( ) Esfenvalerate CAS. 66230-04-4 S - -cyano-3-phenoxybenzyl-s-2-4-chlorophenyl -3-methylbutyrate C25H22ClNO3 419.91-7 mp 60.6-61.5, 59-60.2, 59 2.63 x10 mmhg20-7, bp 151-167 5.0 x10 mmghg 25 0.3ppm / 25,,,,,DMSO, DMF, LD50 88.5 mg/kg (, ADI 0.02 (mg/kg/ ),,,,, Fenvalerate S,S 19,,,, 2588-32 -
( ) Fenvalerate CAS. 51630-58-1 4-Chloro- - 1-methylethyl benzeneacetic acid cyano 3-phenoxyphenyl methyl ester C25H22ClNO3 419.91-8 mp 37-54,23 1.1 x10 mmhg 25 10Pa 20 bp 300 4.9 kpa 1ppm 20 / 23,,, LD50 451 mg/kg(dmso) (, ADI 0.02 (mg/kg/ ),,,, 172t,,, 105kL, 71t '94 1983, 2902, IARC 3-33 -
( ) Hexachlorobenzene HCB CAS. 118-74-1 Perchlorobenzene CCl 6 6 284.78-5 mp 231, 230 1.09 x10 mmhg20 bp 332, 323-326, 0.133kPa 114 0.005ppm 25 / 0.62g/100mL LD50 10,000 mg/kg (, ADI (mg/kg/ ),1979,POPs, 2729-34 -
( ) Hexachlorocychlorohexane - - HCH, BHCbenzene hexachloride CAS. - 58-89-9 Lindane-HCH - 319-85-7 HCH 608-73-1 1,2,3,4,5,6-Hexachlorocyclohexane CHCl 6 6 6 290.83 - -, -6 - mp 112.9, 113-9.4x10 mmhg, 0.03 mmhg bp 323 0.013Pa 20 - mp 312, 309-310 - - 7.3mg/L / - 5mg/L -,,,, - LD50 88mg/kg ( ), 91mg/kg ADI 0.008 (mg/kg/ ) ( ), 76, 100mg/kg (, 0.0125 (mg/kg/ ) - LD50 18g/kg (,,,, 1949, 1971, - 2761, - HCH -, -, -, - - -,, -35 -
( ) Heptachlor Drinox, Heptamul CAS. 76-44-8 1H-1,4,5,6,7,8,8-Heptachloro-3a,4,7,7a-tetrahydro-4,7-methanoindene C10HCl 5 7 373.32, -4 mp 95-96 3x10 mmhg25 bp 135 0.053 Pa 25 0.056ppm 25 /,,,,, LD50 100( ), 162( ) mg/kg(, ADI 0.0005 (mg/kg/ ), 1950, 1972, 1986,,POPs, 2761, IARC 3-36 -
( ) Heptachlor epoxide CAS. 1024-57-3 1,2,,4,5,6,7,8,8-Octachloro-2,3,3a,4,7,7a-hexahydro-4,7-methano-1H-indene C10HCl 5 7O 389.32 mp 157-160 bp 200 0.35ppm 25 / 0.0275mg/100mL LD50 62 mg/kg(, ADI (mg/kg/ ) 1950, 1968, 1986,POPs -37 -
( ) Kelthane Dicofol CAS. 115-32-2 2-Chloro- - 4-chlorophenyl - - trichloromethyl benzenemethanol C14HCl 9 5O 370.49 mp 78.2-79.5, 77-78 0.053Pa 25 bp 225 0.8mg/L, / 0.01g/100mL22, UVmax 226, 258, 266, 276nm 4.43, 2.82, 2.85, 2.60, LD50 1,495, 575mg/kg(, ADI 0.002 (mg/kg/ ),, 88t, 105t, 98t,89t '94 1957, 2761, IARC 3-38 -
( ) Kepone Chlordecone CAS. 143-50-0 1,1a,3,3a,5,5a,5b,6-Decachlorooctahydro-1,3,4-methano-2H-cyclobuta cd penta- len- 2-one C10Cl10O 490.64-7 mp 350 3x10mmHg25 4,000ppm 100 / 0.00076g/100mL,,, LD50 125, 95 mg/kg (, ADI (mg/kg/ ),,,, 2761-39 -
