( ) ( ) () () CPC joe8688@ms17.hinet.net 0933-763586 103 1 2 3 4 5 6 2014 2
烟 2014 3 2014 4
2014 5 (1) (1) (2) (2) (3) (3) (4) (4) (5) (5) (6) (6) ( ( )1. ( ( ) ) ( ( )2. ( ( ) ) ( ( )3. ( ( ) ) ( ( )4. ( ( ) ) ( ( )5. ( ( ) ) ( ( )6. ( ( ) ) ( ( )7. ( ( ) ) ( ( )8. ( ( ) ) ( ( )9. ( ( ) ) ( ( )10. ( ) ( ) ( ( )11. ( ( ) ) ( ( )12. ( ( ) ) 2014 6
2014 7 93511 400 2014 8
2001-08-16/ /18/ 2014 9 2011-04-14/ /A10/ 2014 10
4 4 1 9 1 2010/10/13 11:01 2014 11 0.01 0.05 2014 12
1 2011413 2014 13 201017 (nickel hydrazine perchlorate) CSB 2014 14
2008 23 60 t-butyllithium (, ) t-butyllithium 43% 116 ( ) 32 H ( 201212 ) 2014 15 (86/12-91/6) / 1 (3.7%) ( ) 1 ( ) 3 (11%) 3 2 (7.4%) 1 (3.7%) 5 (19%) 11 1 5 4 (15%) 6 (22%) 1 (3.7%) 38 16 3 3 (11%) 12 26 837 2014 16
1993-10-21/ /07/ 1979-07-17/ /03 2 432 31 41 2003-11- 22/ /1/ 31 300 2014 17 - - 萘 4-2014 18
Chemical Abstracts. Service CA CAS. NO. 196971 CA CAS. NO. 1 201381622:52:25 CAS 73,008,476 5 2014 19 20121030PM09:27:03 2014 20
2014 21 2014 22
2014 23 2014 24
2014 25 2014 26
2014 27 2 45 1. 2. 3. 4. 5. 2014 28
2014 29 ( ) ( ) ( 4 / 3/ 100 ) ( ) 1 40,000*5 + 40,000*40 = ( ) 2 30,000*5 + 30,000*40 = ( ) 3 100= ( ) 2014 30
2014 31 2014 32 6 *1 *2 (9) (10) (11) 3
6 1 / / 2 / 3 // 4 / / / / / 5 / 6 7 / / / / / / / / 8 / / / / / 9 / 10 / / / 11 / 12 / / 13 / / 14 / / / / 1 2 / / / / 3 4 / / / 2014 33 10 1 2 3 4 1 2 11 1 2 3 4 5 12 1 2 1 2 3 ( ) 13 1 2 3 14 2014 34
14 CNS15030 CNS15030 17 2014 35 18 1 2 3 4 5 6 / 1 2 3 4 2014 36
2014 37 ppm mg/m 3 4 31 Acetone Benzene (CH 3 ) 2 CO C 6 H 6 750 1 1780 3.2 75 Chlorine Cl 2 0.5 1.5 182 Ethyl acetate CH3COOC2H5 400 1440 209 Formaldehyde HCHO 1 1.2 226 n-hexane CH3(CH2)4CH3 50 176 237 Hydrogen sulfide H2S 10 14 443 452 Trichloromethane ( ) (Chloroform) 481 Toluene Xylene (o-m-p-) C6H5CH3 CHCl3 C6H4(CH3)2 434 2014 38 100 10 100 376 49
M (g/gmole) (mg/m 3 ) (ppm) 24.45 24.45 25 1atm760mmHg 2014 39 ppm mg/m 3 f/c.c. mg/m 3 ppm ( M 24.45) 1 PEL-TWAPEL-STELPEL-C 110 10100 PEL-STEL=PEL-TWA E.F * 1001000 1000 * 2 ( ) ( ) ( ) * * ( ) * / // ( ) 2014 40
1.1.2.2-1.2- - 1.4 1-2- 1.1.1-1.1.2- 呋 ( ) ( ) ( ) 2014 41 腈 - ( ) ( ) ( ) 2014 42
300 100 ( ) 50 50 40 * * 4065 * 65 ** 7 ** 10 ** 30 2014 43 1-3 ( ) 4-6 ( ) ( ) 7-11 12. (33 ) 13. 2014 44
34 2014 45 2014 46
