HJ HJ/T 201 2005 HBC 12 2002 The technical requirement for environmental labeling products Water based coatings 2005 11 22 2006 01 01
... III 1... 2... 3... 4... 5... 6... A ( )... B ( ) VOC... 8 C ( )... 12 D... 13 E... 15 F ( )... 18 G ( )... 22 H A ISO 11890-2:2000... 25 I A ISO 11890-2:2000... 27
VOC HBC12 2002 GB/T1.1 2000 HBC 12 2002 VOC ECD GB18582 2001 C VOC 2 ISO11890-2:2000 VOC VOC VOC 250 VOC VOC A D E F G B C H I 2005 11 22 2006 1 1 HBC12 2002 HJBZ 4-1994 HJBZ 4-1999 HBC 12-2002 III
HJ/T 201 2005 1 2 GB 601 GB 3186 GB/T 6750 GB 18582 2001 ISO 11890 2 VOC 2 Paints and varnishes-determination of volatile organic compound VOC content-part 2:Gas-chromatographic method 3 3.1 volatile organic compound VOC 101.3 kpa 250 3.2 volatile organic compound content 1 / g/l VOC 4 4.1 4.2 1 g/kg VOC
5 HJ/T 201-2005 5.1 5.2 1 1 80 g/l VOC 150 g/l 80 g/l 250 g/l 10 g/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg 500 500 100 90 75 60 60 6 6.1 6.2 VOC A 6.3 E 6.4 GB 18582 2001 6.5 F 6.6 G
HJ/T 201 2005 A ( ) A.1 VOC 2 ISO 11890 2:2000 VOC 0.1% 15% A.2 A.2.1 (VOC) 101.3 kpa 250 A.3 A.4 A.4.1 A.4.2 A.4.3 40 300 1 A.4.4 A.4.4.1 FID FID 300 10 A.4.4.2 A.4.4.3 FT-IR A.4.5
HJ/T 201-2005 0.32 6% / 94% A.4.6 FT-IR A.4.7 A.4.8 A.4.9 A.4.10 A.4.11 A.4.12 A.4.12 A.4.12.1 99.995% A.4.12.2 99.995% A.4.12.3 A.5 A.5.1 A.5.2 99% A.5.3 99% A.5.4 VOC VOC VOC VOC 250 3 251 250 A.6
HJ/T 201 2005 GB 3186-82 A.7 A.7.1 GB/T6750 A.7.2 D A.7.3 A.7.3.1 C A.7.3.2 A.7.4 A.4.4.2 FT-IR A.4.4.3 A.7.3 B A.7.5 A.7.5.1 A.7.5.1.1 0.1 mg A.7.4 A.5.1 A.5.3 A.7.5.1.2 A.7.3 A.7.5.1.3 r i m m ci is = (1) is A A ci r i i m is g m ci i g A is A ci i A.7.5.2 1.0 A.7.6 1g 0.1mg 10mL A.7.7
HJ/T 201-2005 A.7.7.1 A.7.7.2 6% / 94% A.3.1 VOC A.7.7.3 1µL m i r A m m A i i is = (2) s is m i 1g i g r i i A i i A is m is g m s A.8 A.8.1 VOC (3) VOC : i n = = VOC m i ρ s 1000 (3) i = 1 VOC VOC g/l m i 1g i g s 23 g/ml 1 000 A.8.2 VOC VOC lw VOC lw = 1 i = n m i i = 1 ρ s m w ρ s ρ w VOC lw VOC g/l m i m w s 1g i 1g g 23 g/ml 1000 (4)
HJ/T 201 2005 w 23 g/ml =0.997 5 g/ml 1 000 A.9 VOC A.10.1 VOC 1% 0.1% VOC lw VOC 1% 0.01% VOC lw A.10 A.10.1 r r 95% 1% 8% A.10.2 R R 95% 2% 11% A.1 5 7 5 5 5 5 % 0.36 11.68 11.83 0.04 0.24 1.22 10.4 2.0 10.3 0.01 0.17 0.88 2.6 1.5 7.4
HJ/T 201-2005 B ( ) VOC B.1 VOC B.2 VOC B.1 B.3 B.3.1 B.3.2 >99.995 % B.3.3 B.4 B.4.1 B.4.2 (DEA) B.4.3 99 % B.5 B.5.1 B.5.2 1 6 % / 94 % DB-1301 60 m x 0.32 mm x 1.0 µm 2 wax DB-wax 30 m x 0.25 mm x 0.25 µm B.5.3 5 L B.6 B.6.1 1 : 6 % / 94 % 60 m x 0.32 mm x 1.0 µm : N 2 : 64 kpa (9 psi ) : 0.77 ml/min : 250 : 1.0 µl, 40:1 : FID 260 8
