1 AAS PERKINELMER

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Transcription:

PerkinElmer AAnalyst AAS

1 AAS PERKINELMER

5 1 2 MHS FIAS FIMS 3 4 5

HCL EDL

EDL EDL 60

PERKINELMER Intensitron

EDL PERKINELMER EDL RF RF EDL

EDL O Corkprene O

10 cm 5 cm 90 o 5 cm 90 o PERKINELMER / PERKINELMER L 301 35 2300 PERKINELMER 4 / 8.5 /

1450BTU/ 12300BTU/ 520KPa 75psig PERKINELMER 2900 14 / 30 / 1450BTU/ 43000BTU/ /

250nm / 4 2 / 7 10Ml/min 4 6Ml/min PERKINELMER AA

C=kA PERKINELMER AA C=K 0 (-K 1 A)

8 K 1 K 0 K 0 1.0 PERKINELMER AA C=K 1 K 2 C K 1 2 C A K 1 K 2 K 3 K 0 K 0 1.0 Unvala 1 Barnett 2 K 3 1 0.2 0.3

2 3 3 2

10 15 3 3

S3 S1 6 S 0.2 0.3 S1 S2 S1 3 2 3 1 3 6 6 3 1 2 S1 S2 10 S2 2

10 3 S2 S3 6 3 1 1 0.0044 mg/l *0.0044/ 0.2 mg/l 3 5 2 10 1 2 3 4 3 / 5

3 33 A B 6

K Na Rb Cs

Ba A B Pb 283.3nm 15 10

1 2 3 4 5

AA WinLab

N040 0100 5cm N040 0101 5cm 10cm N040 0102 10cm

N040 0103 10cm PerkinElmer TotalFlow AA WinLab

1 2

1 2 3 2 4 1 2 2 3 1 2 2 6 3 AA WinLab 4 Inst Method Editor signal type Emission 5 6 2 7 7 2 20 8 2 21 AA WinLab 1 2

3 File Change Technique Toolbar Technique 4 Flame Furnace 5 OK AA WinLab 1 2 8 2 2 10 3 2 15 4 2 15 5 2 17 6 2 20 7 2 21 3 7 5 7

1 3 7 2 2 4 3 1 2 1 2 3 4 5 6 7 2 4 AA WinLab

1 2 3 1 2 3 4 O O O 4 2mm 5

1 2 1 2 3 O O 4 1 2 3 4 5 6

AA WinLab 1 3 7 2 2 4 3 2 8 4 5 1 2 6

1 2 O 3 15 3 3 16 O O O 1 3 7 2 2 4 3 2 8 4 5 2 10 6 1 2 7 O 8 Corkpreen 0047 2014 Kalrez O 0992

1044 9 10 2 9 2 12 5 9 1 2 4 2 2 8 3 250mL 4 2 9

5 2 4 1 2 3 4 5 6 7 8 1 2 3 4 on/off 2 23 1 2 5 2 2 20 3 2 22 2 1 4 Toolbar Flame 5 Flame Control Air N2O 6 Flame Control Flame On/Off 3 7

1 2 3 QTA-cell 1 P 2 3 P max max

1 on/off 2 3 1 2 8 2 4 3 11 5 2 9 6 2 5 7 2 21 8 3 7

A B C PERKINELMER

PERKINELMER 1 2 PERKINELMER PERKINELMER PERKINELMER 1 2 1 2

1 2 3 4

1 3 7 2 3 8 3 3 11 4 3 16 1 2 3 1 5 2 1 5 2 5 3 1 V/V 5 4 5

1 Flame Control Flame 2 3 Flame Control Bleed Gases 1 3 7 2 2 4

3 2 8 4 5 3 23 3 6 7 6 1 2 3 7 1 2 8 9 10 O

3 7 2 4 2 8 2 9 2 4 10 V/V 15 V/V 10min 2 9 2 4

1 2 3 8 3 16 MIBK 1 5 2 5 3 1 V/V 5 4 5 5 3 7 6 2 8 7 8 3 33 Cu Ag Hg

1 V/V HCl 5 2 3 7 3 2 8 4 5 2 8 O

1 2 3 6 2 15 4 O 5 6 1/4

7 8 9 O O O 10. 11. 2 9 3 28 0.1% Triton X 100 1 20cm 2 3 AA WinLab 1 1 3 23

2 3 0303 0135 4 3 26 5 3 28 6 7

1 3 7 2 2 4 3 1 2 3 4 O O O 4 2mm Allen 5 1 3 23 2 3 4 PTFE 5 O

6 1 2 3 4 O 1 1 1 1 4 7 1 O 2 O O 3

4 5 6 PTFE 7 8 1 0.6mm 20cm 2 0303 0135 3 4

1 1 2 2 O O

3 1 2 3 4 5 6

AA WinLab 1 3 7 2 2 4 3 2 8 4 5 3 23

1 3 7 2 3 3 32 4 5 6 7 8 9 5 9 1 3 7 2 2 4 3 2 8 4 250mL 5 2 9

6 2 4 1 3 7 2 3 3 32 4 5 6 7 8 9 3 33 10 1 3 7

2 3 3 33 4 5 6 7 8 9 10. 11.

1 1+1 5 gas removal 600kPa 6bar 85psig 600kPa 6bar 85psig cracking the valve

PerkinElmer PerkinElmer 8 8 EST 1 800 7624002 PerkinElmer PerkinElmer

Burner components Spray chamber....................................... 0057-0948 Burner end cap...................................... 0057-0984 Flow spoiler......................................... 0057-2561 Impact bead......................................... 0057-2615 Burner head cleaning tool.............................. 0303-1573 Kalrez O-ring for end cap.............................. 0992-1044 Burner gasket kit (0047-0988) Includes the following gaskets: 3 Viton O-rings for end cap (general use).................. 0990-2147 5 Corkpreen gaskets for end cap (use with organics)......... 0047-2014 3 O-rings for the neck of the spray chamber................ (for the burner head) 0990-2219 3 impact bead O-rings................................. 0990-2236 3 O-rings for end cap retaining plate...................... 0990-2240 Burner heads 5 cm, single-slot burner head for nitrous oxide-acetylene operation N040-0100 5 cm, single-slot burner head for air-acetylene operation....... N040-0101 10 cm, single-slot burner head for air-acetylene operation...... N040-0102 10 cm, three-slot burner head for air-acetylene operation...... N040-0103 Drain system Drain tube.......................................... 0250-7987 Nebulizers Standard stainless steel nebulizer kit...................... 0303-0352 Platinum alloy nebulizer kit............................. includes a platinum alloy capillary assembly and tantalum venturi 0303-0299 Corrosion-resistant plastic nebulizer kit................... 0303-0404 Nebulizer supplies O-ring kit, includes all O-rings used with the nebulizer and the PTFE disk.................................... N930-0065 Sample tube (nebulizer capillary tubing), 3 m............... 0990-8265 Apiezon grease, 1 tube................................. 0303-0405 Cleaning wires, pack of 5.............................. 0303-0135

Nebulizer components Item Description Part No. A Capillary assemblies: Stainless steel capillary assembly.................. 0303-0354 Platinum alloy capillary assembly................. 0303-0433 Plastic capillary assembly with integral sample tube... 0303-0402 Plastic capillary assembly with long integral sample tube for use with an autosampler...................... 0057-0957 B Venturi: Stainless steel................................. 0303-1810 Platinum alloy................................. 0303-3124 Plastic....................................... 0303-1920 1 Regulator..................................... 0303-1460 2 PTFE disk.................................... 0303-1802 3 O-ring on capillary assembly..................... 0990-2102 4 Spring....................................... 0303-1806 5 O-ring....................................... 0990-2005 6 Insert........................................ 0303-1812 7 Locking ring.................................. 0303-1456 8 Nebulizer body................................ 0303-0353 9 End cap...................................... 0303-1808 10 O-ring....................................... 0990-2239 11 Magnet/tube clamp assembly..................... N040-1159 12 Bar magnet................................... 0992-3133

PerkinElmer AAnalyst AAS

1) 2)

1. 2. 3. 4. 1. 2. 3. AS-800 HGA Aanalyst 700 THGA Aanalyst 600 800 1. 1. 2. 3. 4.

