37 ( ) 5 min 1.1 磷酸盐沉淀法 97% 1.4 膜分离技术法 / MAP Ganrot Z [4] Hiagari Driver J [5] Cathie W P [12] NF NF90 NF % NF 99.2% Ostara Pearl R Pr

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1 37 12O 12O Environmental Science & Technology Vol.37 No.12O Dec 薛勇刚 1,2, 吴芳芳 2, 刘旭军 1, 戴晓虎 1* X703 A doi /j.issn O (2014)12O A Review on Phosphorus Recovery Technology and Its Application in the Sewage Sludge Recycling XUE Yonggang 1 2, WU Fangfang 2, LIU Xujun 1 DAI Xiaohu 1* 1. State Key Laboratory of Pollution Control and Resource Reuse, Tongji University, Shanghai , China; 2. Suzhou Institute of Tongji University, Suzhou , China Abstract Phosphorus (P) recovery is an important choice in wastes recycling technology. The development of wastewater treatment technology and the wastes recycling technology have promoted the P recovery technology. And many new P recovery technologies were developed in some countries, which offer a new way for recycling of phosphorus resources. Key words phosphorus recovery; struvite; sewage sludge; biogas liquid; SSA 42% 26% 7% (5%) [1] 180 t 500 t t t [2] [3] 100~ ZX SZSD xue.tongji@gmail.com * wffrebel@126.com

2 37 ( ) 5 min 1.1 磷酸盐沉淀法 97% 1.4 膜分离技术法 / MAP Ganrot Z [4] Hiagari Driver J [5] Cathie W P [12] NF NF90 NF % NF 99.2% Ostara Pearl R Process ph Crystal Green Bl 觟 cher C [13] [6] 1.2 生物富集法 [14] 1.0 MPa 25 NY Yuan Z [7] EBPR NY (PAOs) 1.5 源分离技术 Wong [8] EBPR-r 7 mg/l 4 28 mg/l 168 t 22% 2050 PAO P 216 t [15] ~100 mg /L Kemacheevakul P [16] ph 1.3 离子交换法 ph mg/l Antonini S [17] 50 L 26 d Petruzzelli [9] REM NUT 36 g 3~20 BV/h NaCl 2% P (0.1 mg/l) 400 BV Bottini A [10] 1.6 其他新型磷回收技术 Ichihashi O [18] Sendrowski A [11] COD HAIX HAIX

3 12O Yilmazel Y D [19] 72.1%NH + 4 -N 49% 95.1% 62.3% 94.1% 2.2 SSA 磷回收技术的发展现状 50% Okano K [20] mg P/a 11% A-CSHs 30% SSA A-CSHs Gifu 75% P [26] SSA SNB SNB 430 kt 30% t 2 35 gp/kg ash [27] Kalmykova Y [28] SSA 2 SSA 170 t SSA - 70% [21] SSA 30% 2.1 沼液磷回收技术的发展现状 10% 2.3 污泥磷回收面临的主要问题 MAP SS [22] (TRF) SSA (WLF) (CPBF) SS MAP (WF) (YWF) - COD - Gebrezgabher S A [23] [29] PAC Fe 2 (SO 4 ) 3 PAM CPAM [24] SS CPAM SS NY SS mg/l 1.02 g/l CPAM 2010 SS 148 mg/l SS [25] 98.9% ( MAP ) NH 4+ -N 3-. NH 4+ -N PO 4 -P 1 000~3 000 mg/l 40~100 mg/l MAP SSA 90% [30] 10% SSA P C/N