( ) Malathion CAS. 121-75-5 Dimethoxyphosphinothioyl thio butanedioic acid diethylester C10H19OPS 6 2 330.36-5 mp 2.9, 4x10 mmhg30 bp 156-157 0.7 mmhg, 0.0053Pa 30,156-157 0.093kPa 120ppm 30 / 0.0145g/100mL,,,,, ph 7.0 5.0 ph 5.26 LD50 1,000( ), 1,375 ( )mg/kg( ADI 0.02 (mg/kg/ ),,, 302t, 291t, 24kL, 30kL '94 1953,,, 3082 3018, 2783,IARC 3-40 -
( ) Mancozeb Manzeb CAS. 8018-01-7 1,2-Ethanediybis carbamodithioato 2- manganese mix. with 1,2-ethanediybiscarbamodithioato 2- zinc ethylenebisdithiocarbamic acid manganese zinc complex CHNSMn 4 6 2 4 x Zn y x:y=10:1 265.3 mp192-204, 192-194 mmhg 6.2ppmpH7.25, / 6-20ppm LD50 5,000mg/kg(, ADI 0.03 (mg/kg/ ),,, 4559t,,, 1107t 3,452t '94 1969, 2210-41 -
( ) Maneb CAS. 12427-38-2 301-03-1 1,2-Ethanediylbis carbamodithioato 2- manganese ethylenebisdithiocarbamic acid manganese CHNSMn 4 6 2 4 n 265.3 mp mmhg /, LD50 g/kg(, ADI (mg/kg/ ),,,, 378t,, 1,507t, 1,204t '94 1956,,, 12,, 2210 2968,IARC 3-42 -
( ) Methomyl Lannate Nudrin CAS. 16752-77-5 N-Methylamino carbonyl oxy ethaimidothioic acid methy ester CH 5 10NOS 2 2 162.21 mp 78-79 0.007Pa25 bp 144 5.8g/100mL 25 /,,, LD50 17mg/kg(, ADI 0.03 (mg/kg/ ),,, 646t, 143t, 447t '94 1970,,,, 2757 Z- - -43 -
( ) Methoxychlor DMDTMarlateMoxic Sixanol CAS. 72-43-5 1,1'- 2,2,2-Trichloroethylidene bis 4-methoxybenzene C16H15Cl3O2 345.65, mp 78-78.2, 86-88 mmhg p,p'- mp 89 bp 346 0.1ppm 22 / 0.0m1g/100mL,,, DDT LD50 6.0, 5.0g/kg(, ) ADI 0.1 (mg/kg/ ), 1960, 2761 p,p'- 88% -44 -
( ) Metiram Polyram CAS. 9006-42-2 Zinc ammonate ethylenebisdithiocarbamate poly ethylenethiuram disulfide ethylenebisdithiocarbamic acid manganese C16H33N11S16Mn3 x 1088.7 x mp140 mp 0.010 mpa 20 / 0.3pH 7,, LD50 10,000 mg/kg(, ADI 0.03 (mg/kg/ ),,,,, 19,1975-45 -
( ) Metribuzin Lexone Sencor Sencoral CAS. 21087-64-9 4-Amino-6-1,1-dimethylethyl -3- methylthio -1,2,4-triazin-5 4H -one CH 8 14NOS 4 214.29 mp 125-126 0.058 mpa20-5 10 mmhg20 1,050ppm 20 /,,,,,, LD50 2,000mg/kg, 2,200 mg/kg ADI 0.0125 (mg/kg/ ) (, 0.013mg/kg/day 40t,,, 22t '94 19-46 -
( ) Mirex Hexachloropenntadiene dimer CAS. 2385-85-5 Dechlorane 1,1a,2,2,3,3a,4,5,5a,5b,6-Dodecachlorooctahydro-1,3,4-metheno-1H-cyclobuta- cd pentalene C10Cl12 545.54-7 mp 485 3x10 mmhg 25 0.6, 0.20ppm 24, 0.1g/100mL24 /,,,,, UV:219.5 nm Log e= 2.0 LD50 235mg/kg, 600 mg/kg(, ADI (mg/kg/ ) Fire ant:,,,,pops, IARC 2B -47 -
