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1 附件 1: 安全数据单样本 ( 中文 ) 报验号 : 第 1 页, 共 5 页化学品安全数据单一标识物品名称 : 甲酸 Formic acid 其它名称 : 蚁酸使用建议及使用限制 : 用于制化学药品橡胶凝固剂及纺织印染电镀等制造商或供货商名称地址及电话 : 聊城煤杉新材料科技有限公司紧急联络电话传真电话 : 二危险标识物质或混合物的分类 : 易燃液体类别 3, 金属腐蚀剂类别 1, 急性毒性 ( 口服 ) 类别 4, 急性毒性 ( 吸入 ) 类别 4, 皮肤腐蚀类别 1B, 严重眼损伤眼刺激类别 1, 生殖毒性类别 2, 特定目标器官毒性单次接触类别 1( 影响器官 : 血液系统肝肾呼吸器官, 影响途径 : 吸入 ), 特定目标器官毒性重复接触类别 1( 影响器官 : 肾, 影响途径 : 吸入 ), 危害水生环境 ( 急性 ) 类别 3 全球统一制度标签要素, 包括防范说明 : 信号词 : 危险危险说明 : 易燃液体和蒸气可能腐蚀金属吞咽有害吸入有害造成严重皮肤灼伤和眼损伤怀疑对生育能力或胎儿造成伤害会损害器官 ( 影响器官 : 血液系统肝肾呼吸器官, 影响途径 : 吸入 ) 长期或重复接触会对器官造成损害 ( 影响器官 : 肾, 影响途径 : 吸入 ) 对水生生物有害防范说明 : 预防 : 在使用前获取特别指示在读懂所有安全防范措施之前切勿搬动远离热源火花明火热表面禁止吸烟保持容器密闭保持低温容器和接收设备接地等势联接使用防爆的电气通风照明设备只能使用不产生火花的工具采取防止静电放电的措施使用所需的个人防护设备戴防护手套穿防护服戴防护眼罩戴防护面具使用本产品时不要进食饮水或吸烟不要吸入粉尘烟气体烟雾蒸气喷雾只能在室外或通风良好之处使用作业后彻底清洗避免释放到环境中应急 : 如皮肤 ( 或头发 ) 沾染 : 立即去除脱掉所有沾染的衣服用水清洗皮肤淋浴沾染的衣服清洗后方可重新使用如误吞咽 : 如感觉不适, 呼叫解毒中心或医生漱口如误吸入 : 将受害人转移到空气新鲜处, 保持呼吸舒适的休息姿势不得诱导呕吐如进入眼睛 : 用水小心冲洗几分钟如戴隐形眼镜并可方便地取出, 取出隐形眼镜继续冲洗火灾时使用水雾, 抗醇泡沫, 干粉或二氧化碳等贮存 : 存放于通风良好的地方保持低温贮存于抗腐蚀带抗腐蚀衬里的容器中存放处须加锁处置 : 按照相关规定处置内装物和容器不导致分类的其他危险 ( 例如尘爆危险 ) 或不为全球统一制度覆盖的其他危险 : 三组成成分信息化学名称化学文摘社登记号码 (CAS No.) 含量 % 甲酸 %

