张志坚, 等 : 硅烷偶联剂在玻纤增强复合材料领域中的应用 1 Y - R - Si - X 3 Y R X 4 Y X Xie 16 3 α γ ~ 13 1

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籍飒太史
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1 张志坚, 等 : 硅烷偶联剂在玻纤增强复合材料领域中的应用 TQ A Use of Silane Coupling Agents in Glass Fiber Reinforced Composites ZHANG ZhijianHUA LeiLI HuanxingCUI Lirong Jushi Group Co. LtdJushi Fiberglass Research InstituteKey Laboratory of Fiberglass Research of Zhejiang ProvinceTongxiang AbstractThe types of silane coupling agents commonly used in glass fiber production and their structurecoupling mechanism and application methods are described. The functions of silane coupling agents in glass fiber reinforced composites including reinforced thermosets and reinforced thermoplasticsare expoudedwith special explanations on the effects of silane structure and amount of addition on the performance of composite materials. Key wordssilane coupling agentcoupling mechanismglass fibercomposite material application ~

2 张志坚, 等 : 硅烷偶联剂在玻纤增强复合材料领域中的应用 1 Y - R - Si - X 3 Y R X 4 Y X Xie 16 3 α γ ~ 硅烷偶联剂的结构 1. 2 硅烷偶联剂的偶联机理

3 张志坚, 等 : 硅烷偶联剂在玻纤增强复合材料领域中的应用玻纤生产中常用的几种硅烷偶联剂 A A A A

4 张志坚, 等 : 硅烷偶联剂在玻纤增强复合材料领域中的应用 2. 2 玻纤生产中硅烷偶联剂的使用方法 % 15% 3% 20 1 Xie 16 2 ph % ~ 60% 1 80% A A ~

5 张志坚, 等 : 硅烷偶联剂在玻纤增强复合材料领域中的应用 3 ph ph h A ph ph 4 ~ 6 ph 7 72 h 120 h A h ph 4 ~ 6 ph Naviroj 23 ph A ph ph 2 ph NaOH ph 17 A A ph 硅烷偶联剂在玻纤增强复合材料中的作用 ph Plueddemann γ - A A h

张志坚, 等 : 硅烷偶联剂在玻纤增强复合材料领域中的应用 Y 3. 2 硅烷偶联剂对玻纤增强复合材料性能的影响 3. 2. 1

6 张志坚, 等 : 硅烷偶联剂在玻纤增强复合材料领域中的应用 Y 3. 2 硅烷偶联剂对玻纤增强复合材料性能的影响 X Y X 3 15 X - Si - O - Si - X X /MPa /MPa - Cl OCH OCH 2 CH OCH 2 CH 2 OCH O= OCH /% X Iglesias 28 APTESγ APDESγ APMESγ X APTES 3 AP- DES 2 APMES PU 24 h SEM APDES > APTES = APMES

张志坚, 等 : 硅烷偶联剂在玻纤增强复合材料领域中的应用 > 26 PP PE X PET PBT ABS 4 3. 2. 1. 2 Y 22 0. 1% Y Y 0. 1% 0.

7 张志坚, 等 : 硅烷偶联剂在玻纤增强复合材料领域中的应用 > 26 PP PE X PET PBT ABS Y % Y Y 0. 1% 0. 6% Y Park 30 A A % 0. 2% 0. 2% 0. 2% 0. 5% Y 26 > Pohl 15 A

8 张志坚, 等 : 硅烷偶联剂在玻纤增强复合材料领域中的应用 3. 3 硅烷偶联剂在玻纤增强热固性和热塑性复合材料中的应用 / A A MPa 74MPa 5 17 Jin 31 A A Saidpour 35 A A Jang 36 A / A J J A Pohl 15 A A A A / A A Lee 32 A A A Berg 33 A A A A PA PBT PET PP 971 A A A PA 37 A A A A A 72 h