EXPLOSIVE ** 1 * POISON 6 FLAMMABLE LIQUID 3 2014 47 2014 48
2014 49 --- 2014 50
2014 51 2014 52
2014 53 MSDS 2014 54
2014 55 2014 56
2014 57 2014 58
2014 59 2014 60
2014 61 2014 62
2014 63 2014 64
2014 65 2014 66
(2014-08-01) 750-950 Propylene 2014 67 2014 68
2014 69 1030811 2014 70
2014 71 20..... ( ) 21..... ( ).. 23. ( ) 25.( ).... 26....( ) 27.... ( ) ( ) 28.( ) 29. ( )..... 30. ( ) 31.( ) / / 32. 34. ( ) 36...... ( ) 37. ( ).. SOP. 39. ( ) SOP 40. ( ) 49. 50. ( ) (18-50) 2014 72 ( )10. (1) (2) (3) (4)
2014 73 40-49 40 37-2-1( ) 3 / // 30 / 41 1 / // 18 6-1/16-1 37-2-2( ) 18-1/29-1/30-1/30-2/37-4( ) / 36-1 ( / ) 2014 74
42 15-1( )15-2 / / / 37-2 30-300 / 12-4 / 30-100 43 3-30 10-1/11-1/23-2 6-1/12-1/12-3/14-2/16-1/19-1/24/31-1/31-2/37-1/37-2 6-2 15-1 ( )15-2 / / / / 2014 75 44 3-15 / 20-200 / 3-30 /10-100 / 1 7-3 10-2 3-15 / 2 7-1/8-1/13-1/14-1 20-200 / / / / 3 7-3 /9-1 3-30 / 4 10-100 5 7-1/8-1/9-1 /14-1 / / / 45 3-15 6-2/12-4/20-1/20-2/21-1/21-2/22-1/23-1/32-1/34-1/38 17/18-3/26-28/29-3/33/39-4 36-1 46 20-632-334-2 3000 2014 76
(20-6) (32-3) (34-2) 3000 (46) 2014 77 0933-763586 joe8688@ms17.hinet.net 2014 78
103 ( ) ( ) () () CPC joe8688@ms17.hinet.net 0933-763586 1 2 3 4 5 6 2014 2 烟 2014 3 2014 4 (1) (1) (2) (2) (3) (3) (4) (4) (5) (5) (6) (6) ( ( )1. ( ( ) ) ( ( )2. ( ( ) ) ( ( )3. ( ( ) ) ( ( )4. ( ( ) ) ( ( )5. ( ( ) ) ( ( )6. ( ( ) ) ( ( )7. ( ( ) ) ( ( )8. ( ( ) ) ( ( )9. ( ( ) ) ( ( )10. ( ) ( ) ( ( )11. ( ( ) ) ( ( )12. ( ( ) ) 2014 5 2014 6
93511 400 2014 7 2014 8 2001-08-16/ /18/ 2011-04-14/ /A10/ 2014 9 2014 10 4 4 1 9 1 0.01 0.05 2010/10/13 11:01 2014 11 2014 12
1 2011413 201017 (nickel hydrazine perchlorate) CSB 2014 13 2014 14 (86/12-91/6) 2008 23 60 t-butyllithium (, ( ) ( ) ) t-butyllithium 43% 116 / 1 (3.7%) 1 3 (11%) 3 2 (7.4%) 11 4 (15%) 38 ( ) 1 (3.7%) 32 5 (19%) 1 5 6 (22%) 1 (3.7%) 16 3 H ( 3 (11%) 201212 ) 12 26 837 2014 15 2014 16 1993-10-21/ /07/ 1979-07-17/ /03 2 432 31 41 2003-11- 22/ /1/ 31 300 - - 萘 4-2014 17 2014 18
Chemical Abstracts. Service CA CAS. NO. 196971 CA CAS. NO. 1 201381622:52:25 CAS 73,008,476 5 20121030PM09:27:03 2014 19 2014 20 2014 21 2014 22 2014 23 2014 24
2014 25 2014 26 2 45 1. 2. 3. 4. 5. 2014 27 2014 28 ( ) ( ) ( 4 / 3/ 100 ) ( ) 1 40,000*5 + 40,000*40 = ( ) 2 30,000*5 + 30,000*40 = ( ) 3 100= ( ) 2014 29 2014 30
