WEEE RoHS 2005.10.15

2005.10.15

WEEE RoHS 2005.10.15

WEEE RoHS 1 1.1. a. b. c. d. e. f. g. h. i. 1.2 Heavy Metals Flame Retardants PBB/PBDE / / PCBs/PCNs/PCTs/CPs PVC and PVC blends / Phthalates Organotins PCP/TeCP/TCP/OPP/Phenol Nickel Release Formaldehyde / Solvent/ODCs Asbestos AZO dyes Disperse dyes 1.3 Cd Pb Hg Cr 6+ PBB PBDE PCBs PCTs PCNs / HCFC/CFC PVC Sb As Be Co Se Tl http://www.dianyuan.com/ - 1 -

WEEE RoHS 1.4 1994 1998 4 2002 4 30 2003 2 13 10 * RoHS 2002/95/EC Proposal for a Directive of the European Parliament and of the Council on the Restriction of the Use of Certain Hazardous Substances in Electrical and Electronic Equipment * WEEE 2002/96/EC Proposal for a Directive of the European Parliament and of the Council on Waste Electrical and Electronic Equipment WEEE RoHS 1.5 WEEE RoHS a. b. c. d. RoHS 95 RoHS WEEE 175 WEEE WEEE 1.6 WEEE RoHS a. b. http://www.dianyuan.com/ - 2 -

WEEE RoHS c. 1.7 WEEE 1.8 1.9 WEEE RoHS 2004 8 13 2005 2 13 EU 2005 8 13 2006 6 30 RoHS 2006 12 31 2008 2 13 2008 12 31 / 1.10 RoHS RoHS 70% RoHS 2004 RoHS 1.11 Basel Convention Montreal FCCC CITES Convention on Biological Diversity 1.12 http://www.dianyuan.com/ - 3 -

WEEE RoHS 91/338/EEC 94/62/EC End of Life Vechicles 2000/53/EC Amendment on End-of-Life Vehicles 2002/525/EC 76 / 769 / EEC Dangerous Substances List 85/467/EEC 6th PCBs / PCTs 89/677/EEC 8th As / Pb 91/157/EEC Batteries and Accumulators 93/11/EEC N-Nitrosamines 96/55/EC Chlorinated solvents 1999/51/EC Tin PCP Cadmium 83/478/EEC 91/659/EEC 85/610/EEC 1999/77/EEC Asbestos 1 European Union / EU 1991 12 1993 11 1 25 4.56 2 25 2 RoHS 2.1 2003 1 27 RoHS 4 1 2006 7 1 PBB PBDE http://www.dianyuan.com/ - 4 -

WEEE RoHS RoHS WEEE WEEE RoHS RoHS Lead - Mercury - Cadmium - Hexavalent chromium - PBB - PBDE -PBDE Tetra-BDE - Penta-BDE - Octa-BDE - Deca-BDE - The Bromine Science and Environmental Forum 8 2005 10 15 2005/717/EC ROHS 2006 7 1, 2004 8 13 12 ROHS 2005 2.2 MCV 2005 8 18 2002/95/EC (2005/618/EC) Lead Pb Mercury Hg Chromium Cr 6+ Cadmium Cd Polybrominated PBB Polybrominated diphenyl ethers PBDE ( ) 0.1% 1000ppm 0.1% 1000ppm 0.1% 1000ppm 0.01% 100ppm 0.1% 1000ppm 0.1% 1000ppm http://www.dianyuan.com/ - 5 -

WEEE RoHS RoHS a unit that cannot be mechanically disjoined into single materials ) 8 2.3 RoHS A B 1500V 1000V 2006 7 1 15 2004 10 25 2.4 RoHS 85% solderable termination coating RoHS? 91/339EEC 91/338/EEC http://www.dianyuan.com/ - 6 -

WEEE RoHS? RoHS 91/339EEC? Hard chrome plating,, 2.5 RoHS 2005 1 2 2005 9 2 10 28 23 22 2.6 RoHS 2.6.1 RoHS RoHS RoHS RoHS CE FCC (PBB) (PBDE) RoHS RoHS RoHS ROHS a. RoHS RoHS RoHS RoHS RoHS b. http://www.dianyuan.com/ - 7 -

WEEE RoHS c. d. RoHS RoHS 2.7.2 a. ROHS b.. ROHS c. ROHS d. ROHS e. 2.8 2.8.1 2.8.2 SONY GP SS 00259 PHILIPS AR 17-5051-126 HITACHI NOKIA Requirement for RoHS RICOH Microsoft H00594 Panasonic 3. RoHS 3.1 a. AAS http://www.dianyuan.com/ - 8 -

