720/730 ICP-OES
720/730 ICP-OES 2010 AA ICP-OES 7700 ICP-MS ICP-OES 720/730 ICP-OES CCD 720/730 ICP-OES ICP-OES (720/730) (725/735) 720/730 ICP-OES CCD ICP-OES 2
1938 1965 1976 HP 5992A GC/MS 1983 HP 5890A GC 1994 4500 ICP-MS 2009 7700 ICP-MS 2010 (HMI & ORS 3 Cell) Varian 1948 1957 AAS 1991 1994 1997 Vista 2006 700 ICP- (Techtron) ICP-OES ICP-OES CCD OES ICP-OES / ICP 720/730 Pb Cd N/P/K S/Ca/ Mg (ASTM D6751 & EN 14214) S P Ca Mg Na K US EPA ILM05.3 US EPA 200.7 (USP 232) Cu ICP 725/735 S P Cu (EN 15837) (ASTM D5185) Pb Cd Cr (WEEE/ RoHs) (US EPA Method 3040A) Au Ag Pt ICP-OES 720 ICP-OES 730 ICP-OES 720 730 3 4 (SVS) (IQ/OQ) 21 CFR 11 3
6000 ICP-OES 730 (SVS) 33% 25% 4 CCD (AIT) (I-MAP) 70000 167 785 nm 4
(CCI) 720/730 (Multi-Cal) ppb 720/730 CCD 720/730 ICP-OES 720/730 EPA (CRDL) 725/735 ICP-OES 725/735 ICP-OES 0 5 10 Ca t (s) 0 5 10 Pb t (s) 10 AIT 5
Fitted (FACT) FACT AutoMax (Spectroscopy Configuration Manager) ICP II US FDA 21 CFR part 11 (MultiCal) FACT Fe Cd 214.438 nm a. b. FACT (500 mg/l Fe) c. Cd Ca 315.887 nm 30 mg/l 370.602 600 mg/l 47.7 mg/l 106% 6
ICP-OES 35 73 CCD VistaChip a b c 720/730 35 73 ICP-OES gutter 720/730 VistaChip VistaChip CaF 2 7
720/730 (VGA 77P) Hg 730 33% 25% (MultiCal) Mg % K % P % Ca mg/kg Na mg/kg Zn mg/kg Fe mg/kg Mn mg/kg Cu mg/kg NIES CRM No.10-8436 8435 1571 1573a 0.134 0.008 0.280 0.008 0.340 0.007 93 3 10.2 0.3 25.2 0.8 12.7 0.7 34.7 1.8 3.5 0.3 0.133 0.002 0.264 0.006 0.332 0.006 90 1 10.7 0.3 23.9 0.8 12.2 0.6 31.9 1.0 3.3 0.1 0.107 0.008 0.318 0.014 0.290 0.022 278 26 16.0 6.1 22.2 1.7 41.5 4.0 16.0 1.0 4.30 0.69 0.105 0.003 0.287 0.006 0.261 0.009 266 10 16.8 0.9 21.2 0.5 42.6 0.8 15.0 0.2 4.03 0.20 0.0814 0.0076 1.363 0.047 0.780 0.049 9220 490 3560 40 28.0 3.1 1.8 1.1 0.17 0.05 0.46 0.08 0.0795 0.0034 1.264 0.022 0.717 0.024 9435 363 3407 79 21.2 0.5 1.9 0.8 0.172 0.002 0.43 0.05 0.62 0 02 1.47 0.03 0.21 0.01 2.09 0.03 82 6 25 3 (270)** 91 4 12 1 0.57 0.01 1.38 0.04 0.187 0.003 1.94 0.06 79 1 24.5 0.7 268 7 83.1 2.0 11.0 0.2 1.2 2.70 0.05 0.216 0.004 5.05 0.09 136 4 30.9 0.7 368 7 246 8 4.70 0.14 1.07 0.01 2.55 0.03 0.207 0.004 4.89 0.01 115 3 29.9 0.7 338 8 234 2 4.57 0.14 730 ICP-OES 50 8
Agilent 720/730 ICP-OES 720/730 ppb ICP Expert II US EPA QC 720/730 5-50 CCV Recovery (%) 120 100 80 60 40 20 0 0:00 0:32 1:01 1:32 2:01 2:31 3:02 3:31 4:01 4:31 5:01 5:32 6:00 6:31 7:01 7:32 8:02 8:30 h:m Ag 328.068 Cu 324.754 Se 196.026 Be 313.042 Cr 267.716 Sb 217.582 Ba 585.367 Mg 285.213 Pb 220.353 As 188.980 K 769.897 V 292.401 Al 237.312 Fe 238.204 Tl 190.794 Ca 315.887 Mn 257.610 Zn 206.200 Cd 214.439 Na 568.821 Lower Limit Co 228.615 Ni 231.604 Upper Limit US EPA CLP ILMO 5.3 (CCV) 8 RSD 1% Al (%) Ca (%) Fe (%) Mg (%) K (%) P (%) Na (%) 2710 2709 2710 2709 1.2-2.6 0.38-0.48 2.2-3.2 0.43-0.60 0.37-0.50 0.106-0.11 0.049-0.062 2.07 0.01 0.376 0.003 2.50 0.03 0.510 0.016 0.497 0.003 0.0677 0.0008 0.0613 0.0003 2.0-3.1 1.4-1.7 2.5-3.3 1.2-1.5 0.26-0.37 0.05-0.07 0.063-0.11 2.00 0.01 1.38 0.01 2.63 0.01 1.15 0.01 0.347 0.001 0.0442 0.0003 0.0636 0.0005 Ti (%) Zn (mg/kg) Mn (mg/kg) Cu (mg/kg) Ba (mg/kg) Sr (mg/kg) Pb (mg/kg) 0.092-0.11 5200-6900 6200-9000 2400-3400 300-400 94-110 4300-7000 0.122 0.001 5815 46 7054 86 2426 20 307 4 90.9 1.1 4433 22 0.03-0.04 87-120 360-600 26-40 392-400 100-112 12-15 0.0234 0.0001 87.2 0.3 483 3 29.2 0.3 367 1 88.7 0.5 10.7 0.1 As (mg/kg) Cr (mg/kg) Ni (mg/kg) Co (mg/kg) Cd (mg/kg) Mo (mg/kg) V (mg/kg) 2710 2709 490-600 15-23 8.8-15 6.3-12 13-26 13-27 37-50 514 4 19.3 0.1 10.4 0.1 8.90 0.06 16.4 0.1 14.9 0.1 48.7 0.5 <20 60-115 65-90 10-15 <1 <2 51-70 15.3 0.1 61.8 0.2 67.7 0.6 11.1 0.1 <0.2 1.51 0.03 60.0 0.2 US EPA 3051A 9
725/735 725/735 7000000 6000000 4000000 2000000 0 Pt 265.945 0.000 33141.900 ICP Expert II Fitted FACT IEC Pt 265.945 (mg/l) 2009 12 7 09:27:55 pm (c/s) --- 6.4 0.000000 0.000000 0.000 1 --- 367.3 2.0000 1.8130-0.187-9.351 2 --- 3694.4 20.000 18.522-1.478-7.390 3 --- 37090.9 200.00 186.25-13.754-6.877 4 --- 369911.3 1961.0 1857.7-103.262-5.266 5 --- 5455279.5 27390 27397 7.494 0.027 0.999993 725 ICP-OES Pt 27000 ppm 0.3 % RSD 10
725/735 725/735 (HF) Robust axial or radial 2 1.6 (mg/l) 1.2 0.8 0.4 0 11:21:45 14:40:51 18:49:59 23:01:14 3:10:07 7:21:07 11:31:39 Ar 404.442 Ba 455.403 Mg 280.270 Mg 285.213 Zn 206.200 (TDS) 25% Nacl 1.0 mg/l 24 24 5 % RSD NIST 1084a nm mg/l mg/l mg/l Ag 328.068 101.4 96.3 250 Al 167.019 (104) 105.6 100 Cr 267.716 98.3 96.9 250 Cu 327.395 100 99.1 250 Fe 238.204 98.9 100.6 100 Mg 279.553 99.5 100.6 100 Mo 202.032 100.3 96.6 250 Ni 231.604 99.7 99.5 250 Pb 220.353 101.1 107.7 1500 Si 251.611 (103) 100.7 250 Sn 189.927 97.2 91.5 250 Ti 336.122 100.4 101.3 250 V 292.401 95.9 101.3 250 725 ICP-OES NIST 1084 Oil SRM 1:10 (Rapid Flow Nebulization) 39 NIST 1761 wt % wt % Al 0.055 0.069 As 0.011 0.012 Co (0.028) 0.022 Cr 0.22 0.231 Cu 0.30 0.318 Mn 0.678 0.720 Mo 0.103 0.104 Ni 1.99 1.943 P 0.040 0.047 S 0.035 0.034 Si 0.18 0.173 Sn (0.05) 0.050 Ti 0.18 0.193 V 0.053 0.055 Cetac Solis-500 720 ICP-OES NIST 1761 Low Alloy Steel SRM 11
2010 ICP-MS AA ICP-OES ICP-MS 7700 ICP-MS ICP-MS AA AA AA www.agilent.com/chem/cn www.agilent.com/chem/contactus:cn 800-820-3278 400-820-3278 customer-cn@agilent.com www.agilent.com/chem/quote:cn http://www.agilent.com/chem/university Access Agilent www.agilent.com/chem/accessagilent:cn 2011 Printed in Taiwan 2011 9 5990-6497CHTW