2. 1 5. 6. 1. 2. 3. 4. 5. 6.

PE PTFE PTFE 1. 2. 3. 4. 30mm

2.7 PE PTFE PTFE PTFE 2-5 1. PTFE FEP 2. 3. 4. 5. 2-5

88 148 AA WinLab 1. 2. 3.

1. 2. 3. 4. method AA WinLab 5. 6. 7. AA WinLab 8. 9. AA WinLab 1. 2. 3. 4. File Change Technique Technique 5. Flame Furnace

6. OK AA WinLab 1. 2. 3. 4. 5. 1. 2. 3. 4. 1. Furnace Control Flush Sampler 2. 1 5. 6. 2 4 1. 2. 3. 1. 2. 3.

4. AA WinLab

1. 1. Furnace Control Align Tip 2. Unlocked Above Tube 2. 3. / / 4. 1. 2. UV 5. 6. Unlocked Above Tube Unlocked Above Tube In Tube Do you want to save this position? yes yes AA WinLab 1.

2. Furnace Control Align Tip 3. In Tube 4. 1. 2. UV 5. 6. In Tip Unlocked Above Tube In Tube Do you want to save this position? yes yes AA WinLab 1 1. 2. 1 3. Furnace Control Align Tip 4. Unlocked Above Tube 5. 6. Unlocked Above Tube

2 1. 2. 1 3. In Sample Cup 4. 5. In Sample Cup Unlocked Above Rinse Do you want to save this position? yes blank 1. AA WinLab 2. blank 1 blank 3. Automated Analysis Setup Location blank 4. 1. 2. UV 5. Automated Analysis Analyze Samples 6. 7. 8. 9. 4 8 blank

L vov

1. 2. dirty clean

MAX

1. 2. 3. Furnace Control Open/Close 4. AA 600 800

1. 2. 3. Furnace Control Open/Close 4. 5. 2500 5 2500 5 6. 7. AA 600 800

2500 5 1. 2.

3. 4. 5.

AA 600 800 L vov 1. 2.

3. 4. 5. 2500 5 2500 5 L vov L vov 1. L vov L vov 2. 3. 4. 5. L vov 6.

7. L vov 2500 10 1. Furnace 2. Furnace Control Condition Tube 2000 10 1. Furnace 2. Furnace Control Cleanout Temp, 3. Start 4. 10 Start

1. 2. 3. 4. 5. 6. 7. 8. 1. 2. AA WinLab File Exit 3. on/off 4. 1. 2. 3. 4. 5. 1.

2. 3. 4. 5. AA600 800

1. 2. 3. 4. 5.

AA600 800

1. 2. 3. 4. 5. 6.

AA600 800

1. 2. 3. 4. 5. 6.

AA600 800

1. 2. 3. 4. 5. 6. AA WinLab 7. 8. dirty clean AAnalyst 800

1. 2. 3. 1. 2. 4. 1. 2. 1. 1. 2. 2. 1. 2. 1. 2.

1. 2. 3. 4. 5. 1. 2. 6. 1. 2. 3. 4. 5. 6. 7. 8. 9.

1:10 1 9 1. 2. 3. 0.5L 4. MAX 4.5L 5.

1. 2. 3. 4. 5. 230V 1.6A slow-blow 6. 7.

L L

1. 2. 3. 4. 1. Furnace Control Flush Sampler 2. 5. 6. 2 4 1. 2. 3. 4. 1. 2. 3. 1. 2. 1. 2.

1. 1. Furnace Control Align Tip 2. Unlocked Above Rinse 3. Unlocked Above Rinse Yes 4. Exit 2. 3 1. 2. 3. 4. Align Autosampler Unlocked Above Rinse 5. 6. Unlocked Above Rinse Yes 7. Exit 8.

1. 2. 3. 1 2 3 4 5

1. 2. 3. 1. 2. 1 2 3 4 5 3. 4. 5. ;

6. 7. 8. 9. 1. 2. 1. 1. Furnace Control Align Tip 2. Unlocked Above Rinse

2. 3. 4. 10mm PTFE 5. PTFE 7mm 6. 7. 8. Align Autosampler Unlocked Above Rinse 9. 10. Unlocked Above Rinse yes 11. Align Autosampler exit 12. 1. 2.

1. 1. Furnace Control Align Tip 2. Unlocked Above Rinse 2. 1. 2. 3. 4.

1. 2. 3. H1 4. H2 H3 5. 6. 7. Align Autosampler Unlocked Above Rinse 8. 9. Unlocked Above Rinse yes 10. Align Autosampler exit 11. 1. 2. 1. 2. 3.

4 1 800 762 4002 8a.m 8p.m 24 800 820 5046

HGA Graphite Furnace: 4 Parts and Supplies 4HGA Graphite Furnace: Parts and Supplies Marker for header Contents page Obtaining supplies, replacement parts, and accessories.................................. 4-3 HGA Graphite Furnace........................................................... 4-4 Graphite components............................................................. 4-4 Matrix modifiers................................................................ 4-6 Window components............................................................. 4-6 Tools......................................................................... 4-6 Furnace gas and cooling systems................................................... 4-7 Parts provided with the AS-800 furnace autosampler.................................... 4-8 Supplies and replacement parts for the furnace autosampler.............................. 4-9 Pump parts..................................................................... 4-10 0993-5258 4-1

HGA Parts and Supplies Obtaining supplies, replacement parts, and accessories Supplies, replacement parts, and accessories can be ordered directly from PerkinElmer, using the part numbers quoted in this guide. PerkinElmer s catalog service offers a full selection of high-quality atomic spectroscopy supplies through the Atomic Spectroscopy Supplies Catalog. To place an order for supplies and many replacement parts, request a free catalog, or ask for information: If you are located within the U.S., call toll free 1-800-762-4002, 8 a.m. to 8 p.m. EST. Your order will be shipped promptly, usually within 24 hours. If you are located outside of the U.S., call your local PerkinElmer sales or service office. What is listed in this chapter This chapter lists the most important replacement parts for your graphite furnace system. Information about other parts and accessories is given in the current PerkinElmer brochures and price lists. 0993-5258 4-3

HGA Parts and Supplies HGA Graphite Furnace Graphite components Shield ring Graphite tube Right-hand graphite contact Left-hand graphite contact Graphite tube with integrated platform Graphite tube with L vov platform Description Pkg. Part No. Pyrocoated graphite tubes with integrated platforms 20 5 Pyrocoated graphite tubes with grooves for L vov platforms 50 20 5 L vov platforms 50 20 5 Pyrocoated graphite tubes (not for use with L vov platforms) 50 20 5 B300-1264 B300-1262 B010-9322 B300-1254 B013-7111 B010-9324 B300-1256 B013-7112 B009-1504 B300-0342 B010-5197 4-4 0993-5258

HGA Parts and Supplies Description Pkg. Part No. Uncoated graphite tubes (not for use with L vov platforms) 50 20 B007-0699 B300-1253 Graphite contacts (left-hand and right-hand) 1 pair B012-8495 Graphite shield rings 5 B010-5113 0993-5258 4-5

HGA Parts and Supplies Matrix modifiers Description Part No. Magnesium nitrate modifier (10 g/l Mg, 100 ml)........... B019-0634 Palladium nitrate modifier (10 g/l Pd, 100 ml)............. B019-0635 Window components Mount Window Collar Description Part No. Window............................................ B008-0850 Mount.............................................. B312-0683 Collar.............................................. B312-0294 Tools Description Part No. Set of tools, for changing the contacts..................... B312-1301 Tube alignment tool................................... B008-0112 Insertion tool for L vov platforms........................ B011-2657 4-6 0993-5258