WEEE RoHS b. ICP-OES ICP Optical Emission Spectrometry Argon c. OES 160 20 60 DCP MIP ICP ICP Inductively Coupled Plasma Torch 20 60 ICP-OES 70 ICP-OES ICP-OES Varian Vista Thermo d. X XRF e. - UV-Vis f. IC 3.2 a. GC b. - GC-MS Thermo Finnigan Trace DSQ Agilent 5973Inert GC-MS c. HPLC d. - HPLC-MS 4 WEEE 4.1 4.2 WEEE % 80 75 70 50 % http://www.dianyuan.com/ - 9 -

WEEE RoHS IT 75 65 75 65 70 50 70 50 70 50 2008 12 31 2008 12 31 70 50 80 75 4.3 WEEE WEEE a. b. c. WEEE 2005 8 13 2006 11 WEEE 1A 1000 1500 WEEE 1A 10 WEEE 4.4 WEEE a. Equipment intended specifically to protect the UK national interest and used solely for a military purpose, e.g. arms, munitions and war material b. Household luminaires c. Filament light bulbs d. Large-scale stationary industrial tools e. Implanted medical equipment and infected medical equipment at end-of-life f. Equipment incorporated into other equipment not covered by the directive WEEE ROHS WEEE WEEE 4.5 a. b. c. http://www.dianyuan.com/ - 10 -

WEEE RoHS d. e. 4.6 * * * CD- ROM ) * 30 * * * WEEE * * * 30 * WEEE * 4.7 WEEE a. WEEE b. * * WEEE c. * * * * d. WEEE e. * * * f. 5 RoHS WEEE a. http://www.dianyuan.com/ - 11 -

WEEE RoHS b. c. d. http://www.dianyuan.com/ - 12 -

2005.10.15

1. IARC 2B a b c d e. f. 2., PCB 3. 1970 450 2000 700 80% 0.5% 1995 2000 10 200 http://www.dianyuan.com/ - 1 -

4. 2003 L37 2003 1 27 WEEE RoHS RoHS (Restrictions on the use of Hazardous Substances) 2006 7 1 6 2004 RoHS 5. WEEE RoHS ROHS http://www.dianyuan.com/ - 2 -

1. 1.1 Sn-Pb 232 327 63 37 183 a b c 1.2 100% ISO9453 JISZ3282 RoHS 0.1Wt% RoHS 2. 2.1 Sn-Pb Sn Cu Ni Ag 2.2 (Ag) (In) (Zn) (Sb) (Cu) (Bi) Bi 3.31 0.857 8 In 0.24 87.2 7 3 Zn 7640 0.108 6 http://www.dianyuan.com/ - 3 -

Cu 12600 0.328 5 Ag 15.9 28.18 4 Sb 138 0.317 2 Pb 3040 0.105 1 a. b. Sn-9Zn 198 c. - - - 96 3. 3.1 a. KT KT 1.0 7700 210 36 0.1 64000 3040 21 0.20 21800000 113500 190 0.3 2100 138 15 0.9 110 3.3 33 0.6 340000 12600 27 1655 42 1.8 23 90 2.6 0.24 10 30 280 15.9 18 0.1 190000 7640 25 b. Sn-37Pb 1.5~2 c. http://www.dianyuan.com/ - 4 -

( ) d. Sn-37Pb e. PCB PCB RA RMA f. 260 345 250 g. h. i. 10 j. SMT k. / 3 l. m. 30~90 4 3.2 http://www.dianyuan.com/ - 5 -

Sn-Cu Sn-Ag Sn-Ag-Cu Sn-Cu Sn-0.7Cu a. b. Sn-Cu c. Sn-Cu d. Sn-Cu Sn-Ag Sn-Ag-Cu 250 Sn-Ag Sn-Ag-Cu Sn-Cu 6 3.3 US Patent5527628 5-50289 NEMI Sn-3.9Ag-0.6Cu Soldertec Sn-3.8Ag-0.7Cu 4 a. SGS ITS RoHS 6 30ppm 2ppm b. c. http://www.dianyuan.com/ - 6 -

1. 1.1 a. b. 1.2 Sn-Pb Pb-Free Solder Sn-Pb PCB 1.3 1991 1998 10 -MD 3. 3.1. 3.2 a. Sn-Cu Sn-Ag Sn-Ag-Cu 220 Sn63-Pb37 40 PCB b. Sn63-Pb37 c. http://www.dianyuan.com/ - 7 -

