1. () 2. () CPC joe8688@ms17.hinet.net 0933-763586 2014 2 1. 2. 3. 4. 5. 烟 2014 3 2014 4 2014 5 2014 6
(1) (2) (3) (4) (5) (6) 1. 2. 3. 4. 5. 6. 7. 8. 9. 10. 11. 12. 2014 7 2014 8 93511 4 4 1 400 9 1 2010/10/13 11:01 2014 9 2014 10 (57) 30 1140 2 2 (20110810 / ) 2001-08-16/ /18/ 2014 11 2014 12
0.01 0.05 2011-04-14/ /A10/ 2014 13 2014 14 1 2011413 201017 (nickel hydrazine perchlorate) CSB 2014 15 2014 16 2008 23 10 60 t-butyllithium (, ) t-butyllithium 43% 116 15 ( ) 32 15 H ( 201212 ) 20130907 2014 17 2014 18
4 (3 1 ) (86/12-91/6) 6.6 ( 330 ) ( ) ( ) / 1 (3.7%) 1 3 (11%) 3 4 2 (7.4%) 11 4 (15%) 38 10/27 4 1 (3.7%) 1 6 (22%) 16 5 (19%) 5 1 (3.7%) 3 3 (11%) 12 26 837 2012/02/02 2014 19 2014 20 (86/12-91/6) 22 8 10 4 44 23 8 0 4 0 3 1 8 1993-10-21/ /07/ 1979-07-17/ /03 2 432 4 31 37 41 2003-11- 22/ /1/ 31 300 2014 21 2014 22 Chemical Abstracts. Service CA CAS. NO. 196971 CA CAS. NO. 1-201381622:52:25 CAS - 萘 4-73,008,476 5 2014 23 2014 24
20121030PM09:27:03 2014 25 2014 26 / / 1 2 3 4 5 6 7 2014 27 2014 28 1800 30 1800 1 + 1600 + 200 1800 ( ) : http://news.ftv.com.tw/newscontent.aspx?ntype=class&sno=201190 7C08M1 http://tw.nextmedia.com/applenews/article/art_id/33650434/issueid /20110907 2014 29 2014 30
6 *1 *2 (9) (10) (11) 3 2014 31 2014 32 6 1 / / 2 / 3 // 4 / / ( ) / / / 5 / 6 7 / / / / / / / / 8 / / / / / 9 / 10 / / / 11 / 12 / / 13 / / 14 / / / / ( / / / ) / / 1 SOP 2 / / / / 3 4 / / / 2014 33 2014 34 10 1 2 3 4 1 2 14 3 CNS15030 11 CNS15030 1 2 3 4 5 17 12 1 2 3 1 2 3 ( ) 13 1 2 3 14 / / / 2014 35 2014 36
18 1 2 3 4 5 6 / 1 2 3 4 2014 37 2014 38 ppm mg/m 3 4 Acetone (CH 3 ) 2 CO 750 1780 31 Benzene C 6 H 6 1 3.2 75 Chlorine Cl 2 0.5 1.5 182 Ethyl acetate CH3COOC2H5 400 1440 209 Formaldehyde HCHO 1 1.2 226 n-hexane CH3(CH2)4CH3 50 176 237 Hydrogen sulfide H2S 10 14 443 Toluene C6H5CH3 100 376 452 Trichloromethane CHCl3 (Chloroform) 10 49 481 Xylene (o-m-p-) C6H4(CH3)2 100 434 2014 39 M (g/gmole) (mg/m 3 ) (ppm) 24.45 24.45 25 1atm760mmHg 2014 40 ppm mg/m 3 f/c.c. 1.1.2.2-1.2- mg/m 3 ppm ( M 24.45) 1 PEL-TWAPEL-STELPEL-C 110-10100 PEL-STEL=PEL-TWA E.F 1.4 * 1001000 1-2- 1000 1.1.1- * 1.1.2- 呋 2 * * * / // 2014 41 2014 42
300 腈 - 100 ( ) 50 50 * * * 65 ** 7 ** 10 ** 30 40 4065 2014 43 2014 44 1-3 ( 2 / 6 ) 34 4-6 ( 3 / 6 ) ( ) 7-11 / / 12. / / ( 3 / 3 ) 13. 2014 45 2014 46 EXPLOSIVE ** 1 * POISON 6 FLAMMABLE LIQUID 3 2014 47 2014 48
2014 49 2014 50 MSDS 2014 51 2014 52 Acetone 2014 53 2014 54
