G-1007-13008 1200 MW IGCCS The feasibility study on 1200 MW IGCC with CCS in Lianyunga 2011 9
动 热 汉 员 赵丽凤 员 员迟 员张 员谢 师 硕
... 1... 4 2.1... 4 2.2... 8 2.2.1... 9 2.2.2... 10 2.3... 12 2.4 CO 2... 14 2.5... 17 2.6... 19 2.7 NOx... 21 2.7.1... 22 2.7.2 NOx... 23 2.7.3 NOx... 25 2.8... 26 1200 MW IGCC... 27 3.1... 27 3.2... 29 3.2.1... 31 3.2.2... 33 3.2.3... 34 3.3 CO 2... 34 3.3.1 CO CO 2... 35 3.3.2... 37 3.3.3... 39 3.3.4 CO 2... 40 3.4... 40 3.5... 44 I
3.5.1 IGCC... 45 3.5.2 IGCC... 47 3.5.3... 48 3.6... 49 3.6.1 IGCC... 50 3.6.2 IGCC... 52 3.6.3... 53 3.7... 54 3.7.1 IGCC... 57 3.7.2... 59 3.7.3... 60 3.8 1200MWe IGCC... 61... 62 II
2010 77% 6.5 kw 2050 1000 50% 70% CO 2 Integrated Gasification Combined Cycle IGCC IGCC CO 2 IGCC SO 2 1/10 NOx 20ppm@15%O 2 (Vol) IGCC 6 8 50 IGCC CO 2 CO 2 IGCC 15-20% IGCC IGCC IGCC IGCC IGCC IGCC CO 2 IGCC IGCC I IGCC GE Texaco 1
Siemens GSP Mitsubishi IGCC IGCC IGCC IGCC 1200 MWe IGCC 2 1300 MWe IGCC 10MWe SNG 5.38 10 8 Nm 3 /60 / 60 / 50 / 100 / 100 1200 MW IGCC IGCC/ 2
3
IGCC IGCC 2.1 IGCC [1] [1, 2] IGCC GEE Shell [1] [1] IGCC IGCC IGCC 4
CO 2 IGCC CO 2 CO 2 IGCC 2. 1 IGCC 2. 2 / 350 10MPa/311 38 NHD 276 GE9351FA 50% N 2 2. 1 50% 50% 2. 2 2. 1 IGCC 5
2. 2 IGCC CO 2 WGS Water Gas Shift NHD CO 2 WGS CO CO 2 H 2 NHD CO 2 90% WGS CO 97%~98% 97% CO 2 CO 2 92% WGS 230 1 286MWe IGV 2 NO x 80mg/Nm 3 16%O 2 NO x N 2 NO x NO x 3 6
2. 3 2. 4 2. 5 CO 2 IGCC CO 2 2. 3-2. 5 CO 2 CO 2 7
CO 2 IGCC CO 2 IGCC CO 2 IGCC IGCC 2.2 H 2 S COS NH 3 IGCC 400 [3] 700 [3] 2. 6 IGCC 3-5 [3] IGCC 2. 6 IGCC CO 2 8
1 WGS 2 CO 2 3 CO 2 CO 2 CO 2 CO 2 WGS WGS WGS WGS WGS CO 2 2.1 2.2.1 2. 1 IGCC - - IGCC LHV% 42.13 44.90 45.46 IGCC MWe 379.30 404.18 409.26 t/hr 152.62 152.62 152.62 MWe 286.0 286.0 286.0 MWe 140.6 166.6 171.8 193.0 158.0 350.0 vol% 52.2 23.0 17.3 vol% 17.0 17.0 17.0 /kw 6441 6867 7038 /MWh 423 417 416 IGCC NO x 2. 1 9
2.8 3.3 1.4% 1.7% [4] 6 /MWh 7 /MWh 2.2.2 IGCC CO 2 2. 2 52.2% WGS 0.9 1.4 CO 2 2. 7-2. 10 2. 2 IGCC 90% Case3-1 Case3-2 Case3-3 IGCC LHV% 36.11 37.04 37.49 IGCC MWe 346.00 354.91 359.18 t/hr 162.41 162.41 162.41 MWe 286.0 286.0 286.0 MWe 133.5 142.7 147.1 193.0 158.0 350.0 vol% 52.2 23.0 17.3 WGS t/hr 16.2 190.5 212.0 /kw 9180 9645 9809 /MWh 531.7 531.4 530.8 CO 2 /MWh 137 148.1 149.4 CO 2 /MWh 163 183.8 185.5 10
