-...2...2...23...24...24...31...32...32...37...38...38...44...46...46...47...49...49...60...73...73
C 0 C 0 C 0 2 2 4
dc = dt k dc = kc dt dc = 2 kc dt dc = 3 kc dt 3 1. 2 kc A, 0 kc A, 0 1
D 2 k k 1 G H d ln k = dt E RT 2
Y k1 Y k > = 1 Z k2 Z k2 Y k1 Z k < = 1 Z k2 Y k2
c γ D = ( ) γ C d b γ A = ( ) γ B a a γ A = ( ) γ C c d γ B ( ) γ b = D ϑ r H f k k CDC = C C 1 1 A G B
dp B dt dc B dt
½ ½ ½
30B 31D 32C 33C 34C 35D 36D 37CAB 38C 39B 40B 41D 42D 43D 44-48 BCADC 49-53 CBCBB 54-58 BB DC C 59-63 AADB B 64-67 CAC C
R S m r ) ) exp( ( ' R G h T k k m r = ) )exp( ' ( R S h T k A m r = RT k R S H m r m r ) ln ( = 2 1 2 1 2 k c k c k k dt dc A A A + =
γ β α γ G B A c c = kc
k 2
dt dc dt dc dt dc dt dc H E B A = = = ) ( 1 ) ( 1 ) ( 1 ) ( 1 dt dc h dt dc g dt dc b dt dc a H E B A = = = ) ( ) ( ) ( ) ( dt dc h dt dc g dt dc b dt dc a H E B A = = = ) ( ) ( ) ( ) ( dt dc h ag dt dc a dt dc b ag dt dc g H E B A = = = ) )( ( ) ( ) )( ( ) )( ( dt dc h g dt dc dt dc g b dt dc g a H E B A = = =
1 b( a kt = [ ]ln[ a b a( b x) ] x) kt = 1 1 [ 2 ( a x) 2 1 a 2 ] dc A dc B dt dt dc D dt dc ν dt i i dς dt α β γ = kc C A B
S r m < 0 H r m r G m k dζ 2 = kc A Vdt
2 A i i kc dt V dn = ν i ν 2 ) ( 2 1 A A A c k dt dc = 2 2 A H kc dt dc = 2 ) 2 1 ( A B kc dt dc = 2 ) 2 ( A A B c k dt dc =
k1k k = k3 2
E a * = ( ε ε ) L A = E * E
] exp[ RT Ea A k =
48, 49
1 r U m =-200kJmol -1 E 1 200kJ mol -1 2 A+B EC=E a - nrt n = 3 298Kabk a =10k b Rln 1 4 2A+B V dc A 1 dξ = - dt V dt dξ dc A dt, A- dt, 5H 2 (g) + I 2 (g) = 2HI(g)H 2 (g)i 2 (g)kh 2 ki 2 kh 2 6 t 1/2 =1.71t 1/3 7 c 0 y y = kc0t 1 y 8 A 25 dc dt A = kc a A c b H + a =
9 aa + bb ==gg + hh A B n = 10 A + A A + A *, A * B + C dc dt * A 2 A 1 A 2 = k kk c 1 c + k k -1 c A k 2 11 [] -2 [] -1 12 13,d[]/dt= 14 15 lg k k 0 = 2Z A Z B A I I, Z A Z B AB Z A Z B 0 I k 16. A +2D == G + HADk A k D k D k A
17. 18. H 2 (g) + I 2 (g) == 2HI(g) 19. 200 kj mol -1 150 kj mol -1 kj mol -1 20. 2AG A 1/3 2/3 A 1/3 21 2A + B D + GABr A r B r A / 22 23 1 H 2 + Cl 2 = 2HCl 2 H 2 + I 2 = 2HI 3 H 2 + 1 / 2 O 2 = H 2 O 4 H 2 + Br 2 = 2HBr 24N 2 O 5 (g) d[ N 2O5 ] k1k2 = k[ N 2O5 ] k = dt, k 1 + 2k2 d[ N 2O5 ] ' = k [ N 2O5 ] dt k = k ' k 2 k -1 25 r U m =150kJ mol -1 E 1 150kJ mol -1
26 27 A γ 2 = kc A A 1 / 3 1 / 2 28 aa + bb gga>g>bk B k G k G k B 29 A+2B,k = 0.4dm 3 mol -1 s -1 30 lg(-dc/dt) lgc 3
=3 39 dcc/dt= -dca/dt= 40 k B 2D(g) kcc(g) A(g)+B(g) K E E(g) -dc B /dt= dc D /dt= 41 1mol 42aA+bB yy+zzk A k B k Y k Z 43 2A 3B,-dc A /dtdc B /dt 44N 2 (g)+3h 2 (g) 2NH 3 (g),t=0 p(nh 3 )=0, dp/dt,n 2 -dp(n 2 )/dt = 45 3/4 1/2 2. 46 7/8 3/4 1.5. 47 A B A 2
48 2*10-2kPa -1 49 50, 51 k=4.62*10-2 s -1, 3/4 52 5d, 15d 53 A Y, 2B Z, A B,,A B Y 54 A,, Z 120kJmoL-1, 80kJmol-1,400K c B :c D = 1000Kc B :c D = 55 I 2 (g)=2iu=160kjmol -1,,I 2 = 56 (1)(2), E1>E2, k1>k2, 57 A k1 Y k2 Z,k1 k2 :ln(k1/s -1 )= -2000K/T +4 ln(k1/s -1 )= -4000K/T +8 E1=,E2=,1000K B,c Y,m = 58 59,, 60 61
62 A+hA*, -dca/dt= 63, 30%,, 64 A+B k1 k-1 P, k1 k2, k1 =2k 1, k-1 = k-1 65 A Y-, A,-dpA/dt= 66 3/4 1/2 2. 67 68 A 2 +B 2 2ABA 2 +B 2 A 2 B 2 ()A 2 B 2 2AB()υ AB =.
1. ka/a=kb/b=ky/y=kz/z=kk 2. -1 3. 4.157dm 3 mol -1 s. 5. 4 k=k0e-ea/rt k0 Ea T T k 6. 3 100kJ mol -1 100kJ mol -1 7. 1/2 A
1/2 A A0
1.,, 14 C =ln2/t 1/2 =ln2/5730=1.209710-4 a -1 = (ln1/0.72) 1/k =(ln1/0.72)1/1.209710-4 =2716a 2.
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