頁數 (Page): 1 of 13 以下測試樣品係由申請廠商所提供及確認 (The following sample(s) was/were submitted and identified by/on behalf of the applicant as): 樣品名稱 (Sample Description) 樣品型號 (Style/Item No.) 收件日期 (Sample Receiving Date) 測試期間 (Testing Period) : : : : ================================================================================================================ 測試需求 (Test Requested): (1) LEAD FREE SOLDER ( 無鉛銲錫 ) 4N PURE Tin ELECTROPLATING ANODE BALL 2017/02/15 2017/02/15 TO 2017/02/21 依據客戶指定, 參考 RoHS 2011/65/EU Annex II 及其修訂指令 (EU) 2015/863 測試鎘 鉛 汞 六價鉻 多溴聯苯 多溴聯苯醚, DBP, BBP, DEHP, DIBP. (As specified by client, with reference to RoHS 2011/65/EU Annex II and amending Directive (EU) 2015/863 to determine Cadmium, Lead, Mercury, Cr(VI), PBBs, PBDEs, DBP, BBP, DEHP, DIBP contents in the submitted sample.) (2) 其他測試項目請見下一頁. (Please refer to next pages for the other item(s).) 測試結果 (Test Results) : 請見下一頁 (Please refer to next pages).
頁數 (Page): 2 of 13 測試結果 (Test Results) 測試部位 (PART NAME)No.1 : 銀色金屬 (SILVER COLORED METAL) 鎘 / Cadmium (Cd) 鉛 / Lead (Pb) 測試項目 (Test Items) 單位 (Unit) 測試方法 (Method) 參考 IEC 62321-5 (2013), 以感應耦合電漿原子發射光譜儀檢測. / With reference to IEC 62321-5 (2013) and performed by ICP-AES. 方法偵測極限值 (MDL) 結果 (Result) No.1 2 n.d. 2 25.7 汞 / Mercury (Hg) 參考 IEC 62321-4 (2013), 以感應耦合電漿原子發射光譜儀檢測. / With reference to IEC 62321-4 (2013) and performed by ICP-AES. 2 n.d. 六價鉻 / Hexavalent Chromium Cr(VI)(#2) µg/cm² 參考 IEC 62321-7-1 (2015), 以 UV-VIS 檢測. / With reference to IEC 62321-7-1 (2015) and performed by UV-VIS. 0.10 n.d. 多溴聯苯總和 / Sum of PBBs - n.d. 一溴聯苯 / Monobromobiphenyl 二溴聯苯 / Dibromobiphenyl 三溴聯苯 / Tribromobiphenyl 四溴聯苯 / Tetrabromobiphenyl 五溴聯苯 / Pentabromobiphenyl 六溴聯苯 / Hexabromobiphenyl 七溴聯苯 / Heptabromobiphenyl 參考 IEC 62321-6 (2015), 以氣相層析 / 質譜儀檢測. / With reference to IEC 62321-6 (2015) and performed by GC/MS. 八溴聯苯 / Octabromobiphenyl 九溴聯苯 / Nonabromobiphenyl 十溴聯苯 / Decabromobiphenyl
頁數 (Page): 3 of 13 測試項目 (Test Items) 多溴聯苯醚總和 / Sum of PBDEs 單位 (Unit) 測試方法 (Method) 方法偵測極限值 (MDL) 結果 (Result) No.1 - n.d. 一溴聯苯醚 / Monobromodiphenyl ether 二溴聯苯醚 / Dibromodiphenyl ether 三溴聯苯醚 / Tribromodiphenyl ether 四溴聯苯醚 / Tetrabromodiphenyl ether 五溴聯苯醚 / Pentabromodiphenyl ether 六溴聯苯醚 / Hexabromodiphenyl ether 七溴聯苯醚 / Heptabromodiphenyl ether 參考 IEC 62321-6 (2015), 以氣相層析 / 質譜儀檢測. / With reference to IEC 62321-6 (2015) and performed by GC/MS. 