HGA Parts and Supplies Furnace gas and cooling systems Description Drain fitting for the automatic connectors,................. to empty the cooling system hoses (2 required) Part No. B019-3243 Gas tube............................................ B050-8264 Tube cutter for the gas tube............................. 0992-3183 Y-connector for the gas tube............................ 0992-0179 Cooling system, 230 V, 50/60 Hz........................ B019-8072 Water hose kit with pressure relief valve.................. B313-0124 Glycerol (85%) for cooling systems...................... B050-5133 Drain fitting Y-connector 0993-5258 4-7

HGA Parts and Supplies Parts provided with the AS-800 furnace autosampler PerkinElmer reserves the right to alter the schedule of parts provided without prior notice. Qty. Item Part No. 1 Furnace autosampler............................ B300-1500 together with the following components: 1 Sample tray, 148 locations........................ B300-1506 1 Sample tray, 88 locations......................... B300-1507 1 Sample tray cover.............................. B300-1505 1 Sample cups, polypropylene, 1.2 ml,............... B051-0397 pack of 2000 1 Sample cups, polypropylene, 2.5 ml,............... B300-1566 pack of 1000 1 Sample cups, polypropylene, 7 ml,................ B300-1567 pack of 100 1 Rinsing port................................... B300-1512 1 Pipet assembly................................. B012-9258 2 Rinse and waste bottles, polyethylene, 2 L........... B010-4344 1 Drain tube.................................... B300-2141 1 Rinse feed assembly: Rigid tube.................................. Flexible tube................................ Front ferrule, 2.45 mm........................ Back ferrule, 2.45 mm......................... Nut........................................ B300-1363 B001-7998 B300-1333 B300-1334 B300-1335 1 Grips for 1.2 ml sample cups..................... B051-0398 1 Wrench for the pump head retaining ring............ B300-1365 1 Quick reference................................ 0993-5260 4-8 0993-5258

HGA Parts and Supplies Supplies and replacement parts for the furnace autosampler Description Part No. Sample cups, polypropylene, 1.2 ml, pack of 2000 for the 148-location tray.................... B051-0397 Sample cups, polypropylene, 2.5 ml, pack of 1000 for the 88- or 148-location tray............... B300-1566 Sample cups, polypropylene, 7 ml, pack of 100 for the 88- or 148-location tray................ B300-1567 88-location sample tray................................ B300-1507 148-location sample tray............................... B300-1506 Rinse pump valve kit (contains both valves)............... B300-1485 Inlet valve assembly (complete)......................... B300-2007 Outlet valve assembly (complete)........................ B300-2006 Tube cutter, for PTFE tubing............................ B051-0268 Solvent resistant rinse and waste bottle, 1 L, PTFE.......... B300-1460 Pipet assembly....................................... B012-9258 Connecting tube, PTFE,............................... to connect the rinse and sample pumps B002-9792 0993-5258 4-9

HGA Parts and Supplies Pump parts 1 Nut, for 1/16'' tube...................... B300-2089 2 Ferrule kit, 1/16''...................... contains 5 back ferrules (2a) and 5 front ferrules (2b) 3 Valve and connector retaining ring......... for rinse pump and sample pump inlets and outlets B008-6142 B009-2450 3 1 2a 2b 4 Outlet valve (rinse pump)................ complete with ferrules (2a, 2b) and nut (1) B300-2006 4 9 5 Inlet valve (rinse pump)................. complete with valve (5a), tube connector (5b), ferrules (7, 8) and nut (9) B300-2007 6 Front ferrule, 2.45 mm.................. B300-1333 7 Back ferrule, 2.45 mm.................. B300-1334 Pump head 8 Nut, for 2.45 mm tube.................. B314-0226 9 Tube connector....................... for the sample pump B300-2010 5a 5b 9 3 6 2b 7 2a 8 1 4-10 0993-5258

THGA Graphite Furnace: 4 Parts and Supplies 4THGA Graphite Furnace: Parts and Supplies Marker for header Contents page Obtaining supplies, replacement parts, and accessories.................................. 4-3 Furnace system supplies.......................................................... 4-4 Furnace..................................................................... 4-4 Furnace gas and cooling systems................................................. 4-5 Matrix modifiers............................................................. 4-5 AS-800 furnace autosampler....................................................... 4-6 Parts provided with the furnace autosampler........................................ 4-6 Supplies and replacement parts for the furnace autosampler........................... 4-7 Pump parts.................................................................. 4-8 0993-5259 4-1

THGA Parts and Supplies Obtaining supplies, replacement parts, and accessories Supplies, replacement parts, and accessories can be ordered directly from PerkinElmer, using the part numbers quoted in the guides provided with the instrument. e-ssentials PerkinElmer Instruments on-line catalog, your single source for quality supplies and accessories. http://essentials.perkinelmer.com/ PerkinElmer s catalog service offers a full selection of high-quality supplies. To place an order for supplies and many replacement parts, request a free catalog, or ask for information: If you are located within the U.S., call toll free 1-800-762-4002, 8 a.m. to 8 p.m. EST. Your order will be shipped promptly, usually within 24 hours. If you are located outside of the U.S., call your local PerkinElmer sales or service office. What is listed in this chapter This chapter lists the most important replacement parts for your graphite furnace system. Information about other parts and accessories is given in the current PerkinElmer brochures and price lists. 0993-5259 4-3

THGA Parts and Supplies Furnace system supplies Furnace Description Part No. Graphite tubes, pack of 20.............................. pack of 5............................................ Graphite tubes, with end caps, pack of 20.................. pack of 5............................................ B050-4033 B300-0641 B300-0655 B300-0653 Graphite contacts, 5 sets................................ B050-4036 O-ring, for the pressure cylinder in the front contact housing and the optical sensor in the rear contact housing............ B013-2870 Insulating sleeve for temperature sensor on rear contact housing B019-9476 Insulating washer for temperature sensor on rear contact housing B008-3633 Set of tools, for changing the contacts and the furnace windows........... B019-3347 Key for furnace windows, separate....................... B050-5339 Grips for graphite tube................................. 0990-7925 Furnace window, quartz................................ B019-8005 Furnace window seal.................................. B050-1236 Graphite contacts Graphite tube Front Rear Temperature sensor Screw Furnace window parts Insulating sleeve Cable shoe Seal Window Insulating washer 4-4 0993-5259

THGA Parts and Supplies Furnace gas and cooling systems Description Drain fitting for the automatic connectors,................. to empty the cooling system hoses (2 required) Part No. B019-3243 Gas tube............................................ B050-8264 Tube cutter for the gas tube............................. 0992-3183 Y-connector for the gas tube............................ 0992-0179 Recirculating cooling system, 230 V, 50/60 Hz............. B019-8072 Water hose kit with pressure relief valve.................. B313-0124 Glycerol (85%) for cooling systems...................... B050-5133 Drain fitting Y-connector Matrix modifiers Description Part No. Magnesium nitrate modifier (10 g/l Mg, 100 ml)........... B019-0634 Palladium nitrate modifier (10 g/l Pd, 50 ml).............. B019-0635 0993-5259 4-5

THGA Parts and Supplies AS-800 furnace autosampler Parts provided with the furnace autosampler PerkinElmer reserves the right to alter the schedule of parts provided without prior notice. Qty. Item Part No. 1 Furnace autosampler............................ together with the following components: B300-1500 1 Sample tray, 148 locations........................ B300-1506 1 Sample tray, 88 locations......................... B300-1507 1 Sample tray cover.............................. B300-1505 1 Sample cups, polypropylene, 1.2 ml,............... pack of 2000 1 Sample cups, polypropylene, 2.5 ml,............... pack of 1000 1 Sample cups, polypropylene, 7 ml,................ pack of 100 B051-0397 B300-1566 B300-1567 1 Rinsing port................................... B300-1512 1 Pipet assembly................................. B012-9258 2 Rinse and waste bottles, polyethylene, 2 L........... B010-4344 1 Drain tube.................................... B300-2141 1 Rinse feed assembly: Rigid tube.................................. Flexible tube................................ Front ferrule, 2.45 mm........................ Back ferrule, 2.45 mm......................... Nut........................................ B300-1363 B001-7998 B300-1333 B300-1334 B300-1335 1 Grips for 1.2 ml sample cups..................... B051-0398 1 Wrench for the pump head retaining ring............ B300-1365 1 Quick Reference............................... 0993-5260 4-6 0993-5259

