABS AS 601 RSO3Na C14C18 AS C1516 ROSO3Na R C1216 SAS cmc Basf Leophen U SAS 27% 80g/L A C17H33CONHCHCOnONa 47
TNN- C17H33CONCH3CH2CH2SO3Na 16~18 AE APE HSB LAS 48
EDTA NTA DTPA P N (CMC) PVP CMC (CMC) 49
1 2 3 4 5 1 2 3 4 5 1. 2002 8 2.. 2002 11 3. 2002 10 4. 2004 6 50
Z0602 13 2 51
C 16 C 18 510m 52
LS A T 53
OH O O PH7 PH 89 PE KOH PH PE 54
OH CH 2 CH 2 O CONH 2 COOCH 3 1 2 3 4 1. 2. 1. 2002 8 2.. 2002 11 3. 2002 10 4. 2004 6 55