1) 19 711 147 21 8.4 11 26.4 4 457.4 64 711 58 71 88.9 137 1 4.3 6 2) 3) 1 5 3-152 -
TG-MS TG MSTG 391ml/min, 1/minHe and 1.2vol% O 2 /He1.mgPt. He TGMS 39 11-3- TGDTA 3 18 11-3-1 11-3-2 MS MW18 MW2 MW44 CO 2 Weight loss [%] -2-4 -6-8 -1-8 15 3 45 6 75-1 9 Temperature [] -2-4 -6 DTA [V] - 153 -
11-3-3 11-3-4 1-9 1-12 MW2 MW18 MW32 MW44 1-1 1-11 MW12 MW14 MW16 MW24 MW25 MW26 MW28 MW3 15 3 45 6 75 9 15 3 45 6 75 9 Temperature [] Temperature [] MW66 MW67 MW68 MW76 MW77 MW99 MW1 1-13 MW33 MW34 MW48 MW64 MW97 MW98 15 3 45 6 75 9 15 3 45 6 75 9 Temperature [] Temperature [] 1-14 - 154 -
11-3-5 11-3-7 11-3-6 Weight loss [%] -2-4 -6-5 -8-1 -1 15 3 45 6 75 9 Temperature [] 3415 44%DTA 11-3-6 MS H 2 H 2 O CO 2 11-3-7 MS MW24(C=C), MW25(C=CH), MW26(C=CH 2 ) MW12C MW44 CO 2 MW12 C CO 2 11-3-8 MW67MW69 11-3-9 MW333448 S HO 2 H 2 O 2 CH 4 O 2 DTA [V] - 155 -
MW333448 MW32 O 2 415 624 H 2 SO 4 S 624 11-3-5 TGDTA CO 2 415624.5x1-1 15 3 45 6 75 9 Temperature [] 1-9 MW2 MW18 MW32 MW44 15 3 45 6 75 9 Temperature [] MW33 MW34 MW48 MW64 MW97 MW98.5x1-11 1-11.5x1-12 1-12 MW12 MW14 MW16 MW24 MW25 MW26 MW28 MW3 15 3 45 6 75 9 Temperature [] MW66 MW67 MW68 MW76 MW77 MW99 MW1.5x1-9 15 3 45 6 75 9 Temperature [] - 156 -
11-4- 11-4-1 11-4-2 11-4-3 Weight loss [%] -2-4 -6-8 -1-8 15 3 45 6 75-1 9 Temperature [] -2-4 -6 DTA [V] - 157 -
1-1 1-12 MW2 MW18 MW32 MW44 15 3 45 6 75 9 15 3 45 6 75 9 Temperature [] Temperature [] MW66 MW67 MW68 MW76 MW77 MW99 MW1 15 3 45 6 75 9 15 3 45 6 75 9 Temperature [] Temperature [] O 2 /He 11-4-5 TGDTA 5 11-4-7 MW16 CH 4 1 3 18 11-4-6 3 MW32H 2 H 2 O 345 5%.5x1-12 1-12 MW12 MW14 MW16 MW24 MW25 MW26 MW28 MW3 MW33 MW34 MW48 MW64 MW97 MW98 1-11 - 158 -
DTA 11-4-6 MS H 2 H 2 O CO 2 11-4-7 MS MW24(C=C)MW25(C=CH)MW26(C=CH 2 ) MW12C MW44 CO 2 MW12 C CO 2 11-4-8 C4C6 11-4-9 MW33 3448 S HO 2 H 2 O 2 CH 4 O 2 MW333448 MW32 O 2 415 6 SO 2 3~45S Weight loss [%] -2-4 -6-8 -1-8 15 3 45 6 75-1 9 Temperature [] -2-4 -6 DTA [V] - 159 -
1-11.5x1-12 MW2 MW18 MW32 MW44 15 3 45 6 75 9 15 3 45 6 75 9 Temperature [] Temperature [] MW66 MW67 MW68 MW76 MW77 MW99 MW1.5x1-1 15 3 45 6 75 9 Temperature [] He TGMS 39 11-5- TGDTA 332 11-5-1 MS MW18 MW2 MW44 CO 2 11-5-2 MW16 CH 4 1-11 1-11 MW33 MW34 MW48 MW64 MW97 MW98 MW12 MW14 MW16 MW24 MW25 MW26 MW28 MW3 15 3 45 6 75 9 Temperature [] 1-12 - 16 -
2 345 4MS MW44(CO 2 )MW12(C), MW24(C=C), MW25(C=CH), MW26(C=CH2) 11-5-3 MW66MW68 MW77 35 MW991 S 11-5-4 4 MW48 SO MW9798 H 2 SO 4 MW33HS MW34H2S S 11-5- 3 457 1% 11-5-1 CO 2 Weight loss [%] -2-2 -4-4 -6-6 -8-8 -1-1 15 3 45 6 75 9 Temperature [] DTA [V] - 161 -
1-1 1-12 MW2 MW18 MW32 MW44 15 3 45 6 75 9 15 3 45 6 75 9 Temperature [] Temperature [] MW66 MW67 MW68 MW76 MW77 MW99 MW1 15 3 45 6 75 9 15 3 45 6 75 9 Temperature [] Temperature [] O 2 /He 11-5-5 TGDTA 5 11-5-6 CO 2 2x1-9 2x1-12 MW12 MW14 MW16 MW24 MW25 MW26 MW28 MW3 3 2 11-5-6 3 MW32H 2 O MW33 MW34 MW48 MW64 MW97 MW98 He 1-12 2x1-11 - 162 -
11-5-8 O 2 11-5-6 MW44 CO 2 11-5-7 MW12C MW44 CO 2 MW12 C CO 2 11-5-9 MW333448 S HO 2 H 2 O 2 CH 4 O 2 MW333448 MW32 O 2 415 624 1-9 Weight loss [%] MW2 MW18 MW32 MW44-2 -4-6 -8-1 -1 15 3 45 6 75 9 Temperature [].5x1-12 1-8 -2-4 -6-8 15 3 45 6 75 9 15 3 45 6 75 9 Temperature [] Temperature [] DTA [V] MW12 MW14 MW16 MW24 MW25 MW26 MW28 MW3 1-9 - 163 -
1-12 MW66 MW67 MW68 MW76 MW77 MW99 MW1 1-12 MW33 MW34 MW48 MW64 MW97 MW98 15 3 45 6 75 9 15 3 45 6 75 9 Temperature [] Temperature [].5x1-1 4 5 3 SO - 164 -
4) 1), 19, (28). 2) (28) 3) LCCO2 (212). 4) (214). - 165 -