4 37 Biotechnology, 2013, 88(2): [2],,,. [J]., 2010, 30(5): Hao Xiaodi, Yi Lankai, Wang Congchen, et al. Situation and [31] prospects ofphosphorus recovery techniques[j]. Acta Scientiae Circumstantiae, 2010, 30(5): (in Chinese) [3] European Fertilizer Manufacturers Association. Phosphorus: [32] essential element for food production[j]. European Fertilizer Manufacturers Association (EFMA), Brussels, [4] Ganrot Z, Broberg J, Byden S. Energy Efficient Nutrient Recovery from Household Wastewater Using Struvite Precipitation and Zeolite Adsorption Techniques: A Pilot Plant Study in Sweden [C]//International Conference on Nutrient Recovery from Wastewater Streams. Edited by Ken Ashley, Don Mavinic and Fred Koch. ISBN: Published by IWA Publishing, London, UK [5] Driver J. Phosphates recovery for recyling from sewage and animal wastes[j]. Phosphorus and Potassium, 1998(216): [6] Britton A, Prasad R, Balzer B, et al. Pilot Testing and Economic Evaluation of Struvite Recovery from Dewatering Centrate MAP at HRSD's Nansemond WWTP [C]//Proceedings of the International Conference on Nutrient Recovery from Wastewater MAP Streams, 2009: [33] [7] Yuan Z, Pratt S, Batstone D J. Phosphorus recovery from Kim E H [34] wastewater through microbial processes[j]. Current Opinion in MAP Biotechnology, MAP [8] Wong P Y, Cheng K Y, Kaksonen A H, et al. A novel post denitrification configuration MAP for phosphorus recovery using polyphosphate accumulating organisms[j]. Water Research, Le Corre [35] 2013, 47(17): h [9] Petruzzelli D, Dell'Erba A, Liberti L, et al. A phosphate-selective sorbent for the REM NUT?process: field experience at 81% massafra wastewater treatment plant[j]. Reactive and Functional 3 Polymers, 2004, 60: [10] Bottini A, Rizzo L. Phosphorus recovery from urban wastewater treatment plant sludge liquor by ion exchange [J]. Separa- tion Science and Technology, 2012, 47(4): [11] Sendrowski A, Boyer T H. Phosphate removal from urine using PAOs hybrid anion exchange resin[j]. Desalination, 2013, 322: [12] Cathie Lee W P, Mah S K, Leo C P, et al. Performance studies of phosphorus removal using cross-flow nanofiltration[j]. Desalination and Water Treatment, 2013 (ahead-of-print): 1-9. SSA [13] Bl 觟 cher C, Niewersch C, Melin T. Phosphorus recovery from sewage sludge with a hybrid process of low pressure wet oxidation [ ] and nanofiltration[j]. Water Research,2012,46(6): [14]. [D]. [1] Liu Y H, Kumar S, Kwag J H, et al. Magnesium ammonium phosphate formation, recovery and its application as valuable resources: a review [J]. Journal of Chemical Technology and, Han Jin. Study on Biogas Slurry Concentration and Separation by Membrane and Liquid Fertilizer Preparation Technology

