2160859 3/2004 3/2004 5 B2
2004 3 2559 2297
... 1 1 (MBST) 6BA 3 2 (SP) 7(4)... 4 3 (G)... 6 4 (A) ()... 11 5 (AW) ()... 17 6 (BA) ()... 20 7 (CH) ( )... 21 8 (CP) ( )... 25 9 (CS) ()... 26 10 (CT) ()... 30 11 (DB) ( )... 33 12 (DS) ()... 35 13 (E) ()... 64 14 (FA) ()... 70 15 (FP) ()... 72 16 (GL) ( )... 78 17 (GOM) ()... 80 18 (GWFC) ( )... 83 19 (L) ( )... 84 20 (LSM) ( )... 93 21 (N) ()... 94 22 (PE) ()... 97 23 (SFL) ( )... 99 24 (SO) ()... 102 25 (WW) ()... 107 26 (SM) ()... 110 i
59 (a) (b) (c) (d ) (e) 2. 3. 4. 5. 1
1 6BA MBST-1 6BA(5)(a) MBST-2 l 6BA(5)(b)(ii) MBST-3 6BA(8)(a) MBST-4 6BA(8)(b) 18 MBST-5 6BA(7)(a) MBST-6 6BA(7)(b)(i) MBST-7 6BA(7)(b)(ii) MBST-8 6BA(7)(c) MBST-9 6BA(7)(d)(i) MBST-10 6BA(9) 3
2 7(4) SP-1 SP-2 SP-3 SP-4 () (a) (b) (c) (d ) () ( ) ( ) () (a) (b) (c) (d) () SP-5 (a) () (b) () (c) () ( ) SP-6 SP-7 SP-8 SP-9 SP-10 SP-11 SP-12 SP-13 ( ) ( ) ( ) ( ) ( ) ( ) 4
SP-14 SP-15 SP-16 ( ) ( ) SP-17 CYANIDE THIS SOLUTION IS POISONOUS SP-18 SP-19 SP-20 SP-21 SP-22 SP-23 SP-24 (a) (b) (c) SP-25 5
3 G-1 24(a) 900 (3 ) G-2 24(a) 900 (3 ) G-3 24(b) 900 (3 ) G-4 25(1) G-5 25(2) G-6 32(1) G-7 32(1)(a) G-8 32(1)(a) G-9 () 32(1)(b) G-10 32(1)(c) G-11 32(1)(c) 14 42 G-12 32(2)(a) G-13 32(2)(b) 6
G-14 32(2)(c) G-14a 32(2) 32(3) G-15 33(1) G-16a 33(2) G-16b 33(2) G-17 34(1) G-18 34(1) G-19 34(2) G-20 34(2) G-21 35(1) G-22 36(1) G-23 7 (250 36(2) ) G-24 36(3) 7
G-25 37(1) 10 001 100 1 1 1 1 011 250 1 1 1 2 1 026 500 2 1 2 3 2 051 750 3 2 3 4 3 076 100 4 2 4 5 4 101 125 5 3 5 6 5 126 150 5 3 5 7 5 151 175 6 4 6 8 6 176 200 6 4 6 9 6 201 225 7 5 7 10 7 226 250 7 5 7 11 7 251 275 8 6 8 12 8 276 300 8 6 8 13 8 300 50 25 50 G-26 37(1) G-27 38 G-28 39(1) G-29 39(2) G-30 39(2) G-31 39(3) G-32 ( ) G-33 ( ) G-34 ( ) 8
(a) (b) (c) G-35 16B(1) 2 G-36 16B(2) 1 G-37 16B(2) (a) (b) (c) () (d ) (e) ( f ) 16C(3) G-38 16D 16E 16C(1)(a) 16C(3) G-39 16D 16E 16C(1)(b) 16C(4) G-40 21 16C(2)(i) 12 12 16C(3) G-41 21 16C(2)(ii) 12 12 16C(4) 9
G-42 16C(3) 16F(2)(a) (i) (ii) (iii) 10
4 () () 12 (a) (b) (c) 96 ( ) 48-12 (a) (b) (i) 4 0.5 (ii) 10 1.5 ( ) (i) 4 0.2 (ii) 10 0.6 A-1 5(1) (2) (a) (b) (c) (i) (ii) A-2 5(3) A-3 5(4) 5(1) A-4 5(4) 5(1) 11
A-5 6(1) 28 A-6 6(1) 28 A-7 6(1) 6(3) 7 A-8 6(1) 6(3) 6(4) A-9 7(1)(a) A-10 7(1)(b) ( ) A-11 7(2)(a) A-12 7(2)(b) A-13 7(2) 7(3) A-14 7(4) A-15 8 A-16 8 A-17 9(1) A-18 9(1) A-19 9(1) A-20 9(1) 9(2) A-21 10(1) 12
A-22 ( 354 ) 10(2) () () ( 354 ) A-23 10(2) A-24 10(3) A-25 10(3) 19(1) A-26 10(4) 10(2) A-27 11(a) A-28 11(b) A-29 12(1)(a) A-30 12(1)(a) A-31 12(1)(b)(i) A-32 12(1)(b)(ii) A-33 12(1)(b)(iii) A-34 13(1) A-35 13(2) A-36 14(1)(a) A-37 14(1)(b)(i) A-38 14(1)(b)(ii) 13
A-39 14(1)(c) A-40 14(2) A-41 14(2) A-42 14(3) A-43 15(1)(a) A-44 15(1)(a) A-45 15(1)(a) 15(1)(b) A-46 15(1) 15(2) A-47 16(a) A-48 16(b)(i) A-49 16(b)(ii) A-50 4 17(1) A-51 17(2) 12 A-52 17(3)(a) A-53 17(3)(b) 5 A-54 17(3)(c) A-55 17(5) 14
A-56 18(a) 19 A-57 18(b) 19 A-58 18(c) 19 A-59 19(1) DANGER CONTAINS ASBESTOS DO NOT INHALE DUST (Follow Safety Instructions) () A-60 19(2) 19(1) A-61 19(2) (a) (b) (c) A-62 20(a) A-63 20(b) A-64 21(a) A-65 21(b) () A-66 21(c) A-67 10(4) A-68 12(3) A-69 13(3) A-70 17(4) 15
A-71 22(1)(a) & 22(2) A-72 22(1)(b) & 22(2) A-73 22(1)(c) 16
5 () AW-1 55 5(1) AW-2 5(2) ( 55 ) AW-3 5(2) ( 55 55 ) AW-4 ( 55 ) 5(2) AW-5 5(3) AW-6 6(1)(a) AW-7 6(1)(b) AW-8 6(1)(c) AW-9 6(2) AW-10 6(4) AW-11 6(5) AW-12 7(1) AW-13 7(2) 17
AW-14 8(1) AW-15 9(a) AW-16 9(b) AW-17 9(c) AW-18 180 10(1) AW-19 10(1) AW-20 10(2) AW-21 10(2) AW-22 10(2) AW-23 300 300 10(2)(a) AW-24 300 750 10(2)(b) 150 AW-25 750 10(2)(c) 200 AW-26 11 AW-27 12 AW-28 12 AW-29 12 AW-30 13(1) AW-31 13(2) AW-32 13(2) AW-33 14 18
AW-34 15(1) AW-35 15(2) AW-36 16(1) AW-37 16(2) 19
6 () BA-1 3(1) BA-2 3(2)(a) BA-2a 3(2)(a) BA-3 3(2)(b) 170 20
7 ( ) CH-1 3(1) CH-2 3(2) 750 (2.5 ) CH-3 4(1) & (2) CH-4 5 CH-5 6(1)(a) CH-6 6(1)(b) CH-7 6(1)(c) CH-8 6(1)(d ) CH-9 6(1)(e) CH-10 6(1)( f ) CH-11 6(1)(g) CH-12 6(2) CH-13 7(1)(a) CH-14 7(1)(b) 21
CH-15 8(1) CH-16 8(1) 8(2) CH-17 9(a) CH-18 9(b) 900 (3 ) CH-19 10 CH-20 100 100 12(1) CH-21 12(2) 10 10 49 50 1 1 1 6 12 24 3 6 12 12 24 36 1.3 900 2 4 8 900 (51 36 36 ) 25 4.5 1 1 2 (1 5 ) 30 ( ) 3 6 12 1 1 1 CH-22 12(3)(a) 22
CH-23 12(3)(b) CH-24 12(3)(c) CH-25 12(4) CH-26 12(5) CH-27 12(6) FIRST AID CH-28 12(7) & (8) CH-29 13 CH-30 30 99 14(1) CH-31 100 100 14(2) 2 CH-32 14(3) CH-33 15(1) 15(2) CH-34 16(a) CH-35 16(b) CH-36 16(c) CH-37 16(d ) CH-38 10A(a) CH-39 10A(b) 23
CH-40 10A(c) CH-41 10B 24
8 ( ) CP-1 4 CP-2 4 CP-3 5 CP-4 5 CP-5 6(1)(a) CP-6 6(1)(b) CP-7 6(1)(c) CP-8 6(2) CP-9 6(2) CP-10 7(1)(a) CP-11 7(1)(b) CP-12 8 CP-13 9 CP-14 10(a) CP-15 10(b) 25
9 () CS-1 5(1) CS-2 5(5) 5 CS-3 6(1)(a)(i) CS-4 5(2) 6(1)(a)(ii) CS-5 6(1)(a)(iii) (A) CS-6 6(1)(a)(iii) (B) CS-7 6(1)(b) CS-8 6(2) CS-9 7(a) CS-10 7(b) CS-11 7(c) 26
CS-12 7(d ) CS-13 7(e) CS-14 7( f )(i) CS-15 7( f )(ii) CS-16 8(a) CS-17 8(b) CS-18 6(1)(a) 8(c) (iii) CS-19 7 8(d ) CS-20 9(i) CS-21 9(ii) CS-22 10(1) CS-23 10(2)(a) CS-24 10(2)(b) CS-25 10(2)(c) 27
CS-26 10(2)(d ) CS-27 10(2)(e) CS-28 10(3) 10(2) CS-29 11(1) CS-30 11(2) CS-31 5(1) 5(2) CS-32 5(1) 5(2)(a)(i) CS-33 5(1) 5(2)(a)(ii) CS-34 5(1) 5(2)(a)(iii) (A) CS-35 5(1) 5(2)(a)(iii) (B) CS-36 5(1) 5(2)(a)(iii) (C) CS-37 5(1) 5(2)(a)(iii) (D) CS-38 5(1) 5(2)(a)(iii) (E) CS-39 5(1) 5(2)(b) CS-40 5(2) 5(3) 28
CS-41 5(2) 5(4) 5(2) (a) CS-42 5(1) 5(2)(c) CS-43 5(6) CS-44 10 13(a) CS-45 11 13(b) CS-46 11 13(b) CS-47 13(c) CS-48 13(c) 29
10 () CT-1 4 CT-2 5(1)(a) CT-3 5(1)(a) 50 CT-4 5(1)(b) CT-5 5(1)(c) 5 CT-6 5(1)(d) 7 CT-7 5(2)(a) CT-8 300 5(2)(b) () CT-9 5(2)(c) CT-10 5(3) CT-11 6(1) CT-12 6(2) CT-13 7 CT-14 8(a) CT-15 8(b) 30
