3 451 INCAX SIGHT JSM 6700S ~ m ~ m ~ m 2% ~ 25% 1 < Fig. 1 Location map of Beier Depr

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1 ACTA SEDIMENTOLOGICA SINICA Vol. 31 No. 3 Jun S X- 25% Ⅰ Ⅱ CO % CO zhoubingtale@ hotmail. com liuli0892@ vip. sina. com P A 0 CO CO 2 CO 2 CO 2 2 mineral trapping 3 CO 2 4 CO 2 CO 2 CO 2 CO CO ~ 10 CO ~ CO 2 14 J 3 b CO 2 K 1 x K 1 t K 1 15 n K 1 d K 1 y 16 BGS 17 K 2 q Eh Q

2 3 451 INCAX SIGHT JSM 6700S ~ m ~ m ~ m 2% ~ 25% 1 < Fig. 1 Location map of Beier Depression in the Hailar Basin μm X 3 and the wells included in this study Location of Beier 81% ~ 94% Depression is modified after Meng et al μm geotectonic units are modified after Yang et al % ~ 10% OLYMPUS 1% ~ 4% % ~ 81% S 0. 1 ~ 0. 5 mm < 2 μm X D /max % ~ 28% 1 4% ~ 16% 3% ~ 17% 2 a c b c d e f % ~ 55% X 8 2

3 Fig 2 2 Sketch map of volcanic quartz s form and dawsonite replacing grains 片钠铝石 3d 2l 5% ~ 25% 15% 2 NaAl OH 2 CO 3 2g h 2i 石英 0. 1% ~ 0. 5% ~ 50 μm 3c 100 μm 2 μm 2j k

4 3 453 Table 1 1 % Content of volcanic material and terrigenous deposit in dawsonite-bearing tuffite % /m Table 2 2 Content of authigenic minerals and matrix in dawsonite-bearing sandstone /m /% /% /% /% /% /% / / / / 15 1 / / / 18 2 / # / / 5 / / / 15 / / / / / 12 / / / / / / 20 2 / / / 22 2 / / / / / # 2-7

沉 454 图3 积学报第 31 卷含片钠铝石沉凝灰岩内自生矿物及共生关系典型照片 a 菱铁矿-Ⅰ Sid-Ⅰ 分布在填隙物中德 2 井 910 68 m 大磨拐河组 b 隐晶质高岭石基质 Ka 德 2 井 911 98 m 大磨拐河组背 910 68 m 伊敏组 d 片钠铝石完全交代颗粒德 6 井 929 25 m 伊散射照片 c 石英次生加大 OQ 被片钠铝石 Daw 交代

5 沉 454 图3 积学报第 31 卷含片钠铝石沉凝灰岩内自生矿物及共生关系典型照片 a 菱铁矿-Ⅰ Sid-Ⅰ 分布在填隙物中德 2 井 m 大磨拐河组 b 隐晶质高岭石基质 Ka 德 2 井 m 大磨拐河组背 m 伊敏组 d 片钠铝石完全交代颗粒德 6 井 m 伊散射照片 c 石英次生加大 OQ 被片钠铝石 Daw 交代德 6 井 m 大磨拐河组 f 片钠铝石被铁白云石蓝色 Ank 交代铁白云石被菱铁敏组 e 片钠铝石被方解石 Cc 交代德 2 井 m 伊敏组染色薄片矿-Ⅱ Sid-Ⅱ 交代德 6 井 Fig 3 Typical micrographs of authigenic minerals and paragenetic relationship in dawsonite-bearing tuffite

6 方解石 1% ~ 2% 2 S 50 ~ 300 μm Ⅰ 3e 3a Ⅱ 铁白云石 100 ~ 500 μm Ⅱ 3f 1% ~ 6% 38% 2 S 黏土矿物 3f < 2 μm X 3 81% ~ 94% / 6% ~ 11% 8% ~ 19% / Ⅱ 3f 5% Ⅱ 菱铁矿 2 /3 1% 65% 2 Ⅰ Ⅱ Ⅰ 20 ~ 60 μm S 3b Table 3 3 /m Relative clay content of dawsonite-bearing tuffite /% / % S I /S I K I /S / / / / / / / / / / / / / / / / / / / / / / / / / / / / / 8 92 /

