SA2-19 9 9 91 2 ( ) Part A () () () IR () Part B () () () () ph () () Part C () () 1
( ) A. ( ) (5ml) ( ) ( 2 2mm 1 1mm) B. (1K5.1K27K1K) (12V) IC741 (2K2K) ( ) (16V 47µ47µ) IR(Spectrometer 55Nicolet) ph (Nikon) SP-87 Part A Cu 2+ IR 2 Cu 2+ ph
Part B 1. I Cu 2 2Cu 2 4I 2CuII 2 (I 2 ).1M (Na 2 S 2 O 3 ) I 2 2Na 2 S 2 O 3 2NaINa 2 S 4 O 6 Na 2 S 2 O 3 Na 2 S 2 O 3 I 2 Cu 2 2. 9 3. (IR) - 4. (C 8 H 8 SO 3 ) n CO 2(g) SO 2(g) H 2 O (g).1m NaOH (aq) (.1M1ml) NaOH ( ) 3 3I 2 6NaOHNaIO 3 5NaI3H 2 O 3
5. 1 1 (1) ( ) ( ) 1 A 1 A B ( ) 2 1 1ml/ 3 ( ) 4
Part C 1. 15mL 8~9 2g 1 5% 5mL 2. 3. IR 1 KBr 5m 2KBr IR (background) 4 sample KBr (51) 5m 5 IR background sample IR 1 2 IR.39g ( CO 2 SO 2 H 2 O).1M 1ml 4. 1ppm2ppm3ppm4ppm 5ppm1ppm15ppm2ppm25ppm3ppm35ppm4ppm 5ppm 1ml 25ml 1g 3 24 SP-87 (C) (QmgCu 2 /g )C v.s Q C v.s C/Q 5. ( ) 5
1 35mL.8M 1 25mL 1mL 6M 3g KI.1M 1.5mL 2g KSCN 15.8M.4M.2M.1M 1 1 ( 1mL/) 1mL 1ppm 3M SP-87 ph 6. (1) 1 35mL 1 25mL (2) 1 1 25mL 7. 1 6 2mL 1 ~6 2 7mL.25M 1 2 8. ( ( ) ) (CaO) 13 13 7.4! Part A 6
5% (2 ) ( ) 2 3 (5X 1X) ( 5X 1X) ( 5X 1X) 3 ( 5X 1X) 7
IR IR (Wavenumbercm 1 ) (4) ) (SO 3 H) 115~125cm 1 15cm 1 31~35cm 1 6~7cm 1 IR 1~12cm 1 (5) 4 IR 5 IR 8
15.5mL 36.4% ( ) 1. 7 Langmuir (R 2.99) (C>1ppm) 8 Freundlich (R 2.7) 6. Adsorption (mgcu 2+ /g PS gel) 4. 2... 1. 2. 3. 4. 5. [Cu 2+ ] (mgcu 2+ /L) 6 1. 1. C/Q 8. 6. 4. 2. Adsorption (mgcu 2+ /g PS gel). 1.. 1. 2. 3. 4. 5. C (mgcu 2+ /L) 1. 1. C (mgcu 2+ /L) 7 8 Langmuir 9 Freundlich ( )
2. 9 1 9 (2ppm) 1 (5ppm) Part B ( ) 1. 11 (ml) 12 18 16 14 12 1 2 3 4 5 6 11 1
(g).6.5.4.3.2.1.55.29.2 12 2 2. 3. 13 21 5 94 4. 16~24 24 ( ) 15 16 ( ) 1 16 V( ) 14 12 1 8 6 4 2 1 5 9 13 17 21 25 29 33 37 41 45 49 53 57 61 65 69 73 77 81 85 89 93 97 T() 13 : 1ppm : 1ml/ 11
12 1 C(ppm) 8 6 4 2 14 T() : 1ppm : 1ml/ 1 5 9 13 17 21 25 29 33 37 41 45 49 53 57 61 65 69 73 77 81 85 89 93 97 8 7 (%) 6 5 4 3 2 1 15 1 (g) (g) (%).94.5 53.19.188.124 65.96.333.252 75.68 12
