化学品安全数据单一标识全球统一制度产品标识符 : 硫磺 Sulfur 其它标识办法 : 胶体硫 ; 硫黄块化学品使用建议和使用限制 : 本品可用于制造染料农药火柴火药橡胶医药等供货商的详细情况 : 紧急电话号码 : 二危险标识物质或混合物的分类 : 易燃固体第 2 类严重眼损伤

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1 编码 : 产品名称 : 硫磺易燃固体造成严重眼刺激警告儿童不得触及使用前请读标签预防 : 远离热源火花明火热表面禁止吸烟容器和装载设备接地等势联接使用防爆的电气通风照明设备戴防护手套穿防护服戴防护眼罩戴防护面具作业后彻底清洗反应 : 火灾时 : 使用灭火如进入眼睛 : 用水小心冲洗几分钟如戴隐形眼镜并可方便地取出, 取出隐形眼镜继续冲洗如仍觉眼刺激 : 求医就诊储存 : 处置 :

2 化学品安全数据单一标识全球统一制度产品标识符 : 硫磺 Sulfur 其它标识办法 : 胶体硫 ; 硫黄块化学品使用建议和使用限制 : 本品可用于制造染料农药火柴火药橡胶医药等供货商的详细情况 : 紧急电话号码 : 二危险标识物质或混合物的分类 : 易燃固体第 2 类严重眼损伤眼刺激第 2 类全球统一制度标签要素, 包括防范说明 : 信号词 : 警告危险说明 : 易燃固体造成严重眼刺激防范说明 : 预防 : 远离热源热表面火花明火和其他点火源禁止吸烟容器和装载设备接地并等势联接使用防爆的 [ 电气通风照明 ] 设备戴防护手套穿防护服戴防护眼罩戴防护面具作业后彻底清洗双手和眼睛反应 : 火灾时 : 使用干粉泡沫或雾状水灭火如进入眼睛 : 用水小心冲洗几分钟如戴隐形眼镜并可方便地取出, 取出隐形眼镜继续冲洗如仍觉眼刺激 : 求医就诊贮存 : 处置 : 按照相关规定处置内装物和容器不导致分类的其他危险 : 三组成成分信息化学文摘社编号成分 ( 由送检化学名称 (CAS No.) 企业提供 ) 硫 % 四急救措施

3 不同暴露途径的急救方法吸入 : 迅速脱离现场至空气新鲜处保持呼吸道通畅如呼吸困难, 给输氧如呼吸停止, 立即进行人工呼吸就医皮肤接触 : 脱去污染的衣着, 用大量流动清水冲洗眼睛接触 : 立即提起眼睑, 用大量流动清水或生理盐水彻底冲洗至少 15 分钟就医摄入 : 饮足量温水, 漱口就医最重要的急性和延迟症状效应 : 必要时注明立即就医及所需的特殊治疗 : 五消防措施适当的灭火剂 : 可用雾状水干粉或泡沫灭火化学品产生的具体危险 : 易燃固体, 在高温高热下可着火燃烧, 释放出有毒气体消防人员的特殊防护行动 : 消防人员必须配戴空气呼吸器消防衣及防护手套, 根据着火原因选择适当灭火剂, 在安全距离以外的上风向灭火六意外释放措施人身防范保护设备和应急程序 : 建议应急处理人员戴正压式呼吸器, 穿防毒工作服不要直接接触泄漏物环境防范措施 : 隔离泄漏污染区, 限制出入抑制和清洁的方法和材料 : 小量泄漏 : 避免扬尘, 用洁净的铲子收集于干燥洁净有盖的容器中, 转移至安全场所大量泄漏 : 用塑料布帆布覆盖使用无火花工具收集回收或运至废物处理场所处置七搬运与储存安全搬运的防范措施 : 密闭操作, 加强通风, 严格遵守操作规程, 建议操作人员佩戴防尘面具, 穿一般防护服, 戴橡胶手套, 戴防护眼镜口罩, 工作现场严禁吸烟安全存储的条件, 包括任何不相容性 : 储存于阴凉通风的仓库内远离火种热源包装必须密封, 切勿受潮搬运时要轻装轻卸, 防止包装及容器损坏应与氧化剂易 ( 可 ) 燃物等分开存放, 切忌混储储区应备有合适的材料收容泄漏物八接触控制人身保护控制参数 : 来源物质名称 TWA 中国工作场所有害因素职业接触限值 - 粉尘硫 8 mgm 3 适当的工程控制 : 严加密闭, 提供充分的局部排风个人保护措施防护眼罩面具 : 佩戴防尘面具皮肤防护 : 穿一般防护服呼吸系统防护 : 可能接触其粉尘时, 必须佩戴防尘面具 ( 全面罩 ) 紧急事态抢救或撤离时, 应该佩戴空气呼吸器高温危险 :