3.3 50 150 50 150 Sn63-37Pb 183 233 333 Sn-0.75Cu 227 277 377 Sn-3.5Ag 221 271 371 Sn-3.5Ag-0.75Cu 218 268 368 Sn-3.0Ag-0.7Cu 218 268 368 Sn-3.0Ag-0.5Cu 218 268 368 4. SnPb63 http://www.dianyuan.com/ - 8 -

1. 1.1 1.2 PCB PCB 1.3 a. b. c. d. 1.4 a. b. PCB c. d. 2. OA R RA AC R RA OA http://www.dianyuan.com/ - 9 -

OA RA RMA RA OA QQ-S-571E S RMA AC ( ) SR SMAR SAR SSAR 2.1 R PCB CFC CFC ODS 80 ODS ODS 2.2 IPA (VOC) a. 1.5~3% b. PCB c. MIL-P-28809 a. 0.800 0.815 0.805 5% 1% b. c. d. e. halide http://www.dianyuan.com/ - 10 -

2.3 VOC VOC 99% VOC VOC VOC --- VOC VOC VOC PCB PCB 2.4 5º-7º 1.2-1.8m/min 250 255 258 2.4.1 a. b. c. d. e., f. g. 0.2%(W/W) 2.5 a. b. PCB (OSP) http://www.dianyuan.com/ - 11 -

c. d. 200 C 250 C 240 C 210 C e. f. g. 3. 3.1 3.2 a. 260 b. ( ) c. d. http://www.dianyuan.com/ - 12 -

4. 4.1 PCB PCB 20 5. 5.1 PCB PCB PCB 5.2 5.2.1 a. PCB b. 5% 2% c. PCB PCB http://www.dianyuan.com/ - 13 -

20KHz PCB 50~3000µg/inch 2 ±10% 5.2.2 a. PCB ENIG Ag OSP SAC 5.3 5.3.1. a. b. PCB c. PCB 5.3.2 a. PCB 800 PCB 100 50% b. PCB 80% c. PCB 5.3.3 PCB 2 /s 1.2m 1 3min 100 120 PCB 130 180 1 3min PCB 1.4m 2.1 http://www.dianyuan.com/ - 14 -

10 210 5.4 5.4.1 a. PCB SMD PCB SMD c. 2-3 PCB SMT PCB PCB PCB 5.4.2 a. PCB 80~100mm b. PCB 1/2 1/3 c. SMT 5 8 d. http://www.dianyuan.com/ - 15 -

250±5 5.5 6 a. PCB 120 2 b. PCB, PCB c. PCB 120 2 d. e. PCB PCB PCB f. PCB PCB g. PCB PCB PCB PCB h. http://www.dianyuan.com/ - 16 -

3.5 PCB PCB PCB PCB PCB 3-7 i PCB PCB PCB j. 6 12 RA k. l. 7. 7.1 http://www.dianyuan.com/ - 17 -

a. PCB b. PCB c. PCB d. ( ) 7.2 a. b. c. d. 7.3 a. PCB b. c. 7.4 8. a. PCB b. 30~40 260 C http://www.dianyuan.com/ - 18 -

250-260 @ 260-270 @ c. d. PCB e. 9. a. Sn Pb 2.4 50% b. Cu 6 Sn 5 Sn-37Pb Cu 6 Sn 5 Sn-0.7Cu c. 250 SnO Sn 1. 2. 280~300 3. 4. 195 5. 190 2 3 4 1. 280~300 195 1.5 http://www.dianyuan.com/ - 19 -

2. 220 CUSN 3. 195~190 20 4. 5. 6. CUSN 1. CU6SN5 2. 0.25WT% CU6SN5 3. 0.3WT% 5~10GK 4. 0.25% SMD 5. 190C 10. Pb-Free SnPb 40 a. IPC A 610C b. Cu Cu 6 Sn 5 Cu 6 Sn 5 c. 11. http://www.dianyuan.com/ - 20 -

11.1 a. b. c. 11.2 a. 80~95% b. PCB c. PCB CFC VOC 11.3 N2 a. N2 Distillation http://www.dianyuan.com/ - 21 -

N2 99.999% b. c. N2 generator 12. PCB PCB PCB PCB a. PCB X/Y PCB PCB 2mm PCB ±0.5mm b. PCB PCB c. PCB PCB 6mm 0 12 10 PCB http://www.dianyuan.com/ - 22 -

275---300 10mm/s---25mm/s (±0.05mm) 5 PCB PCB PCB PCB PCB PCB 0.7mm 10mm 5mm http://www.dianyuan.com/ - 23 -

1. 1.1 20W 30W 40W 50W 60W 1.2 a. 40W 60W 80W b. c. 24V d. e. http://www.dianyuan.com/ - 24 -