HJ/T 201 2005 : 100 1 min 20 /min 260 20 min B.6.2 2 : wax 30 m x 0.25 mm x 0.25 µm : N 2 43 kpa (6 psi ) : 0.34 ml/min : 240 : 1.0µlL, 40:1 : FID 250 : 60 1min 20 /min 240 20min B.7 B.7.1 ( ) B.6.1 B.6.2 B.6.1 B.6.2 6% / 94% wax t M B.7.2 10% t R 1 B.1 t t R ( ) M = t R t r ( DEA ) M (1) B.1 r C min min Acetone (as solvent) 56 8.193 0.082 4.501 0.067 65 7.688 0.036 4.926 0.110 78 7.891 0.055 5.170 0.136 Acetonitrile (as solvent) 81-82 8.189 0.082 5.851 0.206 2-Propanol (Isopropanol) 82.4 8.037 0.068 5.093 0.128 Triethylamine (TEA) 88.8 9.029 0.160 4.366 0.053 1-1-Propanol 97 8.365 0.098 5.965 0.218 108 8.836 0.142 6.445 0.267 Toluene 110.6 10.183 0.266 6.269 0.249 Acetic Acid 117 8.616 0.122 9.593 0.592 1-118 9.135 0.169 6.955 0.320 (PM) 9.322 0.187 6.955 0.320 120 PM (, ) 9.655 0.217 7.637 0.390 ( DPM) 90-91 13.035 0.529 10.065 0.641 DPM ( ) /12mm 13.227 0.547 10.136 0.648 9
HJ/T 201-2005 B.1 1 C min min DPM (, ) 13.472 0.570 10.478 0.684 n-butyl Acetate 124-126 10.466 0.292 6.377 0.260 (DMEA) 133-134 9.895 0.240 7.201 0.345 2- (EE) 135 9.674 0.219 7.790 0.406 ( PMA) 140-150 11.142 0.355 7.778 0.405 (MIAK) 141-148 11.304 0.370 7.144 0.339 (MAK) 147-153 11.672 0.403 7.529 0.379 (PnP) 11.036 0.345 7.999 0.428 149.8 PnP (, ) 11.304 0.370 8.496 0.479 (EP) 149.5-153.5 10.739 0.317 8.561 0.486 2-Amino-2-methyl-1-propanol (AMP-95) 165 10.374 0.284 9.076 0.539 3- (EEP) 166/755mm 12.546 0.484 8.821 0.513 (PnB) 12.204 0.453 8.885 0.519 170 PnB (, ) 12.468 0.477 9.362 0.568 (EB) 175 11.914 0.426 9.462 0.579 Limonene 175-177 13.214 0.546 7.770 0.404 2- -1- (2EH) 185 13.336 0.557 10.078 0.642 1,2- (PG) 187 10.388 0.285 10.994 0.737 (EG) 197 9.981 0.247 11.330 0.772 197 12.533 0.483 11.266 0.765 N- (NMP) 202 14.479 0.662 12.161 0.857 205 14.061 0.624 13.502 0.996 (White Spirit) Start End 150-215 10.500 0.295 4.750 0.092 16.000 0.803 9.500 0.583 Dipropylene glycol (DiPG) 13.798 0.600 12.935 0.937 DiPG ( ) 14.134 0.631 13.407 0.986 229~232 DiPG ( ) 14.289 0.645 13.678 1.014 DiPG ( ) 14.553 0.669 13.996 1.047 (DPnP) 14.835 0.695 10.883 0.725 DPnP ( ) 14.970 0.708 10.964 0.734 212 DPnP ( ) 15.123 0.722 11.110 0.749 DPnP ( ) 11.493 0.788 (DEEA) 218-219 15.085 0.718 11.742 0.814 (DPnB) 16.065 0.809 11.651 0.805 DPnB ( ) 16.210 0.822 11.729 0.813 222 DPnB ( ) 16.403 0.840 11.846 0.825 DPnB ( ) 12.243 0.866 10