CT-16 8(c) CT-l7 9(1) CT-18 9(2) CT-19 9(3) CT-20 10 (a) (b) (c) (d ) CT-21 11(1) CT-22 11(2) CT-23 12(a) CT-24 12(b) CT-25 13 CT-26 14(1) CT-27 14(2) CT-28 15(a) 31
CT-29 15(b) 18 CT-30 18 16 CT-31 17(a) CT-32 17(b) 32
11 ( ) DB-1 4 DB-2 5 DB-3 6 DB-4 7(1) DB-5 7(2) DB-6 7(3) DB-7 8 5 DB-8 8 DB-9 9(1) DB-10 9(2) 2 DB-11 9(3) DB-12 10(1) DB-13 10(2) DB-14 11 DB-15 12 DB-16 13(1) DB-16a 13(2) 33
DB-17 14(1) & (2) 2 (a) (b) (c) (d ) DB-18 14(3) DB-19 14(4) DB-20 14(5) DB-21 2 2 15(1) DB-22 15(2) DB-23 16(1) & (2) (a) (b) 10 1 6 1 DB-24 16(3) DB-25 16(4) DB-26 16(5) DB-27 17(a) 2 100 (4 ) NOSMOKING DB-28 17(b) 2 DB-29 18(1) DB-30 18(2) DB-31 18(3) ( ) 34
12 () () 1 1 () (a) (b) (c) DS-1 5(1), 6(1) 2 9(2) DS-2 5(1), 6(1) 9(3) (a) (b) (c) DS-3 5(1), 6(1) 9(4) (i) 3 3 (ii) 3 50 (iii) 50 500 (iv) 500 50 75 75 100 100 150 150 200 DS-4 5(1), 6(1), 9(5) 100 DS-5 5(1), 6(1) 9(6) 35
DS-6 8 (i) (ii) 1 2 (iii) 2 2 (iv) 3 1 3 (v) 4 1 4 DS-7 DS-6 5(1), 8 DS-8 6(1)(a), 8 (a) (b) DS-6 DS-9 6(1)(b), 8 (a) (b) DS-6 DS-10 6(1)(c), 8 (a) (b) DS-6 ( 1 2 ) DS-11 5(2), 6(2), 10 (a) (b) (c) (d ) 36
(e) DS-12 11(a) DS-13 11(b)(i) DS-14 11(b)(ii) DS-15 11(b)(iii) DS-16 11(c) DS-17 12(a) DS-18 12(b) DS-19 12(c) DS-20 12(d ) DS-21 13(a) DS-22 13(b) DS-23 13(c) DS-24 13(d ) DS-25 13(e) 37
DS-26 14 DS-27 15 38
1 2 6 7 8 () 1. 2. 3. 4. Name of Substance Classification Particular Risks Safety Precautions 1, 1, 1-1, 1, 1-Tri- Harmful 20/22 21 chloroethane; Methyl Chloroform 1, 1, 2, 2-1, 1, 2, 2-Tetra- Toxic 26/27 10, 20, 32, 39 chloroethane 1, 1-1, 1-Dichloro- Flammable and 11, 20 6/8, 13, 25, 27 ethane; Ethylidene Harmful Chloride 1, 2-1, 2-Diamino- Flammable and 10, 21/22, 34, 8, 13, 22, ethane; Ethylene- Corrosive 43 30/31/33 diamine 1, 2- Ethylenediamine ( 1, 2- (see 1, 2-Diamino- ) ethane) 1, 2-1, 2-Dimethoxy- Flammable and 10, 19, 20 13, 20/21 ethane; Ethylene Harmful Glycol Dimethyl Ether 1, 2-1, 2-Dichloro- Flammable and 11, 20 6/8, 13, 25, 27 ethane; Ethylene Harmful Dichloride 1, 4-1, 4-Dioxan Flammable and 11, 19, 20 6/8, 13, 27 Harmful 1, 5-1, 5-Naphtha- Harmful 20, 36/37/38, 22, 24, 32, 39 lene Diisocyanate 42 1- -2, 3-1-Chloro-2, 3- expoxypropane () (see Epichloro-hydrin) 2, 2-2, 2 -Iminodi- ethylamine (see ( Diethylene- ) triamine) 2, 4, 6-2, 4, 6-Trimethyl-1, -1, 3, 5-3, 5-trioxan (see ( Paraldehyde) ) 2-2-Ethoxy- Flammable and 10, 36 13, 20 ethanol; Ethylene Irritant Glycol Monoethyl Ether 39
2-2-Butoxy- Harmful 20/21/22, 37 20/21 ethanol; Ethylene Glycol Monobutyl Ether 2-2-Methoxy- Flammable and 10, 20/21/22, 13, 20/21 ethanol; Ethylene Harmful 37 Glycol Monomethyl Ether 2--1, 2-Methyl- 3- buta-1, 3-diene ( ) (see Isoprene) 2--1-2-Propen-1-ol () (see Allyl Alcohol) 2--2-2-Methylbutan-2-ol; Flammable and 11, 20 6/8, 13, 20/21 tert-pentanol Irritant 2- -2-2-Methyl-propan- () 2-ol (see tert-butyl Alcohol) 3, 3-3, 3 -Dimethoxy- benzidine ( (see o-dianisidine) ) 3, 5, 5-3, 5, 5-Trimethyl- -2- cyclohex-2-enone ( (see Isophorone) ) α, α - ( ) 1. 2. 3. 4. Name of Substance Classification Particular Risks Safety Precautions α, α -Dimethylbenzyl Hydroperoxide (see Cumene Hydroperoxide) α, α - α, α -Dichloro- ( toluene (see Benzal ) Chloride) α - α -Chloro- ( ) toluene (see Benzyl Chloride) α - α -Naphthylamine Harmful 20/21/22, 33, 18, 30 β - containing less 45 1% 1- than 1% of β -Naphthylamine; 1-Naphthylamine β - β -Naphthol; Harmful 20/22 20/21 2-2-Naphthol Ethanediol; Ethylene Harmful 22 20 Glycol Ethylene Glycol ( 2- Monoethyl Ether ) (see 2-Ethoxy-ethanol) 40
1. 2. 3. 4. Name of Substance Classification Particular Risks Safety Precautions Ethylene Glycol ( 1, 2- Dimethyl Ether ) (see 1, 2-Dimethoxyethane) Ethylene Glycol ( 2- Monobutyl Ether ) (see 2-Butoxy-ethanol) Ethylene Glycol ( 2- Monomethyl Ether ) (see 2-Methoxyethanol) Acetylene; Ethyne Flammable 5, 6, 11 8, 13, 27 Ethylbenzene Flammable and 11, 37 6/8, 13, 25 Irritant Ethyl Glycol ( Acetate (see 2- -2- Ethoxyethyl Acetate) ) Ethyl Mercaptan; Flammable and 11, 20 6/8, 13, 21, 38 Ethanethiol Harmful Ethanethiol () (see Ethyl Mercaptan) Amyl Acetate; Flammable 10 13, 19 Pentyl Acetate Pentyl Acetate ( ) (see Amyl Acetate) Ethyl Alcohol; Flammable 11 6/8, 13 Ethanol Ethanol (see Ethyl ( ) Alcohol) Acetaldehyde Flammable and 12,36/37 2/6/8,13,25,27 Irritant Acetyl Chloride Flammable and 11 14, 34 6/7, 8, 13, 20/21, Corrosive 22 Diethyl Ketone (-3- ) (see Pentan-3-one) Diethylamine Flammable and 11, 36/37 6/8, 13, 22, 25 Irritant Diethyl Ether Flammable 12, 19 2/6/8, 13, 25, 27 Xylene, all Isomers Flammable and 10, 20 13, 20/21 Harmful Xylenol, all Isomers Toxic 24/25, 34 16/17, 24, 38 Dimethylamine Flammable and 13, 36/37 8, 13, 22, 25 Irritant Dimethyldi- Flammable and 11, 36/37/38 6/8, 13, 20 chlorosilane Irritant 41
Dimethyl Flammable and 10, 20/21, 36 13, 22, 24, 30 Formamide Harmful Dimethyl Ether Flammable 13 8, 13, 27-4, Diphenyl- Harmful 20, 36/37/38, 42 22, 24, 32, 39 4 - methane-4, 4 -diisocyanate Diethylenetri-amine; Corrosive 21/22, 34, 43 22, 30/31/33 2, 2-2, 2 -Iminodiethyl- amine Manganese Dioxide Harmful 20/22 21 Butane Flammable 13 8, 13, 27 Carbon Disulphide Flammable and 11, 26 13, 23, 25, 27, 37, Toxic 39-1, 3, 5- Dichloro-1, 3, 5- ( triazine- trione (see Dichloro- ) isocyanuric Acid) -1, 3, 5- Dichloro-1, 3, 5- triazine- ( trione, Sodium Salt of ) 1. 2. 3. 4. Name of Substance Classification Particular Risks Safety Precautions (see Sodium Salt of Dichloroiso-cyanuric Acid) -1, 3, 5- Dichloro-1, 3, 5- triazine- ( trione, Potassium Salt of (see Potassium Salt ) of Dichloroisocyanuric Acid) Ethylene Dichloride ( 1, 2- (see 1, 2-Dichloro- ) ethane) Dichloro- Harmful 20 20 methane; Methylene Dichloride Dinitrotoluene, all Toxic 23/24/25, 33 10, 24, 31, 38 Isomers Dinitrobenzene, all Toxic 26/27/28, 33 10, 24, 30/31, 39 Isomers Dichloroiso- Oxidizing and 8, 22, 31, 36/37 7, 22, 35-1, cyanuric Acid; Harmful 3, 5- Dichloro- 1, 3, 5-triazinetrione 42
