--------------------------------------------------------------- 1 1.1 ----------------------------------------------------------- 1 1.2 ---------------------------------------- 1 --------------------------------------------------------- 3 2.1 --------------------------------------------- 3 2.1.1 --------------------------------------------- 3 2.1.2 ---------------------------------------- 7 2.2 ----------------------------- 8 2.2.1 ----------------------------------------- 8 2.2.2 ---------------------------------------- 11 2.3 ----------------------------------------19 2.3.1 ------------------------19 2.3.2 ------------------------25 ---------------------------------33 3.1 ---------------------------------------------33 3.1.1 -------------------------------------33 3.1.2 --------------------------------34 3.1.3 --------------------------------35 3.2 ---------------------------------------39 3.2.1 -----------------------------------------39 3.2.2 --------------------------------------41 3.2.3 ---------------------------------------------------43 3.2.4 -----------------------------------------49 3.2.5 ---------------------------55 3.2.6 --------------------------------------58 i
3.2.7 -----------------------------------------64 -------------------------------------------------------------- 69 -------------------------------------------------------------------70 1.1 ------------------------------------71 3.1 -------------------------------------------------------72 3.2 -------------------------------89 3.3 ------------------------------------94 3.4 ---------------------------------99 3.5 --------------------------- 103 3.6 -------------------------------------- 130 3.7 ---------------------------------------- 133 3.8 ---------------------------------------- 139 3.9 ----------------------------------- 145 3.10 -------------------------------- 146 3.11 -------------------------------- 149 3.12 -------------------------------------- 151 3.13 -------------------------------------- 154 3.14 ------------------------------ 163 3.15 ------------------------------------------------ 172 3.16 --------------------------- 176 3.17 ---------------------------------------- 178 ii
2.1 --------------------------------------------- 5 2.2 ------------------------------------------------ 8 2.3 ----------------------------------------------------- 8 3.1 ---------------------------------------------34 3.2 -----------------------------------36 iii
2.1 ----------------------------------- 4 2.2 1999 ------------------------------ 6 2.3 -----------------------------------------26 3.1 ----------------------------42 3.2 --------------------62 iv
1.1 1.2 1
1.1 3.1 3.2 3.3 3.4 3.5 3.6 3.9 3.10 3.11 3.12 3.13 3.14 3.15 3.16 3.17 2
2.1 2.1.1 55 :1 2 PS PET 1520% 88 8.9% 87 5% Thermoplastics Type Thermosetting Type PVCPEPPABSPS 3
General Purpose Plastics High Performance Plastics PVC / HDPE/LDPE PP PSABS Engineering Plastics PolyacetalPOM PolyamidePA Nylon 6Nylon 66 Polycarbonate PC Polyethylene TerephthalatePET 2.1 2.1 2.1 4