2 附件 1: 安全数据单样本 ( 中文 ) 报验号 : 第 2 页, 共 5 页四急救措施必要的急救措施吸入 : 速脱离现场至空气新鲜处保持呼吸道通畅呼吸困难时给输氧给予 2-4% 碳酸氢钠溶液雾化吸入就医皮肤接触 : 脱去污染的衣着, 立即用水冲洗至少 15 分钟若有灼伤, 就医治疗眼睛接触 : 立即提起眼睑, 用大量流动清水或生理盐水彻底冲洗至少 15 分钟就医食入 : 误服者立即漱口, 给饮牛奶或蛋清立即就医最重要的急性和延迟症状效应 : 主要引起皮肤粘膜有刺激症状其表现有结膜充血鼻炎支气管炎 ; 皮肤接触可引起炎症和溃疡误服甲酸可至死 ( 致死量约 30 克 ) 除消化道症状外, 常因急性肾功衰竭或呼吸功能衰竭而死亡慢性中毒 : 可能有血尿和蛋白尿必要时注明立即就医及所需的特殊治疗 : 五消防措施适用和不适用的灭火剂 : 可用抗醇泡沫干粉二氧化碳沙土等灭火化学品产生的具体危险 : 可燃其蒸气与空气可形成爆炸性混合物, 遇明火高热能引起燃烧爆炸与强氧化剂接触可发生化学反应具强腐蚀性刺激性, 可致人体灼伤消防人员的特殊防护行为 : 消防人员必须穿全身耐酸碱消防服, 在上风向灭火若不小心接触, 立即撤离现场, 隔离器具, 对人员彻底清污蒸气比空气重, 易在低处聚集封闭区域内的蒸气遇火能爆炸蒸气能扩散到远处, 遇点火源着火, 并引起回燃储存容器及其部件可能向四面八方飞射很远如果该物质或被污染的流体进入水路, 通知有潜在水体污染的下游用户, 通知地方卫生消防官员和污染控制部门在安全防爆距离以外, 使用雾状水冷却暴露的容器六意外释放措施人身防范保护设备和应急程序 : 隔离泄漏污染区, 限制出入切断火源疏散泄漏污染区人员至安全区, 禁止无关人员进入污染区, 切断火源建议应急处理人员戴自给式呼吸器, 穿化学防护服不要直接接触泄漏物, 在确保安全情况下堵漏抑制和清理的方法和材料 : 用沙土或其它不燃性吸附剂混合吸收, 然后收集运至废物处理场所处置也可以将地面洒上苏打灰, 用大量水冲洗, 经稀释的洗水放入废水系统如果大量泄漏, 利用围堤收容, 然后收集转移回收或无害处理后废弃七操作与储存安全操作的防范措施 : 分装和搬运作业要注意个人防护搬运时要轻装轻卸, 防止包装及容器损坏密闭操作, 加强通风操作人员必须经过专门培训, 严格遵守操作规程建议操作人员佩戴自吸过滤式防毒面具 ( 全面罩 ), 穿橡胶耐酸碱服, 戴橡胶耐酸碱手套远离火种热源, 工作场所严禁吸烟使用防爆型的通风系统和设备防止蒸气泄漏到工作场所空气中避免与氧化剂碱类活性金属粉末接触搬运时要轻装轻卸, 防止包装及容器损坏配备相应品种和数量的消防器材及泄漏应急处理设备倒空的容器可能残留有害物安全存储的条件, 包括任何不相容性 : 储存于阴凉通风的库房远离火种热源保持容器密封应与碱类食用化学品易 ( 可 ) 燃物等不相容物质分开存放, 切忌混储采用防爆型照明通风设施禁止使用易产生火花的机械设备和工具储区应备有泄漏应急处理设备和合适的收容材料八接触控制人身保护

3 附件 1: 安全数据单样本 ( 中文 ) 报验号 : 第 3 页, 共 5 页控制参数 : 最高容许浓度 : 中国 MAC 未制定标准前苏联 MAC(mgm 3 ):1;TLVTN:OSHA 5ppm,9.4mgm 3 ;ACGIH 5ppm,9.4mgm 3 ;TLVWN:ACGIH 10ppm,19mgm 3 ( 监测方法 : 气相色谱法 ) 工程控制 : 生产过程密闭, 加强通风个人防护设备眼睛防护 : 戴化学安全防护眼镜皮肤防护 : 戴橡胶耐酸碱手套呼吸防护 : 可能接触其蒸气时, 必须佩戴自吸过滤式防毒面具 ( 全面罩 ) 或自吸式长管面具紧急事态抢救或撤离时, 建议佩戴空气呼吸器外观 ( 物理状态颜色等 ) 气味气味阙值 ph 值熔点凝固点初始沸点和沸腾范围闪点蒸发速率易燃性 ( 固态气态 ) 上下易燃极限或爆炸极限蒸气压力蒸气密度相对密度可溶性分配系数 :n- 辛醇水自动点火温度分解温度粘度九物理及化学性质无色透明液体 58 C 易燃液体和蒸汽 1.59( 空气 =1) 1.23( 水 =1) 与水混溶, 不溶于烃类, 可混溶于醇十稳定及反应性反应性 : 化学稳定性 : 危险反应的可能性 : 应避免的条件 : 避免光照, 远离高温不相容的物质和材料 : 强氧化剂强碱活性金属粉末食用化学品易 ( 可 ) 燃物等危险的分解产物 : 一氧化碳二氧化碳十一毒理学信息急性毒性效应 : 食入 : 意外食入本物质可能有害食入酸性腐蚀物能导致口腔周围或内部咽喉和食道的灼伤也可能立即出现明显的疼痛感, 并有吞食与说话的困难严重接触能导致呕血和浓的粘液休克重度低血压脉搏快而弱浅呼吸和皮肤湿冷胃壁发炎和食管组织破裂等症状未及时治疗的休克最终能导致肾衰竭严重的病例可能显示有胃和腹部穿孔并有腹膜炎腹部僵直与发烧等症状食