1. 2. 3. 4. Name of Substance Classification Particular Risks Safety Precautions Sodium Salt of Oxidizing and 8, 22, 31, 36/37 7, 22, 35 Dichloroiso- Harmful -1, 3, cyanuric Acid; 5- Dichloro-1, 3, 5-triazinetrione, Sodium Salt Potassium Salt of Oxidizing and 8, 22, 31, 36/37 7, 22, 35 Dichloroiso- Harmful -1, 3, cyanuric Acid; 5- Dichloro-1, 3, 5-triazinetrione, Potassium Salt Butanone; Ethyl Flammable 11 6/8, 13, 19, 27 Methyl Ketone; Methyl Ethyl Ketone Butanol, all Isomers, Flammable and 10, 20 13 with the exception Harmful 2- -2- of 2-Methyl- propan-2-ol; Butyl Alcohols Butyl Alcohol, all Isomers with the exception of tert- ( ) Butyl Alcohol (see Butanol) Triethylamine Flammable and 11, 36/37 6/8, 13, 22, 25 Irritant Trimethyl- Flammable and 13, 36/37 8, 13, 22, 25 amine Irritant Boron Trifluoride Toxic 14, 26, 35 8, 16/17, 22, 24, 30, 39 Chromium Trioxide Oxidizing and 8, 35, 43 24, 30/31/33 Corrosive ( Hexane (Mixture of Flammable 11 6/8, 13, 19, 25, 27 5% Isomers containing a maximum of 5% ) n-hexane) ( Hexane (Mixture of Flammable and 11, 20/21, 40 6/8, 13, 19, 20, 5% Isomers containing Harmful 25, 27 more than 5% ) n-hexane) Trichloro- Harmful 20/22 21 ethylene Boron Trichloride Toxic 14, 26/28, 34 8, 16/17, 22, 24, 30, 39 Antimony Corrosive 34, 37 20/21, 22 Trichloride Phosphorus Corrosive 34, 37 6/7, 20/21, 22 Trichloride 43
( ) 1. 2. 3. 4. Name of Substance Classification Particular Risks Safety Precautions Trichloromethane (see Chloroform) () Trichloro- ( (methyl) silane ) (see Methyl-trichlorosilane) Trichlorosilane Flammble 15, 17 6/7, 13, 20/21, 37 Calomel (see ( Mercurous Chloride) ) Vanadium Pentoxide Harmful 20 18 Phosphorus Corrosive 35 18, 22, 30/31/33 Pentoxide Hexa- Toxic 23, 36/37/38, 42 16/17, 22, 24, 32, methylene 39 Diisocyanate Antimony Corrosive 34, 37 20/21, 22 Pentachloride Phosphorus Corrosive 34, 37 6/7, 20/21, 22 Pentachloride Pentachloro- Toxic 23/24/25 16/17, 24, 30/33, phenol 38 Reaction Product: Irritant 36/38, 43 24, 31/33 A- Bisphenol A- Epichloro- ( hydrin Epoxy Resin (number average 700) molecular weight not more than 700) -3- Pentan-3-one; Flammable 11 6/8, 13, 27 Diethyl Ketone Ethyl Methyl Ether Flammable 13 8, 13, 27 Toluene Flammable and 11, 20 6/8, 13, 25, 27 Harmful Toluene- Toxic 26, 36/37/38, 42 16/17, 22, 24, 32, ( diisocyanate 39 ) (Mixture of Isomers) Methylamine Flammable and 13, 36/37 8, 13, 22, 25 Irritant Methane Flammable 11 6/8, 13, 27 Cresol, all Isomers Toxic 24/25, 34 16/17, 20/21, 24, 38 Methylglycol Acetate ( (see 2-Methoxy- -2- ethyl Acetate) ) 44
1. 2. 3. 4. Name of Substance Classification Particular Risks Safety Precautions Methyl Ethyl Ketone ( ) (see Butanone) Ethyl Methyl Ketone ( ) (see Butanone) Methyl- Flammable and 11, 14, 36/37/38 6/7, 13, 22, 33 trichloro-silane; Irritant () Trichloro- (methyl) silane Methyl Methacrylate Flammable and 11, 36/37/38, 43 6/8, 13, 25, 27 Irritant ( Methyl Chloride ) (see Chloromethane) Methyl Chloroform ( 1, 1, 1- (see1, 1, 1, Trichloro- ) ethane) ( Methyl Bromide ) (see Bromomethane) Methyl Acrylate Flammable and 11, 20/22, 6/8, 13, 27 Irritant 36/37/38 ( Tetrachloro- ) ethylene (see Perchloroethylene) Titanium Corrosive 14, 34, 36/37 6/7, 20/21, 22 Tetrachloride Carbon Toxic 26/27 10, 20, 32, 39 Tetrachloride; Tetrachloromethane Tetrachloro- ( ) methane (see Carbon Tetrachloride) Tetrahydro-furan Flammable and 11, 19, 36/37 6/8, 13, 25, 27 Irritant Acetone Flammable 11 6/8, 13, 19, 27 Ethyl Propionate Flammable 11 6/8, 13, 19, 25, 27 Isopropyl Formate Flammable 11 6/8, 13, 27 Methyl Alcohol; Flammable and 11, 23/25 6/8, 13, 16, 20 Methanol Toxic Methanol (see ( ) Methyl Alcohol) Propanol, all Flammable 11 6/8, 13 Isomers; Propyl Alcohol 45
1. 2. 3. 4. Name of Substance Classification Particular Risks Safety Precautions Pentanol, all Isomers with the exception of tert-pentanol (see ( ) Amyl Alcohol) Amyl Alcohol, Flammable and 10, 20 13, 20/21 Mixed Isomers, with Harmful the exception of tert- Pentanol; Pentanol Phosphorus, White Flammable and 17, 26/28, 35 4, 16/17, 22, 24, or Yellow Toxic 30/31/33, 39 Formaldehyde Irritant 36/37, 43 22 5% Solution, at least 30% 5% but not more than 30% Formaldehyde Toxic 23/24/25, 43 10, 22, 24 30% Solution, more than 30%; Formalin Ortho- Irritant 36 21 10% phosphoric Acid, more than 10% 25% but not more than 25% acid; Phosphoric Acid Ortho- Corrosive 34 20/21, 22 phosphoric Acid, 25% more than 25% acid; Phosphoric Acid 2, Paraldehyde; 2, 4, Flammable 10 8, 13, 25, 27 4, 6--1, 6-Trimethyl-1, 3, 3, 5-5-Trioxan Perchloro- Harmful 20/22 21 ethylene; Tetrachloroethylene Sodium Irritant 31, 36/38 21 Hypochlorite 5% Solution, containing at least 5% but not 10% more than 10% Active Chlorine Sodium Corrosive 31, 34 20/21, 24 Hypochlorite 10% Solution, containing more than 10% Active Chlorine Calcium Oxidizing and 8, 31, 34 20/21, 22, 37 Hypochlorite, Corrosive 39% concentration of Active Chlorine more than 39% Polychloro- Harmful 33 10, 12, 29, 35 PCB biphenyls; PCB 46