( ) Nitrofen NIP TOKniclofen CAS. 1836-75-5 2,4-Dichloro-1-4-nitrophenoxy benzene C12H7Cl2NO3 284.10-6 mp 70-71 8x10 mmhg40,1.06 mpa bp 180-190 40,0.266mPa 250 0.7-1.2ppm22 / 3.4 0.1g/100mL21,,,,,n- LD50 3.58g/kg, 740 mg/kg(, ADI (mg/kg/ ),,,,, 1963,1982, 2779 2588, IARC 2B -48 -
( ) 4-4-Nitrotoluene CAS. 99-99-0 p-nitrotoluene p-methylnitrobenzene, CHNO 7 7 2 137.14, mp 53-54, 54.5 0.173 kpa65 bp 238, 238.2 160ppm 20 / 2.41 0.1g/100mL20.5,,,, LD50 1,960mg/kg(, ADI (mg/kg/ ),, 1,800t '85 2,4- B,,, 1664-49 -
( ) trans- trans-nachlor CAS. trans-39765-80-5 3734-49-4 1,2,3,4,5,6,7,8,8-nonachloro-2,3,3a,4,7,7a-hexahydro-4,7-methano-1H-indene C10HCl 5 9 444.23 mp 128-130 mmhg25 6.4 x10-2 g/ml, /,,,,, LD50 500 mg/kg(, ADI 0.0005 (mg/kg/ ) 1950,1972,,1986,POPs trans-, cis-chlordane, trans-, cis-nonachlor, oxychlordane -50 -
( ) Octachlorostyrene CAS. 29082-74-4 pentachloro trichloroethenyl benzene CCl 8 8 379.71 mp mmhg25 25 / 6.29,,,,, LD50 3,710 mg/kg(, ADI (mg/kg/ ) -51 -
( ) Oxychlordane CAS. 27304-13-8 2,3,4,5,6,6a,7,7-Octachloro-1a,1b,5,5a,6,6a-hexahydro-2,5-methano-2H-indeno- 1,2-b oxirene C10HCl 4 8O 423.74 mp 98-101 mmhg25 /,,,,, LD50 457 mg/kg (, ADI 0.0005 (mg/kg/ ) trans-, cis-chlordane 1950, 1972, 1986,POPs trans-, cis-chlordane, trans-, cis-nonachlor, oxychlordane -52 -
( ) Polybrominated biphenyls PBBs polybromobiphenyls CAS. 67774-32-7 59536-65-1 C12HBr 4 6 627.59 C12HBr 9 C12Br10 C12HBr 4 6-5 C12HBr 4 6:mp72,119-121 C12HBr 4 6:7.6 x10 mmhg90 C12HBr 2 8:mp 200-250 C12Br 10:mp 380-383 0.1g/100ml18 / C12HBr 4 6: 11 g/kg C12HBr 2 8: 20-30 g/kg LD50 21.5g/kg(, ADI (mg/kg/ ), PBBs,, 2,2',4,4',5,5'-hexabromobiphenyl mp 119-121, 1973 BP-6,, BP-6-53 -
( ) Polychlorinated biphenyls PCBsAroclorClophen Kanechlor CAS. 11097-69-1 27323-18-8 1336-36-3 polychlorobiphenyls C12HCl 9 C12Cl10 327-5 mp 10-253, 233-253 6x10 mmhg20,0.01pa -2 bp 603-648 25, 10 Pa 20, / 6.30 10-0.01 g/ml 5.58-6.57 congener, isomer LD50 5mg-10g/kg, 1.3-11.3g/kg (,ADI (mg/kg/ ),,,,,, 1972,1974,,, POPs, 2315, IARC 2A PCBs,, 10, 209 43 PCBs PCDFs Arochlor 1242, 1254, 1260,Kanechlor-200,-300,-400,-500,-600 100 Co-planar PCBs3,3',4,4'-TCB 0.001, 3,3',4,4',5-PCB 0.15, 3,3',4,4',5,5'-HCB 0.006-54 -