CO 2 6 7.9 8.0 25.7% 27.4% 27.6% 2. 7-2. 8-2. 9-2. 10 - IGCC CO 2 CO 2 CO 2 + IGCC 11
2.3 IGCC H 2 S COS Fe Mn Zn Cu Ca 15 20 2 Rectisol Selexol NHD NHD Selexol MDEA MEA IGCC Selexol MDEA IGCC Selexol MDEA Selexol IGCC IGCC Selexol NHD MDEA H 2 S 12
H 2 S MDEA MDEA MDEA H 2 S CO 2 H 2 S CO 2 MDEA H 2 S H 2 S CO 2 NHD H 2 S NHD H 2 S CO 2 9 2. 11 MDEA MDEA H 2 S H 2 S H 2 S CO 2 NHD MDEA NHD H 2 S H 2 S NHD NHD 2. 11 2. 3 MDEA NHD IGCC MDEA NHD t/h 152.80 152.62 kj/kg 21236 21236 443.51 443.34 13
MW 10.42 10.39 MW 22.32 22.26 MW 0.10 0.09 MW 1.76 1.75 MW 0.09 0.07 Claus MW 2.13 2.12 MW 1.11 1.11 Slag MW 7350.93 6432.07 kg/h 405.58 405.55 45.00 45.05 MDEA NHD IGCC 2. 3 MDEA 3269kJ/kg H 2 S NHD MDEA 83%NHD NHD IGCC MDEA MDEA NHD NHD 2.4 CO 2 CO 2 MDEA Selexol NHD CO 2 CO 2 IGCC CO 2 CO 2 CO 2 IGCC NHD MDEA CO 2 CO 2 2. 4 CO 2 IGCC CO 2 Ref NHD MDEA Ref NHD MDEA CO 2 % - 90 90-90 90 14
LHV% 43.64 35.38 31.92 46.32 36.10 32.53 MWe 444.93 392.16 351.47 412.01 362.14 322.73 t/hr 172.83 188.36 186.64 150.79 170.07 168.17 MWe 286.00 286.00 285.88 286.00 285.89 286.01 MWe 228.10 206.00 166.38 178.30 156.21 117.36 /kw 8156 11302 11836 8470 12487 12718 /MWh 448 573 606 439 589 619 2. 4 IGCC MDEA Selexol CO 2 IGCC Selexol CO 2 2. 5 CO 2 IGCC CO 2 Ref NHD MDEA Ref NHD MDEA CO 2 % - 90 90-90 90 LHV% 45.46 37.49 34.34 45.76 36.92 35.21 MWe 409.26 359.18 330.38 460.50 404.01 380.59 t/hr 152.62 162.41 160.285 170.62 185.50 183.22 MWe 286.0 286.0 286.0 286.0 286.0 286.0 MWe 171.8 147.1 131.40 225.3 203.0 179.46 /kw 7083 9809 9881 6720 9548 9430 /MWh 416 531 551 408 525 537 2. 5 IGCC IGCC MDEA CO 2 0.9 14 /MWh Selexol CO 2 CO 2 0.6 2. 5 MDEA CO 2 IGCC 15
11.12 10.55 WGS NHD CO 2 7.97 8.83 CO 2 MDEA NHD CO 2 Selexol MDEA 2. 12 2. 13 CO 2 Selexol NHD MDEA CO 2 2. 12 CO 2 MDEA Selexol Selexol CO 2 39% 16% CO 2 Selexol 120%MDEA 10% 2. 13 CO 2 NHD Selexol CO 2 CO 2 2. 12 2. 13 CO 2 NHD NHD CO 2 CO 2 Selexol CO 2 16
MDEA IGCC Selexol MDEA IGCC Selexol CO 2 2.5 IGCC IGCC IGCC GE Siemens 2. 6 2. 6ISO 50Hz MW % kj/kwh) GE PG6581B 42.1 32.2 11175 GE PG9171E 126.1 33.8 10656 GE PG9351FA 256.2 37 9729 Simens 94.2 157 34.4 10465 Simens 94.3A 265 38.5 9351 Mitsubishi 701D 139.4 34.2 10529 Mitsubishi 701F 252.5 37.3 9643 3 IGCC IGCC 2. 7 GE Siemens IGCC IGCC 2. 7 GE 1200MWe E F E GE PG9171E 17