5. 13 14 1 15 B-1 B-2 SO 3 H B-1 CH CH 2 CH CH2 HC CH 2 SO 2 n SO 3 H B-1 CH CH 2 B-2 6. 11 1 1. 16.1M 17 6 (ml) 18 16 14 12 1 8 6 4 2 17.2 9.75 4.75 2.3 13.55 13.5 6.65 6.4 3.5 12.85 13 12.85 12.85 6.1 6.5 6.5 6 2.6 2.5 2.5 2.3 2.3 1.3 1.2 1.95.83.75.8M.4M.2M.1M 1 2 3 4 5 6 16 13
(ml) 2.5 2 1.5 1.5 1 2 3 4 5 6 7 8.1M 2.3 1.3 1.2 1.95.83.75.75.75 17.1M 2. 1 18 5 43.5 (%) 4 3 2 21.2 31.8 35.8 1.8.4.2.1 (M) 18 1 3. ppm(mg/l)! 4. 19 5. 2ppm1ppm5ppm 44.44% 44.86%83.62% 14
V( ) 18 16 14 12 1 8 6 4 2 5 15 25 35 45 55 65 75 85 95 15 115 125 135 145 155 165 175 185 19 T() : : 1ml/ 1. 1ml/ 5ml/ 1ml/ 2. 2 (5ml/) (39 ) (1ml/) (24 ) 3. 1mL/ 5mL/ 7.%74.23% 4. V( ) 9 8 7 6 5 4 3 2 1 1ml/ 5ml/ 1 6 11 16 21 26 31 36 41 46 51 56 61 66 71 76 81 T() 2 : : 1ppm 15
ph (21) 1. ph 2.263.554.3 5.42 11.32%23.64%48.56%29.91% 2. ph5.42 Cu ph4.3 5.42 ph4.3 ph5.42 3. ph H 16 V( ) 14 12 1 8 6 ph=2.26 ph=3.55 ph=4.31 ph=5.42 4 2 1 11 21 31 41 51 61 71 81 91 11 111 21 ph T() : : 5ml/ 1. 22 5 131 19 2. 1 3 5 56.45%51.66%4.55% 3. 2.5V 4. 1mL1ppm 1mL 1 3 5 5 4mL SP-87 23 1 16
18 16 14 V( ) 12 1 8 6 4 2 1 11 21 31 41 51 61 71 81 91 11 111 121 131 141 151 161 171 181 22 T() : : 1ppm : 5ml/ C(ppm) 1 9 8 7 6 5 4 3 2 1 1 3 5 5 1 15 2 25 3 T() 23 : : 1ppm : 5mL/ 1 ( ) 24 1 17
4~5 (ml) 12 1 8 6 4 2 1.4 8.3 6.6 4.7 3.4 2.3 1.6 1.1.7.5.4.3 1 2 3 4 5 6 7 8 9 1 11 24 Part C 1. 25 6 36% (8 36%) 2. 26 6 (ml) 3..8.7.6.5.4 1 2 3 4 5 6 25 18
(ml).5.45.4.35.3.25.2.15.1.5.45.45 26 1. ( ) ) 2. (CaO) ( ) 3. 13 13 7.4 ( 27) 4. 9.98 13.2 (9.98g) (13.2g) 27 19
1. 5% IR 36.4% 2. Langmuir 3. 4. 1 AB 2 3 (75.68%) (65.96%) (53.19%) (1) (2) 5. 6. 7. ph ph4.3 ph2.26 8. 1 3 5 9. 1 1. 2
11. 13 13 7.4 1. 2. http://www.ptepb.gov.tw/unit91/polilone/life.htm 3. MORRISONBOYD p.436~p.437 67 4. George Odian () p.872~p.873 78 5. (1996) 43 5 p.19~p.52 6. http://w3.ev.ncu.edu.tw/w3backup/accomplishment/paper/six/6.htm 7. http://www.ev.nchu.edu.tw/l61/tlhuang/ling_master/chap2.htm 8. p.329~p.338 7 9. Lloyd I. Osipow p.51~p.56 69 1. (1997) p.165~p.172 11. p.98~p.99 68 12. (21) p.17~p.26 13. - http://www.dfmg.com.tw/dasp/ dfaux-1/wa4-2.htm 14. http://www.biocozy.com.tw/watertre.htm 15. p.122~p.164 7 21