( ) Polychlorinated dibenzo-p-dioxins PCDDs CAS. 1746-01-6 2,3,7,8-TCDD 2,3,7,8-tetrachlorodibenzo- p-dioxin2,3,7,8-tcdd C 12HOCl 7 2 C12OCl 2 8 C12HOCl 4 2 4 2,3,7,8-TCDD: 321.97-10 2,3,7,8-TCDD:mp305-306 6.4 x10 mmhg20-9 PCDDs:mp 80-330 1.9 x10 mmhg 25 700-7 2,3,7,8-TCDD:2x10 g/kg / 25,7.2ng/L, 1.9ng/100-5 ml Koc= 4.68 x10,,, 1mg/ml 20-25,, 310nm LD50 283.7 g/kg(, TDI 5pg/kg / ( ) LD50 0.6-2.0 g/kg(, TWI 10 pg/kg / ( ) VSD 0.01 10pg/kg/day( ),,,, /,,,,,,,,,, 0.5ng/Nm, 3 80ng/Nm, 3 0.1ng/Nm, TDI 5,10 pg/kg/day, IARC 1 2,3,7,8-TCDD PCDDs 75,,, 2,3,7,8-TCDD, TEF 2,3,7,8-TCDD TEF=1.0 1,2,3,7,8- PCDD 0.51,2,3,4,7,8-HCDD 0.11,2,3,6,7,8-HCDD 0.11,2,3,7,8,9-HCDD 0.11,2,3,4,6, 7,8- HCDD 0.01OCDD 0.001 1976, 2,4,5-T, 2,3,7,8-TCDD, 2,4,5-T 2,3,7,8-TCDD -55 -
( ) Polychlorinated dibenzofurans PCDFs CAS. 51207-31-9 2,3,7,8-TCDF 2,3,7,8-tetrachlorodibenzofuran 2,3,7,8-TCDF C 12HOCl 7 C12OCl8 C12HOCl 4 2 4 2,3,7,8-TCDF: 305.98 mp mmhg25 25 / 2,3,7,8-TCDF TDI 5pg/kg / LD50 1,000 g/kg(, 10 pg/kg / ) LD50 6,000 g/kg(, TWI 0.01 10pg/kg/day LD50 5-10 g/kg(, VSD PCBs, 0.5ng/Nm, 3 3 3 80ng/Nm, 0.1ng/Nm, TDI 5, 10 pg/kg/ day, IARC 32,3,7,8-TCDF PCDFs 135 2,3,7,8-TCDD 1.0 TEF 10 2,3,7,8-TCDF 0.1 1,2,3,7,8,-PCDF 0.052,3,4,7,8-PCDF 0.5 1,2,3,4,7,8-HCDF 0.1 1,2,3,6,7,8-HCDF 0.1 2,3,4,6,7,8-TCDF 0.11,2,3,7,8,9-HCDD 0.11,2,3,4,6,7,8,-HCDD 0.01 1,2,3,4,7,8,9-HCDF 0.01 OCDF 0.001-56 -
( ) Pentachlorophenol PCPPentaPenchlorol CAS. 87-86-5 CHCl 6 5O 266.34-4 mp 190-191, 191 1.1 x10 mmhg20,16pa 100 bp 309-310, 309, 40mmHg 211.2, 0.02Pa20 80ppm 30 / 0.0014g/100mL,,, LD50 146( ), 175( )mg/kg(, ADI (mg/kg/ ),,,,,,,,, 1955,1963,1971,1990,, 3155-57 -
( ) p- p-octylphenol CAS. 1806-26-4, 27193-28-8 4-1,1,3,3-tetramethyl phenol, 4-octyl phenol, 1-Hydroxyoctyl benzene C14H22O 206.33 mp83.5-84.0 mmhg bp 276.0 760mmHg /,, LD50 2,160mg/kg, ADI (mg/kg/ ),,, 10,000t '95, -58 -
( ) nyl phenol CAS. 25154-52-3 C15H24O 220.35,, mp 2 0.01kPa 20 bp 293-297, 295 / 3.28,,,,, LD50 1,620 mg/kg(, ADI (mg/kg/ ),,,, 20,000t,,, '95,,,,,, 4, 3, Q,, A, 3145-59 -
( ) Permethrin CAS. 52645-53-1 3-2,2-Dichloroethenyl -2,2-dimethylcyclopropanecarboxylic acid 3-phenoxy- phenylmethy ester C21H20Cl2O3 391.29-6 mp 34-39, 34-35, 1x10 mmhg 50 bp 220 0.05 mmhg 10Pa 20 0.2ppm 30 / 0.02mg/100mL, 6.5, 6.1,,,, LD50 3,801mg/kg( ( ), ADI 0.05 (mg/kg/ ) LD50 539( ),464( )mg/kg(,,,, 26t, 154,,, t, 40t, 60kL, 10t, 8t, 18t '94 1985,,, 2902,IARC 3,, trans- -60%,cis- -40% -60 -