3.2 3.2-1 3.2-1 1 () 4060 90 95 6080 90 90 100 ( ) 65 70 9099 90 90 90 70 1. 83 (thinner) 3.2-2
3.2-2 (lacquer) 3.2-2 alkyd ( ) alkyd alkyd (, phenolic) (polyurethane, PU) ( /, epoxy) (Vinyl) alkyd (Melamine) (Polyester) (Chlorinated Rubber) ( paint) (varnish) ( /, acrylic) 2
3.2.1 high solid 95 90 3.2-3 3.2-3 VOCs () 9599 9599 9598 7090 6090 6090 9095 9095 9095 6080 5080 5080 1996 3
70 (A) (B) (C) (A) (B) ( ) (C) ( ) 2. 1953 Shumit (1) 1970 50 (-OH) 33 270 750 1,000 5 (2) 1966 66 1985 4
5 8 20 n W mix φiwi i1, 2 n i= 1 W mix W i φ i TLV TLV TLV mixture φ1 TLV 1 1 φ2 φn + +... + TLV TLV 2 n 5
TLV mixture TLV 1, TLV 2 TLV n φ 1, φ 2 φ n TLV 3. (1) 37 (A) 6
(B) (C) (D) (E) 3.2-4 3.2-4 ( %) ( %) 2040 30130 3060 5100 3555 5150 3555 30150 5770 0100 95100 05 7080 030 5075 035-1996 A. (vinyl) B. (binder) 50 7
8 1015 1015 A. (polyester) (acrylic resin) (monomer) B. (close linking) (butyl) (melamine) (methyl) 7030 4050 C. D.
E. (NDA) F. ( ) (isocyanate) (carboxyl) (amino) (2) 9
10 10 1965 80 1985 60 (A) (B) (C) (D) (E) (F) (G) (H) (A) (B) (C) (D) (E) (F) (A) (B) (C) (D) (E) (F) (G) (H) 3.2-5
3.2-5 (soapless) (soap free) (core shell) IPN () ph - 1996 36 130140 (one coat) 11
(silanol) (3) (polyethylene) (vinyl nylon) 12
13 100250m 3040m 3.2-6 1 1. 2. 3. 40 4. 5. 6. 1. 2. 3.35 4. 5. (10KG/ ) 6. 2 1. 2. 1. 2. 3 1. 2. 3. 1. 2. 3. 4 1. 2. 3. 1. 2. 5 1. 2. 3. 1. 2. 3.
14 3.2-6 6 1. 2. 3. 4. 5. 1. 2. 3. 4. 5. 7 1. 2. 3. 4. 1. 2. 3. 4. 8 1. 2. 1. 2. 9 1. 2. 3. 4. 1. 2. 3. 4. 10 1. 2. 3. 1. 2. 3. 11 1. 2. 1. 2. 12 1. 2. 3. 4. 5. 1. 3. 4. 5. 13 1.1. 14 1. 2. 1. - 1996
(4) (vehicle) 3.2-7 15
3.2-7 - 1996 UV A. 3.2-8 - 1996 16
UV (radical) 3.2-9 3.2-9 (oligomer) (acrylate) (polyene) (polythiol) (spirane) - 1996 3.2.2 1. (1) (2) (3) (1) 17
(teflon) 8090 (2) (pig) (3) (batch) 2. (airless) (1) 18
A. B. 19
20
30 40 21
3.2-1 HVLP LVMP (2) 22
3.2-2 3.2-10 3.2-3 3.2-11 3.2-2 - 1996 23
3.2-10 1. 2. 2. 3. 3. 4. 4. 5. 5. 1. 1. 2. 3. 3. 4. 4. 5. 5. 1. 1. 2. 2. 3. 3. 4. 4. 1. 1. 2. 2. 3. 3. 4. - 1996 3.2-3 24
3.2-11 1. (blushing) (1) ( (1) 80%RH ) (2)Thinner (2) (3) ( ) (3) (4)(4) (1) (2) (3) 2. (1) 3. (1) (1) (2) (3) (4) (2) (5) () (3) (6) (7) 4. ( ) (1) (1) (2) (2) (3) (3) (4) 5 (1) (1) (2) (2) (3) (4) (5) thinner 6. (1) (1) (2) thinner (2) (3)blushing ( ) (3) (4) (5) (6) ( 7. (1) (1) :( (2) Silicon (2) ) (3) (setting time) (4) (3) (4) (5) 8. metallic ( (1)Spray gun ( ) (1) ) (2) (2) (3) (3) or - 1996 25
26 (3) (A) (B) (C) (D) HVLP (F) (G) (H) (I) (J) 3. (1) (A) (B) (C) (A) (B) (C) (D) (E)
27 (A) (B) (C) (90 )(D) (E) 7 (A) (B) (C) (D) (E)
(A) (B) 28
(2) E.D. E.P. 95 29
30
+ + ph 1. 1. 2. 2. 3. (MEQ) 1. 2. 1. 2. 1. (mhos/cm) 1. 2. 2. 3. () 100 1. 1. 2. 2. 3. 3. - 1996 3.2-13 31
32 3.2-13 1. 1. 1. 2. 3. 4. 5. 6. 7. 8. 1. 2. 3. 1 4. 5. 12 6. 7. 8. 1. 2. 3. 4. 5. 6. 7. 1. 2. 3. 1 4. 5. 6. 7.1. 2. 3. 4. 5. 6. 1. 2. 3. 4. 5. 6-1. 6-2. 1. 2. 3. 4. 5. 6. 7. 1. 2. 3-1. 3-2. 4. 12 5. 6-1. 6-2. 7. 1. 2. 3. 4. 1. 2. 3. 4. - 1996
33 3.2-13 1. 2. 1-1. 1-2. 1-3. 1-4. 1-5. 1-6. 2. 1. 2. 3. 4. 1. 2. 3. 4. 1. 2. 3. 4. 1. 2. 3. 4. 1. 2. 3. 4. 5. 6. 7. 8. 1. 2. 3. 4. 5. 6. 7. 8. 1. 2. 3. 4. 5. 6. 7. 1. 2. 3. 1 4. 5. 6-1. 6-2. 7.1. 2. 1. 2.1. 2. 1. 2. - 1996
F. 34
(3) 1950 1960 80 100m 35
. 3.2-14 3.2-14 36
(A) (B) (C) (D) (A) (B) 3.2-15 37
3.2-15 15020 15070 12 1 1 1 98 20 500 ( ) 1 250-1996 3.2-16 3.2-16 1 1. 1. 2. 2. 3. 40 3.35 4. 4. 5. 5. (10KG/ ) 6. 2 1. 1. 2. 3 1. 1. 2. 2. 3. 3. 38
39 3.2-16 4 1. 2. 3. 1. 2. 5 1. 2. 3. 1. 2. 3. 6 1. 2. 3. 4. 5. 1. 2. 3. 4. 5. 7 1. 2. 3. 4. 1. 2. 3. 4. 8 1. 2. 1. 2. 9 1. 2. 3. 4. 1. 2. 3. 4. 10 1. 2. 3. 1. 2. 3. 11 1. 2. 1. 2. 12 1. 2. 3. 4. 5. 1. 2. 3. 5. 13 1.1. 14 1. 2. 1.
EPC EPCelectrophoretic powder coating, EPC 3.2-17 40
41 3.2-17 () 160 3.2.3 1. (1)
(2) (3) (4) (5) 2. 3. 42
4. 5. 6. 7. ( ) (VOCs) 8. 43
44 9. 10. 11. (1)
(2) (3) (MEK) 45
( ) 12. (1) (2) (3) (4) (5) (6) (7) (8) (9) 46