HJ/T 201 2005 B.1 2 C min min 2-EH (EEH) 16.132 0.815 11.993 0.840 229 EEH (, ) 20.871 1.252 15.193 1.170 (DB) 231 15.585 0.765 12.743 0.917 2,2,4- -1,3- (TMPD) 232 15.709 0.776 13.753 1.022 (PPh) 16.883 0.884 15.029 1.153 243 PPh (, ) 17.014 0.896 15.416 1.193 245 17.631 0.953 13.067 0.951 (DEG) 245 13.368 0.560 14.248 1.073 (EPh) 247 16.705 0.868 16.150 1.269 (DEA) 251 18.137 1.000 13.543 1.000 11
HJ/T 201-2005 C ( ) C.1 1 30 m x 0.32 mm x 1.0 µm 260 280 45 4 min 8 /min 230 10 min 35 kpa 1.0 µl C.2 2 6% /94% 60 m x 0.32 mm x 1.0 µm 250 260 80 1min 10 /min 230 15 min 64 kpa 1.0 µl 12
HJ/T 201 2005 D.1 13 D D.1.1 2.0 m 3.2 mm 60 80 10 µl 20 µl 10 ml D.1.2 DMF D.2 D.2.1 200 240 150 ma 80 30 /min 170 99.995% D.2.2 R 0.2 g 0.2 g 0.1 mg 2 ml 1 µl R W i g W 2 H O A 2 H O g Wi AH 2O R = 1 W A H 2O i A i R W i ( A R = W H 2O H O B) 2 A i 2
HJ/T 201-2005 W i g W 2 H O g A i A 2 H O B D.3 0.6 g 0.1 mg 2 ml 15 min 5 min 1 µl H 2 O % = A H 2 O A i W W C i 100 R 3 A H 2 O A i W i g W c g R 3 D.4 D.4.1 : 1.6% D.4.2 : 5% 14
HJ/T 201 2005 E.1 15 E E.1.1 50 ml E.1.2 E.1.2.1 NH 4 CH 3 COO E.1.2.2 CH 3 COOH =1.05 E.1.2.3 C 5 H 8 O 2 = 0.975 E.1.2.4 0.25 % V/V 25 g E.1.2.1 3 ml E.1.2.2 0.25 ml E.1.2.3 100 ml ph = 6.0 2 5 E.1.2.5 HCl =1.19(1+5) E.1.2.6 NaOH 30 g/100 ml E.1.2.7 I 2 c I 2 =0.1 mol/l 40 g E.1.2.8 10 ml 12.7 g 1 000 ml E.1.2.8 KI E.1.2.9 K 2 Cr 2 O 7 c 1/6 K 2 Cr 2 O 7 =0.100 0 mol/l 4.9030 g 120 1 000 ml E.1.2.10 1 g/100 ml 1 g 100 ml E.1.3 c Na 2 S 2 O 3 =0.1 mol/l 25 g Na 2 S 2 O 3 5H 2 O 2 g Na 2 CO 3 1 000 ml E.1.3.1 GB601 E.1.4 HCHO 36 % 38 % E.1.4.1 10 ml E.1.4 500 ml E.1.4.2 5.0 ml E.1.4.1 250 ml 0.1 mol/l E.1.2.7 30.0 ml 30 g/100 E.1.2.6 0.7 ml 10 min 1+5 E.1.2.5 5 ml 2 ml 10 min 100 ml E.1.3.1 1 g/100 ml E.1.2.10 1 ml
HJ/T 201-2005 V 0 V 1 ) C Na 15.0 2 S 2O 3 mg / ml ) = 1 5.0 V 0 V 1 ml ml C Na2S2O 3 mol/l 15.0 1/2HCHO 5.0 ml E.1.4.3 E.1.4.2 20.00 µg/ml 2 5 E.2 E.2.1 50 ml 0.00 0.50 1.00 3.00 5.00 8.00 ml 50 ml, 2.5 ml E.1.2.4 60 30 min 10 mm 414 nm E.2.2 2 g 0.001 g 50 ml 10 ml 10 100 ml 50 ml 2.5 ml E.1.2.4 60 30 min 10 mm 414 nm 50 ml E.3 c mg/kg m C = 5 2 W m µg g E.4 16
E.4.1 HJ/T 201 2005 : 2.8 % E.4.2 : 10 % 17
HJ/T 201-2005 F ( ) F.1 40 mg/kg 40 mg/kg 40 mg/kg 50 mg/kg F.2 F.3 F.3.1 F.3.2 F.3.3 40 300 1 F.3.4 FID 300 10 F.3.5 0.32 mm C F.3.6 F.3.7 F.3.8 F.3.9 18
HJ/T 201 2005 19 F.3.10 F.3.11 F.3.11.1 99.995% F.3.11.2 99.999% F.3.11.3 F.4 F.4.1 F.4.1.1 99% F.4.1.2 99% F.4.1.3 99% F.4.1.4 99% F.4.2 99% F.4.3 F.5 F.6 F.6.1 F.6.1.1 C F.6.1.2 C F.6.2 F.6.2.1 F.6.1 F.6.2.2 1 µl F.4.1 F.1 F.6.2.3 1 g 10 ml 1 µl