THGA Parts and Supplies Supplies and replacement parts for the furnace autosampler Description Part No. Sample cups, polypropylene, 1.2 ml, pack of 2000 for the 148-location tray.................... B051-0397 Sample cups, polypropylene, 2.5 ml, pack of 1000 for the 88- or 148-location tray............... B300-1566 Sample cups, polypropylene, 7 ml, pack of 100 for the 88- or 148-location tray................ B300-1567 88-location sample tray................................ B300-1507 148-location sample tray............................... B300-1506 Rinse pump valve kit (contains both valves)............... B300-1485 Inlet valve assembly (complete)......................... B300-2007 Outlet valve assembly (complete)........................ B300-2006 Tube cutter, for PTFE tubing............................ B051-0268 Solvent resistant rinse and waste bottle, 1 L, PTFE.......... B300-1460 Pipet assembly....................................... B012-9258 Connecting tube, PTFE,............................... to connect the rinse and sample pumps B002-9792 0993-5259 4-7

THGA Parts and Supplies Pump parts 1 Nut, for 1/16'' tube B300-2089 2 Ferrule kit, 1/16'' contains 5 back ferrules (2a) and 5 front ferrules (2b) 3 Valve and connector retaining ring for rinse pump and sample pump inlets and outlets B008-6142 B009-2450 3 1 2a 2b 4 Outlet valve (rinse pump) complete with ferrules (2a, 2b) and nut (1) B300-2006 4 9 5 Inlet valve (rinse pump) complete with valve (5a), tube connector (5b), ferrules (7, 8) and nut (9) B300-2007 6 Front ferrule, 2.45 mm B300-1333 Pump head 7 Back ferrule, 2.45 mm B300-1334 8 Nut, for 2.45 mm tube B314-0226 9 Tube connector for the sample pump B300-2010 5a 5b 9 3 6 2b 7 2a 8 1 4-8 0993-5259

HGA AS-800 5 HGA HGA

AAnalyst 800 AAnalyst 800

AAnalyst 800 2000 /s Ramp time 0 Ramp time 1 99 HGA

Y

AAnalyst 800

2 450mL/minute 10 10 5 0 2000 2300

20 120 10 1 10 20 3000 10 2000 /s 10 350 400kPa 1300mL/min 0 50 250 ml/min 2 450 ml/min 2.5L/min 350kPa 12

0 99 1 20 3000 10 EN61010-1-1993 1 ( ) 2 2 EN61010-1-1993 EN61010-2-061 1996 CSA LR45111 EMC EN61326-1 1997 : 15 35 2.8 20 80 1 10 5L 36 5 90 40 2.5L/min 400m 3 / 300kPa 8mm 230V,50/60Hz 140VA EMC EN61326-1 1997 200mm 375mm 500mm 18kg AS-800

88 148

AS-800 1 AS-800 2 1.2mL,2.5mL 7mL 3 AA WinLab 1. 2. 3 4.5mL 3. 4. 5.

4 5 6. 7. 8. 3 7 9. 10. 11. AS-800 88 148 0.1mL 1.0 L 99 L 5 L EMC 15 35 2.8 20 80 270mm 200 mm 340 mm 7kg

PerkinElmer AAnalyst AAS

AY 1 AY 2 AY 3 AY 4 AY 5 AY 6 AY 7 AY 8 AY 9 AY 10 AY 11 AY 12 AY 13 BC 1 BC 2 BC 3 TIBC BC 4 BC 5 BC 6 BC 7 BC 8 BC 9 BC 10 BC 11 BC 12 BC 13 BC 14 BC 15 BC 16 BC 17 BC 18 EN 1 EN 2 EN 3 EN 4 EN 5 EN 6 EN 7 EN 8 FP 1 FP 2 FP 3

FP 4 FP 5 FP 6 FP 7 FP 8 FP 9 FP 10 FP 11 FP 12 FP 13 FP 14 FP 15 FP 16 FP 17 FS 1 FS 2 FS 3 FS 4 GC 1R GC 2 GC 3 GC 4R GC 5 HF GC 6 ID 1 ID 2 ID 3 ID 4 ID 5 ID 6 ID 7 ID 8 ID 9 ID 10 ID 11 ID 12 ID 13 ID 14 MT 1 MT 2 MT 3 MT 4 MT 5 MT 6R

MT 7 MT 8 MT 9 MT 10 MT 11 MT 12 MT 13 MT 14 PC 1 PC 2 PC 3 PC 4 PC 5 PC 6 PC 7 PH 1 PH 2 PH 3 PH 4 B 12 PH 5 PH 6 PL 1 PL 2 PL 3R PL 4 PL 5 PL 6 GN 1 GN 2 GN 3

AY 1 0.05N 0.025N 0.1N 2 3 3 v/v 4 5.0g 20 0.05N 0.025N 15 Whatman 42 50 50

AY 2 20 2.5g 125 25 PH 7.0 15 AY 3 1 3v/v 0.5g 2.0g 30 200 2 400 1.00 0.05g 100 10 1 1 60 80 1 250 1 1 10 10 5 250 5 v/v

1 AY 4 0.5g 2g 475 600 4 12 1 MIBK 1g 500 5 20 50 1 w/v

AY 5 0.5g 2.0g 70 1 1g 10 2 4 70 50 1 w/v

AY 6 2 4 2.5g 600 25 30 45 10 70 100 1 AY 7 10g 2g 550 4 10 3N 10 100 1 1

AY 8 250 1 1g 10 2N 100 1 AY 9 1g 150 500 1 10 20 2N 100 1 AY 10 404.4nm 2.5g 250 150 30 K 2 O 20 25 100 K 2 O 20 404.4nm

AY 11 2 1 3 2g 300 30 6N 80 90 4 100 100 2 1 5 1g 1g 4g 10 20 400 6N 200 5 2 1 3 AY 12 30 5 100

AY 13 MIAK 1g 250 20 20 30 10 50 Whatman #541 100 8N 20 100 50 200 g 5.0 8 * PH 1.6+0.1 10 30 25 5 10.0 MIAK** *8 25g8 60 HOAc 500 ** MIAK

BC 1 0.1 w/v 1 50 / 0.1 w/v 0.1 w/v 120 4

BC 2 1 50 1 50 /

BC 3 TIBC 20 w/v TCA 1 2 95 TIBC 5mg/L 20 w/v TCA 3 1.0 20 w/v TCA 90 15 TIBC 2.0 5mg/L 5 200mg 30 4 2.0 20 w/v TCA 90 15 95 / TIBC 10 w/v TCA 10 w/v TCA 1 2 2 TIBC 2 1 2

BC 4 1 10

BC 5 4 6 BC-3 1 5 / 10 v/v 10 v/v 5 v/v 5 v/v

BC 6 MIBK 3 2 1 1 Vortex 2 6M Foamkill Nutritional Biochemical Corp. 50 10 2.0 MIBK 2 1mg/L 20mg HAuCl 4 3H 2 O 0.1M 0.1M 1 1 100 0.1M 0.1M 1 1 MIBK BC 7 1 100

BC 8 EDTA MIBK EDTA APDC MIBK APDC 95 Triton X-100 TX Rohm&Haas Philadelphia PA Triton X-100 10 v/v 6 10 6 1 10 TX 1 2 APDC EDTA 0.05 1.5M 1.5 MIBK 5 1 700g 10 20 10 BC 9 1 100 0.5 w/v 1 200 1 5000 1 2000 0.5 w/v

BC 10 1 100 1 5 / 1 100

BC 11 EDTA MIBK EDTA APDC EDTA PH PH 4.5 5.0 100 PH 5.05 0.1 MIBK APDC Triton X-100 TX Rohm&Haas Philadelphia PA 10 v/v 3N 3N PH 5.05 0.1 40 1 10 TX 1 2 APDC EDTA 1.5 1.5M 3 MIBK 20 3500g 20 PH BC 12 1.0 1 50 0.1 / 1.0 1.0