2014 55 2014 56 Dust Gas Fume( 烟 )Smoke() Vapor Spray MistFog() Aerosol ppm% mg/m 3 f/cc 2014 57 2014 58 * * *VCM 皘 HCNTDIH 2 S HF * * *NH 3 CO SO 2 2014 59 2014 60
Lc50Ld50 TLVPEL 烟 2014 61 2014 62 IDLH 10ppm 750ppm 25mg/m 3 1000ppm 1780mg/m 3 200ppm 1mg/m 3 262mg/m -- 3 400ppm 5ppm 983mg/m 3 7.5mg/m 3 -- 100ppm 376mg/m 3 2ppm 5.2mg/m 3 100ppm 100ppm 435mg/m 3 lmg/m 3 80mg/m H 3 150ppm 2 SO 4 712mg/m 3 3ppm 5ppm HF 20ppm 16mg/m 2.6mg/m 3 3 50ppm 1ppm 269mg/m 75ppm 3 1.4mg/m 3 350ppm 1910mg/m 3 2014 63 IDLH 20000ppm 25000ppm 20000ppm 2000ppm 10000ppm 10000ppm -- 1000ppm l000ppm 2014 64 IDLH ppm 100 6 ( ) 40 5ppm 7.5mg/m 3 0.05ppm 0.16mg/m 3 0.1ppm 0.1mg/m 3 0.3ppm PH 0.4mg/m 3 3 0.1ppm 0.63mg/m 3 5ppm SiH 6.6mg/m 3 4 0.5ppm 1ppm 2.8mg/m 3 10ppm 29mg/m 3 200 -- -- -- -- 2000 2014 65 2014 66
2014 67 2014 68 59 2 45 1. 2. 3. 4. 5. 8 (81-125)+(82) 5 81 *1- *2-3- 4- *5-6- 7- *82 6 9 8 81-125 3 7 1 2 2014 69 2014 70 40-49 40 37-2-1(1) 3 / // 30 / 42 15-115-2 / / / 37-2 30-300 / 12-4 / 30-100 41 1 / // 18 43 3-30 6-1/16-1 37-2-2(3) 10-1/11-1/23-2 6-1/12-1/12-3/14-2/16-1/19-1/24/31-1/31-2/37-1/37-18-1/29-1/30-1/30-2/37-4( ) 2 6-2 / 36-1 15-1 15-2 / / / / ( / ) 2014 71 2014 72
44 3-15 / 20-200 / 3-30 /10-100 / 1 7-3 10-2 3-15 / 2 7-1/8-1/13-1/14-1 20-200 / / / / 3 7-3 /9-1 3-30 / 4 10-100 5 7-1/8-1/9-1 /14-1 / / / 45 3-15 6-2/12-4/20-1/20-2/21-1/21-2/22-1/23-1/32-1/34-1/38 17/18-3/26-28/29-3/33/39-4 36-1 46 20-632-334-2 3000 2014 73 (20-6) (32-3) (34-2) 3000 (46) 2014 74 1. 2. MSDS 3. 4. 5. 6. 7. 8. 9. 10. 11. 12. 13. 14. SOP 1. 2. 3. 4. 5. / / / / / / / / / / / / / / ( / ) /4S/ / / / /5S/ /SOP / / / 2014 75 2014 76 1. 2. 3. 4. 5. 6. 0933-763586 joe8688@ms17.hinet.net 2014 77 2014 78
*2 1 2 3 ( / / ) ( ) 11 *1 1 2 3 4 5 12 (1020703) *1 1 *3 2 1 3 ( / / / / // / / / ) 2 1 2 3 4 1 2 3 *4 5 6 1 2 7 ( ) 13 *1 1 2 3 14 *1 1 2 2 *2 ( 1 29-1-3/30-1-5 3 1 2 2 CNS15030 3 CNS15030 / ) 1 4 15 *1 ( ) 1 2 *2 5 1 2 16 *1 3 22 1 2 3 4 5 6 7 / 23 1 2 3 4 5 24 6 18 *1 2 6 *1 *3 25 1 2 / / / / 3 4 LEL30% 5 6 7 2M / 8 / 9 26 19 *1 / / / 20 *1 1 2 ( / / // / / ( / / ) / ) 3 *2 *2 / / / *6 21 *1 1 2 3 4 5 *2 22 *1 50 3 10 *1 ( 1 CNS15030 2 CNS15030 ) 1 2 3 4 1 () 2014 2 () 2014