7 沥青 % ~ 5% CO 2 Ⅱ Ⅱ 4 NaAlCO 3 OH 2 + 3SiO 2 + K + 1 Fig 4 Paragenetic sequence of dawsonite-bearing tuffite Na Al CO 2 CO 2 CO 2 NaAlSi 3 O 8 + CO 2 CO 2 OH 2 + 3SiO 2 + H 2 O = NaAlCO Springerville St. Johns CaAl 2 Si 2 O 8 + 2Na + 2CO 2 + 2H 2 O = CO BGS precursor 2g h CO 2 37 KAlSi 3 O 8 + Na + + CO 2 + H 2 O = 2NaAlCO 3 OH 2 + 2SiO 2 + Ca SiO 2 CO 2 CO CO 2 CO 2 CO CO 2 Al HCO - 3 CO 2 CO 2 CO CO 2 35 CO 2 31 CO 2 CO 2

8 Ca Mg Fe Limantseva 46 CO 2 Al 2 Si 2 O 5 OH 4 + 2HCO Na + = 2NaAlCO 3 OH 2 + 2SiO 2 + H 2 O 4 Na Al BGS 3. 5% 13. 4% 17 8% 15 Springerville St. Johns 22-X1 State HCO - 3 Na Al CO 2 1% ~ 17% 16 Ca Mg Fe 1% ~ 17% 33 5% ~ 25% 15. 5% CO 2 Ⅱ San Jorge Fe Ca 3. 3% ~ 38. 9% 18 Mg Fe 10% ~ 23% Ca Mg FeCO 3 20 Worden 15 CO 2 CO % ~ 22% 1% ~ Ⅰ 12% Ⅱ 3 25% CO 2 CO 2 CO 2

9 a United Kingdom Perspective J. Oil & Gas Science and Technology-Rev. IFP Stevens S H Pearce J M Rigg A A J. Natural analogs for geologic storage of CO 2 An Integrated global research program C Conference Proceedings CD 1st National Conference on Carbon Sequestration Washington D C Xu T F Apps J A Pruess K. Numerical simulation to study mineral trapping for CO 2 disposal in deep aquifers J. Applied Geochemis- try References 1 IPCC Metz B Davidson O de Coninck H et al. IPCC Special report on carbon dioxide capture and storage C. New York Cambridge University Press IPCC. Climate Change 2007 Synthesis Report. Contribution of Working Groups I II and III to the Fourth Assessment Report of the Intergovernmental Panel on Climate Change C. Geneva Switzerland Intergovernmental Panel on Climate Change Gunter W D Perkins E H McCann T G. Aquifer disposal of CO 2 -rich gases reaction design for added capacity J. Energy Conversion and Management Oelkers E H Cole D R. Carbon dioxide sequestration a solution to a global problem J. Elements Oelkers E H Gislason S R Matter J. Mineral carbonation of CO 2 J. Elements Gislasona S R Wolff-Boenischa D Stefanssona A et al. Mineral sequestration of carbon dioxide in basalt A pre-injection overview of the CarbFix project J. International Journal of Greenhouse Gas Control Pettijohn F J. Sedimentary Rocks Third edition M. New York Harper and Row Blockley S P E Pyne-O'Donnella S D F Lowe J J et al. A new and less destructive laboratory procedure for the physical separation of distal glass tephra shards from sediments J. Quaternary Science Reviews White A F Claassen H C Benson L V. The effect of dissolution of volcanic glass on the water chemistry in a tuffaceous aquifer Rainer Mesa Nevada C. US Geology Survey Water-Supply Paper J Meng Qian Liu Li J Wang Jianwei Bao Zhidong Chen Mengjin et al. Differentiation of sandstones tuff fillings and its effect on porosity An example from the Paleozoic sandstones in Northwestern Ordos J. Chinese Journal of Geology Qu Xiyu et al. Reservoir characteristics and processes controlling porosity in Tongbomiao Nantun Formation from Beier Depression China and from Tanan Depression Mongolia J. Journal of Jilin University Earth Science Edition Haszeldine R S Quinn O England G et al. Natural geochemical analogues for carbon dioxide storage in deep geological porous reservoirs 14 Liu L H Yuko Suto Greg Bignal et al. CO 2 injection to granite and sandstone in experimental rock /hot water systems J. Energy Conversion and Management Worden R H. Dawsonite cement in the Triassic Lam Formation Shabwa basin Yemen A natural analogue for a potential mineral product of subsurface CO 2 storage for greenhouse gas reduction J. Marine and Petroleum Geology Moore J Adams M Allis R et al. Mineralogical and geochemical consequences of the long-term presence of CO 2 in natural reservoirs an example from the Springerville-St. Johns Field Arizona and New Mexico USA J. Chemical Geology Baker J C Bai G P Hamilton P J et al. Continental-scale magmatic carbon dioxide seepage recorded by dawsonite in the Bowen-Gunnedah-Sydney basin system eastern Australia J. Journal of Sedimentary Research 1995 A Zalba P E Conconi M S Morosi M et al. Dawsonite in tuffs and litharenites of the Cerro Castano Member Cerro Barcino Formation Chubut Group Cenomanian Los Altares Patagonia Argentina J. The Canadian Mineralogist Hay R L. Zeolite weathering in Olduvai gorge Tanganyik J. Bulletin of Geological Society of America CO 2 J Dong Linsen Liu Li Zhang Ge et al. The mineral trapping of CO 2 for pyroclastic rocks J. Acta Sedimentologica Sinica J Dong Linsen Liu Li Meng Qian et al. Generation of dawsonite cement of pyroclastic rocks in Tongbomiao Formation in Tanan Sag of Tamtsag Basin in Mongolia J. Journal of Jilin University Earth Science Edition J Yang Ting Wang Jianxin Wang Pu et al. Sedimentary facies of Nantun Formation in Beixi Area of Beier Sag J. Xinjiang Petroleum Geology Zinkemagel U. Cathodoluminescence of quartz and its application to sandstone petrology G. Contribution to Sedimentology No. 8 Printed in Germany J Zhang Benqi Yu Hongzhong Jiang Zaixing et al. Characteristics