BC 13 n n 6 v/v n 1 10 0.5 / / 6 v/v n 1 10 6 v/v n 0.15M BC 14 0.2 g Zn/g 1g 550 3 3N 25 0.36N 0.36N BC 15 0.2 g Zn/g 5g 125 25 10 1 2 100

BC 16 25 1 7X o Matic Linbro Chemical New Haven CT 30 250 150 10 1 0.5 5 1 5 BC 16 1cm 0.5g 500 150 1 7X o Matic Linbro Chemical New Haven CT 30 1 110 0.5g 50 6 1 200 5 5 5 10 10mg 100 1 5 1 50

BC 18 90 400 4 0.5g 150 3 5 2 35 825rpm EN 1 1 1 0.999g 2.074g 1.414g 25.14g 1 1 1 10,000 g/ml 1250 g/ml 400 g/ml 400 g/ml 0.45 g/ml g/ml d.f. d.f. /

EN 2 0.1 g/l 10 g/l MIBK APDC 1 w/v APDC APDC MIBK 0.45 PH 4 5 750 1 35 MIBK 7 1 APDC 30 APDC MIBK 20 MIBK MIBK 20 MIBK 5 PH 4 0 2 5 10 g/l 750 20 MIBK 7 1 APDC 30

EN 3 6N 516 11.6N 1 6N 5 1 0.45 15 5 6N 0.45 1 50 5 6N 700 1 15 g/l 20 EN 4 5 w/v 5 w/v 0.25 w/v 5 v/v 0.45 5 w/v 0.25 w/v 5 v/v g/ml g/ml ml / ml

EN 5 8 10 20 25 24 100 30 3 15 10 10 50 S&S 589 g/m 3 g/ml 50 / m 3

EN 6 5 v/v 48 2 w/v 0.1M 10.60g 15 5 30 50 20 250 1 5 10 5 30 5 12 88 250 5 30 Ultramax 2 PH 2 2 2 0.1M 2 0.2 5 2000 5 10 0.1M 10 g g/ml d.f. d.f. ml / ml

EN 7 1 g/l 0.1N 0.32g 100 0.1 w/v 0.100g 100 0.1 w/v 0.1g 50 95 100 1.0N 40g 1 0.25N 7.0 sp.gr.1.84 1 APDC w/v 1g APDC 100 1.5 200 1 MIBK 95 0.08mg/mL 0.2263g 1 2 g/ml 5 15mg 0.5 0.5 1 200 0.5 g/ml 100 25 100 200 25 g/l PH 2 0.1N 20 0.1 2 5 Whatman 40 200 2.0 1.0N 2 0.25N 2 5 1 APDC 10 MIBK 3

MIBK g/l g/l / EN 8 MIBK MIBK DDC 20g 380 0.45 MIBK MIBK 15 102g 500 14 1M 1 1M 4g 100 10 25 50 75 100 g/l PH 1 2 Van Dorn 0.45 200 100 16 100 250 2 PH 3.6 0.1 7 DDC 500 15 MIBK 30 MIBK 2 3

FP 1 5 2 5 10 250 10 5 100 0.5 FP 2 4 5 / 1 2 10g 100 10 10 w/v 95 150 1 200 450 450 10 200 650 150 100 40 w/v PH 3 4 5 APDC 1 2 10 MIBK 30 MIBK MIBK

FP 3 4 6g 2.5 50 w/v 1 2 190 100mm 1 2 8 500 10 1 1

FP 4 1 5g 5 5 60 30 10 120 150 1 50 40 100 5 APDC 5 MIBK 5 MIBK

FP 5 450 500 3 4 7 25g 5g 135 2 450 500 2 450 500 1 10 1N 25 FP 6 1g 250 2 3 30 1 50 3 5 Whatman2 100 2.0 30

FP 7 10g 10g 250 40 2 35 70 3 2 70 5 1.0 15 15 25 FP 8 2 200g 350 Vycor 300 24 Vycor 500 16 10 5 30 25

FP 9 MIBK / 10g 50 30gMIBK FP 10 1 Na K 3g 6g 400 100 50 10 50 180mg/L 100mg/L 40mg/L 7000mg/L 70mg/L 700mg/L 130mg/L

FP 11 7 20 100 10 5 0.5 FP 12 TCA 5 100 50 24 w/v TCA 5 30 5 50 1 5 w/v 5.0mg/L 0.6mg/L 1.6mg/L 5.0mg/L 500mg/L 1.2 w/v TCA 500mg/L 1.2 TCA

FP 13 APDC 283.8nm 25g 120 250 350 500 500 16 250 500 1 2 5 1N 2 3 S S589 50 5 1N 1N 20 60 4 10 2 3 PH 5.4 4 APDC 2 30 60 5 BuOAc 30 60 283.3nm

FP 14 Na K 1 3 / 50 250 5 2 100 2 1 10 MIBK 5 FP 15

FP 16 2 3 1 2 25 100 1 20 30 2.0 APDC 1 10 MIBK 5

FP 17 1g 25 4 3g 200 10 20 30 g/ml 0.005M 20 1 3 125 5 1 w/v 5 1 w/v DDDC Whatman 1 PS

FS 1 3N 196 15.4N 1 10 000 g/ml 15.98g 1 1 1000ppm 3N 0.5g 100 30 3N 50 3N ppm g/ml d.f. / g d.f. ml / FS 2 7.5M 490 15.4N 1 0.3M 19.6 15.4N 1 0.3N 24 0.1g 30 500 1 4 7.5M 100 wt g/ml 0.01 d.f. / g

FS 3 17.8M 0.1N 2.8 17.8M 95 1000 0.5g 50 0.1N 0.1N ppm g/ml 50 / g FS 4 4 24 4 v/v 3 v/v 15g 1.5895g 4 4 5 10 15 20 1 4 5 10 15 20 g/ml 0.500g 250 3 3 500 10 4 1 10 g/ml 3 5 10 15 20 100 4 0.3 0.5 1 1.5 2 g/ml 6 4 1/4 6 7mm 22 2 24 24 4 20 g/ml 2 g/ml 4 g/ml

GC 1R 1g 3 1 100 50 200 50 100 g/ml g/ml 0.02 2.14 / g g/ml 0.02 1.67 / g g/ml 0.02 1.89 / g GC 2 1g 0.1ppm

50 5 w/v 3g 3g 500 10 w/v 0.100 w/v 0.1354g 100 1N 0.001 w/v 1N 1 100 0.100 1 4 250 25 50 1 20 100 20 10 21 2L/min 2 3 g 0.001 0.2 2.0 g 250 25 18N 10 7N 100 g ppm g /

GC 3 1 w/v 17.08g 1 10mg/mL 100 6 10 100 4 10 100 3 0.1 0.3g 10 10 6 2 3 100 1 3 0.1 0.3g 4 10 10 100 0.1 0.3g 4 100 10 wt g/ml 0.01 d.f. / g d.f. /

GC 4R 1 2 5 w/v 2 0.1g 0.6g 1800 o F 1000 15 100 20 5 200 5 1 10 1 wt g/ml d.f. 0.02 / g d.f. GC 5 HF AY-3

GC 6 10 v/v 15 v/v MIBK 25 v/v 10g 400 25 15 15 20 25 25 100 100 2 Whatman 125 75 125 15 MIBK 15 1 2 1 2 35 10 v/v 35 10 v/v 25 10g 800 25 80 30 20 15 1 75 125 15 MIBK oz/ton g/ml 0.0583 wt g/ml 0.01 / g

ID 1 5 w/v NIST 100 0.5000g 25 5 15 100 1 v/v 22 0.5 w/v

wt g/ml d.f. 100 / g d.f. ml / ID 2 GC-4 NIST

ID 3 85 1.67 w/v 500 7.5g2 250 1 w/v 6 v/v 1g 125 6 4 30 4 20 100 wt g/ml d.f. 0.01 / g d.f. ml / ID 4 70 5 w/v 0.2 w/v 1 v/v 1.5 v/v 100mg72BS 30 5 4 2 20 5 v/v 100 4.0 5 w/v ppm g/ml d.f. 100 / g d.f. ml /

