检测报告 TEST REPORT 委托单位名称 Client Name 产品名称 Name product 聚合物锂离子电池 Polymer lithium ion battery 制造厂商 Manufacturer 商标型号 Trade mark & model 检测类别 Test sort 351220 委托测试 Safety Entrust Test 中检集团南方电子产品测试 ( 深圳 ) 股份有限公司 CCIC Southern Electronic Product Testing (Shenzhen) Co., Ltd. 地 址 : 深圳市南山区西丽街道沙河路 43 号电子检测大厦 邮政编码 /P.C.:518055 Address: Electronic Testing Building No.43 Shahe Road, Xili Road, Nanshan District, ShenZhen, Guangdong, China 电话 /TEL:86-755-26628136 传真 /FAX:86-755-26701436 网址 /Internet:http:// www.ccic-set.com 电子信箱 /E-Mail:Molly.chen@ccic-set.com 1
样品名称 Name sample 中检集团南方电子产品测试 ( 深圳 ) 股份有限公司 CCIC Southern Electronic Product Testing (Shenzhen) CO., Ltd. 检测报告 聚合物锂离子电池 Polymer lithium ion battery TEST REPORT 商 标 Trade mark / 制造厂商 Manufacturer 型号规格 Model/Type 351220 委托单位 Client 取样方式 Sampling method Sent by client 送检日期 Application data 样品数量 Quantity samples 标称电压 Nominal voltage 3.7V 标准充电电流 Standard charge current t 12mA 放电终止电压 Cut-f 2.75V 检验项目 (Test item): 20/01/27 完成日期 Completing Date 43PCS Test1: 高度模拟 Altitude simulation Test2: 温度试验 Thermal Test Test3: 振动 Vibration Test4: 冲击 Shock Test5: 外短路 External short circuit Test6: 撞击 / 挤压 Impact/Crush Test7: 过充电 Overcharge Test8: 强制放电 Forced discharge 检测依据 (Reference documents): 组 充电限制电压 Limited Charge 最大充电电流 Max. Charge Current 最大放电电流 Max.Discharge Current 检验环境 Environment condition 4.20V 60mA 60mA 20/03/10 20~25 45~75%RH 额定能量 / 容量 Rate Energy/Capacity 充电截止电流 End Charge Current 电池数量 Cells Number 2 60mAh/0.222 Wh 1.2mA 1PCS 关于危险货物运输的建议书试验和标准手册 ( 五次修订版本 )38.3 节 : 金属锂电池和锂离子电池 Recommendations on the Transport Dangerous Goods,Manual Test and Critera section 38.3:Lithium metal and lithium ion batteries (ST/SG/AC.10/11/Rev.5/Amend.1&Amend2). 检验概况 (Summary): 对电池或电池组进行了 T1 至 T8 项试验, 试验 T1 至 T5 按顺序进行, 使用相同电池或电池组, 试验 T6 和 T8 使用未另外试验过的电池或电池组, 试验 T7 使用原先试验 T1 至 T5 中使用过的未损坏的电池组进行 试验 Each Cell/battery type is subjectd to tests 1 to 8,Tests 1 to 5 are conducted in sequence on the same Cells/batteries,Tests 6 and 8 are conducted using not otherwise tested Cells/ batteries,test 7 using undamaged batteries previously used in Tests 1 to 5. 质量损失 loss%=(m 1 -M 2 )/M 1 100
式中 :M1 是实验前的质量,M2 是试验后的质量, 如果质量损失不超过表 3.8.3.1 所列的数值, 视为 无质量损失 Where M 1 is the mass before the test and M 2 is the mass after the test. When mass loss does not exceed the values in Table 38.3.2.2, it shall be considered as "no mass loss". M cell or battery loss limit M<1g 0.5% 1g M 75g 0.2% M>75g 0.1% 试验 T1 至 T4 如果电池组无渗漏 无排气 无解体 无破裂和无起火, 并且每个试验电池组在试验后的开路电压不小于其在进行这一试验前电压的 90% 则认为符合要求 In test 1 to 4 batteries meet this requirement if there is no leakage,no venting, no disassembly, no rupture and no fire and if the open circuit voltage each test battery after testing is not less than 90% its voltage immediately prior to this procedure. 