5 12O [D]. Hangxhou: Zhejiang Forestry University, (in Chinese) rus in wastewater treatment-options in Germany[J]. Water Science & Technology, 2011, 64(1): [27] Schipper W J, Korving L. Full-scale Plant Test Using Sewage [15] Mihelcic J R, Fry L M, Shaw R. Global potential of phosphorus recovery from human urine and feces [J].Chemosphere, Sludge Ash as Raw Material for Phosphorus Production[C]// 2011,8 4(6): Ashley K, Mavinic D, Koch F, Proc. International Conference [16] Kemacheevakul P, Polprasert C, Shimizu Y. Phosphorus recovery from human urine and anaerobically treated wastewa- [28] Kalmykova Y, Karlfeldt Fedje K. Phosphorus recovery from on Nutrient recovery. 2009: ter through ph adjustment and chemical precipitation [J]. Environmental Technology, 2011, 32(7): ment, municipal solid waste incineration fly ash[j]. Waste Manage- [17] Antonini S, Nguyen P T, Arnold U, et al. Solar thermal evaporation of human urine for nitrogen and phosphorus recovery in MAP [J] (3) [29],,,. Vietnam[J]. Science of the Total Environment, 2012, 414:592- Ma Quanzhi, Xiang Liancheng, Song Yonghui, et al. Technology development of flocculating pretreatment of livestock and 599. [18] Ichihashi O, Hirooka K. Removal and recovery of phosphorus poultry manure slurry and of phosphorus recovery by MAP as struvite from swine wastewater using microbial fuel cell[j]. crystallization[j].journal of Environmental Engineering Technology, (3) (in Chinese) Bioresource Technology, 2012, 114: [19] Yilmazel Y D, Demirer G. Nitrogen and phosphorus recovery [30],,,. from anaerobic co-digestion residues of poultry manure and [J]., 2007, 27(7): maize silage via struvite precipitation[j]. Waste Management & Research, Yuan Peng, Song Yonghui, Yuan Fang, et al. Nutrient removal [20] Okano K, Uemoto M, Kagami J, et al. Novel technique for and recovery from swine wastewa ter by crystallization of phosphorus recovery from aqueous solutions using amorphous magnesium ammonium phosphate[j]. Acta Scientiae Circumstantiae, 2007, 27(7): (in Chinese) calcium silicate hydrates (A-CSHs)[J]. Water Research, [21] Donatello S, Cheeseman C R. Recycling and recovery routes [31],,,. for incinerated sewage sludge ash (ISSA): a review[j]. Waste [J]., 2011,34(12):181- management, 2013, 33(11): [22]. [D]. Duan Jinming, Fang Hongda, Lin Jinmei, et al. Nutrient removal from swine wastewater by struvite precipitation with, Xing Ze. Adsorption and Its Utilization of Nutrient from Biogas Slurry by Zeolite [D]. Chongqing: Southwest University, Technology, 2011, 34(12): (in Chinese) ammonia adsorption on zeolite[j]. Environmental Science & (in Chinese) [32],,,. [23] Gebrezgabher S A, Meuwissen M P M, Prins B A M, et al. E- : [J]. : conomic analysis of anaerobic digestion: a case of green power, 2013, 43(8): biogas plant in the Netherlands[J]. NJAS-Wageningen Journal Xie Qiang, Xie Jie, Chi Lina, et al. A new sorbent that simultaneously sequesters multiple classes of pollutants from water: of Life Sciences, 2010, 57(2): [24]. [D]. Surfactant modified zeolite[j]. Sci China Tech Sci, 2013,43(8):, (in Chinese) Xu Guorui. The Research on Concentration Technology for [33],,. Biogas Slurry Using Nanofiltration Membrane and Subsequent [J]., 2012, 2(6): Development of Concentrated Biogas Slurry as Liquid Organic Fertilizer[D]. Hangzhou: Zhejiang University, (in Chi- synthetic wastewater as struvite by red mud -seeded crystal- Hu Yi, Song Yonghui, Qian Feng. Phosphorus recovery from nese) lization[j]. Chinese Journal of Environmental Engineering, [25],,,. 2012, 2(6): (in Chinese) [J]. :, 2013, [34] 29 Kim E H, Yim S B, Jung H C, et al. Hydroxyapatite crystallization from a highly concentrated phosphate solution using pow- (1). Yang Xue, Wan Chunli, Du Maoan, et al. Simultaneous recovery of nitrogen and phosphorus in fermentive liquid by strutive Materials, 2006, 136(3): dered converter slag as a seed material[j].journal of Hazardous precipitation[j]. Journal of Harbin University of Commerce: [35] Le Corre K S, Valsami-Jones E, Hobbs P, et al. Struvite crystallisation and recovery using a stainless steel structure as a Natural Sciences Edition, 2013, 29(1). (in Chinese) [26] Petzet S, Cornel P. Towards a complete recycling of phospho- seed material[j]. Water Research, 2007, 41(11):

5- 此針對特殊高氨氮工業廢水, 研究經濟有效的去除氨氮的處理方法是很有意義的 1. 生物脫氮方法 1.1 傳統生物脫氮方法傳統的生物脫氮理論認為微生物脫氮是經由有機氮

5- 此針對特殊高氨氮工業廢水, 研究經濟有效的去除氨氮的處理方法是很有意義的 1. 生物脫氮方法 1.1 傳統生物脫氮方法傳統的生物脫氮理論認為微生物脫氮是經由有機氮淺談氨氮廢水處理技術 5-1 淺談氨氮廢水處理技術李中光, 劉新校, 邱惠敏李中光, 劉新校, 邱惠敏萬能科技大學環境工程系萬能科技大學環境工程系 051 桃園市中壢區水尾里萬能路 1 號 051 桃 Tel: 園市 0-515811-55718, 中壢區水尾

37 ( ) 5 min 1.1 磷 酸 盐 沉 淀 法 97% 1.4 膜 分 离 技 术 法 / MAP Ganrot Z [4] Hiagari Driver J [5] Cathie W P [12] NF NF90 NF % NF 99.2% Ostara Pearl R Pr

37 ( ) 5 min 1.1 磷酸盐沉淀法 97% 1.4 膜分离技术法 / MAP Ganrot Z [4] Hiagari Driver J [5] Cathie W P [12] NF NF90 NF % NF 99.2% Ostara Pearl R Pr