4 九物理及化学性质外观 ( 物理状态颜色等 ) 气味气味阈值 ph 值熔点凝固点初始沸点和沸腾范围闪点蒸发速率易燃性 ( 固体气体 ) 上下易燃极限或爆炸极限蒸气压力蒸气密度相对密度可溶性分配系数 : 正辛醇水自动点火温度分解温度粘度黄色块状固体 (γ- 硫 ): 107 ;( β- 硫 ): 115 ;( 无定形硫 ): gm³ 2.1 不溶于水 232 十稳定及反应性反应性 : 化学稳定性 : 在常温下稳定危险反应的可能性 : 燃烧时释放出有毒和腐蚀性硫氧化物气体, 与强氧化物剧烈反应 ( 尤其是呈粉末状态时 ), 有着火和爆炸的危险应避免的条件 : 火星静电高温不相容材料 : 强氧化剂易 ( 可 ) 燃物危险分解产物 : 硫氧化物十一毒理学信息暴露途径 : 吸入, 食入, 经皮吸收, 眼睛接触有关物理化学和毒理学特点的症状 : 急性毒性效应 : 吸入后会导致咳嗽咽喉刺激皮肤接触会导致皮肤发红刺激眼睛接触后会导致发红刺激食入会导致恶心呕吐腹痛等症状慢性毒性或长期毒性效应 : 长期或重复接触皮肤可能导致皮炎此物质对呼吸道有影响, 可能导致慢性支气管炎毒性的度量值 ( 如急性毒性估计值 ): LD50(Oral, rat): >2000 mgkg LD50(Dermal, rat): >2000 mgkg LC50(Inhalation, rat): >5.43 mgl4 h 十二生态信息

5 毒性 : 持久性和降解性 : 低生物累积潜力 : 低在土壤中的流动性 : 低其它有害效应 : 十三处置考虑处置方法 : 用安全掩埋法处置破损容器禁止重新使用, 要在规定场所掩埋十四运输信息联合国编号 :1350 联合国正式运输名称 : 硫运输危险分类 :4.1 包装类别 ( 如果适用 ):III 环境危险 : 用户的特殊防范措施 : 十五管理信息国内化学品安全管理法规 : 本化学品安全数据单遵照了以下相关国家标准 :GB GB GB GBT GB GB GB GB GB GA GBZ 以及相关法规 : 铁路危险货物运输管理规则危险化学品安全管理条例十六其它信息参考文献联合国关于危险货物运输的建议书规章范本联合国全球化学品统一分类和标签制度制表日期注 1: 当产品为含有两种以上危险物质的混合物时, 应依据其混合后的危险性, 制作安全数据单注 2: 制造商供应商应根据实际情况确保安全数据单所含信息的正确性, 并适时更新注 3: 如由于产品特性而不存在或不可得某些信息时 ( 如固体不存在沸点 ), 应在表格中以标识

6 Chemical Safety Data Sheet Section 1 IDENTIFICATION GHS Product identifier: Sulfur. Other means of identification: Recommended use of the chemical and restrictions on use: Raw material of dye, pesticide, match, gunpowder, rubber, medicine, etc. Supplier s details: Emergency phone number: Section 2 HAZARDS IDENTIFICATION Classification of the substance or mixture: Flammable solid Category 2 Serious eye damageeye irritation Category 2 GHS Label elements, including precautionary statements: Signal word: Warning Hazard statement(s): Flammable solid. Causes serious eye irritation. Precautionary statement(s): Prevention: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Ground and bond container and receiving equipment. Use explosion-proof [electricalventilatinglighting...] equipment. Wear protective gloves protective clothingeye protectionface protection. Wash hands and eyes thoroughly after handling. Response: In case of fire: Use chemical powder, foam or water spray for extinction. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical adviceattention. Storage: Disposal: Dispose of contentscontainer in accordance with localregionalnationalinternational regulations. Other hazards which do not result in classification: Section 3 COMPOSITIONINFORMATION ON INGREDIENTS Chemical Name CAS No. Concentration% Sulfur % Section 4 FIRST AID MEASURES

7 Description of necessary first aid measures If inhaled: If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician. In case of skin contact: Wash off with soap and plenty of water. Consult a physician. In case of eye contact: Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. If Ingestion: Rinse mouth with water. Consult a physician. Most important symptomseffects, acute and delayed: Indication of immediate medical attention and special treatment needed, if necessary: Section 5 FIREFIGHTING MEASURES Suitable extinguishing media: Use foam, chemical power or water spray. Special hazards arising from the chemical: The material is a kind of flammable solid. It may burn at high temperature and fire and release toxic fumes. Special protective actions for fire-fighters: Wear self-contained breathing apparatus for firefighting if necessary. Use water spray to cool unopened containers. In case of fire in the surroundings, use appropriate extinguishing media. Section 6 ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures: Use personal protective equipment. Avoid breathing vapors, mist or gas. Ensure adequate ventilation. Remove all sources of ignition. Evacuate personnel to safe areas. Environmental precautions: Do not enter into spillage area. Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Methods and materials for containment and cleaning up: Contain spillage, and then collect in an clean container according to local regulations Section 7 HANDLING AND STORAGE Precautions for safe handling: Wear protective gloveseye protectionface protectionprotective clothing. Avoid contact with skin and eyes. Avoid inhalation of vapor or mist. Keep away from sources of ignition - No smoking. Conditions for safe storage, including any incompatibilities: Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Keep away from flammable materials and oxidizers. Section 8 EXPOSURE CONTROLSPERSONAL PROTECTION Control parameters: Source Material TWA China Occupational Exposure Limits for Hazardous Sulfur 8 mgm 3 Agents in the Workplace - Dust Appropriate engineering controls: Local exhaust ventilation or a process enclosure ventilation system may be required.

