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4 万吨 / 年二氯丙醇生产装置 39 2500 C2614 34 8000 87813243 87568641 3000 135 4.5 % 20 80 10 10 10 5 2006 5 2006 8 4

2 4km 5

2002-2020 23.3 2018 2006 39 [1999]60528 25922m 2 [2002D]155 50539m 2 [1999]60519 1414m 2 [96]14688 33861m 2 [2003D]280 9763m 2 () 6

2011 212012 [2013]92012 [2013]183 [2009]38 [2010]7 [2013]892 7

h 4 t/a 8000 % 96.0 1. Q/321001GNA +% 0.035 124-2016* % 3.0 HCl 0.5 / / 800m 2 / 300m 2 / 17500t/h 1600m 3 /h 305 /h 22000Nm 3 /h 160m 3 /h 100m 3 /h 40m 3 / 5m 3 / 5600t/d 150m 2 280m 2 8

/ t/a 99% / 30731.6 99% / 30380.3 99% / 204 99% / 30 99% / 624 30% / 220 / / 2640 / 142kwh/t 568000 / 1.9 76000 HCl 30% C3H6Cl2O -114.2 11.19 1 1.27 1.26362 17.8 290.0 1.4746 318.4 1390 2.12=1 0.13kpa739-4 174 11.37 14.45 176 73.9, LCLo: 1300 ppm/30m; LCLo: 3000 ppm/5m LC50: 3124 ppm/1h LC50: 1108 ppm/1h LD5031500 mg/kg() PC-TWA5mg/m 3 LD5090mg/kg( ) LC50 200mg/kg( ) 11

848.2 2640 11589.6 25 15052.8 12

30731.6 40000 471 204 HCl 30380.3 0.6 785 6195.3 30 30 2640 15052.8 25 30% 220 33 624 624 139 1426 48.2 64829.9 64829.9 20m 3 4 1200*20000 1 1400*20000 1 6.3m 3 2 5m3 1 1000*10500 1 800*7000 1 10m 3 1 5m 3 1 10m 3 1 100m 3 3 130m 3 1 20m 3 1 14

1 HCl TJ36-79 GBZ1-2010 1996 lncm=0.470lnc 3.695 lnc m =0.607lnC 3.166 Cmmg/m 3 C mg/m 3 5mg/m 3 2.2-2 mg/m 3 NO x S0 2 PM 10 HCl 1 0.25 24 0.10 1 0.50 24 0.15 24 0.15 0.07 0.05 0.015 GB3095-2012 (TJ36-79) TVOC 8 0.6 GB18883-2002 1 0.05 * GBZ1-2010GBZ1-2010 GBZ2.1-2007 GBZ2.2-2007 GBZ2.1 TJ36-79 TJ36-79 2 15

2.2-3 mg/l mg/l ph 69 DO 5 3 COD 20 30 SS* 30 60 1.0 1.5 0.2 0.3 * 250 250 0.005 0.01 0.05 0.5 SSSL63-94 GB3838-20022 3 3 GB30962008 3 4a GB30962008 4a LeqdB(A) 3 65 55 4a 70 55 16

m mg/m 3 kg/h mg/m 3 HCl 20 100 0.65 0.20 20 600 0.6 0.25* TVOC / / / 3.0* GB16297-1996 GB/T13201-1991 m h -1 GB8978-19964 GB18918-2002A 17

A ph 6~9 mg/l 6~9 SS 400 10 BOD 5 COD 300 500 GB8978-1996 4 10 50 20 1 2.0 0.5 45 58 TP 8 CJ343-2010 0.5 800 / GB18918-200 2 A GB12348-20083 4a db(a) 3 65 55 4a 70 55 GB12348-2008 18

m 3 /h 1# 100 + 2# + 100 + (%) (m) (m) () 90 20 0.1 90 6 0.1 20 + 6 19

m 3 /d / (%) ph / SS 60 49 COD COD 90 90 90 90 1.7 SS 60 90 20

1 1 1290.3m 3 /a3.91m 3 /d COD 2240m 3 /d 2 5600m 3 /d + 6.2-1 2240m 3 /d3.91m 3 /d 2243.91m 3 /d 20158 2015125WSpHCOD 6.2-1 21

6.2-1 2 20 / 5 m 3 /d 10 m 3 /d 5 m 3 /d 2007 9 10 m 3 /d 15 m 3 /d 5 m 3 /d 2015 5 GB18918-2002 1 A 1 5 m 3 /d 2 10 m 3 /d A 2 /O 22

2010 11 15 m 3 /d 3 5 m 3 /d A2/O 3 m 3 /d 2 m 3 /d A 2014 6 2014 2015 3 5 db(a) 75~80 60 80~85 25 30dB(A) GB12348-2008 3 GB12348-2008 4 23

t/a S1 S2 HW11 HW11 900-013-11 1 179 900-013-11 2 1441 S3 HW45 261-084-45 3 12 S4 / / 11 / / / / / / 1643 / / 280m 2 1632t/a GB18597-2001 100 GB18597-2001 24

GB18599-2001 1 1 HJ/T169-2004 GB18218-2009 A 6.2-1 6.2-2 6.2-1 LD 50 () mg/kg LD 50 ()mg/kg LC 50 4 mg/l 1 <5 <1 <0.01 2 5<LD 50 <25 10<LD 50 <50 0.1<LC 50 <0.5 3 25<LD 50 <200 50<LD 50 <400 0.5<LC 50 <2 1 20 20 2 21 20 3 55 1 12 3 2 6.2-2 % LD 50 mg/kg LC 50 mg/m 3-114.2 / / / 46001h / / 290 3-19 199 31500 / 30% 1390 / / / / / / / 174 / 73.9 90 / 2 25