1. 2. 3. 4. Name of Substance Classification Particular Risks Safety Precautions Petroleum Flammable 11 6/8, 13, 25, 27 Distillates and Coal Tar Distillates of complex and 23 variable composition, flash point below 23 C Petroleum Flammable 10 13 Distillates and Coal Tar Distillates of complex and variable composition, flash point equal to or 23 greater than 23 C and equal to or less 66 than 66 C Dieldrin Toxic 23, 24, 25 10, 38 (HEOD85%) (HEOD85%) Mercury, Organic Toxic 26/27/28, 33 10, 18, 24, 30, 39 Compounds of, with the exception of those specified elsewhere in this list Mercury, Inorganic Toxic 26/27/28, 33 1, 10, 18, 24, 39 Compounds of, with the exception of Mercuric Sulphide and those specified elsewhere in this list Sodium Harmful 7, 22, 31, 49 6/7, 22, 24, 37 Hydrosulphite; Sodium Dithionite Pyridine Flammable and 11, 20/21/22 6/8, 13, 22, 24 Harmful Octane, all Isomers Flammable 11 6/8, 13, 25, 27 Hydrazine Flammable and 10, 26/27/28, 10, 13, 19, Toxic 34, 40 30/31/33, 39 tert-butyl Alcohol; Flammable and 11, 20 6/8, 13 2- - 2-Methyl- Harmful 2- propan-2-ol Benzal Chloride; Irritant 36/37/38 33 Benzylidene α, α Chloride; α, α -Dichlorotoluene tert-pentanol ( 2-- (see 2-Methyl- 2-) butan-2-ol) 47
1. 2. 3. 4. Name of Substance Classification Particular Risks Safety Precautions Benzyl Chloride; Flammable and 10, 36/37/38 13, 33 α - α -Chlorotoluene Irritant Epichloro- Flammable and 10, 26/27/28, 40 8, 10, 13, 19, 1- -2, hydrin; 1-Chloro-2, Toxic 30/31/33, 39 3-3-epoxypropane Turpentine Flammable and 10, 20/21/22 13 Harmful Hydrazine Solution, Corrosive 24/25, 34, 40 30/31/33 5% at least 5% but not 64% more than 64% Benzyl Alcohol Harmful 20, 22 22 Benzene Flammable and 11, 23/24, 39, 6/8, 10, 13, 20, 25 Toxic 45 Arsine Toxic 23/25 1, 16/17, 19, 24, 38 Styrene Flammable and 10, 36/37 13, 19, 21 Irritant Phenylene- Toxic 23/24/25, 43 16/17, 24, 38 diamine, all Isomers Benzyl Benzoate Harmful 22 21 Benzaldehyde Flammable and 10, 22 13, 20 Harmful Benzoyl Chloride Corrosive 34 20/21, 22 Caustic Potash () (see Potassium Hydroxide) Caustic Soda ( (see Sodium ) Hydroxide, Anhydrous) Aniline Toxic 23/24/25, 33 10, 24, 30/31, 38 Aniline, Salts of Toxic 23/24/25, 33 10, 24, 30/31, 38 Cumene; Isopropyl Flammable and 10, 37 13, 20 Benzene Irritant Sodium Dichromate Irritant 36/37/38, 43 18, 24 Potassium Irritant 36/37/38, 43 18, 24 Dichromate Ammonium Explosive and 1, 8, 36/37/38, 13, 24, 29 Dichromate Irritant 43 Phosphorus, Red Flammable 11, 16 6, 11, 13, 37 Fluorine Toxic 7, 26/27, 35 6/8, 19, 30/31/33, 39 Ammonia, Flammable and 10, 23 6/8, 13, 21, 32 Anhydrous Toxic 48
1. 2. 3. 4. Name of Substance Classification Particular Risks Safety Precautions Ethylidene Chloride; ( 1, 1- (see 1, 1-Dichloro- ) ethane) Ethylene Glycol () (see Ethanediol) Ammonia Solution Irritant 36/37/38 22 with at least 10% 10% but not more than 35% 35% Ammonia Ammonia Solution Corrosive 34, 36/37/38 6, 20/21, 22 35% with more than 35% Ammonia Arsenic Compounds Toxic 23/25 1, 16/17, 24, 38 Sodium Fluoride Toxic 23/24/25 1, 16/17, 22, 38 Potassium Fluoride Toxic 23/24/25 1, 16/17, 22, 38 Methylene ( ) Dichloride (see Dichloromethane) Maleic Anhydride Irritant 22, 36/37/38, 42 18, 24, 33 Maleic Acid Irritant 22, 36/37/38 22, 24, 31 Benzylidene ( ) Chloride (see Benzal Chloride) Sodium Toxic 23/24/25 1, 16/17, 22, 38 Fluorosilicate Potassium Toxic 23/24/25 1, 16/17, 22, 38 Fluorosilicate Ammonium Toxic 23/24/25 1, 16/17, 22, 38 Fluorosilicate Perchloric Acid, Corrosive 34 19, 24, 30 with at least 10% 10% but not more than 50% 50% acid Perchloric Acid, Oxidizing and 5, 8, 35 2, 19, 22, 50% more than 50% Corrosive 30/31/33 Sodium Nitrite Oxidizing and 8, 25 16/17, 38 Toxic Sodium Perchlorate Oxidizing and 9, 22 10, 11, 18, 23 Harmful Potassium Nitrite Oxidizing and 8, 25 16/17, 38 Toxic Potassium Oxidizing and 9, 22 10, 11, 18, 23 Perchlorate Harmful Thionyl Chloride Corrosive 14, 34, 37 20/21, 22, 26 Oxalic Acid Harmful 21/22 20/21 49
1. 2. 3. 4. Name of Substance Classification Particular Risks Safety Precautions Oxalic Acid, Salt of Harmful 21/22 20/21 Potassium Oxidizing and 8, 22 40 Permanganate Harmful Hydrogen Flammable 11 6/8, 13 Sodium Dithionite ( (see Sodium ) Hydrosulphite) Isoprene; 2- Flammable 12 2/6/8, 13, 25, 27 2--1, Methylbuta-1, 3-3-diene Isopropyl- ( ) benzene (see Cumene) Isopropyl Alcohol ( ) (see Propanol) 2- Allyl Alcohol; Flammable and 11, 26, 36/37/38 6/8, 13, 16, 19, -1-2-Propen-1-ol Toxic 33, 39 Isophorone; 3, 5, 5- Irritant 36/37/38 22 3, 5, 5- Trimethyl- -2- cyclohex-2-enone 1, 3-Benzene- () diol (see Resorcinol) Sodium Irritant 36/38 22 Hydroxide Solution with at least 1% but 1% not more than 5% 5% Sodium Hydroxide Sodium Corrosive 35 22, 23, 31/33 Hydroxide Solution, with more than 5% 5% Sodium Hydroxide Potassium Corrosive 35 22, 23, 31/33 Hydroxide; Caustic Potash Potassium Irritant 36/38 22 Hydroxide Solution with at least1% but 1% not more than 5% 5% Potassium Hydroxide Potassium Hydroxide Corrosive 35 22, 23, 31/33 Solution with more 5% than 5% Potassium Hydroxide Hydrofluoric Acid Toxic and 26/27/28, 35 6/8, 19, 22, Corrosive 30/31/33, 39 50