GE PG9351FA 50%~70% GE E GE PG9171E F GE PG9351FA 2. 7 LHV % IGCC MW) MW Wabash River 1995 41.20% 262 GE 7221FA 192 Tampa 1996 38.90% 250 GE 7221FA 192 Buggenum 1994 43.00% 254 Puertollano 1997 N/A 300 Siemens V94.2 Siemens V94.3 156 190 Cool Water 1984 31.2% HHV 96 GE 7E 65 NAKOSO 2008 42% 220 Mitsubishi M701DA 142 Shell Per+ 1998 36.70% 115 GE MS6541B 2*55 Api Energia 1999 40.40% 244 ISAB 2000 38.00% 521 ABB GT 13E2 Siemens V94.2 1*189MW 2*161MW Sarlux 2000 44.60% 452 GE MS9001E 3*136 AGIP 2006 N/A 250 Siemens 1*173 V94.2K SVZ Sustec 1997 45.30% 45 GE MS6551B 1*45 Delaware 2002 N/A 120 Pinon Pine 1998 40.60% 100 GE MS6001FA GE MS6001FA 2*90 1*76 18
2.6 IGCC NOx -183-196 PSA Pressure Swing Adsorption 30%~93% 78% 4000m 3 /h 4~5 40%~50% 2. 8 300t/d 3000~4000t/d 99% 30~93% 40~50% 0.37~0.43kWh/m 3 O 2 0.45kWh/ m 3 O 2 19
99% 46%~68% 2. 8 IGCC 40000~60000m 3 /h95%~99% 2. 8 IGCC 300t/d IGCC [5, 6] [5] 2. 14 2. 14 20
IGCC NOx 2.7 NOx IGCC [3] NO X IGCC NO X IGCC IGCC IGCC NO X 2. 15 2. 16 2. 15 2. 16 24bar 30%vol 166 IGCC NO X 9E 200MWe IGCC 21
IGCC NHD PG9171E 136MWe IGV NO X 2.7.1 NO X IGCC NO X 2. 17 2. 18 NOx NOx 30% NOx 80mg/Nm 3 2. 17 NOx 2. 18 NOx 2. 19 IGCC NO X IGCC IGCC NO X IGCC 22
2. 19 NO X 10% 43.67% IGCC 0.78 NO X 80mg/Nm 3 0.9 NO X NO X IGCC NO X 2. 19 IGCC 2.7.2 NOx NO X IGCC NO X IGCC 2. 9 2. 9 NO X IGCC t/h 80.60 Mwe 136.07 Mwe 91.696 IGCC Mwe 205.97 IGCC % 43.323 NO X mg/nm 3 (@16%O 2 ) 146.91 IGV 5.25 0.8565 23
NOx 80mg/Nm 3 NO X NO X NO X 80mg/Nm 3 IGV NOx 2. 20 39% NOx 80mg/Nm 3 N 2 NOx N 2 100% NOx 31mg/Nm 3 IGCC 2. 21 IGCC IGCC 39% 39% 42.71% 42.46% NOx 30% NOx 30% 2. 20IGCC NO X 24
2. 21IGCC NOx NOx 2.7.3 NOx NOx NOx IGCC NOx NOx NOx NOx NOx 25
NOx NOx 2.8 IGCC 2. 10 IGCC 2. 10 CO 2 NOx NHD NHD GE GE9171E GE9351FA 26
1200 MW IGCC IGCC IGCC 3.1 IGCC IGCC GE PG9171E PG9351FA 3. 1 3. 1 GE9E 9FA PG9171E PG9351FA MWe 124.6 255.6 % 33.46 36.9 12.32 15.3 kg/s 408.69 629.31 [7] 3. 1 GE [8] 27
3. 17FA 9FA [7] GE 3. 2 PG9171E 136MWe PG9351FA 286MWe IGV [7, 9] 3. 3 3. 2 GE ISO 6B 7EA 9E 6FA 7F 9F 46 MW (50/60 Hz) 80 MW (60 Hz) 136 MW (50 Hz) 92 MW (50/60 Hz) 232 MW (60Hz) 286 MW (50Hz) 3. 3GE9E 9FA PG9171E PG9351FA MWe 136.48 285.86 * % 35.31 39.56 12.32 15.87 547.44 621.29 t/h 1591.60 2409.61 28