4 附件 1: 安全数据单样本 ( 中文 ) 报验号 : 第 4 页, 共 5 页道胃及幽门的括约肌能在少至数周, 或长至数年内发生狭窄病人可能由于腹膜肾或肺部等的感染引起昏迷和抽搐, 随后死亡眼睛 : 如果进入眼睛, 物质会引起眼睛的严重损伤皮肤 : 皮肤接触酸性腐蚀性物质可引起疼痛和烧伤这种烧伤比较深并有明显的边缘, 往往愈合过程较慢, 并会形成疤痕组织吸入 : 能刺激某些人的呼吸系统体内对这种刺激的反应能进一步引起肺部受损伤慢性毒性或长期毒性效应 : 长期或多次接触酸类物质, 能引起牙齿的腐蚀和口腔粘膜的肿胀或溃疡经常能发生肺部气道刺激, 并伴有咳嗽和肺部组织炎症也可能发生胃肠紊乱长期接触可导致皮炎或结膜炎长期接触呼吸道刺激物可能会导致气管疾病, 包括呼吸困难和相关身体组织的疾病毒性的数值度量 ( 如急性毒性估计值 ): 甲酸 : 半致死剂量 (LD50) 经口 - 大鼠 - 1,100 mgkg 半致死浓度 (LC50) 吸入 - 大鼠 - 4 h mgl 半致死浓度 (LC50) 吸入 - 大鼠 h - 15,000 mgm 3 十二生态信息生态毒性 : 对水生生物有害持久性及降解性 : 生物蓄积性 : 高在土壤中的流动性 : 高其它不利效应 : 该物质对环境有危害, 应特别注意对水体的污染十三处置考虑处置方法 : 容器清空后仍可能有化学品危害或危险存在如有可能, 请将容器返还给供应商循环使用否则 : 如果容器不能通过彻底清洗来保证无任何杂质残留, 或者该容器不能再被用于储存相同产品, 则把所有容器穿孔, 以防循环使用, 然后在批准的填埋处进行填埋在有可能的地方保留警告标签和 SDS, 同时遵守任何有关该产品的通告十四运输信息联合国编号 :1779 联合国运输名称 : 甲酸, 按重量含酸大于 85% 运输危险种类 :8+3 包装类别 :II 海洋污染物 ( 是否 ): 使用者的特殊防范措施 : 十五管理信息国内化学品安全管理法规 : 甲酸 (CAS: ) 出现在以下法规中 : 中国现有化学物质名录, 化学品首次进口环境管理第二类化学品, 危险化学品名录, 工作场所有害因素职业接触限值, 常用危险化学品的分类及标志本化学品安全技术说明书遵照了以下相关国家标准 : GB , GB , GB ,GBT ,GB ,GB ,GB ,GB , GB ,GB ,GA ,GBT ,GBZ 以及相关法规 : 危险货物运输管理规则危险化学品安全管理条例联合国关于危险货物运输的建议书 ( 简称 UN RTDG)

5 附件 1: 安全数据单样本 ( 中文 ) 报验号 : 第 5 页, 共 5 页参考文献制表日期十六其它信息. 联合国关于危险货物运输的建议书规章范本联合国全球化学品统一分类和标签制度 2012 年 08 月 09 日注 1: 当产品为含有两种以上危险物质的混合物时, 应依据其混合后的危险性, 制作安全数据单注 2: 制造商供应商应根据实际情况确保安全数据单所含信息的正确性, 并适时更新注 3: 如由于产品特性而不存在或不可得某些信息时 ( 如固体不存在沸点 ), 应在表格中以标识

