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3 EcoSEC GPC Differential weight fraction Cumulative weight fraction Log molar mass ml/minri IMPP Detector response (mv) IMPP THF 11 DMSO Retention time (minutes) 12 TSKgel SuperH3000, 3 µm, 6.0 m ID 15 cm 2 THF 0.6 ml/min RI (EcoSEC GPC system) 35 C 20 µl IMPP 1

4 PC/ABS RIUV PC/ABS GPC TSKgel SuperMultiporeHZ-M, 4 µm, 4.6 mm ID 15 cm 2 THF 0.35 ml/min RI (EcoSEC GPC system) UV (EcoSEC GPC 254 nm) 35 C 10 µl PC/ABS at 1 g/l 1 PC/ABS M w M z PDI a 4 b ± ± ± 3, ± ± ± ± 1, ± ,064 ± ± ± 1, ± ,364 ± ± ± 1, ± Striegel, A.M.; Yau, W.W.; Kirkland, J.J.; Bly, D.D. Modern Size-Exclusion Liquid Chromatography 2nd ed; Wiley: New York, Mori, S.; Barth, H.G. Size Exclusion Chromatography; Springer: New York,

5 4 RIPHB PHB APHB PHB BGPC TSKgel SuperHZM-M, 3 & 5 µm, 4.6 mm ID 15 cm 2 Chloroform 0.30 ml/min RI (EcoSEC GPC system) 35 C 25 µl polyhydroxybutyrate (PHB) at 1g/L Sample M w M z PDI PHB A b ± ± ± ± 0.38 PHB B ± ± ± ± 0.30 a 3

6 5 S S R R C 6 H 13 poly(3-hexylthiophene-b-[1-hexene]) C 6 H 13 poly(3-hexylthiophene) poly(1-hexene) 4

7 6 RIUV -b- 1- GPC 7RIUV 3- GPC 8RIGPC TSKgel SuperMultipore 2 + TSKgel mixed bed x2 THF 0.35 ml/min RI (EcoSEC GPC system) UV (EcoSEC GPC 254 and 350 nm) 40 C 10 µl poly(3-hexylthiophene-b-[1-hexane]) 5

8 TSKgel GMHHR-H, mixed bed, 7.8 mm ID 30 cm 2 DMF with 0.01% LiBr 1.0 ml/min RI (EcoSEC GPC System), MALS (Wyatt DAWN 8+) 50 C 100 µl thermoplastic polyurethanes 6

9 10 RI VISCGPC TSKgel GMPWXL, 13 µm, 7.8 mm ID 30 cm 2 H 2O with 0.1 mol/l NaNO 3 and 0.02% NaN ml/min RI (EcoSEC GPC System), VISC (Wyatt ViscoStar ) 35 C 250 µl hyaluronic acid 3 Sample M w M z PDI a [η] (ml/g) R η (nm) Non-crosslinked , Crosslinked

10 12 GPC TSKgel SuperAWM-H, 9 µm, 6.0 mm ID 15 cm 2 HFIP 0.35 ml/min RI (EcoSEC GPC System) 40 C 20 µl virgin and recycled nylon 4 13 M w ± 46 b ± ± ± 210 M z ± ± 1,105 PDI a 1.41 ± ± Crespo, J.E; Parres, E.; Peydro, M.A.; Navarro, R., 2013, 53,

11 14 RIMALS GPC TSKgel SuperMultiporeHZ-M, 4 µm, 4.6 mm ID 15 cm 3 THF 0.35 ml/min RI (EcoSEC GPC System), MALS (Wyatt DAWN 8+) 35 C 30 µl rubber 5 RI MALS M w M z ± 0.02 b ± ± ± ± ± ± ± ± ± ± ± PDI a 9

12 15HECGPC TSKgel SuperMultiporePW-H, 8 µm, 4.6 mm ID 15 cm 3 H 2O with 0.1 mol/l NaNO 3 and 0.02% NaN ml/min RI (EcoSEC GPC System) 35 C 25 µl hydroxyethylcellulose 6 HEC HEC M w M z ± 0.04 b ± ± ± ± ± ± ± ± ± ± ± ± ± ± ± 0.23 PDI a 10

13 16PMMA GPC TSKgel SuperMultiporeHZ-M, 4 µm, 4.6 mm ID 15 cm 2 + TSKgel SuperHZ2500, 3 µm, 4.6 mm ID 15 cm 1 THF 0.35 ml/min RI (EcoSEC GPC System) 35 C 20 µl PMMA based molding resin M w M z ± 0.15 b ± ± ± ± ± ± ± 0.03 PDI a 11