1. 2. 3. 4. Name of Substance Classification Particular Risks Safety Precautions Lead Alkyls (C 1 -C 5 ) Toxic 26/27/28, 33 10, 19, 22, 30/31, (C 1 -C 5 ) 39 Cumene Oxidizing and 11, 35 2/6/8, 11, 13, 23, α, α - Hydroperoxide; α, Corrosive 31/33 α -Dimethyl- benzyl Hydroperoxide Cyclo- Explosive and 3, 35 2/6/8, 11, 13, 23, hexanone Corrosive 28, 31/33 Hydroperoxide Chlorine Toxic 23, 36/37/38 6/8, 19, 38 Chloroacetyl Corrosive 34, 37 8, 20/21, 22 Chloride Chloro- Flammable and 13, 20 8, 13, 27 methane; Methyl Harmful Chloride Hydrogen Fluoride, Toxic and 26/27/28, 35 6/8, 19, 22, Anhydrous Corrosive 30/31/33, 39 Mercurous Chloride; Harmful 22 40 Calomel Hydrogen Sulphide Flammable and 13, 26 6/8, 13, 19, 21, 39 Toxic Hydrogen Cyanide Flammable and 12, 26/27/28 2/6/8, 10, 13, 19, Toxic 39 Sodium Hydroxide, Corrosive 35 22, 23, 31/33 Anhydrous; Caustic Soda Hydrogen Cyanide, Toxic 26/27/28, 32 1, 6, 16/17, 24, ( Salts of, with the 25, 39 exception of Complex Cyanides such as ) Ferrocyanides, Ferricyanides and Mercuric Oxycyanide Sodium Sulphide Corrosive 31, 34 20/21/, 22 ( Sodium Cyanide ) (see Hydrogen Cyanide, Salts of) Hydrogen Chloride, Corrosive 35, 37 6/8, 22, 30/31/33, Anhydrous 38 ( Potassium Cyanide ) (see Hydrogen Cyanide, Salts of) Zinc Chloride Corrosive 34 6/7, 20/21, 24 Stannic Chloride Corrosive 34, 37 6/7, 20/21, 22 51
1. 2. 3. 4. Name of Substance Classification Particular Risks Safety Precautions Nitrocellulose ( (see Cellulose ) Nitrate) Chloroform; Harmful 20 20/21 Trichloromethane Chlorobenzene Flammable and 10, 20 13, 20/21 Harmful Succinic Anhydride Irritant 36/37 21 Nitrobenzene Toxic 26/27/28, 33 10, 19, 24, 30/31, 39 Oleum, containing Corrosive 14, 35, 37 22, 26, 30/31/33 SO 3 at least 20% but not 20% more than 65% SO 3 65% Sulphuric Acid, at Irritant 36/38 22 5% least 5% but not 15% more than 15% Nitric Acid, at least Corrosive 35 19, 22, 23, 31/33 20% 20% but not more 70% than 70% Sulphuric Acid, Corrosive 35 22, 26, 30/31/33 15% more than 15% Nitric Acid, more Oxidizing and 8, 35 19, 22, 30/31/33 70% than 70% Corrosive Sodium Chlorate Oxidizing and 9, 20/22 10, 11, 13, 23 Harmful Potassium Chlorate Oxidizing and 9, 20/22 10, 11, 13, 23 Harmful Silver Nitrate Corrosive 34 20, 22, 31 Nitric Acid and Oxidizing and 8, 35 19, 22, 26, Sulphuric Acid, Corrosive 30/31/33 Mixture of, 30% concentration more than 30% Nitric Acid Cellulose Nitrate; Flammable 11 13, 27, 31/33 Nitrocellulose ( (containing a maximum of 12.6%) 12.6% Nitrogen) Chloroacetic Acid Toxic 23/24/25, 35 16/17, 18, 30/31/33 Sulphuryl Chloride Corrosive 14, 34, 37 20/21, 22, 26 Iodine Harmful 20/21 19, 21 Bromine Corrosive 26, 35 6/8, 19, 20/21, 22, 25 52
1. 2. 3. 4. Name of Substance Classification Particular Risks Safety Precautions Beryllium Toxic 26/27, 37, 39 10, 18, 22, 24, 39 Peracetic Acid, Oxidizing and 5, 22, 34 2, 23, 30 10% more than 10% Corrosive Lead Compounds Harmful 20/22, 33 10, 16/17 with the exception of those specified elsewhere in this list Beryllium Toxic 26/27, 37, 39 10, 18, 22, 24, 39 Compounds with the exception of Aluminium Beryllium Silicates Bromo- Toxic 26 1, 6/8, 19, 20/21, methane; Methyl 23, 39 Bromide Dilauroyl Peroxide Oxidizing and 11, 36/37/38 2/6/8, 11, 13, 23, Irritant 31/33 Dibenzoyl Peroxide ( (see Benzoyl ) Peroxide) Methyl Ethyl Explosive and 3, 23/24/25, 2/6/8/, 11, 13, Ketone Peroxide Toxic 36/37/38 23, 28, 31/33 Benzoyl Peroxide; Explosive and 3, 36/37/38 2/6/8, 11, 13, 23, Dibenzoyl Peroxide Irritant 28, 31/33 Sodium Peroxide Oxidizing and 8, 35 7, 23, 31/33 Corrosive Hydrogen Peroxide Corrosive 34 24, 33 Solution containing at least 20% but not 20% more than 60% 60% Hydrogen Peroxide Barium Peroxide Oxidizing and 8, 20/22 10, 23 Harmful Cyclo- Explosive and 3, 35 2/6/8, 11, 13, 23, hexanone Peroxide Corrosive 28, 31/33 ( Formalin (see Formaldehyde 30%) Solution, more than 30%) Resorcinol; 1, Harmful 22, 36/38 22 3-Benzenediol Bromoacetic Acid Toxic 23/24/25, 35 16/17, 30/31/33, 38 p-dichloro- Harmful 22 20/21 1, 4- benzene; 1, 4-Dichlorobenzene 53
1. 2. 3. 4. Name of Substance Classification Particular Risks Safety Precautions Calcium Carbide Flammable 15 6/7, 13, 37 Potassium Chromate Irritant 36/37/38, 43 18, 24 o-dichloro- Harmful 20 20/21 1, 2- benzene; 1, 2-Dichlorobenzene Zinc Dust; Zinc Flammable 10, 15 6/7, 13, 37 Powder ( Zinc Dust; Zinc Flammable 15, 17 6/7, 13, 37 ) Powder (Pyrophoric) 25% Acetic Acid, 25% Corrosive 34 19, 20/21, 22 or more but not 90% more than 90% Acetic Acid, more Flammable and 10, 35 13, 19, 22, 90% than 90% Corrosive 30/31/33-2- 2-Ethoxyethyl Flammable and 10, 20/21 13, 20 Acetate; Ethyl Harmful Glycol Acetate -2-2-Methoxy- Flammable and 10, 20/21 13, 20 ethyl Acetate; Harmful Methylglycol Acetate Ethyl Acetate Flammable 11 6/8, 13, 19, 25, 27 n-butyl Acetate Flammable 11 6/8, 13 Methyl Acetate Flammable 11 6/8, 13, 19, 25, 27 Isopropyl Acetate Flammable 11 6/8, 13, 19, 25, 27 Acetic Anhydride Flammable and 10, 34 13, 20/21, 22 Corrosive o-dianisidine; 3, Toxic 26/27/28, 33, 45 10, 18, 24, 30/31, 3, 3-3 -Dimethoxy- 39 benzidine o-dianisidine Salts Toxic 26/27/28, 33, 45 10, 18, 24, 30/31, 39 Cyclohexane Flammable 11 6/8, 13, 27 Cyclo- Flammable and 10, 20 13, 21 hexanone Harmful Cyclohexanol Harmful 20/22, 37/38 20/21 ( Magnesium, Powder Flammable 15, 17 6/7, 13, 37 ) (Pyrophoric) Magnesium, Powder Flammable 11, 15 6/7, 13, 37 or Turnings ( Phosphoric Acid ) (see Orthophosphoric Acid) 54
1. 2. 3. 4. Name of Substance Classification Particular Risks Safety Precautions Tricresyl Phosphates, Harmful 21/22 24 Mixtures of, containing a maximum of 1% of 1% Esterified o-cresol; Tritolyl Phosphates Tricresyl Phosphates, Toxic 23/24/25, 39 16/17, 24, 38 Mixtures of, containing more than 1% of 1% Esterified o-cresol; Tritolyl Phosphates Tritolyl Phosphates ( (see Tricresyl ) Phosphates) Furfuryl Alcohol Harmful 20/21/22 16/17, 20/21 2-Furaldehyde; Flammable and 10, 23/25 13, 16, 20/21, 38 Furfural; Toxic Furfuraldehyde Formic Acid, at Corrosive 34 19, 20/21, 22 25% least 25% but not 90% more than 90% Formic Acid, more Corrosive 35 19, 22, 30/31/33 90% than 90% Alcohol, Denatured ( ) (see Ethyl Alcohol) Hydrochloric Acid, Irritant 36, 38 24 10% at least 10% but not 25% more than 25% Hydrochloric Acid, Corrosive 34, 37 22, 24 25% more than 25% PCB ( PCB (see Polychloro- ) biphenyls) 55