5 PVC PE PP 5.4 PVC PE PMMA PS PPABS PVC.PE.PP.ABS.PS 2.1
5% 1 1999 4000 100 90% 2.2 1999 % % 100 330 2.4 2.4 100 500 5,792 42.5 44.9 500 1,000 2,727 20 64.9 1,000 4,000 3,412 25.1 90 4,000 10,000 795 5.8 95.8 1,000,000 566 4.2 100 13,622 100 100 1999 2 6
3 4 5 6 7 2.1.2 1. 2.2 1 7
2.2 2. 2.3 1 2.3 2.2 2.2.1 8
PVC PVC SHEET a.pvc PVC PVC 80 150 PVC b. 360 218 PVC PVC PVC PVC 9
c. PVC PVC PVC d. PVC PVC 520 825 e. f. g. h. 200 i. j. k. 10
3.9 MEK TOLUENE 3.7 3.8 2.2.2 1 PU PE PE 1 1PE 1996 2 16 9 20 62 26 PE 30 11
N 2 PURGE AIR 10 48 27 PE 2 N 2 a. N 2 b. PE 30 mj 125 PE 30gm 3 PE 2 N 2 purge 125 a. 70 25 b. a. vent stremer fine fluff purge air 400mmH 2 O silo PE vent b. PE 12
a. vent b. N 2 purge c. 2 1 10µm 30gm 3 30mJ 8.0bar 420 30Brinell 200 1 1 1 1 4.18 0.25 0.25 3 4 a. b. c. d. 13
2 02 02 A. B. C. 1. 2. 3. 23 4. 5. 421 6. 8 30 7. 8. I. II. III. IV. 9. X I. PE II. 14
3 03 03 A. B. C. 1. 2. 3. 28 4. 5. 529 6. 7 7. 8. I. II. III. IV. 9. 56 I. II. 15
4 04 04 A. B. C. 1. 2. 3. 28 4. 5. 10 15 6. 8 30 7. 8. I. II. III. IV. 9. 14 I. II. III. 16
5 5 05 05 A. B. C. 1. 2. 3. 28 4. 5. 513 6. 7 05 7. 8. I. II. III. IV. 9. PE PE I. II. III. 17
6 a. b. 7 a. b. c. d. e. 8 a. PE PE b. PE c. 9 a. b. 10 PEEVA 18
MSDS a. b. (11) a. b. c. d. 2.3 2.3.1 () 1. 1 2 3 4 5 19
2. (1) (2) (3) 5 2 (4) (5) 100 10 () 1. 1 2 3 2. (1) (2) (3) 70 () 1. (1) 20
(2) 2. (1) (2) (3) (4) 286 (5) () 1. (1) 2. (2) (1) 30mA 0.1 (2) () 1. (1) (2) 21
2. (1) 11.4KV (2) (3) () 1. (1) (11.4KV) 400KVA 2. (1) (2) BIL KV 75 (3) () 1. (1) 2. (1) (2) ON OFF (3) ON FAILURE 22
ACTUATOR CAM ON OFF () 1. (1) (2) 2. (1) GUARD LOCKING 2 1 0 (2) 1. 1 2 3 4 2. 1 2 23
3 4 5 6 7 1. 1 2 3 4 5 2. 1 2 3 4 24
5 ( ) 1. (1) 2. (1) (2) 2.3.2 2.3 25
2.3 1. 1. 1. 1. 3.1 2. 3.2 3. 3. 3.3 26
27 2.3 () 1. 1. (1) (2) (3) (4) (5) (6) (7) 2. 2. ( ) (1) (2) (3) (4) (5) (6) (7) (8) 3. 3. 101 30 ~100 29 30
28 2.3 () 4. 4. (1) (2) (3) (4) (5) (6) 5. 5. 6. 6.
29 2.3 () 7. 7. (1) (2) (3) (4) (1) (2) (3) (4) (5) (6) (7) (8) 3.16 8. 8. 9. 9. 1. 1. 3.5 2. 2. (1) (2) (3) (4) (5) (6) (7) 3.6
30 2.3 () 3. 3. (1) (2) (3) (4) (5) 3.17 4. 4. 5. 5. 6. 6. 3.14
31 2.3 () 7. 7. 3.15 1. 1. 1. 2. 2. 3. 3. 4. 4.
32 2.3 () 5. 5. 1. 1. 2. 2. (1) (2) (3) (4) (5) (6) 1. 1. / /
3.1 3.1.1 PDCA 3.1 Plan( )Do( )Check( )Action( ) ( PDCA) PDCA 3.1 33
34 3.1 3.1.2 PLAN DO CHECK ACTION
(WTO) 3.1.3 3.2 () 1. 2. 3. / 4. 35
3.2 36
() / ( = ) / () () 1. PDCA 2. 3. 37
4. () () () () / / / / 38
() 3.2 PDCA 3.2.1 () () 1. 2. 3. 39
4. 5. 6. () * * * * * * * xxx 40
3.2.2 () PDCA () 1. 2. HAZOPFMEAFTA 3. 4. 5. 6. 7. 8. 9. 3.1 41
3.1 1. 3 H 2. 6 H 3. 3 H 4. 3 H 5. 3 H 6. 6 H 7. 3 H 8. 3 H / / / / / / / / 42
( ( ) ( ) 91 ) 09 10 11 12 08 91.10. 92.01. 91.10. / 20000 15000 91.10. 5000 3.2.3 () 43
() 1. 2. 3. 4. 5. 6. 7. 8. ( ) 9. (1) ( ) (2) ( 44
45 ) (3) ( ) (4) ( ) (5) ( ) 10. / / / ( ) 11. (1) (2) (3) (4) (5) (6) (7) (8) 12. (1) (2) (3) (4) (5) (6) (7) 13. 14. 15. 3.16 16.