八溴聯苯醚 / Octabromodiphenyl ether 九溴聯苯醚 / Nonabromodiphenyl ether 十溴聯苯醚 / Decabromodiphenyl ether 鄰苯二甲酸丁苯甲酯 / BBP (Butyl Benzyl phthalate) (CAS No.: 85-68-7) 鄰苯二甲酸二丁酯 / DBP (Dibutyl phthalate) (CAS No.: 84-74-2) 鄰苯二甲酸二 (2- 乙基己基 ) 酯 / DEHP (Di- (2-ethylhexyl) phthalate) (CAS No.: 117-81-7) 鄰苯二甲酸二異丁酯 / DIBP (Di-isobutyl phthalate) (CAS No.: 84-69-5) 鄰苯二甲酸二異癸酯 / DIDP (Di-isodecyl phthalate) (CAS No.: 26761-40-0; 68515-49-1) 參考 IEC 62321-8/CD (2013), 以氣相層析儀 / 質譜儀檢測. / With reference to IEC 62321-8/CD (2013). Analysis was performed by GC/MS. 鄰苯二甲酸二異壬酯 / DINP (Di-isononyl phthalate) (CAS No.: 28553-12-0; 68515-48-0) 鄰苯二甲酸二正辛酯 / DNOP (Di-n-octyl phthalate) (CAS No.: 117-84-0)
頁數 (Page): 4 of 13 測試項目 (Test Items) 六溴環十二烷及所有主要被辨別出的異構物 / Hexabromocyclododecane (HBCDD) and all major diastereoisomers identified (α- HBCDD, β- HBCDD, γ- HBCDD) (CAS No.: 25637-99-4 and 3194-55-6 (134237-51-7, 134237-50-6, 134237-52-8)) 鹵素 / Halogen 鹵素 ( 氟 ) / Halogen-Fluorine (F) (CAS No.: 14762-94-8) 鹵素 ( 氯 ) / Halogen-Chlorine (Cl) (CAS No.: 22537-15-1) 鹵素 ( 溴 ) / Halogen-Bromine (Br) (CAS No.: 10097-32-2) 鹵素 ( 碘 ) / Halogen-Iodine (I) (CAS No.: 14362-44-8) 單位 (Unit) 聚氯乙烯 / PVC ** 銻 / Antimony (Sb) 測試方法 (Method) 參考 IEC 62321 (2008), 以氣相層析 / 質譜儀檢測. / With reference to IEC 62321 (2008). Analysis was performed by GC/MS. 參考 BS EN 14582 (2007), 以離子層析儀分析. / With reference to BS EN 14582 (2007). Analysis was performed by IC. 以紅外光譜分析及焰色法檢測. / Analysis was performed by FTIR and FLAME Test. 參考 US EPA 3050B (1996), 以感應耦合電漿原子發射光譜儀檢測. / With reference to US EPA 3050B (1996). Analysis was performed by ICP-AES. 方法偵測極限值 (MDL) 結果 (Result) No.1 - Negative 2 n.d. 鈹 / Beryllium (Be) 參考 US EPA 3050B (1996), 以感應耦合電漿原子發射光譜儀檢測. / With reference to US EPA 3050B (1996). Analysis was performed by ICP-AES. 2 n.d.
頁數 (Page): 5 of 13 備註 (Note): 1. = ppm;0.1wt% = 1000ppm 2. n.d. = Not Detected ( 未檢出 ) 3. MDL = Method Detection Limit ( 方法偵測極限值 ) 4. "-" = Not Regulated ( 無規格值 ) 5. **= Qualitative analysis (No Unit) 定性分析 ( 無單位 ) 6. Negative = Undetectable 陰性 ( 未偵測到 ); Positive = Detectable 陽性 ( 已偵測到 ) 7. (#2) = a. 當六價鉻結果大於 0.13 µg/cm², 表示樣品表層含有六價鉻. / The sample is positive for Cr(VI) if the Cr(VI) concentration is greater than 0.13 µg/cm². The sample coating is considered to contain Cr(VI). b. 當六價鉻結果為 n.d. ( 濃度小於 0.10 µg/cm²), 表示表層不含六價鉻. / The sample is negative for Cr(VI) if Cr(VI) is n.d. (concentration less than 0.10 µg/cm²). The coating is considered a non-cr(vi) based coating c. 當六價鉻結果介於 0.10 及 0.13 µg/cm² 時, 無法確定塗層是否含有六價鉻. / The result between 0.10 µg/cm² and 0.13 µg/cm² is considered to be inconclusive - unavoidable coating variations may influence the determination.
