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1 4 5 Vol. 4 No Journal of Food Safety and Quality Oct., 2013 王海蓝 1, 陈引生 2, 石晶盈 (1., ; 2., ; 3., ) 3* 摘要 :,, 关键词 : ; ; Progress in ion chromatography in food analysis WANG Hai-Lan 1, CHEN Yin-Sheng 2, SHI Jing-Ying 3* (1. College of Food Science and Engineering, Jiangsu Agri-Animal Husbandry Vocational College, Tasizhou , China; 2. Department of Electromechanical Engineering, Jiangsu Agri-animal Husbandry Vocational College, Tasizhou , China; 3. College of Food Science and Engineering, Shangdong Agricultural University, Taian , China) ABSTRACT: The application of ion chromatography technologies in analysis and governance of food was reviewed in this paper. In all of them, the detection of inorganic anion, organic acid, common food additives, glucide and other organic compounds in food were described respectively and the possible development of ion chromatography technologies in food analysis in the future was predicated. KEY WORDS: ion chromatography; food analysis; application (ion chromatography, IC) Small [1] 20 70,,,,,,, [2],,,, [3-5] 1 无机离子 1.1 无机阴离子基金项目 : ( ) (ZR2010CQ039) ( ) Fund: Supported by the National Natural Science Foundation of China ( ), Natural Science Foundation of Shandong Province of China(ZR2010CQ039) and Specialized Research Foundation for the Doctoral Program of Ministry ( ) * 通讯作者 :,, jyshi2003@gmail.com *Corresponding author: SHI Jing-Ying, Associate Professor, College of Food Science and Engineering, Shandong Agricultural University, Taian , Shandong Province, China. jingdaping@gmail.com

2 1438 4, 30 mmol/l NaOH+φ( )15%,, NO 3- NO 2- Cl - SO 2-4 PO 3-4, 0.02~0.04 mg/l, 2~120 mg/l, 10% [6],,,, 80% Ionpac AS9-HC 9 mmol/l Na 2 CO 3,,, [7] [8] -, ph,,, 3%, OnGuard IIRP, [9], [10] AgNO 3 Cl -, Ag Cl -, [11] [12],, [13] [14] [15] [16] [17,18] [19] [20],,,,, [21], [22] 861, Metrosep A Supp4-250, 3.1 mmol/l Na 2 CO 3 ~1.0 mmol/l NaHCO 3, [23] SO 2-3 [24], [25],, Dionexdx ICS-90, [26] [27] [28] [29] -,,, [30], [31] [32],, [33] -, 0.01 µg/ml, ph,,, [34], [35] F - Cl - SO NO 3 4, [36] CHCl 3, [37],,, F - NO - 2 Cl - NO 3- PO 3-4 SO 金属离子,,

3 5, : 1439 [38] - 6,, 6,, 5 min,,, [39] ICS3000, CG50A+CS50A 80 mmol/l H 2 C 2 O mmol/l KOH Ultimate 3000 varible wabeleng detector, 35,,,,, [40] [41], [42], C mol/l, 4 [43] 2 食品添加剂 2.1 酸味剂,, /,,,, [44],, [45], 6, [46] [47] IonPac AS14A, 5% 5 mmol/l Na 2 CO 3-5 mol/l NaOH,,, [48] - [49] - 6 ( ), 2.2 甜味剂,,,, [50] IonPac AS17-C,,, 3 ( ) ( ),, [51] - [52] 6 [53] -,, 2.3 防腐剂 ph 7, [54], 0.5 µg/ml 0.8 µg/ml,, [55]

4 1440 4,,,,,, [56], 1 mg kg -1 [57], 0.02 mg/l 2.4 人工合成食用色素,, Chen [58],,,,, ( ) 3 糖类,,,, -,,, pmol, [59,60], [61], Metrosep carb1,, 8 mmol/l NaOH, 1.0 ml/min, 25 min [62] CarboPac PA10, NaOH/NaAc, 1.0 ml/min,,, /, [63] ICS ,, Capillary CaborPac PA20,, 10, 2.5~75 µg/l, 4 其他化合物的分析 Jaime [64] - -MS (paralytic shellfish poisoning toxins, PSP), PSP, [65] ( ),, 5 展望,,,, : 1 ; 2 ; 3

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