A.1 30% 6.2-3 6.2-3 Q q q/q q/q 50 0.5 0.01 5000 240 0.048 0.088 30% 200 2 0.01 5000 100 0.02 500 GB 18218-2009 (HJ/T1692004) q 1 /Q 1 + q 2 /Q 2 + qn/qn 1 q 1 q 2 qn t Q 1 Q 2 Qn t qn/qn 0.0881 3 6.2-4 26

6.2-4A B C 6.2-4 1 2 A/B/C 6.2-5 6.2-5 1 2 3 4 5 27

2 1 1 2 30% 2 1 CO 2 28

2 6.3-1 6.3-1 (/) 10-5 10-1 10-3 10-3 3 1 29

A. B. 3 0 3 6.3-3 6.3-3 / / / / / / / / / / / / / / / / / / 30

[2010]113 [2012]221 2013 10 10 32000020130185 1 1 QHSE QHSE ) 2 6.5-1 31

3 1 8 2 4 3QHSE 1 3 4 4 5 20 () 32

6 QHSE 3 7 25 8 6 9 5 4 1 a b c d e f a b 2 a 33

b c d a b c 3 a b c d e f a b c 5 1 20 3 34

2 1 3850m 3 540 m 3 500 m 3 3000 m 3 1 8000 m 3 2 1650 m 3 324 m 3 2 2000 m 3 60-100L 3 1080 691m 3 2268 m 3 228m 3 600 m 3 400 m 3 100m 3 3 3000m 3 Q=300 m 3 /h 4 DCS 35

7 PH 6 1 COD 2 2 5 1. 2. Kg 4. 3. 1 10 10 2 50 50 3 5 5 4 8 8 5 1500 1500 6 CO 2 200 200 7 2 2 8 3 3 9 2 2 10 1 1 / 11 2 2 12 50 50 13 ph 6 6 14 20 20 15 2 2 16 1000 17 1000 0769-22619802 0315-2961263 0413-4255885 0413-4255885 025-86331599 021-65877348 021-39506392 025-82090500 3000m 3 / / 36

2L 2L 2L 2L 2L 2L 2L 2L 2L 2L 2L 2L 21.8 0.000698 1.8 0.0000684 32 0.00096 2.1 0.0000714 20.7 0.000704 10 0.00035 24.3 0.000923 2.1 0.0000861 28.6 0.00112 2.5 0.0000975 37

2016.9.17 2016.9.18 mg/m 3 1 2 3 1 2 3 0.25 2L 2L 2L 2L 2L 2L 0.20 0.02L 0.02L 0.024 0.051 0.022 0.041 1 2 TVOC 3.0 0.0024 0.856 0.842 0.0128 0.600 0.696 0.25 2L 2L 2L 2L 2L 2L 0.20 0.02L 0.02L 0.044 0.02L 0.141 0.040 TVOC 3.0 0.0511 1.14 0.872 0.263 0.749 0.609 0.25 2L 2L 2L 2L 2L 2L 0.20 0.02L 0.02L 0.02L 0.02L 0.049 0.02L TVOC 3.0 0.136 0.770 0.868 0.265 0.657 0.692 38

ph COD NH 3 -N SS ph COD 2016.9.18 NH 3 -N SS 39

ph 7.02 7.03 7.01 7.03 COD 1840 1870 1810 1830 NH 3 -N 31.8 31 31.4 32.5 SS 18 16 14 14 4690 4390 4850 4270 619 784 733 785 ph 7.02 7.04 7.05 7.05 COD 1730 1760 1980 1720 2016.9.18 NH 3 -N 30.5 31.1 32.2 32.8 SS 17 15 14 14 4690 4400 4850 4270 799 749 734 758 40

56.7/ 51.1 / 57.4/ 50.7 / 54.3/ 50.9 / 54.7/ 51.3 / 55.0/ 51.6 / 54.8/ 50.4 / 53.9/ 50.5 / 53.6/ 50.1 / 55.9/ 50.6 / 55.6/ 50.4 / 53.9/ 49.8 / 54.2/ 48.9 / 54.7/ 49.4 / 54.3/ 49.9 / 54.0/ 50.1 / 54.5/ 50.3 / 1 41

2 13 [2000]38 3 4 42

CODSSpH TP (1) (2) 43

COD / / / / 0.9360.753 0.0220.022 / 0.9360.753 0.0220.022 SS / / / / / 0.1350.135 1.228/ 0.012 / 0.1350.135 1.228/ 0.012 15052.8t/a COD0.936t/a 0.022t/aSS0.135t/a 1.228t/a 15052.8t/aCOD0.753t/a 0.022t/aSS0.135t/a 1.228t/a 0.012t/a 44

100 9.1-1 kg/h m m TVOC 1.53 36.01 0.1 85.58 100 GB/T13201-91 45

1 1# COD 1 1# COD 1 2# 1 1# 2015 814.7 46

3000 135 39 4 / 2006 8 15052.8t/a COD0.936t/a 0.022t/aSS0.135t/a 1.228t/a 15052.8t/aCOD0.753/a 0.022t/aSS0.135t/a 1.228t/a 0.012t/a 100 48

10 11 GB18597-2001 GB18599-2001 12HJ/T 1692004 13 / 54

1 2 13 [2000]38 3 4 1 2 SO 2 NOxVOCs COD PbCr HgCdAs 1/ 2/ GB/T13201-91 1 2 3 55

4 56