頁數 (Page): 6 of 13 #flow 重金屬流程圖 / Analytical flow chart of Heavy Metal 根據以下的流程圖之條件, 樣品已完全溶解 ( 六價鉻測試方法除外 ) These samples were dissolved totally by pre-conditioning method according to below flow chart. (Cr 6+ test method excluded) 測試人員 : 王志瑋 / Technician : JR Wang 測試負責人 : 張啟興 / Supervisor: Troy Chang 剪裁 製備樣品 / Cutting Preparation 測試樣品重量 / Sample Measurement 鉛 Pb 鎘 Cd 依據不同樣品的材質而以適當的酸進行消化 ( 如下表所示 ) / Acid digestion by suitable acid depended on different sample material (as below table) 汞 Hg 硝酸 / 鹽酸 / 氫氟酸的微波消化 / Microwave digestion with HNO 3/HCl/HF 六價鉻 Cr 6+ (Note**) 添加適量消化液 / Add appropriate amount of digestion reagent 溶液 / Solution 過濾 / Filtration 殘渣 / Residue 加熱至適當溫度進行消化萃取 / Heat to appropriate temperature to extract 感應耦合電漿原子發射光譜儀 / ICP-AES 1) 鹼熔融法 / Alkali Fusion 2) 鹽酸溶解 / HCl to dissolve 冷卻後過濾樣品 / Cool, filter digestate through filter 樣品材質 / Sample Material 消化酸液種類 / Digestion Acid 鋼, 銅, 鋁, 焊錫 / Steel, copper, aluminum, solder 王水, 硝酸, 鹽酸, 氫氟酸, 雙氧水 / Aqua regia, HNO 3, HCl, HF, H 2O 2 玻璃 / Glass 硝酸, 氫氟酸 / HNO 3/HF 金, 鉑, 鈀, 陶瓷 / 王水 / Aqua regia Gold, platinum, palladium, ceramic 銀 / Silver 硝酸 / HNO 3 塑膠 / Plastic 硫酸, 雙氧水, 硝酸, 鹽酸 / H 2SO 4, H 2O 2, HNO 3, HCl 其他 / Others 加入適當的試劑至完全溶解 / Added appropriate reagent to total digestion 加入發色劑顯色 / Add diphenyl-carbazide for color development 以紫外光 - 可見光光譜儀, 量測樣品溶液在 540 nm 的吸收度 / measure the absorbance at 540 nm by UV-VIS Note** (For IEC 62321) (1) 針對非金屬材料加入鹼性消化液, 加熱至 90~95 萃取. / For non-metallic material, add alkaline digestion reagent and heat to 90~95. (2) 針對金屬材料加入純水, 加熱至沸騰萃取. / For metallic material, add pure water and heat to boiling.