HJ/T 201-2005 F.1 1 2 3 4 5 ( ) 6 ( ) 7 F.1 F.6.3 F.6.3.1 F.4.1 0.1 mg, F.3.9 F.4.3 F.4.2 F.6.3.2 r i m m ci is = 1 is 20 A A ci r i i m is g m ci i g A is A ci i r 5% F.6.4 1g 0.1 mg F.6.5 F.6.5.1 F.6.5.2 1 µl m r A m i i is i = 2 ms Ais
HJ/T 201 2005 m i 1g i µg/g r i i A i i A is m is µg m s, g 5%, 21
HJ/T 201-2005 G ( ) G.1 5 mg/kg 1,2-5 mg/kg 1,1-10 mg/kg 1,1,1-0.01 mg/kg 1,1,2-0.01 mg/kg 0.01 mg/kg 0.001 mg/kg G.2 G.3 G.3.1 G.4 G.4.1 G.4.2 1 1- G.4.3 1 2- G.4.4 1 1 1- G.4.5 1 1 2- G.4.6 G.4.7 G.4.8 99% G.4.9 G.4.10 G.4.11 ( ) 1 g G.4.9 0.1 mg 50 ml G.5 G.5.1 G.5.2 ( : 30 m 0.25 mm 0.25 µm ) G.5.3 22
HJ/T 201 2005 G.6 G.6.1 1.0 ml/min 42 9 min 50 /min 250 2 min 250 300 : 30 ml/min G.7 G.7.1 G.6.1 0.2 µl G.1 1 2 3 1,1-4 5 6 1,2-7 1,1,1-8 9 1,1,2- G.1 G.7.2 1 g 25 ml G.7.1 G.7.3 1g G.7.2 0.1mg 50 ml 0.2 µl 2 R 23
HJ/T 201-2005 A W W A i S R = 1 i S W S g W i g A i A S R 5% G.7.4 1 g 0.000 1 g 1 ml 50 ml G.8 G.8.1 C i A i A s W s g S g R A i W S C i mg / kg ) = 2 A S R 5% G.8.2 W mg/kg W = W + 0.858 x (W 1,1- + W 1,2- )+ 0.637 x (W 1, 1,1- + W 1,1,2- ) +0.552 W + 0.711W (3) 0.858 0.711 0.637 0.552 S 24
HJ/T 201 2005 H A ISO 11890-2:2000 H.1 A ISO 11890-2:2000 H.1 A ISO 11890-2:2000 A ISO 11890-2:2000 A.1 1 2 A.2 A.2.1 3 3.1 3.2 3.4 A.3 4 5 A.4 A.4.1 6 6.1 6.2.1 A.4.2 6.2.2 6.2.3 6.2.4 A.4.3 A.4.4.3 6.3 6.4.3 A4.5 6.5 A.4.6 A.4.12 A.4.12.1 A.4.12.2 A.4.12.3 6.6 6.12 6.12.1 6.12.2 6.12.3 A.5 A.5.3 7 7.3 A.5.4 A.6 8 A.7 9 A.7.1 A.7.2 A.7.3 A.7.4 A.7.5 A.7.5.2 A.7.6 A.7.7 A.7.7.1 9.1 9.2 9.3 9.4 9.5 9.5.2 9.6 9.7 9.7.1 A.7.7.2 A.7.7.3 9.7.2 A.8 10 10.1 10.2 A.8.1 10.3 A.8.2 10.4 10.5 A.9 11 A.10 A.10.2 12 12.2 25
HJ/T 201-2005 A H.1 13 Annex A C ISO 11890-2:2000 Annex B 26
HJ/T 201 2005 I A ISO 11890-2:2000 I.1 A ISO 11890-2:2000 I.1 A ISO 11890-2:2000 A A.1 VOC 15 0.1 ISO11890-2 2 A.2 2 VOC ISO11890 decopaint VOC (EC of THE EUROPEAN PARLIAMENTAND of THE COUNCIL of on the limitation of emissions of volatile organic compounds due to the of organic solvents in certain paints and varnishes and vehicle refinishing products and amending Directive 1999/13/EC) ISO11890-2 3.2 ISO11890-2 3.3 ISO11890-2 3.4 3.2 3.2 A.4.2 A.4.5 A.4.12.1 6 VOC VOC 94 99.995 ISO11890-2 5 A.5.4 A.6 A.7.1 99.996 VOC VOC GB/8186 82 GB/T6750 86 ISO 11890-2:2000(E) ISO1513 ISO 11890-2:2000(E) ISO2811 A.7.2 A.7.4 A.7.7.2 VOC VOC ISO11890-2 10.1 10.2 10.5 A.8.1 A.8.2 VOC VOC VOC VOC VOC A.10 ISO11890-2 13 27
HJ/T 201-2005 I.1 A ISO11890-2 Annex A C ISO11890-2 Annex B 28