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/ TEL03-5919133E-mailyang-ming@itri.org.tw / V2. 1 / 198

() 2 / 198

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Hazard Communication 5 / 198

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96.10.19 3 0960145703 (97.12.31) ~ ~ 8 / 198

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(96.10.19) **** 12 / 198

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) 14 / 198

2. 3. 4. 5. 6. 7. : () :(: ) : 1. 2. 3. 4. :1. 2. 3.. 4... 5. 15 / 198

(1. 2. 3. ) COCO 2 H 2 N 2 1. 2. 3. 16 / 198

17 / 198

1712742 () ( 4-4-15) pentoharbital276 276 18 / 198

19 / 198

- (1). (2). (3). (4). (5). (6). (7). (8). (9). 20 / 198

(90%) (Eye Contact) 21 / 198

() 22 / 198

主要毒物在體內作用之目標部位 鎳 砷 鎘 有機鉛 一氧化碳 鉻 汞 氟化物 硒 錳 鉛 甲基汞 鈷 碘131 硫氧化物 氨 錳 鎂 鈹 鋅 一氧化碳 鎘 臭氧 氮氧化物 過氧 化乙醯硝酸鹽 鈷 石綿 四羧基鎳 硫化氫 砷 含氯碳氫化合物 氟化物 鉛 鍶90 汞 鎘 鋅 鉛 砷 氟 化物 釩 砷 鈹 鎳 氟化物 皮膚 脂肪 鎘 第 23 / 198頁 含氟碳氫化合物

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- 3(3839 52) 126124 61941 () 6 (5) 100*45cm66 6 60.18mg/m 3 0.11mg/m 3 363 (1) (2) 27 / 198

28 / 198

HCL 0.2kg/min 0.5 m/s 2000 ( 1000 0 ) 1000 2000 5 ppm (TLV) 100 ppm (IDLH) 0 1000 2000 3000 4000 5000 () 6000 29 / 198

900 30 / 198

31 / 198

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2.1 33 / 198

5.1 6.1 34 / 198

GHS () () () () () () 35 / 198

(Toluene) 36 / 198

(Hydrogen fiuoride) 37 / 198

38 / 198

GHS(MSDS) 2350-100.06 39 / 198

(CNS 9329 Z 1025) 40 / 198

- 41 / 198

- 96.09.1400 ( ) - 1. 2. a. b. c..wmv d. e. f. h. 42 / 198

() 43 / 198

- 94.06.14 70?? 44 / 198

O 2 CNS 1261; Z1001(7.1) H 2 Cl 2 CNS 2571;Z1010 C 2 H 2 CNS2224;Z1008(7) HCl NH 3 H 2 SCH 2 CHCl CH 2 CH 2 O1-3- CH 2 =CHCH= CH 2 CO CNS1325 ; Z1003(5.9) CNS1332 ; Z1004(4.1.2) COCl 2 NO HCNC 2 H 3 NO F 2 SO 2 CH 3 NH 2 Br 2 HCHO O 3 M.S.D.S

(-) 46 / 198

(-) 47 / 198

- 48 / 198

49 / 198

-.. (24hr.. )68 50 / 198

-- -( 24hr ) - ( 24hr 24hr ) 51 / 198 -- )

MSDS Material Safety Data Sheet. 52 / 198

MSDS MSDS 53 / 198

-MSDS 2. 5. 6. 7. 8. 9. PH/ 10. 11. 12. / 13. 14. 15. 16. 54 / 198

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(Explosive Range) 990726.mpg 58 / 198

() Vo1% Vo1% 4.0 60 175 1.4 7.6 257 2.6 13 465 2.5 100 305 15 28 4.0 16 1.3 a 7.9 a 160 1.8 8.4 560 1.8 8.4 405 1 1.6 10 385 1.9 9.5 465 59 / 198

2-315% 2-315% 1 60 / 198 90-100 40-50 30 4 1 4 0.15 (2%)60.1g/mole22.414 :7.3 ()

卥 61 / 198

(1/2) 1. Vo1% Vo1% 1.4 7.6 257-43 2.6 13 465 18 2.5 81 305 4.0 75 4.0 16 1.9 9.5 1.8 11.8 321-17 C A S. N O 12164-94-2 A M M O N IU M A Z ID E 131-74-8 A M M O N IU M P IC R A M T E 94-36-0 B E N Z O Y L P E R O X ID E 75-91-2 T E RT-B U T Y L H Y D R O P E R O X ID E 62 / 198

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(2/2) Hood 1.8 663 1.8Hood(0.68M 3 )THF 39gHood(1.8%v) 7.3 kg :LC 50 :1807ppm;TWA:35ppm;LEL:12.5%UEL:74.2%;CO 66ppm TDI:;0.005ppm;LC 50 :9700ppb/4hr; 0.025mmHg/25(33ppm) THF: LD 50 :1650mg/kg;TWA200ppm;LEL:2%,UEL:11.8%;FP: -17;BP:66; 145mmHg/25(19%V) :LC 50 576ppm/4hr;TWA 2ppm;LEL:3.0%UEL:17.0%; FP:-1.1; Bp:78, 88mmHg/20(11.5%v) 64 / 198

