1 1. 1985 plastic (plastics)
2 ( ) (styrene) ( ) (polymerizing) poly ploystyrene polyvinyl chloride (plastic resin) (Binder) plasticizer stabilizer fillers,
2. 23 ~ 39 18 1820 Thomas Hancoak 3
1839 Charles Goodyear (Vulcanization) Curing 100 50 1869 John Wesley Hyatt 10000 Celluloid Rayon Fiber 1909 Bakelite ( Phenol Formaldehyde) 4
Leo Bakeland 1918 Hans John 1930~1940 PVC ethenoid plastics (vinyl plastics ) 1930 I.G. Farben PVC I. Ostromislensky 1912 PVC 1940 contact resins1941 1945~1955 1960 PPO 1970 1960 20 1973 5
1960 1959 1966 1960 1975 I C I 1972 [ ] PES 1980 PEEK Poly Ether Ether Ketone1976 BT 6
7 2000 PVC PVC PVC -, -
(g/cm 3 ) (*1000psi) (ft*lb/in) (V/mil) ( 0 C)( ) : 0.92-0.93 0.9-2.5 480 82-100 0.95-0.96 2.9-5.4 0.4-14 480 80-120 1.49-1.58 7.5-9.0 1.0-5.6 110 PVC - - -, 0.90-0.91 4.8-5.5 0.4-2.2 650 107-150 - 1.08 10.0-12.0 0.4-0.5 1775 60-104 ABS, 1.05-1.07 5.9 6 385 71-93, 1.11-1.19 11 2.3 450-500 54-110 1.2-1.3 3.0-8.0 1.1-6.8 250-600 60-104 2.1-2.3 1.0-4.0 2.5-4.0 400-500 288 8
(g/cm 3 ) (*1000psi) (ft*lb/in) (V/mil) ( 0 C)( ) : 1.34-1.45 5.0-9.0 0.2-0.6 260-400 150-177 1.65-1.92 5.5-7.0 0.3-0.4 350-400 120-150 1.69-1.95 5.0-18.0 0.3-18.0 140-400 177-288 : SMC1.7-2.1 8.0-20.0 8.0-22.0 320-400 150-177 BMC1.7-2.3 4.0-10.0 15.0-16.0 300-420 150-177 : 1.45-1.52 5.0-9.0 0.2-0.4 350-400 120 1.50-1.55 7.0-9.0 0.4-0.5 300-330 120 1.8-2.0 5.0-10.0 0.6-18.0 170-300 150-200 - 1.47-1.52 5.5-13.0 0.2-0.4 300-400 77 : 2.12-2.15 4.0-9.5 0.6-10.0 350-450 230 1.60-2.30 3.0-9.0 0.3-0.5 350-450 150-230 : 1.06-1.40 4.0-13.0 0.2-10.0 400-650 120-260 1.6-2.0 5.0-15.0 0.3-0.4 300-400 150-260 1.7-2.0 10.0-30.0 300-400 150-260 9
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3. (Cellulose) (Rubber) A. (Plant resins) (Essential oil), resenes (Terpenes) 12
(1) (Rosin) Dammars(2) (Semifossilresins ) East india Bath(3) Capals,kauIi,Congo (4) elemi mastic sandarac 1. (Rosin) (Pine tree) 90% abietic acid 10% resmes Terpenes 68% 20%terpentine 29% Terpine (gum rosin ) (Wood resins) (Bleaching earth) (Fdura1) Tall oil rosin Tall oil (rosin acids) (Methyl ester) Glycerol ester (estergum)197.6 13
239 ( Hydrogenated methyl ester ) (Soduizn soap 2.Dammars Dammars Dammar (enamels) (Varnish ) (Agatis tree ) 3.Copal (Copal resins) Copal (fossil resins) (Congo) kauri (Amber) 14
4. gum accroideselemi mastic sandarac lignin B. (Protein) (Amino acid) 1. (Animal proteins ) (Silk) (Woo1) (Casein) ( ) 35 (tanning) (hydrophilic 15
group) 2 (alum) 1/4 3/4 (Hardening bath) (Synthetic fiber) 16
2. (Vegetable proteines) 48 1 7 37 (Sodium sulfite) (Zeill) (gluten) ; 17
C. (Shellac) ( 1/40 Shellac D. (Asphalt and Related plastics) (asphalt ) (Trinidad 18
170~190 F 3000 Gilsonite 270~375 A. (Cellophane) (Viscose rayon ) (Cuprammonium rayon) 19
(Vulcanized fiber ) 1. 75 0.05~2 2. Alkali cellulose ( ) 20
600 1200 300 90 17 40 20 55 20 (1) (2) 10 30 (Coagulation solution) 4 25 0.0010.0015 0.002 21
(Viscose rayon ) ( ) 3. (Sweitzer s reagents ) B. 22
1. (Cellulose nitrate ) 50 55 25 20 ( ) ( ) (Camphor) 2. (Cellulose acetate) 23
3. 24
C. (Cellulose ethers) 1. 400 25
A. 1872 (Bayer) 1909 (Para) 1. 1.1~1.5 1 26
16 2. (Two stage resins ) 0.8 3. (Cast resins ) 1.5~2.5 27
5~10 3~7 150~175F Friedel-Crafts 1. (Molding powders) 60% 90% (Bulk factor) 28
2. (Pressure molded products ) 285 24 3. 29
(75~90%) (Neoprene) B. ( ) C. 30
, 31
D. 2:1, A. 32
(Carbon black) (Antioxidant ) B. 1. 33
2. 300% 3. 1 (1-Butene) 34
4. C. ( 335 ) 35
36
D. 1. (PTFE) 450~550F PTFE( ) PTFE 37
2. CTFE CFE PTFE PTFE CTFE 3. ( FEP)PTFE 550F A. 1.4 38
PVC PVC 325~400 PVC 160F 212F 3000psi 2000psi 180F 2300psi 2000psi 39
30~80% PVC(Propylene modified PVC ) 25% PVC 40
B. 1. (PVF) 2. TFE C. ( ) 1~15 50% 41
(graft polymer ) D. (saran) 160 350F 200 42
A. (Polystyrene) 43
20~40% 50% 100% (ABS) 60% ABS ABS 44
B. 90% C. 45
A. (Polyester) B. (Alkyds) glyceryl tartrate glyceryl phthalate 320F C. (Unsaturated resins) 46
D. (Saturated resins) (Fiber and Film forming resin ) 370 F 530F E. 47
A. (Polyamide) (Nylon)Veramides B. (Flexible foams) (Rigid foams) 48
SiO (Bond energy ) CC 1.5 Si-C (Hydrolysis ) 300 400C (Silicone Resins ) ( ) 49
14,000psi 400F 51,000psi 600F 1500F 50
R90522707 R90522732 R90522729 51