46 ()
1. 2. A. ( ) ( ) B. 47
C. ( ) ( ) ( ) D. i. ii. 48
iii. E. 3.2.4 () 49
() 1. 3.10 2. 3. 3.4 4. 5. 3.12 6. 3.6 7. 3.15 8. 3.5 9. 3.11 10. 3.13 11. 3.14 12. 3.17 50
1. : 2. 3. 3.1 3.2 3.3 3.4 3.5 3.6 4. 5. : 5.1 5.2 5.3. 5.4 5.4.1 5.4.2 5.5 5.6 5.7 51
1. 2. 3. 3.1 3.2 3.3 4. 5. 5.1 5.1.1 5.1.2 5.1.3 ON 5.1.4 ON 5.1.5 5.1.6 3.1.7 5.2 5.2.1 5.2.2 5.2.3 5.2.4 52
53
1. 2. 3 4. 4.1 4.1.1 4.1.2 4.2 5 5.1 5.2 5.2.1 ( ) 5.2.2 5.2.3 5.2.4 5.2.5 5.3 5.4 5.5 5.6 6. 6.1 6.2 7. 54
3.2.5 () () 1. 2. 3. 4. : 5. 55
6. 6 7. 8. 9. 10. 11. 12. 56
() 1. 2. 3. 3.1 3.2 3.3 4. 4.1-11P12-01 4.2-12P17-01 4.3-13P27-02 4.4-14P27-03 4.5-11P28-02 57
1. 2. 3. 4. ( ) 5. 6. 7. a b. 8. 9. 10. 11. 12 13. 1 2 3 3.2.6 () 58
59 () 1. ( ) 2. 3. (1) (2) (3) (4) 4.
(1) (2) (3) (4) 5. (Proactive) (Reactive) 6. 7. (1) (2) (3) (4) (5) (6) 8. 9. 10. (1) 60
(2) (3) (4) 11. 12. 13. 14. 15. 1 2 3 (OHSAS 18001 ) 4 5 6 7 16. 17. 61
18. 3.2 01. 01. 02. 03. 04. 04. 05. 06. 05. 07. 06. 08. 09. 10. 07. 11. 08. 12. 13. 09. 14. 10. 15. 11. 16. 17. 18. 62
63 () 91/07/19 91/07/22 91/07/23 91/07/24 91/07/26
81 82 83 84 85 86 87 88 89 90 2 7 3 1 0 3 6 9 11 5 F.R. 5% 7% 2% 6% 1% 3% 7% 3% 3% 1% FSI 2 3 6 8 2 9 7 4 3 1 S.R. 1% 3% 2% 1% 2% 1% 1% 3% 2% 1% 500K 500K 600K 650K 660K 700K 710K 750K 820K 880K 3.2.7 () PDCA PDCA 64
2000 () ( ) 1. 2. 3. 4. 5. 6. 7. 8. 9. 10. 11. ( ) 12. 65
13. 14. 15. 16. ( ) 17. 18. 19. 66
() 67
91 91 8 22 14 00 16 30 12 1232, : 91 (09/18~20) 11 91/12/31 ( ) 91.09.30 68
69
01. 2001 02. 1999 03. 2001 04. 2001 05. 2002 06. 2002 07. 2001 08. 2001 09. 2000 10. 2001 11. 1998 12. 1998 13. 1999 14. 2000 70
1.1 http://cesh.moeaidb.gov.tw/ http://www.ttpia.com.tw/ http://www.cla.gov.tw/ http://www.iosh.gov.tw/ http://www.nfa.gov.tw/ http://www.cdc.gov.tw/ http://www.cesh.itri.org.tw/ http://www.isha.org.tw/ http://www.osha.gov/ http://www.nfpa.org/ http://www.cdc.gov/niosh/ http://www.hse.gov.uk/ http://www.epsc.org/ http://www.anquan.ac.cn/ http://www.cis-safety-inf.org.cn/ http://www.oshc.org.hk/ 71
3.1 : API 750FMEA HAZOPJSA 1 What-if (Failure Modes and Effects Analysis, FMEA ) (Hazard and Operability Study, HazOp 2) (Fault Tree Analysis) 1. 2. 3. 4. 5. 1. ERPG-3 IDLH 72
2. 3. 38(100) /.. 1 (Proactive) (Reactive) : : 73