36 *1 23 *1 1 2 ( ( ) ( / ) 3 ( 1 2 3 4 ) 4 5 *2 15-1 25 37 *1 *2 *26 *27 *4 *28 40 1 37-2-1 3 / // 30 2 36 41 1 1 18 37 37-2-2 18-1/29-1/30-1/30-2/37-4 36-1 38 42 1 15-115-2 37-2 30-300 2 12-4 30-100 43 1 3-30 10-1/11-1/23-2 6-1/12-1/12-3/14-2/16-1/19-1/24/31-1/31-2/37-1/37-2 6-2 15-1/15-2 44 1 7-3 10-2 3-15 2 7-18-113-114-1 20-200 / / / 3 7-3 *29 1 2 / 3 //// / / / 4 5 9-1 3-30 4 6 7 10-100 5 7-18-19-1 14-1 8 9 10 11 12 / 13 14 45 3-15 6-2/12-4/20-1/20-2/21-1/21-2/22-1/23-1/32-1/34-1/38 / / / 15 17/18-3/26-28/29-3/33/39-4 36-1 30 *1 46 20-632-334-2 3000 1 2 3 4 / 5 / / / / // ( )=() 6 () 7 () 8 () 9 () 10 / 1. (1. 2. 3. )(19-1) () 11 / / () 12 / () 13 2. ( / / / / / / / () 14 / / (29-1) () 3. (29-2) *2 4. (29-3) 1 2 3 () 4 5. / (29-4) () 5 () 6. / / (29-5) 31 *1 7. (29-6) 8. / / (29-7) 9. 1. ( )//2 //3. //4. (154). *2 32 *1 *3 *33 ( 1. ) 2.3M (170) 34 *1 *2 3. (171) 3 () 2014 4 () 2014
4. // // LEL30 (177). 5. //(168-179) () 50M 6. (184-1) () 50M () () 1000M 15M () 15M 500 1. (C5) () 7M 100 60 2. 1.8M 2M (C35) 3. (C11) 4. (21 1) 5. (21 2) *1. 2M (C19) 6. (41) 2. 90 (C20) 7. 3 (237) *3. (C21) 8. (238) 4. 7M (C22) 9. (C11 1) *5. 2M (224) 10. (159) *6. 2M ( 224 ) (225) 11. 1.5M 2M 10 2.5M (161-163) 7. 30 (227) *8. 1.5M 1.5M (228) 9. 40 <3 (C48) 10. 2F7.5M (C151-1-2) 1. TOSHMS(23) 11. 30 (229) 2. 29/99/299/499// (500 ) (/999/1000 ) 12245 112345 12. 75 (230) 3. 13. (232) ( 14. *(1 )2M 4. 1. 2. 3. (3) (2 ) 2M * 5. CNS14253 (281) (3-1) 6. (238) 7. (C11 1) 8. 1. 2/62. 3/63. 3/3 (17-1) 1.CNS 2. 3. 28 4. 2. 5. 3. 6. 2M / / / / / 7. / // /30 / / // 1.5M // 2F 7.5M 2M *1. (88-92) 1. 3 2. 3. 4. 5. 4. (7) 6. 7. 8. 9. 10. (1hr) *2. (98-102) / /() / / / / / / / / / 1 5 10 / / 2 10 7 O 2 18 H 2 S10PPM CO35PPM 3 4 5 ( 26 )... 5 () 2014 6 () 2014
( ) 5 59 / / / 6 7 8 60 61 59 9 62 10 63 11 12 13 14 6 15 16 7 8 17 18 19 20 21 21-1 9 5 6 / / 7 3 12 1 2 3 4 4 13 1 2 3 4 7 () 2014 8 () 2014
14 / / 15 16 / / 17 / / / 18 1 3 1, 10 2 ppm 19 10, 100 1.5 mg/m 3 20 1 2 18 3 100, 1000 1.25 f/cc 4 21 5 1000 1 21 22 23 / 24 ppm mg/m 3 4 Acetone (CH 3 ) 2 CO 750 1780 31 Benzene C 6 H 6 / 1 3.2 6 75 Chlorine Cl 2 0.5 1.5 182 Ethyl acetate CH 3 COOC 2 H 5 400 1440 7 209 Formaldehyde HCHO 1 1.2 8 226 n-hexane CH 3 (CH 2 ) 4 CH 3 50 176 237 Hydrogen sulfide H 2 S 10 14 253 Isopropyl alcohol (CH 3 ) 2 CHOH 400 983 9 443 Toluene C 6 H 5 CH 3 100 376 10 / 452 Trichloromethane CHCl 3 (Chloroform) 10 49 481 Xylene(o-m-p-isomerC 6 H 4 (CH 3 ) 2 100 434 / / / / / 17 (g/gmole) (mg/m 3 ) (ppm) 24.45 24.45 25 18-29 // / / / / / / / / / 30 31-36 / / / / 10 10 mg/m 3 30mg/m 3 37 %SiO 2 +2 %SiO 2 +2 10 1 mg/m 3 4 mg/m 3 38-50 / / 0.15 f/cc / 1 2 3 4 / / / 5 mg/m 3 10 mg/m 3 ( / / / / ) 5 7 8 9-10 / 85 / / / ( ) / 16 / / // 3 // 30 // 10 // 3 9 () 2014 10 () 2014