14 1730 GPC TSKgel GMHXL, 9 µm, 7.8 mm ID 30 cm 1 THF 1.0 ml/min RI (EcoSEC GPC System) 35 C 100 µl synthetic rubber 18 GPC TSKgel GMHXL, 9 µm, 7.8 mm ID 30 cm 2 DMF with 0.02 mol/l LiBr 1.0 ml/min RI (EcoSEC GPC System) 35 C 100 µl polyimides M w M z A ± 0.01 b ± ± ± 0.02 B ± ± ± ± 0.01 C ± ± ± ± 0.01 PDI a 12

15 ±0.01 b ± ± ± M w ± ± ± ± M z PDI a ± ± ± ± ± ± ± ± GPC TSKgel SuperHZ4000, 3 µm, 4.6 mm ID 15 cm + TSKgel SuperHZ3000, 3 µm, 4.6 mm ID 15 cm + TSKgel SuperHZ2000, 3 µm, 4.6 mm ID 15 cm THF 0.35 ml/min RI (EcoSEC GPC System) 35 C 10 µl block copolymer 4 Kabanov, A.V.; Okano, T. Challenges in Polymer Therapeutics. In, Volume 519; Maeda, H.; Kabanov, A.V.; Kataoka, K., Okano, T. eds.; Academic Press: New York, 2003; pp

16 1.SBP R G R H Detection Method RI 250 nm 278 nm 310 nm M W a ± b ± ± ± R G,z (nm) a 43 ± 1 43 ± 1 45 ± 1 42 ± 1 R H,z(nm) c 53 ± 1 43 ±1 43 ± 1 44 ± 1 [η] W (dl/g) 3.5 ± ± ± ± GPC 1.0 RI QELS VISC M for RI M for UV TSKgel GMPWXL, 13 µm, 7.8 mm ID 30 cm 2 Detector response (V) nm 278 nm & 250 nm 250 nm 278 nm RI 310 nm 1.0x10 6 Molar mass H 2O with 0.05 mol/l NaNO 3 and 0.1% NaN ml/min RI (EcoSEC GPC System), UV (EcoSEC GPC 310, 278, and 250 nm), MALS (Wyatt DAWN HELEOS II), QELS (Wyatt QELS TM ), VISC (Wyatt ViscoStar) 35 C 200 µl sugar beet pectin Retention time (minutes) Fishman, M. L.; Chau, H. K.; Qi, P. X.; Hotchkiss Jr., A. T.; Yadav, M. P. 2013, 92, (2),

17 22 RI UV GPC TSKgel SuperMultiporeHZ-M, 4 µm, 4.6 mm ID 15 cm 2 THF 0.35 ml/min RI (EcoSEC GPC System) UV (EcoSEC GPC 254 nm) 35 C 10 µl polycarbonate based resin 11 M w M z PDI a ± 335 b ± ± 3, ± ± ± ± 1, ± ,064 ± ± ± 1, ± ,364 ± ± ± 1, ±

18 12 RI MALS VISC Detection Method M w M z PDI a RI ± b ± ± ± 0.04 MALS ± ± ± ± 0.18 VISC ± ± ± ± GPC TSKgel SuperMultiporeHZ-H, 6 µm, 4.6 mm ID 15 cm 3 THF 0.35 ml/min RI (EcoSEC GPC System), MALS (PSS SLD 7000 Light Scattering Photometer), VISC (PSS ETA-2010 Viscosity detector) 35 C 25 µl synthetic rubber 16

19 HO 1 O OR hυ, H 2 O O O 3 OR OH H 2 O + HO O HO O HO O 13 M w PDI % PEG % PEG 8, GPC M w Detector response (mv) min MM 29,525 5 min MM 7, min MM 3, min MM 2, min MM 2, min MM 1, min MM min MM min MM min MM 149 MM is calculated according to polystyrene standard TSKgel SuperH3000, 3 µm, 6.0 mm ID x 15 cm x 2 + TSKgel SuperH4000, 3 µm, 6.0 mm ID x 15 cm x 1 chloroform 0.38 ml/min UV (EcoSEC GPC 278 nm) 40 C 10 µl alkoxyphenacyl polycarbonate homopolymer, 1-2 mg/ml Retention time (minutes) 6 Sun, S.; Chamsaz, E. A.; Joy, A.., 2012, 1 (10), Givens, R. S.; Heger, D.; Hellrung, B.; Kamdzhilov, Y.; Mac, M.; Conrad, P. G.; Cope, E.; Lee, J. I.; Mata-Segreda, J. F.; Schowen, R. L.; Wirz, J. J. 2008, 130,