74 1 1 /
1 :xxx xxx xx xx xx / / Flare N 2 Flare Steam Purge Steam Purge xxx B10042 B10043 B10044 B10045 B10046 B10047 B10048 B10049 xxx 75
2 :xxx xxx xx xx xx / ( ( / ) B10045 P3 C 4 B10046 Flare P3 D 4 B10047 Steam Purge P3 C 4 P2 C 3 B10048 WI B10049 Steam Purge WI P3 C 4 xxx xxx 76
3 1. 11. 2. 12. 3. 13. 4. 14. 5. 15. 6. 16. 7. 17. 8. 18. 9. 19. 10. 4 P1 5 / PM P2 1~4 / P3 5 1 1 1 10 P4 1 5 1 P5 10 1 / 77
A B C D E 5 ( ) NT 500 1 NT 3 ~1 100~500 / 1 ( NT 50~100 1 ~3 ) NT 10~50 ~1 NT 10 6 P1 P2 P3 P4 P5 A 1 1 2 3 3 B 1 2 3 3 4 C 2 3 4 4 5 D 3 4 4 4 5 E 4 5 5 5 5 7 ( ) 1-2- 3-4 5 4-5- 78
8 : / xx / / ( ) B10018 AN VOC xxx 90.09.30 4 404 ( ) 4 lb/year 176 lb/year B10019 HQ xxx 91.12.31 4 HQ B10048 xxx 91.12.31 4 xxx xxx xxx xxx 79
9 : / xx B10048 xxx 91.12.31 90 90 90 91 ( ) 1 20% 90.07.15 90.09.30 AN 1 BATCH 2 3 4 2 30% 90.07.15 90.09.30 AN 3 20% 90.09.30 90.10.15 AN 4 stream 30% 91.01.01 91.03.31 stream WWI AOGI xxx xxx xxx 80
10 : / xxx B10018 90.09.15 xxx ( ) 5HP MEHQ VOC B10019 xxx HQ B10048 xxx xxx xxx xx 81
1 (inherent hazard) (interact hazard) a. a A 1.1 b B 1.2 c C 1.3 b. a b Q>20%TQ (oxidation) (nitration) (halogenation) (organmetallics) (diazotization) (hydrogenation) (thermal decomposition) (polymerization) (sulphonation) (condensation) (LEL) (UEL) ( 25% ) 100 P 10psig(1.75atm.Abs) T>AIT P 20kg/cm 2 P 500mmHg P( ) 4( ) Q 82
kg TQ T AIT P P 1.4 83
1.1 i.e. NOTE 45 45 A / ( / ) / 84
1.2 i.e. NOTE 45 45 B 85
1.3 i.e. NOTE 45 45 C ( / ) 86
1.4 1. 20,000 25,000 >4,000 2. 3. 4. 87
( ) 1008-R-101 R-101 SEFM-1201 2 HAZOP 1008.1 1008.2 1008.3 TRCA-1 1008.4 3 4 TR-101/102/103 LICA-103 1008.5 (LICA/LCV-103 4 3 LCV-103BY-PASS ) 1008.6 R-101 LICA-103 3 2 88
89 N Y 3.2 ( CD ) /SOP N Y
1. 1 2 1 3 4 2. 2 3. 1 3 2 3 1 NO 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 90
NO 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 91
2 : / NO 92
3 : / 93
3.3 92 1 92 12 003 1 2 3 4 5 6 7 8 9 10 11 12 ( ) 1. 2. 3. 1 4. 1. 10,000 2. 3. 4. 94
3.3 ( ) 1 2 3 4 5 6 7 8 9 10 11 12 5. 6. 1. 2. 3 3. 3 13,500 4. 5. 6. 1 3,500 95
3.3 1 2 3 4 5 6 7 8 9 10 11 12 ( ) 1. 2. 1. 2. 3. 4. 5. 3,000 6. 3,000 7. 96
3.3 1 2 3 4 5 6 7 8 9 10 11 12 ( ) 1. 2. 10,000 3. 1. 2. 60.000 30? 30-45?45? 3.? 10,000 4. 5. 97