9 张志坚, 等 : 硅烷偶联剂在玻纤增强复合材料领域中的应用 A A PA6 67% 39 A A PA6 40% % /MPa h PBT Mohd Ishak 40 PET PBT A - A PBT PBT 41 PBT A PBT /GF PP A A A 10. 6% 13% A % PET 42 PP PET A PET /GF A PP 43 A A A A

10 张志坚, 等 : 硅烷偶联剂在玻纤增强复合材料领域中的应用 A / - A A PP 45 SEM A PP A PP 46 A A % /MPa /MPa /% /% A PA66 A A A PBT A A A PP A A A

11 张志坚, 等 : 硅烷偶联剂在玻纤增强复合材料领域中的应用 J. Annual Technical Conference C. D. Han G. Sugerman. Titanate coupling agent update J. Annual Technical Conference A J J J α - 9. α - 19 J J M J H. F. WuD. W. DwightN. T. Huff. Effects of silane coupling agents on the interphase and performance of glass-fiber reinforced 48 polymer compositesj. Composites Science and Technology NUC MMCA M A. ChavesE. R. PohlL. VecereL. Hwang. Organofunctional silanes and their mixtures. US 2007 / A MMCA - 16Y. J. XieA. S. Hill CallumZ. F. XiaoH. MilitzC. Mai. Silane coupling agents used for natural fiber / polymer composites J. Composites Part AApplied Science and Manufacturing MMCA M J. 1. J J. 19. J J J S. J. Monte. Theory and use of organic titanate coupling agent 21. J

12 张志坚, 等 : 硅烷偶联剂在玻纤增强复合材料领域中的应用 S. Naviroj S. R. Culler J. L. KoenigH. Ishida. Structure and Adsorption Characteristics of Silane Coupling Agents on Silica and E-Glass FiberDependence on phj. Journal of Colloid and Interface Science E. P. Plueddenmann. Silane coupling agentsm. New York Plenum Press D. 35S. H. SaidpourM. W. Richardson. Glass fibre coating for optimum mechanical properties of vinyl ester compositesj. Composites Part AApplied Science and Manufacturing J. K. K imm. L. ShamJ. W u. Nanoscale characterisation of interphase in silane treated glass fibre compositesj. Compositespart A / 25. γ - MPS J D. 38X. S. BianL. AmbrosioJ. M. KennyL. NicolaisA. T Dibenedetto. Effects of Moisture Content on the Creep Behavior 26. of Nylon - 6 Thermoplastic Composites J. Journal of reinforced D plastics and composites J. 39S. Sterman J. G. Marsden. The effect of silane coupling agents J. G. IglesiasJ. G. BenitoA. J. AznarJ. BravoJ. Baselga. Effect of Glass Fiber Surface Treatments on Mechanical Strength of Epoxy Based Composite MaterialsJ. Journal of Colloid and Interface Science J S. J. ParkJ. S. Jin. Effect of Silane Coupling Agent on Interphase and Performance of Glass Fibers / Unsaturated Polyester Composites J. Journal of Colloid and Interface Science J. S. JinS. J. ParkJ. R. Lee. Influence of silane coupling a- gents on the surface energetics of glass fibers and mechanical interfacial properties of glass fiber-reinforced composites J. Journal of Adhesion Science and Technology G. W. LeeN. J. LeeJ. JangK. J. LeeJ. D. Nam. Effects of surface modification on the resins-transfer moulding RTMof glass-fiber /unsaturated-polyester composites J. Composites Science and Technology J. BergF. R. Jone. The role of sizing resins coupling agents and their blends on the formation of the interphase in glass fiber composites J. Composites Part AApplied Science and Manufacturing in improving the properties of filled or reinforced thermoplastics J. Polymer Engineering & Science Z. A. Mohd IshakA. AriffinR. Senawi. Effects of hygrothermal aging and a silane coupling agent on the tensile properties of injection molded short glass fiber reinforced poly butylene terephthalatecomposites J. European Polymer Journal PBT J PET J J. / / J KH550 J J J J J. 49. J

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