2 8 9 SYMBOLS Classification Symbols Explosive Oxidizing Flammable Toxic 56
Classification Symbols Harmful Corrosive Irritant Prescribed Form of Label 57
3 LIST OF PARTICULAR RISKS Single risks 1. Explosive when dry 2. Risk of explosion by shock, friction, fire or other sources of ignition 3. Extreme risk of explosion by shock, friction, fire or other sources of ignition 4. Forms very sensitive explosive metallic compounds 5. Heating may cause an explosion 6. Explosive with or without contact with air 7. May cause fire 8. Contact with combustible material may cause fire 9. Explosive when mixed with combustible material 10. Flammable 11. Highly flammable 12. Extremely flammable 13. Extremely flammable liquefied gas 14. Reacts violently with water 15. Contact with water liberates highly flammable gases 16. Explosive when mixed with oxidizing substances 17. Spontaneously flammable in air 18. In use, may form flammable/explosive vapour-air mixture 19. May form explosive peroxides 20. Harmful by inhalation 21. Harmful in contact with skin 22. Harmful is swallowed 23. Toxic by inhalation 24. Toxic in contact with skin 25. Toxic if swallowed 26. Very toxic by inhalation 27. Very toxic in contact with skin 28. Very toxic if swallowed 29. Contact with water liberates toxic gas 30. Can become highly flammable in use 31. Contact with acids liberates toxic gas 32. Contact with acids liberates very toxic gas 58
Single risks 33. Danger of cumulative effects 34. Causes burns 35. Causes severe burns 36. Irritating to eyes 37. Irritating to respiratory system 38. Irritating to skin 39. Dangers of very serious irreversible effects 40. Possible risk of irreversible effects 41. Risk of serious damage to eyes 42. May cause sensitisation by inhalation 43. May cause sensitisation by skin contact 44. Risk of explosion if heated under confinement 45. May cause cancer 46. May cause heritable genetic damage 47. May cause birth defects 48. Danger of serious damage to health by prolonged exposure 49. Spontaneously combustible in air when wet Combinations of risks 14/15. Reacts violently with water, liberating highly flammable gases 15/29. Contact with water liberates toxic, highly flammable gas 20/21. Harmful by inhalation and in contact with skin 20/21/22. Harmful by inhalation, in contact with skin and if swallowed 20/22. Harmful by inhalation and if swallowed 21/22. Harmful in contact with skin and if swallowed 23/24. Toxic by inhalation and in contact with skin 23/24/25. Toxic by inhalation, in contact with skin and if swallowed 23/25. Toxic by inhalation and if swallowed 24/25. Toxic in contact with skin and if swallowed 26/27. Very toxic by inhalation and in contact with skin 26/27/28. Very toxic by inhalation, in contact with skin and if swallowed 26/28. Very toxic by inhalation and if swallowed 27/28. Very toxic in contact with skin and if swallowed 36/37. Irritating to eyes and respiratory system 36/37/38. Irritating to eyes, respiratory system and skin 59
Combinations of risks 36/38. Irritating to eyes and skin 37/38. Irritating to respiratory system and skin 42/43. May cause sensitisation by inhalation and skin contact 60
4 LIST OF SAFETY PRECAUTIONS Single safety precautions 1. Keep locked up 2. Keep in a cool place 3. Keep away from living quarters 4. Keep contents under... ( ) (appropriate liquid to be specified) 5. () Keep under... (inert gas to be specified) 6. Keep container tightly closed 7. Keep container dry 8. Keep container in a well ventilated place 9. Do not keep the container sealed 10. Keep away from food, drink and animal feeding stuffs 11. () Keep away from... (incompatible materials to be indicated) 12. Keep away from heat 13. Keep away from sources of ignition---no Smoking 14. Keep away from combustible material 15. Handle and open container with care 16. When using do not eat or drink 17. When using do not smoke 18. Do not breathe dust 19. ( Do not breathe gas/fumes/vapour/spray ) (appropriate wording to be specified) 20. Avoid contact with skin 21. Avoid contact with eyes 22. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 23. Take off immediately all contaminated clothing 24. After contact with skin, wash immediately with () plenty of... (to be specified) 25. Do not empty into drains 26. Never add water to this product 27. Take precautionary measures against static discharges 28. Avoid shock and friction 29. This material and its container must be disposed () of safely by... (to be specified) 30. Wear suitable protective clothing 61
Single safety precautions 31. Wear suitable protective gloves 32. In case of insufficient ventilation, wear suitable respiratory equipment 33. ( ) Wear eye/face protection (appropriate wording to be specified) 34. () To clean the floor and all objects contaminated by this material use... (to be specified) 35. In case of fire and/or explosion do not breathe fumes 36. ( During fumigation/spraying wear suitable ) respiratory equipment (appropriate wording to be specified) 37. In case of fire, use... (indicate in the ( space the precise type of fire-fighting equipment; ) if water increases the risk, add Never use water ) 38. ( If you feel unwell, seek medical advice (show the ) label where possible) 39. ( In case of accident or if you feel unwell, seek ) medical advice immediately (show the label where possible) 40. If swallowed seek medical advice immediately and show this container or