E F 12.5bar 16bar 4-6bar F 20-22bar 22bar 30bar E F IGCC 50% N 2 IGCC 3. 4 E IGCC 200MWe F IGCC 400MWe 400MWe IGCC 200MWe 1.9 F E 2.4 IGCC 1200MWe 9E 9F 463.9 t/h 11133.6 t/d 11200 t/d 2000 t/d 5 2000t/d 1 1200t/d 3. 4 E F IGCC GE 9E-IGCC GE 9F-IGCC % 50 50 t/h 79.33 152.62 MWe 136.00 286 MWe 90.52 171.8 IGCC MWe 23.78 48.04 IGCC MWe 202.73 409.26 IGCC % 43.05 45.46 3.2 2.2 IGCC IGCC 29
3. 5 Tampa IGCC 11.5MPa [10] 482 227 [11] [10] Wabash River 370 11MPa [12] Buggenum IGCC Shell Shell 4.6MPa 900 [13] Puertollano IGCC 235 [14] IGCC IGCC Puertollano IGCC 235Tampa IGCC IGCC 3. 5 IGCC Tampa [10] Wabash [12] Buggenum [13, 15] Puertollano [14] 1250-1450 1400 1200-1600 1200-1600 482 370 250 235 MPa/ 11.5/321 11/318 12/325 12.6/329 MPa/ N/A N/A 4.6/259 3.4/241 N/A N/A N/A 235 30
3.2.1 l Case3-1 10MPa l Case3-2 4MPa l Case3-3 10MPa l Case3-4 l Case3-5 l Case3-6 3. 6 IGCC Case3-1 Case3-2 Case3-3 case3-4 Case3-5 Case3-6 IGCC % 41.27 40.02 41.26 40.27 40.62 40.77 IGCC MWe 196.80 190.81 196.75 192.02 193.70 194.39 t/h 80.83 80.83 80.83 80.83 80.83 80.83 MWe 136.0 136.0 136.0 136.0 136.0 136.0 MWe 82.20 75.76 82.15 77.07 78.87 79.61 vol% 17.5 17.5 17.5 17.5 17.5 17.5 t/h 23.0 23.0 23.0 23.0 23.0 23.0 t/h 152.2 - - - 79.33 - t/h - - 104.75 - - 54.59 t/h - 118.91 - - 56.94 - t/h - - - 87.89-42.08 3. 2-3. 3 IGCC IGCC 1.25 6MWe 31
3. 2 IGCC 3. 3 IGCC case3-1 case3-3 IGCC 0.25 32
3.2.2 230-380IGCC 10 320 3. 4-3. 7 IGCC 320 320 230IGCC 0.06 320 3. 6 NO X 3. 7 320 3. 4 3. 5 33
3. 6 3. 7 320 NO X 390 320IGCC 0.24 NO X IGCC 3.2.3 IGCC IGCC 1 10MPa 3.3 CO 2 CO 2 IGCC CO 2 WGS CO 2 CO 2 CO 2 IGCC 30%-92% CO 2 EP Energy Penalty COE Cost of Electricity CO 2 34
EP WGS CO 97% CO 2 CO 2 92% CO 2 90% WGS CO 90% CO 2 CO 2 CO 2 CO CO 2 3.3.1 CO CO 2 CO Selexol CO 2 WGS CO Selexol CO CO WGS CO CO / 0.3 CO [16] CO 3. 8 WGS COS COS WGS WGS CO CO 2 COS H 2 S COS Selexol WSG WSG COS 35
COS 3. 8 Selexol CO 2 Selexol H 2 S Selexol CO 2 Selexol H 2 S Selexol H 2 S CO 2 Selexol WSG WSG Selexol CO 2 WGS CO 3. 8 Selexol CO 2 50% 50%CO 2 IGCC 3. 7 3. 7 CO 2 10MWe WGS CO 1.13 IGCC 3. 8 CO CO 2 CO 2 36
3. 7 IGCC t/hr 157.76 157.86 CO 2 % 50.00 50.00 MWe 286.00 285.76 MWe 165.47 155.86 CO 2 MW 15.34 14.46 % 14.11 14.52 MW 387.77 377.48 (LHV) % 41.67 40.54 3.3.2 CO 2 1 CO 2 3. 9 CO 2 CO 2 CO 2 CO 2 CO 2 3. 9 CO 2 CO 2 CO 2 CO 2 CO 2 CO 2 CO 2 CO 2 CO 2 CO 2 3. 10 3. 11 3. 12 3. 13 CO 2 CO 2 CO 2 CO 2 37