制造商提供的锂离子电池为单电芯电池, 根据标准规定, 单电芯电池应作为电池来评估, 按照电池的测试要求进行测试 The Lithium-ion Batteries submitted by manufacturer are single cell batteries,according to the standard,a single cell Battery is considered a Cell and shall be tested ac cording to the testing requirements for cell. 备注 (Remark): 编号 B01#-B10# B#-B19# 是在一个充放电周期完全充电的可充电电芯 ; Rechargeable cells B01#-B10# B#-B19# are fully charge at first cycle; 编号 C11#-C15# 是在一个充放电周期 50% 设计额定容量状态的可充电电芯 ; Rechargeable cells C11#-C15# at 50% the design rated capacity at first cycle; 编号 B20#-B23# 是在 50 个充放电周期后完全充电的可充电电芯 ; Rechargeable cells B20#-B23# are fully charged after 50 cycles; 编号 C24#-C33# 是在一个充放电周期完全放电的可充电电芯 ; Rechargeable Cells C24#-C33# ard in fully Discharged at first cycle; 编号 C34#-C43# 是在 50 个充放电周期后完全放电的可充电电芯 ; Rechargeable cells C34#-C43# are in fully discharged after 50 cycles; 检验结论 (Test conclusion): 测试样品符合联合国 关于危险货物运输的建议书试验和标准手册 38.3 要求 The test samples comply with section 38.3 Recommendations on the Transport Dangerous Goods,Manual Test and Critera. ( 检验单位盖章 stamp) 检测 : Tested by 审核 : Reviewed by 批准 : Approved by 20 年 03 月 10 日 20 年 03 月 10 日 20 年 03 月 10 日 3
测试流程 Test Procedure 预处理 Pretreatment 标记 Marking 样品编号 Samples :B01#-B10# 样品编号 Samples :C11#-C15# 样品编号 Samples :B#-B23# 样品编号 Samples :C24#-C43# 高度模拟 Altitude simulation 温度试验 Thermal test 振动 Vibration 撞击 / 挤压 Impact/Crush 过充 Overcharge 强制放电 Forced dischage 冲击 Shock 外短路 External short circuit 完成 Finished test 4
测试结果 Test results: Test T.1 高度模拟 Altitude siuiation 电池在压力等于或低于 11.6 千帕和环境温度 (20±5 ) 下存放至少 6 小时 Cells are stored at a pressure 11.6 kpa or less for at least six hours at ambient temperature (20±5 ). 要求 Requirement; 电池如无渗漏 无排气 无解体 无破裂和无燃烧, 并且每个试验电池在试验后的开路电压不小于其在进行这一试验前电压的 90%, 电池即符合这一要求 Cells meet this requirement if there is no leakage, no venting, no disassembly, no rupture and no fire and if the open circuit voltage each test cells after testing is not less than 90% its voltage immediately prior to this procedure. 测试数据如下表 Test Date showed in table below; 样品状态 State sample 一个充放电周期完全充电 At first cycle,in fully charged states 序号 No. 质量 (g) 试验前 Pre-test 电压 (V) 质量 (g) 试验后 After test 电压 (V) 质量损失 loss (%) 电压比 after test/ pre-test(%) 判定 Status B01# 1.492 4.19 1.491 4.18 0.07 99.76 PASS B02# 1.483 4.18 1.483 4.17 0.00 99.76 PASS B03# 1.514 4.19 1.513 4.18 0.07 99.76 PASS B04# 1.496 4.18 1.496 4.18 0.00 100.00 PASS B05# 1.508 4.18 1.506 4.18 0.13 100.00 PASS B06# 1.512 4.19 1.512 4.17 0.00 99.52 PASS B07# 1.488 4.19 1.487 4.18 0.07 99.76 PASS B08# 1.496 4.18 1.494 4.18 0.13 100.00 PASS B09# 1.484 4.18 1.484 4.17 0.00 99.76 PASS B10# 1.495 4.19 1.493 4.18 0.13 99.76 PASS 备注 Notes: 试验后电池无渗漏 无排气 无解体 无破裂和无燃烧, 环境温度 24.5 After the test,the cells are no leakage,no venting, no disassembly, no rupture and no fire. Ambient temperature:24.5. 5