label 41. ( Keep at temperature not exceeding... C ) (to be specified) 42. ( ) Keep wetted with... (appropriate material to be specified) 43. Keep only in the original container 44. () Do not mix with... (to be specified) 45. Use only in well ventilated areas 46. Not recommended for interior use on large surface areas Combination of safety precautions 2/6/8. Keep container tightly closed, in a cool well ventilated place 2/8. Keep in a cool well ventilated place 2/8/11. Keep in a cool, well ventilated place away from... ()... (incompatible materials to be indicated) 2/8/11/43. Keep only in the original container in a cool, well ventilated place away from... () (incompatible materials to be indicated) 2/8/43. Keep only in the original container in a cool, well ventilated place 2/11. Keep in a cool place away from... () (incompatible materials to be indicated) 6/7. Keep container tightly closed and dry 62
Combination of safety precautions 6/8. Keep container tightly closed and in a well ventilated place 16/17. When using do not eat, drink or smoke 20/21. Avoid contact with skin and eyes 30/31. Wear suitable protective clothing and gloves 30/31/33. Wear suitable protective clothing, gloves and ( eye/face protection (appropriate wording to be ) specified) 30/33. Wear suitable protective clothing and eye/face ( ) protection (appropriate wording to be specified) 31/33. ( Wear suitable gloves and eye/face protection ) (appropriate wording to be specified) 41/43. Keep only in the original container at temperature () not exceeding... C (to be specified) 63
13 () E-1 5(1) E-2 5(1) E-3 5(2) E-4 6 E-5 6 E-6 7(a) E-7 7(b) E-8 7(c) E-9 7(d ) E-10 7(e) E-11 7( f ) E-12 8(1) 64
E-13 8(1) E-14 8(2) E-15 8(2) E-16 8(3) E-17 9 E-18 10 E-19 11 E-20 12(1) E-21 13(1) E-22 13(1) E-23 13(2) E-24 13(3) E-25 14(a) E-26 14(b) E-27 14(c) 65
E-28 15(a) E-29 15(b) E-30 15(c) E-31 15(d ) E-32 16(1) E-33 16(3) E-34 16(4) DANGER LIVE WIRES UNAUTHORIZED ENTRY PROHIBITED 50 E-35 17(a) E-36 17(b) E-37 17(c) 66
E-38 18 E-39 19(1) E-40 19(1) DANGER UNDER REPAIR 50 E-41 20 E-42 21(1) E-43 21(2) E-44 22 E-45 23 E-46 24(a) E-47 24(b) E-48 24(c) E-49 25 DANGER HIGH VOLTAGE 50 67
E-50 26(1) E-51 26(2) (a) (b) E-52 27 E-53 28(1) E-54 28(1) E-55 28(2) E-56 28(2) E-57 29(1) E-58 29(1) E-59 ( 29(1) 29(2) ) E-60 29(1) 29(3) DANGER SUBSTATION UNAUTHORIZED ENTRY PROHIBITED 50 68
E-61 30(1) E-62 30(2) E-63 30(2) 69
14 () FA-1 100 100 3(1) FA-2 3(2) 10 10 49 50 1 1 1 6 12 24 3 6 12 12 24 36 1.3 900 2 4 8 900 (51 36 36 ) 25 4.5 1 1 2 (1 5 ) 30 ( ) 3 6 12 1 1 1 FA-3 3(3) FA-4 3(3) FA-5 3(3) FA-6 3(3) FA-7 3(4) FA-8 3(5) FA-9 3(6) FA-10 3(7) FIRST AID 70
FA-11 4(1) FA-12 4(2) 1 FA-13 4(3) FA-14 4(4) FA-15 100 100 5 1 FA-16 6 FA-17 () 7 71
15 () FP-1 4(1)(a) FP-2 4(1)(b) 68 C FP-3 ( ) 4(1)(c) FP-4 4(1)(d ) & 3 (e), & 44 13(1)(b) FP-5 ( ) 4(2)(a) FP-6 10 ( ) 4(2)(b) FP-7 4(3) FP-8 4(3) FP-9 5(1) FP-10 5(2) FP-11 ( 6(1) ) FP-11(a) 6(1) FP-11(b) 6(1) FP-12 6(1) (a) (b) (c) 72
FP-13 6(4) FP-14 7(1) FP-15 7(2) FP-16 7(3) FP-17 7(3) NO SMOKING 180 FP-18 NO SMOKING 7(4) FP-19 13(1)(b) (a) (b) (c) (d ) FP-20 13(1)(b) (a) (b) FP-21 13(1)(b) (a) (b) ( ) FP-22 13(1)(b) FP-23 13(1)(b) (a) (b) FP-24 13(1)(b) (a) (b) FP-25 (a) (b) 13(1)(b) FP-26 13(1)(b) (a) ( ) (b) ( ) 73
FP-27 35 9(1)(a) FP-28 35 9(1)(b) FP-29 9(2) Inflammable Substance FP-30 10(1) FP-31 10(1) FP-32 10(2) FP-33 11 FP-34 13(1)(b) FP-35 13(1)(b) FP-36 13(1)(b) FP-37 13(1)(b) FP-38 13(1)(b) FP-39 12 FP-40 12 FP-41 13(1)(b) 74
FP-42 () 12 FP-43 12 FP-44 12 FP-45 12 FP-46 12 FP-47 12 FP-48 13(1)(a) FP-49 13(1)(b) FP-50 (a) () 13(1)(b) (b) (c) ( ) () FP-51 13(1)(b) FP-52 13(1)(b) FP-53 13(1)(b) FP-54 13(1)(b) FP-55 13(1)(b) FP-56 13(1)(b) FP-57 13(1)(b) FP-58 ( ) FP-59 13(1)(b) FP-60 ( ) FP-61 13(1)(b) 75
FP-62 (1) 13(1)(b) (2) FP-63 13(1)(b) FP-64 13(1)(b) FP-65 13(1)(b) FP-66 13(1)(b) FP-67 13(1)(b) (a) (b) (c) FP-68 13(1)(b) FP-69 13(1)(b) FP-70 150 13(1)(b) FP-71 BOILER 13(1)(b) ROOM FP-72 ( ) FP-73 13(1)(b) FP-74 13(1)(b) FP-75 FP-76 FP-77 EXIT 13(1)(c) 180 ( ) ( ) FP-78 ( 13(1)(b) ) 76
FP-79 13(1)(b) FP-80 13(1)(b) FP-81 13(1)(b) (a) (b) (c) FP-82 ( ) 13(1)(b) FP-83 12 FP-84 8(1)(a) FP-85 8(1)(b) 77
16 ( ) GL-1 4(a) GL-2 4(a) GL-3 5(1) GL-4 5(1) 6 GL-5 5(1) 5(2) 28 GL-6 5 6(1) GL-7 6(2) GL-8 6(1) 6(2) GL-9 6(1) 6(3) GL-10 7(1) GL-11 7(2) GL-12 7(4) GL-13 7(5) GL-14 7(6) 7(1) 7(2) 7(4) 7(5) 78
GL-15 8(1)(a) GL-16 8(1)(b) GL-17 8(1)(c) GL-18 8(2) GL-19 8(3) 8(1) 8(2) GL-20 9(1) GL-21 9(2) 9(1) GL-22 9(3) GL-23 9(4)(a) 9(1) GL-24 9(4)(b) 9(1) GL-25 9(4)(b) GL-26 10 79
17 () GOM-1 (a) 4(1) & 5(1) (b) (c) (d ) (e) 1. 2. 3. 4. 5. 6. 7. 8. 9. 10. 11. 12. 13. 14. 15. 16. 17. GOM-1A 5(2)(a) GOM-1B 5(2)(b) GOM-1C 5(2)(c) GOM-2 6(2)(a) GOM-3 6(2)(b) 3 80
3 A () B () GOM-4 4 7 4 6 40 6 10 40 10 12 65 12 15 90 15 20 140 20 22 165 22 30 190 30 40 320 40 50 400 50 55 450 55 150 800 150 800 1. 2. 3. 4. 5. 6. 7. 8. 9. 10. 11. 12. 13. GOM-5 8 81
GOM-6 2 2 9 GOM-7 5 10 GOM-8 11(1)(a) GOM-9 11(1)(b) GOM-10 11(1)(c) GOM-11 11(2) GOM-12 11(3) GOM-13 11(3) GOM-14 11(4) GOM-15 12(1) () GOM-16 12(2) () GOM-17 () 12(3) 82
18 ( ) GWFC-1 18 3(1)(a) GWFC-2 3(1)(b) 18 GWFC-3 4(1) GWFC-4 4(2) GWFC-5 5 GWFC-6 6(1) GWFC-7 6(2) 83
19 ( ) L-1 4(a) L-2 4(a) L-3 4(a) L-4 4(b) L-5 4(c) L-6 4(d ) L-7 4(e) L-8 4(e) L-9 4(e) L-10 4(e) L-11 12 5(1) L-12 5(1) L-13 ( ) 5(2) 1 L-14 5(2) L-15 4 5(3) 1 L-16 5(3) L-17 ( ) 5(4) L-18 5(4) 84
L-19 5(5) L-20 5(5) L-21 6A(2) L-22 7A L-23 7A L-24 7B(1) L-25 7B(1)(a) L-26 5 7B(1)(b) ( ) L-27 7B(1)(c) 7A ( ) L-28 7C(a) L-29 7C(b)(i) L-30 7C(b)(ii) L-31 7D(1) L-32 7D(2)(a) L-33 7D(2)(b) L-34 7D(2)(b) 85