3.3 1 2 3 4 5 6 7 8 9 10 11 12 ( ) 1. 10,000 2. 3. 98
3.4 1. (1) (2) (3) (4) (5) (6) ( ) (7) 2. (1) (2) (3) (4) (5) ( ) 3. (1) : a. b. 99
c. d. (2) : a. ( ) b. c. d. e. 4. 58 (1) (2) 2.8 5T(5 ) (3) 100
(4) ( ) a. b. c. a. ( ) b. CNS2930 c. d. e. f. CNS2930( ) (1) (2) a. b. c. d. 101
5. 1 ( 0.25 1 ) (1) (2) (3) 6. (1) (2) (3) (4) (5) (6) 102
3.5 1. 2. 2.1 2.2 3.1 () 3.2 4.1 (1) 103
4.2 (1) (2) (3) (4) (5) (6) (7) (8) (9) (10) (11) (12) (13) 4.3 (1) (2) (3) (4) (5) (6) (7) (8) (9) / 104
(10) (11) (12) 4.4 (1) (2) (3) (4) 4.5 (1) (2) (3) (4) (5) (6) (7) (8) (9) (10) (11) (12) (13) 105
4.6 (1) (2) (3) (4) 106
5.1 / ( / ) ( ) 107
6.1 5.1 6.1.1 ( 7-1) (1) (a) (b) (c) ( )(d) ( ) (2) (a) (b) (c) (d) (e) (f) (3) (a) (b) (4) (a) (b) (5) ( ) 6.1.2 ( 7-2) ( 7-3) ( ) 6.1.3 6.2 6.2.1 108
6.2.2 7-4 6.2.3 ( / ) 6.2.4 6.3 6.3.1 (1) (2) (3) (4) (5) (6) 6.3.2 (1) (2) (3) (4) (5) (6) (7) (8) (9) 109
6.3.3 ( 7-5 ) 6.3.4 6.3.5 6.3.6 6.4 6.4.1 (a) (b) (c) (d) (e) 6.4.2 : (1) (2) (3) (4) (5) (6) 6.4.2 6.4.3 ( 7-6 ) 6.4.4 110
6.4.5 6.5 6.5.1 6.5.2 6.5.3 6.5.4 6.5.5 7-7 6.5.6 6.5.7 7-8 6.5.8 20 6.5.9 6.5.10 6.5.11 6.5.12 / 6.5.13 ( ) 111
6.5.14 6.6 6.6.1 6.6.2 6.6.3 6.6.3 6.6.4 6.6.5 6.6.6 6.6.7 6.6.8 6.6.9 6.6.10 112
24 6.6.11 6.6.12 ( 7-9) 6.6.13 (a) (b) (c) (d) (e) (f) (g) (h) 6.6.14 6.6.15 6.6.16 6.6.17 6.6.18 6.6.19 113
6.6.20 6.7 6.7.1 3 6.7.2 6.7.3 6.8 6.8.1 6.8.2 7-10 ( 7-11) 6.8.2 6.8.3 6.8.4 6.8.5 7-12 6.8.6 114
6.8.7 7-13 6.9 6.9.1 6.9.2 7-1 7-2 7-3 7-4 7-5 7-6 7-7 7-8 7-9 7-10 7-11 7-12 7-13 115
7-1 ( ) A. 1. 2. 3. 4. 5. B. 1. 2. 3. 4. 5. 6. 7. C. 1. 2. D. 1. 2. : E. 1. 2. 3. 4. 1. 2. 116
7-2 : : : : // ( ) : 117
7-3 ( ) () () 118
7-4 10 5-9 (5 ) (3 ) 5 (2 ) / A. A. (5 ) (3 ) (2 ) B. B. (5 ) (10 ) (7 ) A. A. (10 ) (7 ) (5 ) B. 2 B. 1 B. 1 (5 ) (3 ) (1 ) C. C. C. (5 ) (3 ) (1 ) A. A. (5 ) (15 ) (10 ) B. B. (5 ) (10 ) (7 ) (5 ) (10 ) (7 ) A. A. (5 ) (3 ) (1 ) B.2 B.2 B.2 (20 5 5 ) (10 ) (0 ) 119
7-5 (1) (2) (3) (4) ( ) (5) (6) (7) I. II. (8) ( ) 120
7-6 1. 2. () 3. 4. 5. 6. 7. 8. 9. 10. 121
7-7 120cm 90cm 122
7-8 123
124 7-9
7-10 1 x 2 x 3 x 4 x 5 x 6 x 7 x 8 x 9 x 10 x 11 x 12 x 13 x 14 x 15 x 16 x 17 x 18 x 19 x 20 ( ) x 21 x 22 x 23 x 24 x 25 x 26 x 27 x 28 x 29 x 125