6 附件 2: 安全数据单样本 ( 英文 ) 报验号 : 第 1 页, 共 5 页 Chemical Safety Data Sheet SECTION 1 IDENTIFICATION Product Name: Formic acid Other Name: aminic acid Recommended use of the chemical and restrictions on use: Supplier s details: Emergency phone number: SECTION 2 HAZARDS IDENTIFICATION Classification of the substance or mixture Flammable liquids Category 3,Corrosive to metals Category 1,Acute toxicity Category 4 (Oral), Acute toxicity Category 4 (inhalation), Skin corrosionirritation Category 1B, Serious eye damageeye irritation Category 1, Reproductive toxicity Category 2,Specific target organ toxicity, single exposure Category 1 (blood system, liver, kidneys, and respiratory organs, inhalation), Specific target organ toxicity - repeated exposure Category 1 (kidneys, inhalation). Hazardous to the aquatic environment, acute hazard Category 3. GHS Label elements, including precautionary statements Signal word: Danger. Hazard statement(s): Flammable liquid and vapor. May be corrosive to metals, Harmful if swallowed. Harmful if inhaled. Causes severe skin burns and eye damage. Causes serious eye damage. May damage fertility or the unborn child. Causes damage to organs (blood system, liver, kidneys, and respiratory organs, inhalation), Causes damage to organs through prolonged or repeated exposure (kidneys, inhalation). Harmful to aquatic life. Precautionary statement(s): Prevention: Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from heatsparksopen flameshot surfaces. No smoking. Keep container tightly closed. Keep cool. Groundbond container and receiving equipment. Use explosion-proof electricalventilatinglightingequipment. Use only non-sparking tools. Take precautionary measures against static discharge. Use personal protective equipment as required. Wear protective glovesprotective clothingeye protectionface protection. Do not eat, drink or smoke when using this product. Do not breathe dustfumegasmistvaporsspray. Use only outdoors or in a well-ventilated area. Wash thoroughly after handling. Avoid release to the environment. Response: IF ON SKIN (or hair): RemoveTake off immediately all contaminated clothing. Rinse skin with watershower. Wash contaminated clothing before reuse. IF SWALLOWED: Immediately call a POISON CENTER or doctorphysician. Rinse mouth. IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Do NOT induce vomiting. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF exposed or if you feel unwell: Call a POISON CENTER or doctorphysician. In case of fire: Use water spray,

7 附件 2: 安全数据单样本 ( 英文 ) 报验号 : 第 2 页, 共 5 页 alcohol-resistant foam, dry chemical or carbon dioxide for extinction. Storage : Store in corrosive resistant... container with a resistant inner liner. Store in a well-ventilated place. Keep cool. Store locked up. Disposal: Dispose of contentscontainer to relevant regulations. Other hazards which do not result in classification: SECTION 3 COMPOSITIONINFORMATION ON INGREDIENTS Chemical Name CAS No. Concentration% Formic acid % SECTION 4 FIRST AID MEASURES Description of necessary first aid measures If inhaled: If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician. In case of skin contact: Take off contaminated clothing and shoes immediately. Wash off with soap and plenty of water. Take victim immediately to hospital. Consult a physician. In case of eye contact: Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. If swallowed: Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician. Most important symptoms and effects, both acute and delayed: Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin, spasm, inflammation and edema of the larynx, spasm, inflammation and edema of the bronchi, pneumonitis, pulmonary edema, burning sensation, Cough, wheezing, laryngitis, Shortness of breath, Headache, Nausea, Vomiting. Indication of immediate medical attention and special treatment needed: SECTION 5 FIREFIGHTING MEASURES Suitable extinguishing media: Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Special hazards arising from the chemical: Carbon oxides. Special protective actions for fire-fighters: Wear self-contained breathing apparatus for firefighting if necessary. Use water spray to cool unopened containers. SECTION 6 ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures: Wear respiratory protection. Avoid breathing vapors, mist or gas. Ensure adequate ventilation. Remove all sources of ignition. Evacuate personnel to safe areas. Beware of vapors accumulating to form explosive concentrations. Vapors can accumulate in low areas. Environmental precautions: Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided. Methods and materials for containment and cleaning up: Contain spillage, and then collect with an electrically protected vacuum cleaner or by wet-brushing and place in container for disposal according to local regulations. SECTION 7 HANDLING AND STORAGE