8 Individual protection measures Eyeface protection: Safety glasses with side shields. Chemical goggles. Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. Skin protection: Wear chemical protective gloves, e.g. PVC. Wear safety footwear or safety gumboots, e.g. Rubber. Impervious clothing, Respiratory protection: Selection of the Class and Type of respirator will depend upon the level of breathing zone contaminant and the chemical nature of the contaminant. Thermal hazards: Section 9 PHYSICAL AND CHEMICAL PROPERTIES Appearance (physical state, colour etc) Odour Odour Threshold ph Melting pointfreezing point Initial boiling point and boiling range Flash point Evaporation rate Flammability (solid, gas) Upperlower flammability or explosive limits Vapour pressure Vapour density Relative density Solubility(ies) Partition coefficient: n-octanolwater Auto-ignition temperature Decomposition temperature Viscosity Yellow mass solid. γ-sulfur:107 ;β-sulfur:115 ; amorphous sulfur: gm³ Insoluble in water Section 10 STABILITY AND REACTIVITY Reactivity: Chemical stability: The material is stable in normal temperature. Possibility of hazardous reactions: On combustion, forms toxic and corrosive gases of sulfur oxides including sulfur dioxide. Reacts violently with strong oxidants, especially if powdered. This generates fire and explosion hazard. Conditions to avoid: Spark, high temperature and static electricity. Incompatible materials: Strong oxidizer and flammable materials. Hazardous decomposition products: SO 2 and SO 3. Section 11 TOXICOLOGICAL INFORMATION Information on the likely routes of exposure: Inhaled, swallowed, skin, eyes. Symptoms related to the physical, chemical and toxicological characteristics: Acute health effects: Accidental ingestion of the material may be harmful and cause cough and throat irritation. Oral intake may cause headache, giddiness, vomit and other symptoms. This

9 material may produce skin and eyes irritation. Chronic health effects: Repeated or prolonged contact with skin may cause dermatitis. The substance may have effects on the respiratory tract. This may result in chronic bronchitis. Numerical measures of toxicity(such as acute toxicity estimates): LD50(Oral, rat): >2000 mgkg LD50(Dermal, rat): >2000 mgkg LC50(Inhalation, rat): >5.43 mgl4 h Section 12 ECOLOGICAL INFORMATION Toxicity: Persistence and degradability: Low. Bioaccumulative potential: Low. Mobility in soil: Low. Other adverse effects: Section 13 DISPOSAL CONSIDERATIONS Disposal methods: Burial in a land-fill specifically licensed to accept chemical. Reuse of broken container is forbidden. Section 14 TRANSPORT INFORMATION UN number: UN proper shipping name: SULPHUR. Transport hazard class(es) : 4.1. Packing group, if applicable: III. Environmental hazards: Special precautions for user: Section 15 REGULATORY INFORMATION Regulations: This safety data sheet is in compliance with the following national standards: GB , GB , GBT , GB , GB , GB , GB , GB , GB , GA , GBZ as well as the following national regulations: Dangerous Goods Transport Administrative Regulation [Published by the Ministry of Railways, 2008], Dangerous Chemicals Safety Administrative Regulation [Published by the State Council, 2011]. Section 16 OTHER INFORMATION References UN Recommendations on the Transport of Dangerous Goods Model Regulations UN Globally Harmonized System of Classification and Labelling of Chemicals Form Date 8-June-2015 Note 1: When products contain two or more hazardous substances, Safety Data Sheets should be prepared based on the risk of the mixture.

10 Note 2: Manufacturer supplier should ensure the correctness of the information contained in the safety data sheets, and updated in a timely manner. Note 3: As a result of product features without the existence of certain information or no data available (such as boiling point does not exist for the solid) in the table with "" logo.

11 硫 Sulfur UN 1350

CODE: PRODUCT NAME:Sodium hydroxide Danger Keep out of the reach of children. Read label before use. Harmful if swallowed. Harmful in contact with ski

CODE: PRODUCT NAME:Sodium hydroxide Danger Keep out of the reach of children. Read label before use. Harmful if swallowed. Harmful in contact with ski 编码 : 产品名称 : 固体氢氧化钠危险儿童不得接触使用前请读标签吞咽有害皮肤接触有害造成严重皮肤灼伤和眼损伤对水生生物有害预防 : 不要吸入粉尘烟气体烟雾蒸气喷雾作业后彻底清洗使用本产品时不要进食饮水或吸烟避免释