7-10 30 x 31 x 32 x 33 UN NO. x 34 x 35 x 36 x 37 x UNLOADING 38 x LOADING 39 x 40 x UNLOADING 41 x 42 x 43 x 44 x 45 x 46 x 47 x 48 x 49 x 50 x 51 x 52 x 53 x 54 x 55 COG x 56 x 57 x 126
7-11 127
20 20 15 15 30 7-12 1. 1-5 / 2. 1-3 / 3. 1-2 / 20 ( )[ ] 1. 1-5 / 2. 1-3 / 3. 1-3 / 20 ( )[ ] 1. 1-3 / 2.1-3 / 3. 15% 2 /15% 4. 1-3 / 15 ( )[ ] 1. 1-3 / 2. 1-3 / 3. 1-3 / 15 ( )[ ] 1. 1-5 / 2. /3-5 / 3. 3-5 / 4. 3-5 / 5. 1-3 / 20 ( )[ ] [ ] 1. 2. 3. 4. 5. 128
7-13 1 20 2 20 3 15 4 15 5 30 1. 90 ()80 () 90 70 () 80 60 () 70 60 ( ) 2. 3. ( ) 4. 5. / 129
3.6 1 2 3 4 5 6 7 8 9 10 11 12 ( ) 1. 2. 3. 4. / /700 5. 700 6. 700 7. 8. 9. / / 10. / 11. / 12. 300 130
3.6 () 1 2 3 4 5 6 7 8 9 10 11 12 ( ) 13 300 14. 300 15. 16. 17. 18. #700 19. #300 #700 20. 21. 22. 23. 700 24. 25. 26. 131
3.6 () 1 2 3 4 5 6 7 8 9 10 11 12 1. / 2. / 85 3. / 4. ( / ) 5. ( ) / 6. / 7. / ( ) 132
(METHYL ETHYL KETONE) 3.7 / (METHYL ETHYL KETONE) 2,, (ETHYL METHYL KETONEMEK2BUTANONE METHYL ACETONEMETHYL2PROPANONEETHYL METHYL CETONEBUTANONE) CAS No.00078-93-3 100 MEK 2.3 3( 1. 2., 3. 1. 5 2. ( )3., :1., 2. 3. :1., 2., 3. 240 300 ml 4. C 133
134,,, 1. 2. 3. 4. 5. 6. 1. 2.,, 3., 4.,, 5.,, 6., 1. 2. 1. 2. 3. 1. 2. 3. 4. 5. 6. 10.
11. 12. 13. ( ) 14. 15. 16. 17. 18. 19. 20. 21. 22. 23. BEI TWA STEL CEILING 200 ppm 250 ppm MEK 2 mg/l 135
3000ppm Teflon4HBarricaleChemrel 1. ( 8 )2. 3. 1. 2. 3. 4. ph / 79.6-6-2 404 1.8 ~ 10 77.5 mmhg @20 2.41 0.805 1 26.829 mg/100ml 1. 2. ) 3. ( ) 4. ( ) ( ) 5. ( )6. 0.5 1 7. 2 1. 1. ( )2. ( ) ( )3. 4. 5. 2, 136
1.100 200 ppm 2. LD50( )2740 mg/kg( ) LC50( )11300 ppm /4H( ) 500 mg/24h 350 ppm ( ), 1. 3000 ppm/7h 6-15 / MEK MEK MEK 24 MEK MEK 3-12 MEK 2.3 1. 2. 1.DOT 49 CFR 2.IATA/ICAO 3 3.IMDG 3 1193 1. 84 2. 3. 137
1.CHEMINFO CCINFO 99-2 2.RTECS TOMES PLUS Vol.411999 3.HSDB TOMES PLUS Vol.411999 / 89.3.31 / 138
139 3. 8 (TOLUENE) - - / - (TOLUENE) METHYLBENZENEMETHYLBENZOLPHENYLMETHANETOLUOL CAS No.108-88-3 100 3 1. 2. 3. 4. 1. 2. 3. ( )4., 5. 1. 2. 20 3. 4. 1. 2. 3. 4. 240300 5. 6. C
140 1. 2. 1. 2. 3. 4. 5. 6. 7. 8. 9. 10. 11. 12. 13. 14. 1. 2. 3. 1. 2. 3. 4. 1. 2 3. 4. 5. 1. 2. 3. 4. 5. 6. 7. 8. 9. 10. 11. 12. 13. ( ) 14. 15. 16. 17. 18. 19.