ID 5 ( ) 1 1 1000ppm 2 50 20 1 1 100 2g 0.1g 50 20 1 1 100 wt g/ml d.f. 100 / g d.f. ml / ID 6 0.25g 5 0.5 10 ppm g/ml d.f. 10 / g d.f. ml /

ID 7 1.2M 0.6M 100 50 12M 1 100g6 1 0.6M 100 5 1g 10 5 10 5 100 1.2M 200 0.6M 100 5 wt g/ml d.f. 0.02 / g d.f. ID 8

ID 9 900 6 8 N TBP 500 500 20 v/v 6N 375 16N 1 0.2N 16.7 12N 1 100 0.1N 1 100 5 w/v 10g mg 1 100 6N Cr 900 250 6N TBP 4g TBP 50 2 15 6N TBP 30 50 20 TBP 25 0.2N 10 5 w/v 1 w/v 0.2N ppm g/ml d.f. 10 / g d.f. ml /

ID 10 15 40 MIBK NIST 1066 1.420gNIST1066 Si 14.1 MIBK 200 1000 g/ml MIBK 1g 200 MIBK 5 100 MIBK MIBK wt g/ml 0.4 / g ID 11 MIBK 10 v/v 2000 g/ml 1g 150 10 10 Whatman 42 100 1g 100 MIBK 90 o g/ml 0.01 / g

ID 12 2N 174.4 11.6N 1 2 g/ml 25 g/ml 80 24 Wiley 70 16 100mg 125 25 2N 4 Whatman 1 2 g/ml 25 g/ml 5 g/ml % g/ml 0.1 / mg ID 13 8 MIBK 8 1 w/v MIBK U.S.P 0.1ppm 80 v/v 2g 25 20 15 20 60 5 5 1 w/v 8 MIBK 1 20 MIBK g/g g/ml 25 / g

ID 14 12 v/v 0.3g 120 2 0.1g 3 150 1 25 Pb ppm g/ml 25 / g MT 1 0.01 0.1 0.1 1.0 0.1 1.0 0.01 0.1 0.01 0.1 0.01 0.1 0.1 1 1 30 0.5g 20 1 1 30 1 Whatman 40 400 1000 5 10 1 Duntch 1 100 10 100 wt g/ml d.f. 0.01 / g d.f. ml /

MT 2 0.05 0.5 0.05 0.5 0.05 0.5 1 5 5 w/v 1g 100 10 100 10 20 100 4 100 wt g/ml d.f. 0.01 / g d.f. 10 25 MT 3 48 1000 g/ml 0.1g 100 4 1 2 0.5 48 100 wt g/ml d.f. 0.01 / g d.f. ml /

MT 4 48 1g 5 48 50 8 ph 4.5 wt g/ml 0.005 / g MT 5 0.04 3 1g 10 5 100 10 0.5g 5 5 100 11.5 85Pb 10Sb 5Sn 0.5g 10 2 85 500 Sb wt g/ml V d.f. 10 4 / g V V 100 V 500 d.f. ml /

MT 6R 1 1 5 1 1 5 v/v 3 10 1 1 1 1 100 10 1 1 wt g/ml d.f. 0.01 / g d.f. ml / MT 7 48 1g 4 48 50 50 wt g/ml 0.005 / g

MT 8 1 10 0 2 1 10 4 w/v 48 400 g/ml 2g 400 75 100 1 48 50 4 500 50 500 wt g/ml 0.5 / g MT 9 1 1 0.5g 50 25 1 1 5 5 wt g/ml d.f. 0.005 / g d.f. ml /

MT 10 1 1 3N 83.3 1 12 w/v 100 100 100 300 A 0.2 1.0 0.02 1.0 0.02 1.0 0.02 1.0 0.005 1.0 0.5g 100 10 1 1 10 B 0.02 2.5 0.5g 100 25 3N 10 12 1 C 0.01 0.2 2.0 8.0 0.1 1.0 0.01 0.5 1.0 9.0 0.01 0.2 0.1 0.6 1.0 6.0 1.0 3.5 0.5g 150 25 30 50 10 50 4 100 wt g/ml V d.f. 10 4 / g V d.f.

MT 11 2 w/v 20g 1 3 1 v/v 2g 100 2 200mg 8 45 10 200mg 5 5 2 25 2 wt g/ml V d.f. 10 4 / g V V 100 V 500 d.f. ml / MT 12 50 g/ml 50 10 0 2 4 50 g/ml 0 2 4 g/ml g/ml 5

MT 13 50 v/v 50 v/v 100 2g 100 1g 2g 10 50 5 50 100 1g 20 50 100 wt g/ml 0.01 / g MT 14 50 v/v 0.2g 150 20 3 1 v/v 100 1 250 500 ppm g/ml d.f. 500 / g d.f. ml /

PC 1 MIBK 5 1 10 MIBK MIBK PC 2 MIBK MIBK / 2 4 3 5 3g 0.4g1 20 / 3 5 65 5 45 5.6g1 10 MIBK/ 1 10 MIBK/

PC 3 3 2 0.3 5 0.3 0.1g 25 1 w/v 5.3g 10 2 30 100 4 / 0.3 90 o PC 4 336 General Mills Chemicals Inc. Minneapolis MN McKesson Corp Minneapolis MN MIBK 3 w/v / 1 v/v 336/MIBK 10 v/v 336/MIBK 1 v/v 336/MIBK 3 w/v / 50 30 MIBK 5 100 L3 1 5 1 336/MIBK MIBK 5.0gPb/U.S. 0.4433g 105 3 250 200 10 336/MIBK 10 336/MIBK 1321mg/L 5.0gPb/U.S.

1.0gPb/U.S. 50 250 1 336/MIBK 0.02 0.05 0.10 gpb/u.s. 2 5 10 3 100 5 1 336/MIBK MIBK 50 30 MIBK 5 5 100 L3 w/v 5 1 336/MIBK MIBK 0.001Pb/U.S. PC 5 5g 50 PC 6 5 5 5 25 0 0.25 0.5 1.0 1.5 5mg/L 5g 5 NIST 1065a 2 5mg/L

PC 7 MIBK 10 v/v 2 1g 250 75 MIBK 100 2 1 MIBK 10 v/v 2 MIBK PH 1 5 w/v 1N 86.2 11.6N 1 1 w/v 5 v/v 100mg 100 1N 5 100 5.00 50 10.0 5 wt g/ml 2 / g

PH 2 NIST 1066 14.1 200 1.420gNIST 1066 1000 g/ml 400mg 250 10 100 60 200 50 30 200 2 100 ppm g/ml d.f. 10 000 / g PH 3 DMA 3N 195 15.4N 1 6N 516 11.6N 1 2N 172 11.6N 1 0.5N 25 2N 1 1000 g/ml 0.1598g 10 1000 1000 g/ml DMA 0.1598g DMA DMA 100 5g 50 1g 50 1g 10 g/g 5g 15 6N 0.5N 100 500 500 20 2N 10 2N 0.5N

50 g/g g/ml 50 / g 1000 g/ml 500 g/ml 1000 g/ml 280nm 283nm PH 4 B 12 B 12 B 12 B 12 10 25 50 B 12 g / g/ml 23.0 / ml no. PH 5 5 g 6N 516 11.6N 1 2500 g/ml 2.5000g 6N 1 4.0 500 20 g/ml 0.2 3 g/ml 5mg 10 1 6N 50 1 50 1 6N g/ml 5 / mg mg/ml 0.05

PH 6 10 v/v 1000 g 100 10 20 15 20 Whatman1 100 10 10 50 60 g/ml 10 40 50 60 g/ml ppm g/ml d.f. 100 / g d.f. ml / ppm g/ml V / g V PL 1 3N 83.3 1 9 w/v 45g 500 3N 9 w/v 9 w/v ppm g/ml d.f. 10 / g d.f. ml /