87% 3. 10 CO 2 3. 11 CO 2 3. 12 CO 2 3. 13 CO 2 2 3. 14 3. 15 CO 2 3. 14 87% 3. 15 CO 2 EP 38
CO 2 90% CO 2 30%EP 4% CO 2 90%EP 17% 3.3.3 CO 2 CO 2 1 CO 2 CO 2 CO 2 CO 2 CO 2 COE -COE /MWh CO 2= (CO t/mwh CO 2= (CO 2 -CO 2 t/mwh 2 COE -COE /MWh (4.1) (4.2) CO 2 CO 2 CO 2 CO 2 3. 16 CO 2 CO 2 CO 2 87%CO 2 CO 2 138 /CO 2 165 /tco 2 CO 2 90%CO 2 3. 16 CO 2 2 3. 17 3. 18 39
CO 2 CO 2 87% 3. 19 3. 20 3. 17 3. 18 3. 19 3. 20 3.3.4 CO 2 CO 2 CO 2 87% CO 2 CO 2 CO 2 85%-90% IGCC 85%-90% 90% IGCC 3.4 40
3. 8 5.52-6.5bar 1.02-1.138bar 14.54bar-19.2bar 3-6bar 3. 8 1 [17] 2 [18] 3 [19] 4 [20] bar 5.52 6.0 6.5 6.15 bar 1.138 1.05 1.02 N/A bar 1.138 1.05 1.02 N/A 2 0.83 0.7 0.72 0.73 6 0.7 0.74 0.62 N/A 4 0.72 0.7 0.72 N/A bar 14.54 12-16 19.2 N/A bar 4.0 3-6 6.0 N/A bar 4.0 3-6 6.0 N/A 3.635 2.7-4 3.2 4 0.83 0.7 0.72 N/A 6 0.74 0.7 0.62 N/A 4 0.72 0.7 0.72 N/A IGCC 41
GE E F 12bar IGCC 1 Case1 2 Case3100% 100% 3 Case3 4 Case4 100% GE9171E NOx IGCC 3. 9 NOx 146.91mg/Nm 3 NOx NOx NOx 3. 9 NOx IGCC t/h 80.60 MWe 136.07 MWe 91.696 IGCC MWe 205.97 IGCC % 43.323 NO X mg/nm 3 (@16%O 2 ) 146.91 IGV 5.25 0.8565 3. 10 IGCC 100% NOx 42
Case4 Case3 0.78 NOx Case2 Case1 1.43 Case2 Case1 6.2MWe 3. 10 IGCC Case1 Case2 Case3 Case4 % 0 100 0 0 % 0 100 0 100 t/h 16.9 0 16.9 0 % 22.6 22.6 22.6 22.6 t/h 80.20 82.12 80.20 77.54 MWe 136.09 135.96 136.09 135.97 MWe 87.31 93.18 87.30 87.93 IGCC MWe 23.65 17.66 21.61 32.36 IGCC MWe 199.75 211.48 201.79 191.54 IGCC % 42.22 43.66 42.65 41.88 NO X mg/nm 3 (@16%O 2 ) 80.00 31.06 80.00 31.06 MWe 0 6.86 0 11.58 MWe 16.45 10.21 14.35 25.45 1 IGCC 43
IGCC IGCC Wabash River Tampa Buggenum Purtollano Buggenum Purtollano 3. 11 99%O 2 Wabash River Tempa Buggenum 95% Puertollano 85% 3. 11 IGCC Wabash River Tampa Buggenum Puertollano N2 95%O 2 95%O 2 95%O 2 85%O 2 IGCC 95% 3.5 IGCC Fue1 IGCC Fue2 95% IGCC 3. 12 N 2 NO X 44
3. 12 vol% CO H 2 CO 2 CH 4 N 2 H 2 O LHV kj/kg Fue1 0.24 0.16 0.06 0.00 0.53 0.00 4405 Fue2 0.33 0.35 0.12 0.02 0.01 0.17 10064 PG 9351FA 3. 12 3. 13 3. 13PG 9351FA Fue1 Fue2 ISO ISO MW 374.62 296.3 % 41.8 38 kg/s 605.35 631.38 18.88 16.59 % 84.13 86.69 % 95.74 114.52 kg/s 663.32 576.61 kg/s 56.27 50.8 kg/s 80.37 72.56 K 868.7 886.78 1.26 1.09 % 46.56 15.92 % 30.52 11.74 3. 13 IGCC Fue1 1.2 45% 100% 95% 3.5.1 IGCC IGCC IGCC IGCC 45