L-35 7E(1) L-36 7E(2)&(3) L-37 7E(2)&(3) L-38 7E(2)&(3) L-39 7E(5) L-40 7F L-41 7G(1) L-42 7G(2)(a) & (b) L-43 7H L-44 7I(a) L-45 7I(b) L-46 7J(1)(a) L-47 7J(1)(b) L-48 7J(2) 86
L-49 7J(3) L-50 7J(4) L-51 8(1) 600 L-52 8(2) 8(1) 600 ( ) L-53 9(1)(a) L-54 9(1)(b) L-55 9(1)(c) L-56 2 9(2)(a) 900 L-57 2 9(2)(b) 200 L-58 9(2)(c) 700 L-59 10(1)(a) L-60 10(1)(b) L-61 11(1) 87
L-62 11(2)(a) L-63 11(2)(a) L-64 11(2)(b) L-65 12 L-66 12A L-67 13(1)(a) L-68 13(1)(b) L-69 13(1)(c) L-70 13(2) L-71 13(2) L-72 14(1) (a) (b) L-73 15(1) (a) (b) L-74 15(2) ( ) 88
L-75 18 15A(1)(a) L-76 15A(1)(b) L-77 15A(1)(c) L-78 18 15A(2)(a) L-79 15A(2)(b) L-80 15B(1) L-81 18 15B(2) L-81a 15C L-82 16(1) L-83 16(2)(a) L-84 16(2)(b) L-85 16(4) 6 L-86 16(5) L-87 17(1) L-88 17(2) 2 89
L-89 18(1)(a) L-90 18(1)(a) L-91 18(1)(a) L-92 18(1)(a) L-93 18(1)(b) L-94 18(1)(b) L-95 18(1)(b) L-96 18(1)(c) L-97 () 18(1)(d ) 1 L-98 18(1)(d ) L-99 6 18(1)(e) L-100 18(1)(e) L-101 18(1)(ea) L-102 18(1)(eb) L-103 18(1)(eb) L-104 18(1)(g) L-105 18(1)(h) 90
L-106 10 18(1)(i) 5% L-107 18A(a) L-108 18A(b) L-108a 18B(1)(a) L-109 18B(1)(b) L-110 18B(1)(c)(i) L-111 18B(1)(c) (ii) L-112 18B(1)(c) () (1995 23 ) (iii) 900 L-113 900 18B(1)(c) (iii) L-114 8B(1)(c) (iv) L-115 18B(1)(c) (v) L-116 18B(1)(d ) 18B(1)(c)(ii) (iii) (iv) (v) L-117 18C(1) & (3) 2 2 91
L-118 18C(2) L-119 18C(4) L-120 18B(1)(5) L-121 L-81a 92
20 ( ) LSM-1 3(a) LSM-2 3(b) LSM-3 4(1) LSM-4 4(2) LSM-5 5 LSM-6 6(1) LSM-7 6(2) 93
() 21 () 85 (A) 90 (A) 140 200 N-1 3(1) (a) (b) 4 6 8 9(1) N-2 3(2) 3(1) 3(1) N-3 28 3(4) N-4 3(5) N-5 4(2)(a) (a) (b) N-6 4(2)(a) 4(2)(b) N-7 4(2)(c) N-8 5(a) 94
N-9 5(b) 5(a) N-10 5(a) 5(c) N-11 6(1) N-12 6(3) ( ) N-13 8 ( ) N-14 4 5 6 8 9(1)(a) N-15 9(1)(a) 9(1)(b) N-16 10 (a) (b) (c) 9(2) N-17 3(3) N-18 9(2)(a) 4(2)(c) 5(c) 6(3) N-19 9(2)(b) 95
( ) (A) 1 L L EP,d = 10 log T 10 e A (t) 2dt o T o P o L EP,d = T o = 8 28 800 T e = ( T o T o ) P o = 20 P A (t) = A () 96
22 () PE-1 5(a) PE-2 5(b) PE-3 5(c) PE-4 6(a) PE-5 6(b) PE-6 6(c) PE-7 7(a)(i) PE-8 7(a)(ii) PE-9 7(b) PE-10 8(a) PE-11 ( 8(b) ) 97
1. 2. ( ) 3. 4. 5. 6. 7. 8. 9. 10. 11. 12. 13. 14. (a) (b) (c) () (d ) ( ) 98
23 ( ) SFL-1 4(1)(a) l 30 SFL-2 4(1)(b) SFL-3 4(2) 30 SFL-4 5 SFL-5 5 SFL-6 6 6 (20 ) SFL-7 7(1) (2) 2 NO SMOKING NO NAKED FLAMES 100 (4 ) SFL-8 8(a) SFL-9 8(b) 99
SFL-10 ( 9(1) ) () 9 2 (a) 1.4 40 (B.C.F.) 40 1 (b) 2 33 33 1 (c) 2 33 () 33 1 (d ) ( ) 9 40 40 1 SFL-11 9(2)(a) SFL-12 9(2)(b) SFL-13 10(1) SFL-14 10(2)(a) FLAMMABLE LIQUID SFL-15 10(2)(b) SFL-16 10(2)(c) SFL-17 10(3) SFL-18 11(1) SFL-19 11(2) 100
SFL-20 11(3) SFL-21 12(1) SFL-22 12(2) SFL-23 13 12 SFL-24 14 SFL-25 15 (a) (b) 101
24 () SO-1 4 1 14(1) SO-2 7 14(2)(a) SO-3 10 14(2)(a) SO-4 15 14(2)(b) SO-5 15 15(2) ( 2A 2B) SO-6 4 2 16 SO-7 17 17(2) ( 3A 3B) SO-8 18(2) SO-9 15 19(a) (a) (b) (c) (b) () (d ) (e) 102
(i) (ii) ( f ) (g) (h) (i) 17(1)(b)(iv) ( j) (2) ( k) (i) (ii) (iii) (iv) (v) (vi) (vii) SO-10 17 19(a) (a) (b) 103
(i) (ii) (iii) (iv) (2) SO-11 19(b) SO-12 19(c) SO-13 ( 20(a) 2A 2B) SO-14 20(a) ( 3A 3B) SO-15 20(b) ( 2A 2B) ( 3A 3B) SO-16 ( 2A 2B) 20(c) ( 3A 3B) 3 SO-17 ( 2A 2B) 21(2) ( 3A 3B) SO-18 4 1(a) (c) (e) 19A(1)(a) ( SO-1) ( 4) 104
SO-19 4 1(b) (d ) ( f ) 19A(1)(b) ( SO-1) ( 4) SO-20 4 2(a) (c) (e) 19A(2)(a) ( SO-6) ( 5) SO-21 4 2(b) (d ) ( f ) 19A(2)(b) ( SO-6) ( 5) 105
1. 14 4 (a) 100 100 ( ) (b) 100 100 ( ) (c) 100 100 (d ) 100 100 (e) 100 100 ( f ) 100 100 ( g) 100 100 ( h) 100 100 2. 16 (a) 20 20 ( ) (b) 20 20 ( ) (c) 20 20 (d ) 20 20 (e) 20 20 ( f ) 20 20 ( g) 20 20 ( h) 20 20 106
25 () WW-1 4 WW-2 5 WW-3 6 WW-4 6 WW-5 160 7(1) WW-6 7(2) WW-7 8 WW-8 9(1) WW-9 16 9(2) WW-10 2 10(1) 2 150 (6 ) 50 (2 ) WW-11 10(2)(a) 2 WW-12 10(2)(b) 1 WW-13 10(3) WW-14 10(3)(a) WW-15 10(3)(b) WW-16 10(3)(c) WW-17 10(3)(d ) 15 (0.6 ) 107
WW-18 600 (24 ) 10(3)(e) 25 (1 ) WW-19 600 (24 ) 10(3)( f ) 250 (9.8 ) WW-20 10(4) WW-21 10(4)(a) WW-22 10(4)(b) WW-23 11 WW-24 12(1) WW-25 12(2) WW-26 12(2) WW-27 13(a) WW-28 13(b) WW-29 13(c) WW-30 14(1) WW-31 14(2) WW-32 14(3) WW-33 15(1) WW-34 15(2) WW-35 15(3) WW-36 16 WW-37 17(1)(a) 108
WW-38 17(1)(b) 17(1)(c) WW-39 17(1)(d ) WW-40 17(2) WW-41 17(3)(a) WW-42 17(3)(b) WW-43 17(3)(c) WW-44 19(a) WW-45 11 15(2) (3) 19(b) 109
26 () SM-1 4 8(1) 1 2 3 SM-2 4 8(1) 1 2 SM-3 4 8(2) 1 SM-4 8(3) 4 1 2 3 SM-5 8(3) 4 1 2 SM-6 8(4) 4 1 SM-7 9(1)(a) SM-8 9(1)(b) SM-9 9(1)(c) SM-10 9(1)(d ) SM-11 9(2)(a) SM-12 9(2)(b) SM-13 9(2)(c) SM-14 9(1)(b) 9(3)(a) SM-15 9(2)(a) 9(3)(b)(i) (b) (c) 110
SM-16 9(3)(b)(ii) 9(3)(a) 9(3)(b) SM-17 10(a) SM-18 10(b) SM-19 ( 11(1)(a) ) SM-20 11(1)(b) SM-21 3 11(1)(c) SM-22 5 11(1)(d )(i) SM-23 11(1)(d )(ii) SM-24 11(2) SM-25 12(a) SM-26 12(b) SM-27 13(1) SM-28 2002 4 1 12 13(2)(b) ( 2002 4 1 ) 12 SM-29 14(a) 111
SM-30 14(b) SM-31 16(1)(a) SM-32 16(1)(b)(i) 14 SM-33 16(1)(b)(ii) SM-34 16(1)(b)(i) 16(1)(c) 21 SM-35 16(1)(d ) () 5 16(1)(a) SM-36 17(a) SM-37 17(b) SM-38 14 17(c) SM-39 17(d )(i) SM-40 14 17(d )(ii) SM-41 19(1)(a) ( ) SM-42 19(1)(b)(i) SM-43 19(1)(b)(ii) SM-44 2002 4 1 12 19(2)(b) ( ) 12 112
SM-45 20(a) SM-46 20(b) SM-47 22(1)(a) SM-48 22(1)(b)(i) 14 SM-49 22(1)(b)(ii) SM-50 22(1)(b)(i) 22(1)(c) 21 SM-51 22(1)(b)(i) 22(1)(d ) 5 22(1)(a) SM-52 23(a) SM-53 23(b) SM-54 14 23(c) SM-55 23(d )(i) SM-56 14 23(d )(ii) SM-57 24(2) ( 14 ) SM-58 33(5) SM-59 33(5) 113
SM-60 28 15(1)(a) SM-61 15(1)(b) SM-62 ( ) 15(2) 15(1) 5 SM-63 21 16(3) SM-64 18(a) ( ) SM-65 14 18(b) 18(a) SM-66 32(2) 32(1) SM-67 28 21(1)(a) SM-68 21(1)(b) SM-69 ( ) 21(1) 21(2) 3 SM-70 23(3) 21 SM-71 32(2) 32(1) 114
4 l 1. 2. 3. 4. 5. 6. 7. 8. 2 1. 2. 3 1. 2. 3. 4. 115