Test T.2: 温度试验 Thermal test 电池在试验温度等于 75±2 下存放至少 6 小时, 接着在试验温度等于 -40±2 下存放至少 6 小时 两个极端试验温度之间的最大时间间隔为 30 分钟 这一程序重复 10 次, 接着将所有试验电池在环境温度 ( 20±5 ) 下存放 24 小时 Cells are to be stored for at least six hours at a test temperature equal to 75 ± 2, followed by storage for at least six hours at a test temperature equal to - 40 ± 2. The maximum time interval between test temperature extremes is 30 minutes. This procedure is to be repeated 10 times, after which all test cells are to be stored for 24 hours at ambient temperature (20 ± 5 C). 要求 Requirement; 电池如无渗漏 无排气 无解体 无破裂和无燃烧, 并且每个试验电池在试验后的开路电压不小于其在进行这一试验前电压的 90%, 电池即符合这一要求 Cells meet this requirement if there is no leakage, no venting, no disassembly, no rupture and no fire and if the open circuit voltage each test cells after testing is not less than 90% its voltage immediately prior to this procedure. 测试数据如下表 Test Date showed in table below; 样品状态 State sample 一个充放电周期完全充电 At first cycle,in fully charged states 序号 No. 质量 (g) 试验前 Pre-test 电压 (V) 质量 (g) 试验后 After test 电压 (V) 质量损失 loss (%) 电压比 after test/ pre-test(%) 判定 Status B01# 1.491 4.18 1.489 4.12 0.13 98.56 PASS B02# 1.483 4.17 1.481 4.11 0.13 98.56 PASS B03# 1.513 4.18 1.511 4.12 0.13 98.56 PASS B04# 1.496 4.18 1.494 4.13 0.13 98.80 PASS B05# 1.506 4.18 1.502 4.12 0.27 98.56 PASS B06# 1.512 4.17 1.508 4.10 0.26 98.32 PASS B07# 1.487 4.18 1.485 4.12 0.13 98.56 PASS B08# 1.494 4.18 1.494 4.13 0.00 98.80 PASS B09# 1.484 4.17 1.481 4.11 0.20 98.56 PASS B10# 1.493 4.18 1.49 4.12 0.20 98.56 PASS 备注 Notes: 试验后电池无渗漏 无排气 无解体 无破裂和无燃烧, 环境温度 24.9 After the test,the cells are no leakage,no venting, no disassembly, no rupture and no fire. Ambient temperature:24.9. 6
Test T.3: 振动 Vibration 电池紧固在振动机平面上, 正弦波形振动, 频率在 7 和 200 赫兹之间摆动再回到 7 赫兹的对数扫频为时 15 分钟 这一振动过程须对三个互相垂直的电池安装方位的每一个方向都重复进行 12 次, 总共为时 3 小时 其中一个振动方向必须与端面垂直 对数扫频为 : 从 7 赫兹开始保持 1gn 的最大加速度直到频率达到 18 赫兹 然后将振幅保持在 0.8 毫米 ( 总偏移 1.6 毫米 ) 并增加频率直到最大加速度达到 8gn( 频率约为 50 赫兹 ) 将最大加速度保持在 8gn 直到频率增加到 200 赫兹 Cells are firmly secured to the platform the vibration machine,the vibration is a sinusoidal waveform with a logarithmic sweep between 7 Hz and 200 Hz and back to 7 Hz traversed in 15 minutes. This cycle shall be repeated 12 times for a total 3 hours for each three mutually perpendicular mounting positions the cell. One the directions vibration must be perpendicular to the terminal face. The logarithmic frequency sweep is as follows: from 7 Hz a peak acceleration 1g n is maintained until 18 Hz is reached. The amplitude is then maintained at 0.8 mm (1.6 mm total excursion) and the frequency increased until a peak acceleration 8 g n occurs (approximately 50 Hz). A peak acceleration 8 g n is then maintained until the frequency is increased to 200 Hz. 要求 Requirement; 电池如无渗漏 无排气 无解体 无破裂和无燃烧, 并且每个试验电池在试验后的开路电压不小于其在进行这一试验前电压的 90%, 电池即符合这一要求 Cells meet this requirement if there is no leakage, no venting, no disassembly, no rupture and no fire and if the open circuit voltage each test cells after testing is not less than 90% its voltage immediately prior to this procedure. 