2. 0.3mm 0.5mm 0.6mm 0.8mm 1.0mm 2.1 345 370 Sn-0.7Cu a. b. c. d. e. 2.2 63Sn-37Pb 183 350 4 / Sn-0.75Cu 220 390 6 / Sn-3.0Ag- 0.5Cu 220 390 6 / 3. http://www.dianyuan.com/ - 25 -

3.1. a. b. c. d. 3-5 3.2 a. b. 3.3. a. b. 150 c. d. 3-5 PCB 4. 4.1 a. Sn-Pb http://www.dianyuan.com/ - 26 -

40 400 30~40W IC 60W 30W 40W 60W 280 320 320 360 360 400 b. 5 3 c. d. e. f. 45 g. 10 60W 360 400 3 5 3 4.2 360-340 60W 80W http://www.dianyuan.com/ - 27 -

3 SMD 80W 300 4.3 a. b. c. d. e. 3-5 f. g. h. 0.8mm i. j., PCB http://www.dianyuan.com/ - 28 -

4.4 a. b. Sn c. 4.5 a. b. c. d. ( ) e. 5. 5.1. 60W 60W Hakko Metcal Weller OK a. 60W 80~ 100W b. c. d. e.,,, OK METCAL ±1 Metcal http://www.dianyuan.com/ - 29 -

5.2 a. b. PCB c. d. e. 3-5S 3 http://www.dianyuan.com/ - 30 -

SMT Surface Mounted Technology SMT 1/10 SMT 40%~60% 60%~80% 30%~50% 1. 1 2 1/3 3. Sn-Ag-Cu 200 183 / 96.5Sn-3Ag-0.5Cu Sn-Ag-Cu (7.5g/mm 3 ) Sn-Pb (8.5g/mm 3 ) http://www.dianyuan.com/ - 31 -

/ SMT 50~70% 2~7 4~8 ZESTRON 2004 30 1. 2. 1 34 ZESTRON http://www.dianyuan.com/ - 32 -

1a/1b ph MPC ZESTRON 1.5bar 2 6 http://www.dianyuan.com/ - 33 -

10 2 OSP OSP ZESTRON OSP ZESTRON OSP http://www.dianyuan.com/ - 34 -

50 40 ZESTRON 5% 95% http://www.dianyuan.com/ - 35 -

20 50 2 3 1 SMD 2 1 http://www.dianyuan.com/ - 36 -

http://www.dianyuan.com/ - 37-3 SMT 2 260, 4

a. b. 1 c. a. b. c. θ X-Y 0.1 / 40m/S², QFP SOP LED SMT SMD 1 http://www.dianyuan.com/ - 38 -

0.2 / 0.1 / θ X-Y θ θ XY ] 2 200 1.27mm SOP28pin, 0.1~0.2mm/ *2 3 4 a. 260 b. c. d. e. f. 5 http://www.dianyuan.com/ - 39 -

±0.05mm 6 6.1 95.5Sn/4.0Ag/0.5Cu( 217 218 ) 96.5Sn/3.5Ag( 221 ) 63Sn-37Pb 183 1 51 27 96.5Sn-3Ag-0.5Cu 217 2 35 20 Sn-Ag-Cu ( 4 ) Sn-Ag Sn-Ag Sn-Ag-Cu 220 225 230 6.2 PCB 8 8 8 63/37 230~245 5~10 PCB http://www.dianyuan.com/ - 40 -

2 /sec 4 /sec OSP Sn-Pb (SMD) Sn-Ag-Cu 250 C( ) 260 C( ) IR50 160~180 C 60~120 220 C 60 250 C 10 IR60 160~180 C 60~120 220 C 60 260 C 10 : --- http://www.dianyuan.com/ - 41 -

- 2~3 PCB PCB 2.5~5µm N2 PCMICA BGA QFP N2 N2 ODS http://www.dianyuan.com/ - 42 -

/, :75.80.100.120.155.155.155.155.155.155!! http://www.dianyuan.com/ - 43 -

MAX 230. MAX 155~160,, 1 / / PCB 4h 2 ( ) z 1 http://www.dianyuan.com/ - 44 -

A B C 1 2 = ND NID 2 ND ND GD H ND GD H ND NID =O.6mm = 2=0.6mm 2 O.3mm O.5ram = 3=0.5mm 3 0.17mm =O.4mm 4 O.4mm 4 O.1mm 2 GD GD NID ND NID ND GD 3 ND GD GD NID (f1) (F1) 4 http://www.dianyuan.com/ - 45 -