Case1 Case2 IGV IGV 19.38 286MW Case3 1.27 10% Case4 T 3 T 3 151 286MW Case5 T 3 T 3 268 10% IGCC 3. 14 3. 14 IGCC Case1 Case2 Case3 Case4 Case5 MW 549.31 440.54 629.03 412.35 331.85 LHV% 43.96 42.99 44.34 41.55 39.99 MW 374.62 286 421.07 286 233.37 MW 259.90 224.11 304.82 193.30 153.98 MW 16.99 13.62 19.45 12.75 10.26 t/h 211.86 173.73 240.47 168.26 140.66 % 95.74 97.24 116.26 107.17 116.26 hr 12263 30789 650 100000 100000 NO X 80mg/Nm 3 (16%O 2 ) NO X 3. 14 IGV IGCC 100MW 1 IGV IGCC 46
T 3 IGCC IGCC 217MW 4% T 3 T 3 3.5.2 IGCC IGCC 70% 30% 288.86MW 115% 70% IGCC 3. 15 3. 15 MW 549.31 490.40 467.16 LHV% 43.96 43.66 43.74 374.62 288.86 256.51 MW MW 259.90 245.38 239.10 MW 16.99 15.17 14.45 t/h 211.86 190.42 181.04 % 95.74 115.00 123.60 hr 12263 42741 73681 47
3. 15 70% 288MW 115% 256.51MW 123.6% 73681 IGCC IGCC 467.16MW IGV T 3 IGCC IGV 3.5.3 IGCC IGV T 3 IGCC IGCC IGCC / IGV 48
3.6 IGCC 50%-90% IGCC IGCC 3. 21 [21] 3. 21 [5] NO X NO X IGCC NHD E 23% vol 276.67 NO X 80mg/Nm 3 NO X NO X 1 49
2 3.6.1 IGCC 3. 22 NO X NO X NO X 80mg/Nm 3 IGV 3. 22 3. 16 IGCC IGCC 39% NO X IGCC 39% NO X 0 39% IGCC 0.082 NO X NO X IGV IGCC NO X IGV IGCC 0.858 50
IGCC NO X 39% 39% NO X 39% NO X NO X IGV IGCC 3. 16 IGCC C0 C1 C2 C3 C4 C5 C6 C7 % 0 10 20 30 39 60 80 100 t/h 0 11.49 22.84 34.18 44.39 67.67 89.54 111.08 t/h 16.9 12.7 8.52 4.09 0 0 0 0 IGV 7.97 8.64 8.84 9.29 9.62 11.84 14.04 16.27 84.62 84.38 84.31 84.14 84.02 83.19 82.37 81.53 % 136.1 136.1 136.0 136.0 136.0 136.1 136.1 136.0 MWe 22.6 22.6 22.6 22.6 22.6 22.6 22.6 22.6 H 2 O vol% t/h 80.20 79.86 79.73 79.56 79.38 78.75 78.19 77.54 NO X 80 80 80 80 80 57.20 41.85 31.06 mg/nm 3 (@16%O 2 ) 0 1.19 2.38 3.57 4.63 7.06 9.34 11.58 MWe 14.35 15.48 16.64 17.80 18.83 21.15 23.33 25.45 MWe 87.3 87.83 88.68 89.47 90.14 89.28 88.59 87.93 MWe IGCC 21.61 22.71 23.86 25.00 26.01 28.23 30.33 32.36 51
MWe IGCC 201.79 201.17 200.79 200.46 200.10 197.10 194.36 191.54 MWe IGCC % 42.65 42.70 42.71 42.71 42.74 42.43 42.14 41.88 0 0.67 1.33 1.99 2.59 3.95 5.23 6.48 MWe 16.45 17.05 17.69 18.31 18.87 20.10 21.26 22.38 MWe 87.31 87.78 88.59 89.35 89.95 89.00 88.23 87.51 MWe IGCC MWe IGCC 23.65 24.23 24.87 25.50 26.05 27.21 28.31 29.36 199.75 199.60 199.69 199.84 199.89 197.85 196.01 194.11 MWe IGCC % 42.22 42.37 42.46 42.57 42.69 42.59 42.50 42.44 3.6.2 IGCC IGV IGCC IGCC 3. 23 3. 23IGCC 52