10 3 459 and diagenetic environments of source rocks by cathodoluminescence J. Petroleum Exploration and Development Industry J. 36. D Xiao Yingying Fan Tailiang Wang Hongyu. Characteristics and diagenesis of the volcaniclastic rock reservoirs from the Nantun Formation within the Sudert structural zone in the Buir depression J. Sedimentary Geology and Tethyan Geology Zhang Fan. The structural character and tectonic evolution of Hailar Basin D. Changchun College of Earth Science Jilin University Johnson J W Nitao J J Steefel C I et al. Reactive transport modeling of geologic CO 2 sequestration in saline aquifers the influence of 27. intra-aquifer shales and the relative effectiveness of structural solubility and mineral trapping during prograde and retrograde J Feng Baohua. Carbon- sequestration iferous- Permian tonsteins formed by hydrolytic reformation of volcanic ash sediments in Northern China J. Acta Sedimentologica Sinica Lu Fengxiang Sang Longkang. Petrology M. Beijing Geological J Publishing House Zhang Hui Zhou Anchao Guo Mintai et al. The effect of depositional setting on alteration of landing Ash J. Acta Sedimentologica Sinica C Li Zhaonai Wang Bixiang Wang Songchan et al. The volcaniclastic rock and their indentification C Bulletin of Institute of Geology Chinese Academy of Geo Chou L Wollast R. Steady-state kinetics and dissolution mechanisms of albite J. America Journey Science Huang W L Longo J M. The effect of organics on feldspar dissolution logical Sciences Hellevang H Aagaard P Oelkers E H et al. Can dawsonite permanently trap CO 2 J. Environment Science and Technology J Liu Na Liu Li Yang Huidong et al. Genetic relationship J Xu Yanbin between dawsonite and clastic feldspar in southern part of Songliao Basin J. Journal of Jilin University Earth Science Edition Chen Ping Xu Yongcheng. NaAlCO 3 OH 2 Distribution and its relationship with oil and gas in Hailer Basin J. Oil and Gas Geology through mineral precipitation in the Rose Run Sandstone Ohio J. J Sun Applied Geochemistry Yumei Guo Naiyan Wang Yan et al. Main gas sources and gas 44 Ryzhenko B N. Genesis of dawsonite mineralization thermodynamic charge history in Yinggehai-Qiongdongnan region J. China Offshore Oil and Gas Geology Liu Li Liu Na Zhou Bing et al. Petrological recording of mantle- magmatic CO 2 leakage on a large-scale in Honggang Anticline Southern Songliao Basin J. Journal of Jilin U- niversity Earth Science Edition CO J. CO 2 J Liu Li Hou Qijun Liu Na et al. Charging time sequence of mantle CO 2 and hydrocarbon in southern Songliao Basin An evidence from dawsonite-bearing sandstones J. Oil and Gas Geology CO 2 J Wang Jiang Zhang Hong Lin Dongcheng. Exploration prospect of CO 2 gas reservior contained helium in Wuerxun Depression Hailar Basin J. Natural Gas R. The First National Conference on Carbon Sequestration Washington DC M M Chang Lihua Cao Lin Gao Fuhong. Igneous Rock Identification Manual M. Beijing Geological Publishing House and the development of secondary porosity J. Chemical Geology Zerai B Saylor B Z Matisoff G. Computer simulation of CO 2 trapped analysis and alternatives J. Geochemistry International Walker T R. Carbonate replacement of detrital crystalline silicate minerals as a source of authigenic silica in sedimentary rocks J. CO 2 J. Geological Society of America Bulletin Limantsevaa O A Makhnachb A A Ryzhenkoa B N et al. Formation of dawsonite mineralization at the Zaozernyi Deposit Belarus J. Geochemistry International Gao Yuqiao Liu Li Qu Xiyu et al. Petrologic characteristics of dawsonite-bearing sandstones in Wuerxun Sag of Hailaer Basin and Gudian CO 2 Gasfield in Songliao Basin J. Journal of Palaeogeography