141 1. 2. 3. 4. 5. 6. 7. 8. 9. 10. 11. 12. 13. 14. 15. 16. 17. 1. 2. 3. 4. TWA STEL CEILING BEIs 100 ppm ( ) 125 ppm ( ) - 0.05 mg/l 0.5mg/L(B) 1.6g (BNs) 1. 2. 500ppm TeflonViton4HBarricadeResponder 1. 2. 3. / 1. 2. 3. 4. ph / / 110.6
480 4.4 ( ) 1.2 7.1 22 mmhg @20 3.1 0.86 1 5458 mg/100 ml 1. 2. 3. 4. 5. 6. 7. 4 8. 1. 4 50ppm 50-100ppm 100ppm 200ppm 500ppm (10000ppm) ( ) (3-5 ) 300ppm (6-7 ) 100ppm 1. 2. LD50( )<870 mg/kg( ) LC50( )6000 ppm/6h( ) 35mg( ) 870ug( ) 1. 2. 3. 200ppm 500ppm 4. ( ) 1500mg/m3/24H( 1-8 ) IARC Group 3 142
/ 1. 2. 3. 4. 300ppm 5. 6.LC50( )24mg/L/96h 1. 2. 3. 1.DOT 49 CFR 2.IATA/ICAO 3 3.IMDG 3 1294 1. 84 2. 3. - 1.CHEMINFO CCINFO 99-2 2.HAZARDTEXT TOMES PLUS Vol.341997 3.RTECS TOMES PLUS Vol.341997 4.HSDB TOMES PLUS Vol.341997 5. - / - - - 89.8.31 143
/ Ns Sc B Nq Sq 144
3.9 Cyclohexanone 50ppm 70ppm Toluene Ethyl acetate Methyl ethyl ketone Methyl isobutyl ketone. Tetrahydrofuran 145
3.10 1 1 1 1. 2 3 1. 2. (A) (B) (C) 2. 2 ( ) 3 146
2 1 2 3 4 5 1. 2. 6 7 8 1. 9 2. 10 147
3 1. 1-1 1-2 1-3 2. 2-1 2-1 2-1 2-1 2-2 3. 3-1 3-1 3-1 3-1 3-2 3-2 3-2 5 3-3 3-3 3-3 4. 4-1 4-1 4-1 4-1 4-2 148
3.11 1. ( ) ( ) ( 2. 3. 4. 5. 6. (1) (2) (3) (4) ( LPG (5) 149
a. b. c. d. e. f. g. 1. 2. 3. 4. a. b. c. d. 150
3.12 1. * * * * * * * * * * * 2. ( ) 29 (1) (2) 151
(3) (4) 36 (1) (2) (3) (4) 3. 4. 1 2 ( ) 3 4 5. 152
(1) (2) (3) 6. 7. 153
3.13 1. (1) 1 (2) (3) (4) 1 A B C B C D 1 2 A 3 4 5 1 B 2 3 C 1 D 1 a. 154
b. B c. CNS 441 d. 1211 1301 2402 e. BC ABC ( ABC ) D f. BC ABC (5) 2 (6) 1 () () () () 2 100m 2 200m 2 100m 2 25m 2 () () 155
2. 1 3 2 4 3 (1) 300m 2 (2) 1500m 2 (3) 1000m 2 ( ) (4) 3000m 2 (5) ( 10 700 ) (1) ( 50 15 ) ( 257 ) (2)11 (3)11 100m 2 1000m 2 * 156
4 CO 2 ( ) CO 2 157
3. 1 5 2 6 3 ( ) 4 7 5 ( ) 11 ( ) ( ) 300m 2 300m 2 100m 2 300m 2 500m 2 300m 2 300m 2 () 300m 2 100m 2 ( ) 158
6 1 600m 2 500m 2 2 50m 100m 3 600m 2 1000m 2 4 50m 5 45m 7 1 2 3 4 5 6 7 8 1248 3 159
4. 8 8 ( ) 12 300m 2 150m 2 100m 2 ( ) ( ) 12 500m 2 150m 2 150m2 12 ( ) ( ) 700m 2 150m 2 150m 2 ( ) ( ) 150m 2 ( ) 160
(1) (2) 1.7Kg/cm 2 130L/min (1) (2) 2.5Kg/cm 2 60L/min 7Kg/cm 2 5. 9 1 2 2.5Kg/cm 2 350L/min 3 4 161
9 3000m 2 5000m 2 10000m 2 6. 1 2 162
1. 3.14 : (1) (2) (3) (4) 2. (1) (2) (3) (4) 3. 3.1 / 3.2 A 12"-150# packing B 12"-150# packing 12"-150# packing 12"-150# packing 3.3 3.4 163