测试数据如下表 Test Date showed in table below; 样品状态 State sample 一个充放电周期完全充电 At first cycle,in fully charged states 序号 No. 质量 (g) 试验前 Pre-test 电压 (V) 质量 (g) 试验后 After test 电压 (V) 质量损失 loss (%) 电压比 after test/ pre-test(%) 判定 Statu s B01# 1.489 4.12 1.489 4.12 0.00 100.0 PASS B02# 1.481 4.11 1.481 4.11 0.00 100.0 PASS B03# 1.511 4.12 1.511 4.12 0.00 100.0 PASS B04# 1.494 4.13 1.494 4.13 0.00 100.0 PASS B05# 1.502 4.12 1.502 4.12 0.00 100.0 PASS B06# 1.508 4.10 1.508 4.10 0.00 100.0 PASS B07# 1.485 4.12 1.485 4.12 0.00 100.0 PASS B08# 1.494 4.13 1.494 4.13 0.00 100.0 PASS B09# 1.481 4.11 1.481 4.11 0.00 100.0 PASS B10# 1.49 4.12 1.49 4.12 0.00 100.0 PASS 备注 Notes: 试验后电池无渗漏 无排气 无解体 无破裂和无燃烧, 环境温度 24.6 After the test,the cells are no leakage,no venting, no disassembly, no rupture and no fire. Ambient temperature:24.6. 7
Test T.4: 冲击 Shock 电池用坚硬支架紧固在试验装置上, 支架支撑着每个试验电池的所有安装面 每个电池经受最大加速度 150gn 和脉冲持续时间 6 毫秒的半正弦波冲击 每个电池在三个互相垂直的电池组安装方位的正方向经受三次冲击, 接着在反方向经受三次冲击, 总共经受 18 次冲击 cells are secured to the testing machine by means a rigid mount which will support all mounting surfaces each test cell. Each cell is subjected to a half-sine shock peak acceleration 150 g n and pulse duration 6 milliseconds. Each battery is subjected to three shocks in the positive direction followed by three shocks in the negative direction three mutually perpendicular mounting positions the battery for a total 18 shocks. 要求 Requirement; 电池如无渗漏 无排气 无解体 无破裂和无燃烧, 并且每个试验电池在试验后的开路电压不小于其在进行这一试验前电压的 90%, 电池即符合这一要求 Cells meet this requirement if there is no leakage, no venting, no disassembly, no rupture and no fire and if the open circuit voltage each test cells after testing is not less than 90% its voltage immediately prior to this procedure. 测试数据如下表 Test Date showed in table below; 样品状态 State sample 一个充放电周期完全充电 At first cycle,in fully charged states 序号 No. 质量 (g) 试验前 Pre-test 电压 (V) 质量 (g) 试验后 After test 电压 (V) 质量损失 loss (%) 电压比 after test/ pre-test(%) 判定 Statu s B01# 1.489 4.12 1.489 4.12 0.00 100.0 PASS B02# 1.481 4.11 1.481 4.11 0.00 100.0 PASS B03# 1.511 4.12 1.511 4.12 0.00 100.0 PASS B04# 1.494 4.13 1.494 4.13 0.00 100.0 PASS B05# 1.502 4.12 1.502 4.12 0.00 100.0 PASS B06# 1.508 4.10 1.508 4.10 0.00 100.0 PASS B07# 1.485 4.12 1.485 4.12 0.00 100.0 PASS B08# 1.494 4.13 1.494 4.13 0.00 100.0 PASS B09# 1.481 4.11 1.481 4.11 0.00 100.0 PASS B10# 1.49 4.12 1.49 4.12 0.00 100.0 PASS 备注 Notes: 试验后电池无渗漏 无排气 无解体 无破裂和无燃烧, 环境温度 24.4 After the test,the cells are no leakage,no venting, no disassembly, no rupture and no fire. Ambient temperature:24.4. 8