11 Diagenesis of Dawsonite-bearing Tuffite in Beier Sag Hailar Basin ZHOU Bing 1 ZHU De-feng 2 LI Chun-bai 2 LIU Li 1 ZHAO Shuang 1 MENG Fan-qi 1 MING Xiao-ran 1 1. College of Earth Science Jilin University Changchun Research Institute of Exploration and Development Daqing Oil field Inc. Daqing Heilongjiang Abstract The dawsonite-bearing pyroclastic rock from Damoguaihe-Yimin Formation in Beier Sag of Hailar Basin was taken as the research object. Polarization microscope Scanning Electron Microscope Energy Disperse Spectroscope alizarin red-s staining Cathode Luminescence and X-ray Diffractomer are used in this research to study its rock type types of authigenic minerals and paragenetic sequences. It is ascertained that the host rock type of dawsonite is tuffite and carbonates are the main authigenic mineral such as dawsonite ankerite and siderite. Content of dawsonite is up to 25%. The paragenetic sequence is shown as sideriteⅠ kaolinite overgrowth quartz dawsonite microcrystalline quartz calcite ankerite sidriteⅡ bitumen. Dawsonite is characterized by replacing feldspar quartz debris and kaolinite matrix which is different from pore-filling dawsonite found in other field implicating that these mass in tuffite could provide origin of metal ions and reacting with diagenetic fluid under the participation of CO 2 which results in precipitation of dawsonite. Large amount of carbonates 15% ~ 44% developed proves that pyroclastic rock owns a relatively well capacity of CO 2 fixation. Key words pyroclastic rock dawsonite diagenesis Beier Depression

GLOBAL GEOLOGY Vol. 29 No. 3 Sept X CO 2 P A doi 10.

29 3 2010 9 GLOBAL GEOLOGY Vol. 29 No. 3 Sept. 2010 1004-5589 2010 03-0442 - 08 124010 100 150 200 200 X - 150 200 100 150 200 CO 2 P578. 6 A doi 10. 3969 /j. issn. 1004-5589. 2010. 03. 011 Experiment