3. 24 IGCC 1.218 IGV 3. 24 IGV [22] [22] IGCC Shell PG9331FA 0.53 IGV 1 [22] PG9331FA 275MW 21.4% PG9171E 136MW 8.8% 2 Shell 3.6.3 E IGCC IGCC NO X 1 2 53
NO X 3 NO X IGCC 30%-50% [22] 50% 3.7 5 150 150 150 3. 25 38 54
3. 25 350 38 8% 150 5% IGCC 1 2 34 3. 17 IGCC Tampa / [10] IGCC / Buggenum Puertollano IGCC IGCC Puertollano IGCC Wabash River NO X Buggenum Puertollano IGCC NO X 55
Buggenum IGCC NO X 8mg/Nm 3[14] Tampa [23] 3. 17 IGCC Tampa [10] Wabash [12] Buggenum [13] Puertollano [14] N/A (1) IGCC 200-300 [15] 3. 25 (2) 0.4MPa 143.6 10 153.6 (3) NO X 20bar 80 10 90 56
(4) 6kPa 36.2 IGCC 3. 26 3. 26 3.7.1 IGCC IGCC NHD PG9171E NO X NO X 80mg/Nm 3 5 IGCC l Case1 350 153 153 57
3. 27 case1 l Case2 350 153 153 3. 28 case2 l Case3 350 153 153 3. 29 case3 l Case4 58
350 l Case5 3. 30 case4 350 153 153 3.7.2 3. 31 case5 3. 18 IGCC Case1 Case2 Case3 Case4 Case5 t/h 80.82 80.82 80.82 80.82 80.82 MWe 136.0 136.0 136.0 136.0 136.0 MWe 82.38 85.71 88.47 89.16 87.70 IGCC MWe 197.03 200.25 202.90 203.56 202.16 IGCC % 41.35 42.03 42.56 42.70 42.41 t/h 45.56 45.56 27.75 20.74 27.75 59
3. 32 IGCC 3. 33 IGCC IGCC 3. 32 3. 33 Case2 150 case1 0.68 3.22MWe 3. 28 95 38 Case3 case1 1.21 5.87MWe case3 case4 case3 0.14 Case5 case3 0.15 150 38 5% 3. 25 IGCC 1.21 230 150 350 230 3.7.3 5 1.21 230-150 60
350-230 350-230 230-150 150 3.8 1200MWe IGCC 1200MWe IGCC 3. 19 3. 19 IGCC CO 2 30bar 5 2000t/d 1 1200t/d 10MPa 90% 16bar 95%O 2 IGV 50% 350-230 230-150 150 1200MWe IGCC 61
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[16] DOE/NETL, Evaluation of Alternate Water Gas Shift Configurations for IGCC Systems [R], 2009. [17] Zhu Y. Evaluation of Gas Turbine and Gasifier-based Power Generation System [D]; North Carolina State University, 2004. [18]. IGCC [D]. ;, 2003. [19]. IGCC [D]. ;, 2008. [20], 43500Nm3/h [R], 2007. [21] Lee C, Lee SJ, Yun Y. Effect of air separation unit integration on integrated gasification combined cycle performance and NOx emission characteristics [J]. Korean J Chem Eng, 2007, 24 (2): 368-73. [22],. IGCC [J]., 2000, 13 (1): 28-32. [23] Tampa IGCC [R], 2006. 63