20 26 A & B: TSKgel SuperMultipore HZ-M, 4 µm, 4.6 mm ID 15 cm 2 C: TSKgel SuperMultipore HZ-M, 4 µm, 4.6 mm ID 15 cm 2 + TSKgel SuperH TSKgel SuperH4000, 3 µm, 4.6 mm ID 15 cm 1 THF 0.35 ml/min RI (EcoSEC GPC System), MALS (Wyatt minidawn TM TREOS ), VISC (Wyatt ViscoStar II) 40 C A & B: poly(norbornene-exo-anhydride) (P1) C: norbornene-exo-anhydride with cyclooctadiene 8 Tuten, B.T.; Chao, D.; Lyon C.K.; Berda, E.B. 2012, 3,

21 14 b b M w PDI b (A) 10 (B) ± % ± % 1.14 ± % (A) 60 (B) ± % ± % 1.22 ± % (A) 40 (B) ± % ± % 1.25 ± % (C) ± % ± % 1.21 ± % 27 poly-β-alkylalanoids Detector response (mv) Detector response (mv) (A) 60 (B) 20 (B) 40 (C) Retention time (minutes) (A) 10 (B) 40 (C) Retention time (minutes) Detector response (mv) Detector response (mv) Retention time (minutes) Retention time (minutes) TSKgel GMHHR-M, 5 µm, 4.6 mm ID 15 cm 2 packed in HFIP HFIP containing 5 mmol/l sodium trifluoroacetate 0.35 ml/min RI (EcoSEC GPC System) 40 C 10 µl selection of poly-ß-alkylalanoid samples 9 Robert, E. C.; Bruessau, R.; Dubois, J.; Jacques, B.; Meijerink, N.; Nguyen, T. Q.; Niehaus, D. E.; Tobisch, W. A. 2004, 76,

22 28 TSKgel SuperH3000, 3 µm, 6.0 mm ID 15 cm 2 THF 0.30 ml/min RI (EcoSEC GPC System) 35 C 20 µl modified polyurethane prepolymer, 10 mg/ml ml/minthf Peak M w M z PDI a All 4,199 ± 46 b 2,643 ± 19 2,011 ± 16 1,387 ± ± ± ± ± ± ± 9 4,606 ± 67 2,655 ± 18 2,024 ± 16 1,403 ± ± ± ± ± ± 1 1,531 ± 31 5,214 ± 109 2,667 ± 18 2,038 ± 16 1,418 ± ± ± ± ± ± 1 2,873 ± ± ± ± ± ± ± ± ± ± ±

23 29 -b- sps-b-fpi x y F F H z 16 sps-b-fpips-b-pi PDI Series a PS-b-Pl sps-b-fpl x x x x a series 1 in acid form; series 2 in Na form SO 3 (H, Na) 30 -b- A PS-b-f PI: =2.5 x 10 4, PDI=1.08 B PS-b-f PI: =6.0 x 10 4, PDI=1.05 Detector response PS-b-P I: =2.1 x 10 4, PDI=1.04 PS: =9.5 x 10 3, PDI=1.05 PS: =1.0 x 10 4, PDI=1.05 PS-b-P I: =4.6 x 10 4, PDI= Retention time (minutes) TSKgel SuperMultiporeHZ-M, 4 µm, 4.6 mm ID x 15 cm THF 0.35 ml/min RI (EcoSEC GPC System) 35 C 20 µl A. series 1, table 13 B. series 2, table Wang, X.; Hong, K.; Baskaran, D.; Goswami, M.; Sumpter, B.; Mays, J., 2011, 7,

24 101606BS-NO.3023 B

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<4D6963726F736F667420576F7264202D2031A1A2A3A8484A3534342D32303136A3A9B9CCB6A8CEDBC8BED4B4B7CFC6F820C1F2CBE1CEEDB5C4B2E2B6A820C0EBD7D3C9ABC6D7B7A82E646F63> 中华人民共和国国家环境保护标准 HJ 544-2016 代替 HJ 544-2009 固定污染源废气硫酸雾的测定离子色谱法 Stationary source emission-determination of sulfuric acid mist-ion chromatography ( 发布稿 ) 本电子版为发布稿