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Natural gas 12.0 14.4 Gasoline 11.6 14.4 Ethylene 10.0 11.7 Propylene 11.5 14.1 Butene-1-1 11.4 13.9 Butene-2-2 11.7 14.0 Isobutylene 12.1 14.8 Benxene 11.2 13.9 66 / 198

67 / 198

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A B 70 / 198

71 / 198,,. :,,,,.,,,,,,,,,, () (),,. :

- 72 / 198

1100 73 / 198

5gal () 74 / 198

& () 75 / 198

-.. 76 / 198

()- 5mmSUS.304 90 6810FM2002 5.8() 77 / 198

()() A. B. 78 / 198

()() : 1. 2. 3. 4... 90.3.7 79 / 198

921 80 / 198

NFPA704M HEALTH HAZARD FIRE HAZARD SPECIFIC HAZARD REACTIVITY 4 3 2 1 0 **3.4** 81 / 198

M.S.D.S 82 / 198

3M & 83 / 198

84 / 198

- () HOOD () UL4 20HDPE 85 / 198

- Hood 4 THF THF HOOD HOOD 86 / 198

87 / 198

- -68 ABCFM200 1. 2. 2. 3M 3.. 88 / 198

1. 2. 3. 4. 5. 6. 7. 89 / 198

() 1. 3. 2. 4. 5. 97.05.27-2.wmv 90 / 198

53- &&& &&... 91 / 198

- 94.8.15BI14 () 92 / 198

. ( & ;) (D2G4) 68C. 93 / 198

96.03.02.wmv - 94 / 198

() - 95 / 198

() 96 / 198

97 / 198

(a) (b) (c) (d)polynoxylin (e) (f) (a)(<3gal) (b)(<5gal) (c)(15gal35gal) (d)300gal 98 / 198

- PVCPEPPPC 99 / 198

100 / 198

- 53: 1.2.. 3.4. 5.6. *** *** 101 / 198

Model //5502 Large Cylinder ERCV Solkaironic Chemicals Inc. Adoplsr lar 29 Liter.Cylinler Eear Push Bar Valve Protection Cover, Front Purge Valve, Front Flange Enlgly, Front Front Pintch Dar Laiting Lugs Murning indel Vessen Clamp Volve Protection Cover, Rear Preasume Cange Volve Handle Orake Release Handle Purge Valve Rear Safely Nut Protectio Shroud (Open to Show port) Cylinder Sittle Reals Tellon Cap Cylinder Posiloner Eychook Safely Pin Farkhll Channeis Cyhader Hohldown Chaus Holddo Holes February 16.1901 Revneal Lon 17.1992 Front Swivel Wheels Description No Seale Rear WheelsOuic Brakes By Eugene Y.Near 102 / 198

No Seale Leaking Cylinder Cap Solkalronic Chemicals Inc. Description Sept. 25,1992 By. E.Y.Ngal Leaking Cap Gasket Folding Cart Slide Scrubber Leaking Cylinder Hinge Cart Fold Flasible Uhes Flasible Uhes Purege.Cap Regulator Cauge Purge Cylinder Strap Indicator Scrubbed Cas 103 / 198

-- 104 / 198

H Hazard Identification A 1 Action Plan Z Zoning M Managing A 2 Assistance T Termination 105 / 198

() : : : : 106 / 198

350CFM 40mmAq 4in 6in 2 4in NFB( ) 2in4in 107 / 198

108 / 198

,, 53, () ( ) 53gal 109 / 198

HPLC - 6.5PPM(TWA 40PPM) () /(250cc) 19.6PPM( ) 110 / 198

- 111 / 198

- () 1. 2. 3.4.5.() 6... () PC.PP. () () **--** 112 / 198

- FR (9) (1)(250K)(2) (35K)(3) (10K) (10K) 5m(4k) PVCPE pc 113 / 198 () SUS.304

114 / 198

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- 18 1. 2. 3. 4. 5. 6. 7. 116 / 198

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Infection( ) Allergy ( ) Toxicity ( ) 119 / 198

- 120 / 198

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HIVHBV 122 / 198

( ) 123 / 198

SARS- (log10pfu) 1.0E+03 7.5E+03 PH 6-7 PH 8 3 6 / 7.5E+03 PH 9 4 +2% 1.0E+05 1.0E+06 56 37 < 30 < 4 +PCR 1.0E+06 4 21 1.0E+06-80 21 124 / 198

WHO WHAT HOW DO DO 125 / 198

(NSC) RG1 E. coli - K12, RG2 RG3 Prions RG4 (Ebola virusmarburg virus..) 126 / 198