Test T.5: 外部短路 External short circuit 电池的温度稳定后使其外壳温度达到 55±2, 然后电池组在 55±2 下经受总外阻小于 0.1 欧姆的短路条件 短路条件持续到电池外壳温度回到 55±2 后继续至少 1 小时, 再观察 6 小时结束试验 Cells be tested are temperature stabilized so that its external case temperature reaches 55±2 and then the cell are subjected to a short circuit condition with a total external resistance less than 0.1 ohm at 55±2. This short circuit condition is continued for at least one hour after the cell external case temperature has returned to 55±2. The cells are observed for a further six hours for the test to concluded. 要求 Requirement; 外壳温度如不超过 170, 并且在试验过程后 6 小时内无解体 无破裂 无起火, 电池即符合这一要求 Cells meet this requirement if their external temperature does not exceed 170 and there is no disassembly, no rupture and no fire within six hours after test. 测试数据如下表 Test Date showed in table below; 样品状态 State sample 序号 No. 最高温度 Highest temperature( ) 判定 Status 一个充放电周期完全充电 At first cycle,in fully charged states B01# 55.6 PASS B02# 55.4 PASS B03# 55.1 PASS B04# 55.3 PASS B05# 55.2 PASS B06# 54.8 PASS B07# 55.3 PASS B08# 55.2 PASS B09# 55.4 PASS B10# 55.2 PASS 备注 Notes: 试验后电池 6 小时内无解体 无破裂 无起火, 环境温度 24.8 After the test,the cells are no disassembly,no rupture and no fire within six hours. Ambient temperature:24.8.. 9
Test T.6: 撞击 / 挤压 Impact/Crush 撞击 Impact(applicable to cylindrical cells not less than 18mm in diameter) 试样电池或元件电池放在平坦光滑的表面上, 一根 3 型不锈钢棒横放在试样中心, 钢棒直径 15.8mm±0.1mm, 长度至少 6cm, 或电池最长端的尺度, 取二者之长者, 将一块 9.1kg±0.1kg 的重锤从 61cm±2.5cm 高处跌落到钢棒和试样交叉处, 使用一个几乎没有摩擦的 对落体重锤阻力最小的垂直轨道或管道加以控制 垂直轨道或管道用于引导落锤沿与水平支撑表面呈 90 度落下 接受撞击的试样, 纵轴应与平坦表面平行并与横放在试样中心的直径 15.8mm±0.1mm 完全表面的纵轴垂直 每一试样只经受一次撞击 The sample cell or component cell is to be placed on a flat smooth surface. A 15.8 mm ±0.1mm diameter, at least 6 cm long, or the longest dimension the cell, whichever is greater, Type 3 stainless steel bar is to be placed across the centre the sample. A 9.1 kg ± 0.1 kg mass is to be dropped from a height 61 ± 2.5 cm at the intersection the bar and sample in a controlled manner using a near frictionless, vertical sliding track or channel with minimal drag on the falling mass. The vertical track or channel used to guide the falling mass shall be oriented 90 degrees from the horizontal supporting surface. The test sample is to be impacted with its longitudinal axis parallel to the flat surface and perpendicular to the longitudinal axis the 15.8 mm ± 0.1mm diameter curved surface lying across the centre the test sample. Each sample is to be subjected to only a single impact. 挤压 /Crush (applicable to prismatic, pouch, coin/button cells and cylindrical cells not more than 18 mm in diameter) 将电池或元件电池放在两个平面之间挤压, 挤压力度逐渐加大, 在一个接触点上的速度大约为 1.5 厘米 / 秒, 直到出现下列的情况之一 ; Cells or componert cell is to be crushed between two flat surfaces. The crushing is to be gradual with a speed approximately 1.5 cm/s at the first point contact,the crushing is to be continued until the first the three options below is reached. (a) 施加的力量达到 13 千牛 ±0.78 千牛 ; The applied force reaches 13 kn ± 0.78 kn; (b) 电池的电压下降至少 100mV; 或 The voltage the cell drops by at least 100 mv; or (c) 电池变形达原始高度的 50% 或以上 The cell is deformed by 50% or more its original thickness. 要求 Requirement; 外壳温度如不超过 170, 并且在试验过程中及试验后 6 小时内无解体 无破裂 无起火, 电池或元件电池即符合这一要求 Cells or componert cell meet this requirement if their external temperature does not exceed 170 C and there is no disassembly,no rupture and no fire during the test and within six hours after test. 10