8 附件 2: 安全数据单样本 ( 英文 ) 报验号 : 第 3 页, 共 5 页 Precautions for safe handling: Avoid contact with skin and eyes. Avoid inhalation of vapor or mist. Keep away from sources of ignition - No smoking. Take measures to prevent the buildup of electrostatic charge. Conditions for safe storage, including any incompatibilities: Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. SECTION 8 EXPOSURE CONTROLSPERSONAL PROTECTION Control parameters: Appropriate engineering controls: Avoid contact with skin, eyes and clothing. Wash hands before breaks and immediately after handling the product. Personal protective equipment Eyeface protection: Tightly fitting safety goggles. Face shield (8-inch minimum). Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Skin protection: Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. Respiratory protection: Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator with multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU). SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Appearance Colorless clear liquid. Odour Odour Threshold ph Melting pointfreezing point Initial boiling point and boiling range Flash point 58 C. Evaporation rate Flammability (solid, gas) Flammable liquid and vapor. Upperlower flammability or explosive limits Vapor pressure Vapor density 1.59 (air=1). Relative density 1.23 (water=1). Water solubility Miscible. Partition coefficient: noctanolwater Autoignition temperature Decomposition temperature Viscosity SECTION 10 STABILITY AND REACTIVITY

9 附件 2: 安全数据单样本 ( 英文 ) 报验号 : 第 4 页, 共 5 页 Reactivity: Chemical stability: Possibility of hazardous reactions: Conditions to avoid: Heat, flames and sparks. Incompatible materials: Strong oxidizing agents, Strong bases, Powdered metals. Hazardous decomposition products: SECTION 11 TOXICOLOGICAL INFORMATION Acute health effects Ingestion: Harmful if swallowed. Causes burns. Inhalation: Toxic if inhaled. Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. Skin: May be harmful if absorbed through skin. Causes skin burns. Eyes: Causes eye burns. Chronic health effects: Long-term exposure to respiratory irritants may result in disease of the airways involving difficult breathing and related systemic problems. Numerical measures of toxicity(such as acute toxicity estimates): formic acid: Oral (rat) LD50: 1100 mgkg, Inhalation (rat) LC50: mgm³15m.. SECTION 12 ECOLOGICAL INFORMATION Toxicity: Harmful to aquatic life. Persistence and degradability: Bioaccumulative potential: High. Mobility in soil: High. Other adverse effects: SECTION 13 DISPOSAL CONSIDERATIONS Disposal methods: Puncture containers to prevent re-use and bury at an authorized landfill. Legislation addressing waste disposal requirements may differ by country, state and or territory. Each user must refer to laws operating in their area. In some areas, certain wastes must be tracked. Recycle containers where possible, or dispose of in an authorized landfill. SECTION 14 TRANSPORT INFORMATION UN number: UN proper shipping name: Formic acid with more than 85% acid by mass. Transport hazard class(es): 8+3. Packaging group: II. Environmental hazards: Special precautions for user: SECTION 15 REGULATORY INFORMATION Regulations: Formic acid (CAS: ) is found on the following regulatory list:"china Classification and Labeling of Dangerous Chemical Substances", "China Dangerous Chemicals Names List", This safety data sheet is in compliance with the following national standards: GB , GB , GB ,

10 附件 2: 安全数据单样本 ( 英文 ) 报验号 : 第 5 页, 共 5 页 GBT , GB , GB , GB , GB , GB , GB ,GA ,GBT ,GBZ as well as the following national regulations: Dangerous Goods Transport Administrative Regulation, Dangerous Chemicals Safety Administrative Regulation, United Nations Regulations on the Transport of Dangerous Goods (UN RTDG). References Form Date SECTION 16 OTHER INFORMATION Model Regulations on the Transport of Dangerous Goods The Globally Harmonized System of Classification and Labelling of Chemicals 09-Aug-2012 Note 1: When products contain two or more hazardous substances, Safety Data Sheets should be prepared based on the risk of the mixture. Note 2: Manufacturer supplier should ensure the correctness of the information contained in the safety data sheets, and updated in a timely manner. Note 3: As a result of product features without the existence of certain information or no data available (such as boiling point does not exist for the solid) in the table with "" logo.

CODE: PRODUCT NAME:Sodium hydroxide Danger Keep out of the reach of children. Read label before use. Harmful if swallowed. Harmful in contact with ski

CODE: PRODUCT NAME:Sodium hydroxide Danger Keep out of the reach of children. Read label before use. Harmful if swallowed. Harmful in contact with ski 编码 : 产品名称 : 固体氢氧化钠危险儿童不得接触使用前请读标签吞咽有害皮肤接触有害造成严重皮肤灼伤和眼损伤对水生生物有害预防 : 不要吸入粉尘烟气体烟雾蒸气喷雾作业后彻底清洗使用本产品时不要进食饮水或吸烟避免释