3.5 3.6 3.7 DCS DCS 3.8 / / 3.9 4. 4.1 (a) (b) 4.2 / (a) (b) (c) (d) (e) 4.3 (a) 164
(b) (c) 4.4 (a) (b) 4.5 (a) (b) 5. : 5.1 () / 5.2 (1) (2) 5.3 (1) (2) () ( ) 165
5.4 (1) ( ) (2) (SOP) SOP 5.5 (1) PID ( (2) / 5.6 (1) (2) 5.7 (1) : (a) (b) (c) () 6. 6.1 6.2 6.3 166
6.1 167
6.2 : : : : : : / / / : : 168
6.3 : : 1. 1.1 : 1.2 1.3 1.4 1.5 1.6 1.7 / 169
6.3 () : 2. 2.1 2.2 2.3 2.4 2.5 2.6 ( : ) 2.7 170
6.3 () : 3. 3.1 3.2 3.3 3.4 3.5 3.6 3.7 3.8 4. (HazOp) : : 171
3.15 1. (1) (2) (3) (4) X (5) (6) (7) (8) (ALTSGPT) (Creatinine) 2. (1) (2) (3) 3. 4. (1) (2) (3) (4) (5) (6) 172
(7) (8) 1.1.2.2 (9) ( ) a. 4-4- - 4,4, ( ) (10) (11) (12) 5. ( ) 6. 7. 8. 9. 10. (1) (2) 173
(3) 11. (1) (2) (3) (4) 12. 13. (1) (2) (3) a. b. c. (4) a. b. c. 14. 15. 174
16. 17. 18. 19. 20. 21. 175
3.16 1 1 2 2 3 30 1 () 29 42 36 () 18 18 18 18 18 18 () 18 176
2 18 18 18 18 18 3 177
3.17 CGTDC 01/5 8 3 5 1 2 1. 8 6 7 2 4 81 12 28 2. 3. 3.1 3.1.1 3.1.2 3.1.3 3.1.4 3.2 178
3.17 () CGTDC 02/5 8 3 5 1 2 8 6 7 2 4 3.2.1 (1) (2) A. B. C. D. E. (3) A. B. C. D. (4) (3) 3.2.2 (1) A. B. C. D. 179
3.17 () CGTDC 03/5 8 3 5 1 2 E. F. G. H. I. J. 8 6 7 2 4 (2) (3) A. B. C. D. (4) (5) 3.2.3 (1) A. 180
3.17 () CGTDC 04/5 8 3 5 1 2 B. C. D. 8 6 7 2 4 E. F. (2) (3) (4) (5) (6) 3.2.4 (1) (2) A. B. C. D. E. 181
3.17 () CGTDC 05/5 8 3 5 1 2 8 6 7 2 4 F. (3) (4) 4. 4.1 4.2 4.3 4.4 4.4.1. 4.4.2 4.4.3 5 5.1 5.2 182
XX XX 1 2 3 4 5 6 7 8 9 10 11 12 1 2 3 4 5 6 7 8 9 10 11 12 ( ) ( ) 183
XX XX () 1 2 3 4 5 6 7 8 9 10 11 12 10 11 12 13 14 15 16 17 18 19 20 184
Team Leader Plant Mgr XX Co-ordinater Safety Scet Supr XX Operation Sect Supr Security Sect Supr Gen Affair Sect Supr Maint Sect Supr Coordinater of Production Safety Engr XX XX XX XX Sales Sect Supr XX XX Operation Engr Maint Engr XX XX XX 185
186
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1. 2. 3. 4. 5. 1. 2. 3. 4. 0.5 0.5 0.5 0.5 0.5 0.5 3 1.3. 2. 4. 1. 4. 2. 5. 3. 6. 190
191
C U 192
193 ( ) 1. 2.MSDS 3. 4. 1 2 3 4 5 2.1 2.2 2.3 4.1 4.2 4.3 5.1 5.2 6.1 6.1 1. 2. 1. 2. 3. 1. 2. 3. 4. 1. 2. 3.
( ) XX XX 1. 2. 3. 4. 5. 194
/, --, --, 91 ISBN 957-01-2390-7( ) 1. 2. 3. 467.4 91020117 41-3 TEL022754-1255 FAX022704-3753 http//www.moeaidb.gov.tw 195 51 11 TEL03591-2294 FAX03591-8470 http//cesh.moeaidb.gov.tw TEL03591-4925 FAX03582-6697 I S B N 957-01-2390-7 G P N 1009103713