测试数据如下表 Test Date showed in table below; 样品状态 State sample 一个充放电周期 50% 设计额定容量状态 At first cycle at 50% the design rated capacity 测试项目 Test item 挤压 Crush 序号 No. 判定 Status C11# PASS C12# PASS C13# PASS C14# PASS C15# PASS 备注 Notes: 电池或元件电池在试验过程中和试验后 6 小时内无解体 无破裂 无起火, 环境温度 24.2 Cells or componert cell are no disassembly and no fire during the test and within six hours after test. Ambient temperature:24.2. 11
Test T.7: 过充电 Overcharge 充电电流为制造商建议的最大持续充电电流的两倍, 试验电压为电池最大充电电压的两倍, 试验在环境温度下进行, 进行试验时间为 24 小时 The charge current is twice the manufacturer's recommended maximum continuous charge current. The voltage the test is the lesser two times the maximum charge voltage the battery,tests are to be conducted at ambient temperature. The duration the test is 24 hours. 要求 Requirement; 电池组如在试验过程中和试验后 7 天内无解体, 无起火, 即符合本项要求 Batteries meet this requirement if there is no disassembly and no fire during the test and within seven days after the test 测试数据如下 Test Date showed in table below; 过充电流 Overcharge current: 2 60mA=120mA 样品状态 State sample 一个充放电周期后完全充电 At first cycle in fully charged states 五十个充放电周期后, 完全充电 After 50 cycles ending in fully charged states 过充电压 Overcharge voltage : 2 4.20V=8.40V 序号 No. 充电总时间 Total time charging: 24hours 判定 Status B# PASS B17# PASS B18# PASS B19# PASS B20# PASS B21# PASS B22# PASS B23# PASS 备注 Notes: 电池组在试验过程中和试验后 7 天内无解体 无起火, 环境温度 24.7 Btteries are no disassembly and no fire during the test and within seven days after the test Ambient temperature:24.7. 12
Test T.8: 强制放电 Forced discharge 电池在环境温度下与 12V 直流电电源串联在起始电流等于制造商给的的最大放电电流条件下强制放电 Each cells is forced discharged at ambient temperature by connecting it in series with a 12V D.C. power supply at an initial current equal to the maximum discharge current specified by the manufacturer. 要求 Requirement; 充电电池如在试验过程中和试验后 7 天内无解体, 无起火, 即符合本项要求 Recharged cells meet this requirement if there is no disassembly and no fire during the test and within seven days after the test. 测试数据如下表 Test Date showed in table below; 样品状态序号 State sample No. 判定 Status C24# PASS C25# PASS C26# PASS 一个充放电周期后完全放电 At first cycle in fully discharged states C27# PASS C28# PASS C29# PASS C30# PASS C31# PASS C32# PASS C33# PASS C34# PASS C35# PASS C36# PASS 五十个充放电周期后, 完全放电 After 50 cycles ending in fully discharged states C37# PASS C38# PASS C39# PASS C40# PASS C41# PASS C42# PASS C43# PASS 备注 Notes: 试验后充电电池在试验过程中和试验后 7 天内无解体 无起火, 环境温度 24.5 After the test,the recharged cells are no disassembly and no fire during the test and within seven days Ambient temperature:24.5. 13
样品照片 Photo document 图片 Photo 1 图片 Photo 2 14
样品照片 Photo document 图片 Photo 3 图片 Photo 4 15
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