F1 f1 Fl fl F1 f1 GD NID GD>2 NID GD 5 3 NID. 6 5 http://www.dianyuan.com/ - 46 -

1. 5 1.1 Sn Sn Sn Sn-10Pb Sn-10Pb 2 a. 1mm( 0.3mm) b. ( ) c. ( ) d. ( ) inemi JEDEC JESD22A121 25 50 75µm 1/3 1/2 PCB 1.2 Kirkendall http://www.dianyuan.com/ - 47 -

Kirkendall Sn-Pb Sn-Pb 30 Kirkendall Kirkendall 1.3 Kirkendall SAC(Sn-Ag-Cu) Sn-Pb SAC Sn-Pb 1000 750 500 1.4 SnPb a. ( BGA ) b. 80 4 ( ) c. 10 ( ) Amkor Fraunhofer Institute 1.5 CAF (CAF) PCB CAF CAF PC CAF Interface Science(Goleta CA) CAF http://www.dianyuan.com/ - 48 -

1 SMT http://www.dianyuan.com/ - 49 -

PBB PBDE 1 / RoHS RoHS 6 7 / RoHS PCB http://www.dianyuan.com/ - 50 -

8 RoHS RoHS RoHS 1 2 3 http://www.dianyuan.com/ - 51 -

4 5 6 7 8 9 10 11 (SPC) 1 2 3 (CPK) 5 http://www.dianyuan.com/ - 52 -

a. b. 1. FR-4 A1 2.FR-4 A2 3.FR-4 A3 FR 4 4.FR-4 AB 5.FR-4 B 100mmX200mm FR4 http://www.dianyuan.com/ - 53 -

PCB (1) (Tg) (2) (CTE) X Y PCB (3) PCB 250 50S (4) SMT PCB <0.0075mm mm (5) 1. PCB PCB PCB PCB Sn-Pb HASL (OSP) Ni/ Au(ENIG) Ag Sn (mm) HASL 4 12 1~2.5 0.005~0.02 Au / 0.2~0.5 OSP 4 12 Ag Ag 5 12 0.05~0.20 Sn 5 12 0.8~1.2 ENIG 4 6 0.05~0.2Au / 3~5Ag 1.1 HASL HASL PCB HASL a. PCB b. c. HASL a. b. HASL c. (<0.64mm) HASL HASL 1.2 OSP OSP PCB PCB OSP PCB HASL http://www.dianyuan.com/ - 54 -

a. HASL b. c. d. e. 1 OSP a. OSP OSP b. PCB OSP c. ICT d. OSP e. OSP 75% OSP 15% OSP f. OSP OSP ICT PCB OSP SMT 12 24 OSP PCB 1.3 ENIG Ni / Au ENIG JEITA (COB) a. b. c. Ni/Au d. e. a. ENIG DELL HP b. HASL 5 c. 1.4. Ag Ag 0.4 0.8 Ag PCB http://www.dianyuan.com/ - 55 -

/ / BGA Ag PCB 22 50% Ag HASL OSP Ag,, Ag HASL OSP HASL 1.5 Sn Sn Ag Sn Cu Sn Sn CH4N2S Sn Sn PCB OSP HASL PCB OSP PCB PCB 2. PCB PCB FR4 Tg 130~145 260~280 PCB http://www.dianyuan.com/ - 56 -

2. PCB PCB JEITA( ) 70 80W http://www.dianyuan.com/ - 57 -

*HAKKO 942 *WELLER WSD80 3. 3.1 a. 0.05 0.2mm 2 2.5 " " SMD 4 QFP PLCC BGA SOP b. PCB 0.5mm 1.5mm c. http://www.dianyuan.com/ - 58 -

SMT 1 0.05~0.2mm, 2~2.5 SMD 1 QFP PLCC BGA SOP 2 PCB 0.5mm 1.5mm 3 1 1 2 3 4 1 2 3 4 http://www.dianyuan.com/ - 59 -

2 2500C - SnO Sn 1 180-2100C 1-3 2 SMT SMT 50-70 3 PCB 1/2-1/3 4 250+50C http://www.dianyuan.com/ - 60 -

PCB http://www.dianyuan.com/ - 61 -

X (XRF) Pb Lead Hg Mercury Cd Cadmium Cr +6 Hexavalent chromium PBB PBDE Sn Tin Cu Copper Fe Iron Ag Silver Ar Argon Nitrogen http://www.dianyuan.com/ - 62 -

http://www.dianyuan.com/ - 63 -

700 2.5 --- --- IBM ----- 90% 30% 1977 http://www.dianyuan.com/ - 64 -

35% 20% 1993 50 200 http://www.dianyuan.com/ - 65 -

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