PL 2 0.5N 41.3 12N 1 2 3g 250 80 90 0.5N 20 200 25 ppm g/ml d.f. 200 / g d.f. ml / PL 3R 98 30 5 10g 125 24/40 10 98

30 1 / 30 40 75 50 23 g/g g/ml d.f. / g d.f. ml / PL 4 0.5N 186g 1 30g 800 3 5 0.3g 110 20 ppm g/ml 5 / g

PL 5 6N 500 1 10g 575 25 5 6N 5 6N 5 6N 5 100 ppm g/ml d.f. 100 / g d.f. ml / PL 6 0.02 g/g 6N 516 11.6N 3N 50 6N 100 MIBK 5 10g 700 10 6N 0.5 3N Bobcock 20 25 2.50 MIBK 2 5 24

MIBK g/g g / GN 1 0 100 g/ml 0.17799g 500 200 g/ml 5.0g 100 1.479g 1 1000 g/ml 25 50 75 100 g/ml 10 100 g/ml 25 1 10.0 200 g/ml 2 3 10 10 g/ml g/ml

GN 2 1 1 4 w/v 100g 144 271 489 148 40 100 g/ml 10 100 g/ml 70 65 4 100 25 1 1 0.1 g 0.1 g/ml 25 1 30 300 g/ml 70 65 4 100 25 1 1 37 g/ml 1 g/ml ppm g/ml d.f. 100 / g d.f. ml /

GN 3 5000 g/ml 7.875g 1 0.5 5 g/ml 0 1000 g/ml 10 100 2 10 5000 g/ml 50 2500rpm 10 10 1 100 g/ml [500 100 g/ml ][3.29][d.f.] d.f. ppm [500 100 g/ml ][3.29][d.f.]/ g V wt ppm 10 4

Ag 47 Ag 1 2 2 3 3 N 2 O-C 2 H 2 328.1nm 0.36mg/L 4 5 HNO 3 v/v Ag 500mg/L 0.787g AgNO 3 50mL 1 v/v HNO 3 1L 5 v/v HNO 3 328.1nm 0.2nm 327.4nm 5

Al 13 Al 1 2 2 3 0.1 Al 1000mg/L 1.000 HCl 1 1 1 v v HCl 1 0.1 309.3nm 237.3nm 257.5nm 309.27nm/309.28 nm 237.31 nm/237.34 nm 257.51 nm/257.54 nm

As 33 As 2 3 N 2 O-C 2 H 2 193.7nm 1.4mg/L EDL HCL 25 1000mg/L 1.320 As 2 O 3 25 20 w/v KOH 20 v/v H 2 SO 4 1 v/v H 2 SO 4 1 193.7nm 60 HCL EDL EDL 1 193.7nm

Au 79 Au 1 2 2 3 3 N 2 O-C 2 H 2 242.8nm 1.8mg/L Au 1000mg/L 0.1000 5 HCl 100 10 v/v HCl

B 5 B 2 B 5000mg/L 28.60 H 3 BO 3 1

Ba 56 Ba 1 2 2 3 0.1 Ba 1000mg/L 1.437 BaCO 3 1 1 1 v/v HCl 1 Ba 5mg/L 1 0.1 553.6nm

Be 4 Be 2 Be 1000mg/L 1.000 1 1 1 v/v HCl 1 1 8

Bi 83 Bi 1 2 2 3 N 2 O-C 2 H 2 223.1nm 2.1mg/L 3 HCL EDL Bi 1000mg/L 1.000 1 1 2 v/v 1 EDL 223.1nm 222.8nm/223.1 nm

Ca 20 Ca 2 3 N 2 O-C 2 H 2 422.7nm 0.048mg/L Ca 500mg/L 1.249g CaCO 3 50mL 10 HCl 1 0.1 0.1 0.1 1.0

Cd 48 Cd 1 2 2 3 3 N 2 O-C 2 H 2 228.1nm 0.11mg/L 4 HCL EDL 10 Cd 1000mg/L 1.000g 1 1 1 v/v 1 EDL

Ce 58 Ce 569.9nm Ce 10,000mg/L 39.13g NH 4 2 Ce NO 3 6 1

Cl 17 Cl 1000 mg/l 1.644g NaCl 1

Co 27 Co 2 3 N 2 O-C 2 H 2 240.7nm 0.71mg/L Co 1000mg/L 1.000g 1 1 1 v/v HCl 1

Cr 24 Cr 1 2 2 3 3 N 2 O-C 2 H 2 357.9nm 0.31mg/L Cr 1000mg/L 3.735g K 2 CrO 4 1 2 NH 4 Cl Cr Cr Cr Cr

Cs 55 Cs 2 3 N 2 O-C 2 H 2 852.1nm 6.1mg/L EDL 0.1 650nm Cs 1000mg/L 1.267g CsCl 1 EDL 0.1

Cu 29 Cu 1 2 2 3 3 N 2 O-C 2 H 2 324.8nm 0.45mg/L Cu 1000mg/L 1.000g 1 1 1 v/v 1 0.2nm 324.8nm

Dy 66 Dy 2 0.1 Dy 1000mg/L 1.148g Dy 2 O 3 1 v/v 1 0.1

Er 68 Er 2 0.1 Er 1000mg/L 1.143g Er 2 O 3 1 v/v 1 0.1

Eu 63 Eu 1 2 2 3 0.1 Eu 1000mg/L 1.158g Eu 2 O 3 1 v/v 1 0.1

Fe 26 Fe 2 3 N 2 O-C 2 H 2 248.3nm 0.43mg/L Fe 1000mg/L 1.000g 50 1 1 1 248.3nm 0.2

Ga 31 Ga 2 0.1 Ga 1000mg/L 1.000g 1 v/v 1 2.5 mg/l 1 287.4nm 0.1 294.4nm 294.36nm/294.42nm

Gd 64 Gd 2 0.1 Gd 1000mg/L 1.153g Gd 2 O 3 1 v/v 100 0.1

Ge 32 Ge 1 2 2 3 HCL EDL Ge 1000mg/L 0.1000g 5 HF 100 HF EDL 265.1nm 265.12nm/265.16nm

Hf 72 Hf 2 1 HF 2000 mg/l Al Hf 10,000mg/L 1.000g 5 100 HF 0.2 1.0

Hg 80 Hg 1 2 2 3 3 N 2 O-C 2 H 2 253.7nm 12mg/L 4 EDL HCL 25 Hg 1000mg/L 1.080g HgO 1 1 1 EDL 253.7nm 1000mg/L 10 Hg I Hg

Ho 67 Ho 2 0.1 Ho 1000mg/L 1.146g Ho 2 O 3 1 v/v 1 0.1

I 53 I 1000mg/L 1.142g NH 4 I 1

In 49 In 1 2 2 3 3 N 2 O-C 2 H 2 303.9nm 2.6mg/L In 1000mg/L 1.000g In 2 O 3 1 1 v/v 1 100

Ir 77 Ir 1 2 2 3 3 N 2 O-C 2 H 2 264nm 62mg/L Ir 5000mg/L 1.147g NH 4 2 IrCl 6 1 v/v HCl 1 v/v HCl 1 /

K 19 K 2 3 0.1 650nm K 1000mg/L 1.907g KCl 1 0.1 404.4nm 404.41nm/404.72nm

La 57 La 2 0.1 La 50,000mg/L 50 58.64g La 2 O 3 250 La 2 O 3 1 0.1

Li 3 Li 1 2 2 3 3 N 2 O-C 2 H 2 670.8nm 0.12mg/L 4 650nm Li 1000mg/L 5.234g Li 2 CO 3 1 1 1

Lu 71 Lu 2 0.1 Lu 10,000mg/L 1.137g Lu 2 O 3 HCl 1 v/v HCl 100 0.1

Mg 12 Mg 1 2 2 3 3 N 2 O-C 2 H 2 285.2nm 0.036mg/L Mg 1000mg/L 1.000g 1 1 1 v/v HCl 1 0.1 0.1