頁數 (Page): 7 of 13 多溴聯苯 / 多溴聯苯醚分析流程圖 / Analytical flow chart - PBB/PBDE 測試人員 : 凃雅苓 / Technician: Yaling Tu 測試負責人 : 張啟興 / Supervisor: Troy Chang 初次測試程序 / First testing process 選擇性篩檢程序 / Optional screen process 確認程序 / Confirmation process Sample / 樣品 Sample pretreatment / 樣品前處理 Screen analysis / 初篩分析 Sample extraction 樣品萃取 / Soxhlet method 索式萃取法 Concentrate/Dilute Extracted solution 萃取液濃縮 / 稀釋 Filter / 萃取液過濾 Analysis by GC/MS / 氣相層析質譜儀分析 Issue Report 撰打報告
頁數 (Page): 8 of 13 可塑劑分析流程圖 / Analytical flow chart - Phthalate 測試人員 : 徐毓明 / Technician: Andy Shu 測試負責人 : 張啟興 / Supervisor : Troy Chang 測試方法 /Test method: IEC 62321-8 樣品前處理 / 分樣 / Sample pretreatment/separation 樣品以 THF 四氫呋喃溶解萃取 / Sample dissolved/extracted by THF 萃取液稀釋 / Dilute Extracted solution 氣相層析質譜儀分析 / Analysis was performed by GC/MS 數據 / Data
頁數 (Page): 9 of 13 六溴環十二烷分析流程圖 / Analytical flow chart - HBCDD 測試人員 : 凃雅苓 / Technician: Yaling Tu 測試負責人 : 張啟興 / Supervisor: Troy Chang 樣品前處理 / Sample pretreatment 樣品萃取 Sample extraction / 超音波萃取法 Ultrasonic method 萃取液濃縮 / 稀釋 / Concentrate/Dilute Extracted solution 萃取液過濾 / Filter 以氣相層析 / 質譜儀分析 / Analysis was performed by GC/MS 數據 / Data
頁數 (Page): 10 of 13 鹵素分析流程圖 / Analytical flow chart - Halogen 測試人員 : 陳恩臻 / Technician: Rita Chen 測試負責人 : 張啟興 / Supervisor: Troy Chang 樣品前處理 / 分樣 / Sample pretreatment/separation 秤重及將樣品放入樣品槽中 / Weighting and putting sample in cell 燃燒彈 / 吸收 Oxygen Bomb Combustion / Absorption 稀釋至固定體積 / Dilution to fixed volume 離子層析儀分析 / Analysis was performed by IC
頁數 (Page): 11 of 13 聚氯乙烯物質判定分析流程圖 / Analysis flow chart - PVC 測試人員 : 凃雅苓 / Technician: Yaling Tu 測試負責人 : 張啟興 / Supervisor: Troy Chang 樣品前處理 / Sample pre-treatment 焰色法檢測 / Flame test 紅外光譜分析 / Sample analyzed by FTIR 確認 C-Cl 鍵波數 / Check wave-number of C-Cl bonding 數據 / Data
頁數 (Page): 12 of 13 根據以下的流程圖之條件, 樣品已完全溶解 / These samples were dissolved totally by pre-conditioning method according to below flow chart. 測試人員 : 王志瑋 / Technician: JR Wang 測試負責人 : 張啟興 / Supervisor: Troy Chang 元素以 ICP-AES 分析的消化流程圖 (Flow Chart of digestion for the elements analysis performed by ICP-AES) 剪裁 製備樣品 / Cutting Preparation 測試樣品重量 / Sample Measurement 依據不同樣品的材質而以適當的酸進行消化 ( 如下表所示 ) / Acid digestion by suitable acid depended on different sample material (as below table) 溶液 / Solution 過濾 / Filtration 殘渣 / Residue 感應耦合電漿原子發射光譜儀 / ICP-AES 1) 鹼熔融法 / Alkali Fusion 2) 鹽酸溶解 / HCl to dissolve 鋼, 銅, 鋁, 焊錫 / Steel, copper, aluminum, solder 王水, 硝酸, 鹽酸, 氫氟酸, 雙氧水 / Aqua regia, HNO 3, HCl, HF, H 2 O 2 玻璃 / Glass 硝酸, 氫氟酸 / HNO 3 /HF 金, 鉑, 鈀, 陶瓷 / Gold, platinum, palladium, ceramic 王水 / Aqua regia 銀 / Silver 硝酸 / HNO 3 塑膠 / Plastic 硫酸, 雙氧水, 硝酸, 鹽酸 / H 2 SO 4, H 2 O 2, HNO 3, HCl 其他 / Others 加入適當的試劑至完全溶解 / Added appropriate reagent to total digestion
頁數 (Page): 13 of 13 #PIC * 照片中如有箭頭標示, 則表示為實際檢測之樣品 / 部位. * (The tested sample / part is marked by an arrow if it's shown on the photo.) ** 報告結尾 (End of Report) **