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Hazards Dose 128 / 198

RISK GROUP BIOSAFETY LEVEL LABORATORY TYPE LABORATORY PRACTICES SAFETY EQUIPMENT 1 Biosafety Level 1 Basic teaching, research GMT None; open bench work 2 Biosafety Level 2 Primary health services; diagnostic services, research Open bench plus BSC for potential aerosols 3 Biosafety Level 3 Special diagnostic services, research As Level 2 plus special clothing, controlled access, directional airflow BSC and/or other primary devices for all activities 4 Biosafety Level 4 Dangerous pathogen units 95.04.11 As Level 3 plus airlock entry, shower exit, special waste disposal Class III BSC, or positive pressure suits in conjunction with Class II BSCs, doubleended autoclave (through the wall), filtered air 129 / 198

() () (:) 130 / 198

(Bio-hazard containment) 131 / 198

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UV 136 / 198

II (75ft/min) 137 / 198

BSC 15~20cm HEPA HEPA 138 / 198

139 / 198

() 140 / 198

2003.12.16 SARS 125SARS 20031220 SARS 141 / 198

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() () () () 271 143 / 198

144 / 198

.... MSDS.. 145 / 198

146 / 198

: 1. 2. : 1.() : 1. () 2.()() : 1. 147 / 198

(): () 1.() 2.() 3. () () 4.() 148 / 198

-. 1.? 2. MSDS? 3. MSDS?? 4. MSDS? 5.??(w/w,v/v)?? 6.? 7.? 8.? 9.? 10.?(1-3 ) 11.? 12. 149 / 198

150 / 198

(N,N-Dimethyl formamide) (N,N-Dimethyl formamide) 95%w/w 1. 2. 3. 4. 5.. 1. 2.20 3. 4.240~300mL. 1. 2.... 1 2 3 03-5326151-420103-5166868 38000 03-5368920 Handling Premises Of Toxic Chemicals 151 / 198

152 / 198

(Chlorine) **-** Chlorine) 99%v/v ** 良 離 若 立 量 療 ***()()*** 153 / 198

Chromium(VI) trioxide Chromium(VI) trioxide99% w/w 1. 2. 1. 2. : : 518865 : 02-27422788 ***()()*** 154 / 198

- 1. () **6-30** 2. (http://ivy3.epa.gov.tw/epalaw/search/lor didispfull.aspx?ltype=08&lname=0148) ** ** 155 / 198

(M.S.D.S) 6-30 Chromium(VI) trioxide /21/037-621088 /037-621088/037-621090 Chromium(VI) trioxide Chromic acidchromic anhydride CAS No. 1333-82-0 100w/w /21/037-621088 () 1. 2. 2001.10.30 3.2002.11.30 156 / 198

( ()) () *1-3 ** () 157 / 198

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- () () 160 / 198

() 161 / 198

() 162 / 198

1.>19.5% 2.IDLH < 10TLV 163 / 198

164 / 198

-() () (( )() 165 / 198

166 / 198

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-, 5 169 / 198

- 170 / 198

-601700-1507000 171 / 198

172 / 198

() () ( ) (O 2 %50TLV) () 173 / 198

SCBA SAR EBA PAPR 174 / 198

175 / 198 - FR (9) (1)(250K)(2) (35K)(3) (10K)[(1) (2)(3)] (10K) 5m(4k) () SUS304 10K PVCPE 15K(200150cm) pc 5k(200150cm) 60 K

176 / 198

50 177 / 198

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: 179 / 198

-- -- A. (1) (2) (3) B. (1) (2) (3) (4) (5) (6) (7) (8) 180 / 198

181 / 198

1. 182 / 198

12160-20 1 5 o C7 183 / 198

- 4 1. 2. () 3. 4.SCBA 5. 6.5S 184 / 198

- () 1.180 2.() 3.(1.5) 4.SCBA 5. 6.5S 185 / 198

.. HoodTHF Hood40 THF THF THF NMRHPLCLCGC. 186 / 198

- SUS.316L 1000psi540psi 2 15000PSI 187 / 198

- PYREX 1001g RuCl 3.3H 2 O5 DMSO1PYREX 200 Hood 188 / 198

- 189 / 198

- ( )4%wNaOH 190 / 198

191 / 198

- ( 14%) 5 { } 1. 2. 3. 4. 5. 6. 7. 192 / 198

- ( 80%~90% ) : 1. 2. 3. 4. 5. 193 / 198

- () () : 1. 2. 3. 4. 5. 194 / 198

(HF) ( )...SCBA. 195 / 198

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- - - 199 / 198

CNS 15030-1 CNS 15030-26 200 / 198

CNS 15030-1 CNS 15030-26 201 / 198

CNS 15030-1 CNS 15030-26 202 / 198

CNS 15030-1 CNS 15030-26 203 / 198

CNS 15030-1 CNS 15030-26 204 / 198

CNS 15030-1 CNS 15030-26 205 / 198

CNS 15030-1 CNS 15030-26 206 / 198

CNS 15030-1 CNS 15030-26 207 / 198