Mn 25 Mn 2 3 N 2 O-C 2 H 2 279.5nm 0.28mg/L Mn 1000mg/L 1.000g 1 1 HNO 3 1 v/v HCl 1 0.2 CaCl 2 10,000 mg/l

Mo 42 Mo 1 2 2 3 Mo Mo 1000mg/L 1.840g NH 4 6 Mo 7 O 24 4H 2 O 1 1 v/v NH 4 OH 1 0.9 mg/l 313.3nm 0.5 2 0.1

Na 11 Na 2 3 0.1 Na 1000mg/L 2.542g NaCl 1 0.1 589.0nm 303.2nm 589.0nm/589.6nm 303.2nm/303.3nm

Nb 41 Nb 1 2 2 3 3 0.1 Nb 10,000mg/L 1.000g 5 HF HNO 3 100 0.2 1.0

Nd 60 Nd 2 0.1 Nd 10,000mg/L 1.167g Nd 2 O 3 HCl 1 v/v HCl 100 0.1 492.4nm

Ni 28 Ni 1 2 2 3 3 N 2 O-C 2 H 2 232nm 1.7mg/L Ni 1000mg/L 1.000g 1 1 HNO 3 1 v/v HNO 3 1 232.0nm 352.5nm 341.5nm

Os 76 Os 2 Os 1000mg/L Ventron Corp.-Alfa Products,Danvers,MA OsO 4 10,000mg/L Alpha Analytical Labs,Newark,NJ OsO 4 1 v/v 290.9nm 1 5 mg/l

P 15 P 1 2 2 3 EDL HCL 10 50,000mg/L 21.32g NH 4 2 HPO 4 100 EDL EDL 213.6nm 213.55nm/213.62nm

Pb 82 Pb 2 3 N 2 O-C 2 H 2 283.3nm 2.7mg/L HCL EDL Pb 1000mg/L 1.598g Pb NO 3 2 1 v/v 1 v/v 1 EDL 216.5nm 217.0nm 283.2nm 10,000 mg/l

Pd 46 Pd 1 2 2 3 3 N 2 O-C 2 H 2 247.6nm 3.1mg/L Pd 1000mg/L 0.1000g 5 HCl 25 100

Pr 59 Pr 1 2 2 3 0.1 Pr 10,000mg/L 1.170g Pr 2 O 3 HCl 1 v/v HCl 100 0.1

Pt 78 Pt 2 3 N 2 O-C 2 H 2 265.9nm 13mg/L Pt 1000mg/L 0.1000g 5 HCl 0.1g 20 1 1 HCl 100 Li,Na,K,Mg,Ca,Cu,Pb,Sr,Ba,Cr,Fe,Co,Ni,Ru,Rh,Ir,Pd, 0.2 1.0 HCl

Rb 37 Rb 2 3 N 2 O-C 2 H 2 780nm 3.2mg/L EDL 0.1 650nm Rb 1000mg/L 1.415g RbCl 100 0.1

Re 75 Re 1 2 2 Re 1000mg/L 1.554g KReO 4 200 1 v/v 1

Rh 45 Rh 2 3 N 2 O-C 2 H 2 343.5nm 0.95mg/L 1 10 HCl Rb 1000mg/L 0.412g NH 4 3 RhCl 6 3H 2 O 10 v/v 10 v/v HCl 100 Rh 10 v/v HCl 1.0

Ru 44 Ru 1 2 2 3 3 N 2 O-C 2 H 2 349.9nm 2.5mg/L 4 10 1000 mg/l Ru 1000mg/L 0.2052g 20 v/v HCl 20 v/v HCl 100 0.5

S 16 S 2000mg/L 8.243g NH 4 2 SO 4 1

Sb 51 Sb 2 3 N 2 O-C 2 H 2 217.6nm 1.8mg/L EDL HCL 10 Sb 1000mg/L 2.743gK SbO C 4 H 4 O 6 1/2H 2 O 1

Sc 21 Sc 1 2 2 3 0.1 Sc 2000mg/L 3.067g Sc 2 O 3 HCl 1 v/v HCl 1 0.1

Se 34 Se 2 3 N 2 O-C 2 H 2 196nm 2.7mg/L EDL HCL 25 3100 3110 0.7nm 1000mg/L 1.000g 2 2 3 10 v/v HCl 10 v/v HCl 1 196.1nm 50

Si 14 Si 1 2 2 Si 1000mg/L 0.2139g 2g 100 251.6nm 1.0

Sm 62 Sm 2 0.1 Sm 10,000mg/L 1.159g Sm 2 O 3 10 v/v HCl 1 0.1

Sn 50 Sn 2 EDL HCL 10 Sn 1000mg/L 1.000g 100 HCl 1 10 v/v HCl 286.3nm 1 3.5 mg/l

Sr 38 Sr 2 0.1 Sr 1000mg/L 2.415g Sr NO 3 2 100 10 HCl 1 1 0.1 460.7nm 1 0.17 mg/l 0.1

Ta 73 Ta 1 2 2 3 1 2000 mg/l Ta 10,000mg/L 1.000g 5 HF HNO 3 100 0.2 1.0 HF 260.9nm 260.86nm/260.82nm

Tb 65 Tb 2 0.1 Tb 1000mg/L 1.176g Tb 4 O 7 HCl 10 v/v HCl 100 0.1

Tc 43 Tc Hareland,et al.,anal.chem.44,520 1972 Nuclear Science Division International Chemical and Nuclear Corporation Pittsburgh Pennsylvania Hareland,Ebersole, Ramachandran Anal.Chem.44,520 1972 500 mg/l 50mg/L 100mg/L 261.4nm 261.4nm 261.6nm

Te 52 Te 2 3 N 2 O-C 2 H 2 214.3nm 1.5mg/L HCL EDL 10 Te 1000mg/L HNO 3 1.000g 50 HCl 1 v/v HCl 1

Th 90 Th Th 10,000mg/L 2.380g Th NO 3 4 4H 2 O 100 570.7nm V.A.Fassel and D.W.Golightly,Anal.Chem.39,466 1967

Ti 22 Ti 1 2 2 3 0.1 Ti 1000mg/L 1.000g 100 1 1 HCl 1 1 1 10 v/v HCl 0.1 Al,Co,K,Mn,Na,Cu,Ca,Cr,Fe,Li,Mg,Mo,P,Cd,Sb,Zn,Ba,Ni,Sn,Sr,Pb,V,F

Tl 81 Tl 2 3 N 2 O-C 2 H 2 276.8nm 2.7mg/L HCL EDL 10 Tl 1000mg/L 1.303g TlNO 3 1

Tm 69 Tm 1 1 2 1 0.1 Tm 1000mg/L 1.142g Tm 2 O 3 HCl 1 v/v HCl 1 0.1

U 92 U 2 0.1 U 10,000mg/L 21.10g UO 2 NO 3 2 6H 2 O 1 0.1

V 23 V 1 1 2 1 0.1 V 1000mg/L 1.000g HNO 3 1 v/v HCl 1 0.1 Fe Al Ti 318.4nm 318.3nm/318.4nm/318.5nm

W 74 W 2 W 10,000mg/L 17.95g Na 2 WO 4 2H 2 O 200 100 10 v/v 1

Y 39 Y 1 1 2 1 0.1 Y 1000mg/L 1.2705g Y 2 O 3 HCl 1 v/v HCl 1 0.1

Yb 70 Yb 2 0.1 Yb 1000mg/L 1.139g Yb 2 O 3 HCl 1 v/v HCl 1 0.1

Zn 30 Zn 1 1 2 3 1 N 2 O-C 2 H 2 213.9nm 0.084mg/L 1 HCL EDL HCL Zn 500mg/L 0.500g 1 1 HCl 1 v/v HCl 1

Zr 40 Zr 2 1 HF 2000 mg/l Zr 10,000mg/L 1.000g 10 1 HF 2 v/v HF 100 0.2 1.0 HF