2014 31 6 *1 *2 (9) (10) (11) 3 2014 32 6 1 / / 2 / 3 // 4 / / / / / 5 / 6 7 / / / / / / / / 8 / / / / / 9 / 10 / / / 11 / 12 / / 13 / / 14 / / / / 1 2 / / / / 3 4 / / / 10 1 2 3 4 1 2 11 1 2 3 4 5 12 1 2 1 2 3 ( ) 13 1 2 3 14 2014 33 2014 34 14 CNS15030 CNS15030 17 18 1 2 3 4 5 6 / 1 2 3 4 2014 35 2014 36
75 182 209 4 31 Acetone Benzene Chlorine Ethyl acetate Formaldehyde 226 n-hexane ppm mg/m 3 (CH 3 ) 2 CO C 6 H 6 Cl 2 CH3COOC2H5 HCHO CH3(CH2)4CH3 750 1 0.5 400 1 50 1780 3.2 1.5 1440 1.2 176 237 Hydrogen sulfide H2S 10 14 2014 37 443 Toluene C6H5CH3 100 376 452 Trichloromethane CHCl3 ( ) (Chloroform) 10 49 481 Xylene (o-m-p-) C6H4(CH3)2 100 434 2014 38 ppm mg/m 3 f/c.c. mg/m 3 ppm ( M 24.45) 1 PEL-TWAPEL-STELPEL-C 110 10100 PEL-STEL=PEL-TWA E.F * 1001000 1000 M (g/gmole) * (mg/m 3 ) (ppm) 24.45 2 ( ) 24.45 25 1atm760mmHg ( ) ( ) * * ( ) * / // ( ) 2014 39 2014 40 1.1.2.2-1.2- 腈 - - 1.4 1-2- 1.1.1-1.1.2- 呋 ( ) ( ) ( ) ( ) ( ) ( ) 2014 41 2014 42
300 1-3 ( ) 100 ( ) 4-6 50 50 ( ) ( 40 * ) * 4065 7-11 * 65 ** 7 12. (33 ) ** 10 ** 30 13. 2014 43 2014 44 34 2014 45 2014 46 EXPLOSIVE ** 1 * POISON 6 FLAMMABLE LIQUID 3 2014 47 2014 48
--- 2014 49 2014 50 2014 51 2014 52 MSDS 2014 53 2014 54
2014 55 2014 56 2014 57 2014 58 2014 59 2014 60
2014 61 2014 62 2014 63 2014 64 2014 65 2014 66
(2014-08-01) 750-950 Propylene 2014 67 2014 68 1030811 2014 69 2014 70 (18-50) 20..... ( ) 21..... ( ).. 23. ( ) 25.( ).... 26...( ) 27... ( ) ( ) 28.( ) 29. ( )... 30. ( ) 31.( ) / 32. 34. ( ) 36..... ( ) 37. ( ).. SOP. 39. ( ) SOP 40. ( ) 49. 50. ( ) 2014 71 ( )10. (1) (2) (3) (4) 2014 72
40-49 40 37-2-1( ) 3 / // 30 / 41 1 / // 18 6-1/16-1 37-2-2( ) 18-1/29-1/30-1/30-2/37-4( ) / 36-1 ( / ) 2014 73 2014 74 42 15-1( )15-2 / / / 37-2 30-300 / 12-4 / 30-100 43 3-30 10-1/11-1/23-2 6-1/12-1/12-3/14-2/16-1/19-1/24/31-1/31-2/37-1/37-2 6-2 15-1 ( )15-2 / / / / 2014 75 44 3-15 / 20-200 / 3-30 /10-100 / 1 7-3 10-2 3-15 / 2 7-1/8-1/13-1/14-1 20-200 / / / / 3 7-3 /9-1 3-30 / 4 10-100 5 7-1/8-1/9-1 /14-1 / / / 45 3-15 6-2/12-4/20-1/20-2/21-1/21-2/22-1/23-1/32-1/34-1/38 17/18-3/26-28/29-3/33/39-4 36-1 46 20-632-334-2 3000 2014 76 (20-6) (32-3) (34-2) 3000 (46) 0933-763586 joe8688@ms17.hinet.net 2014 77 2014 78
( / / ) ( ) 14 *1 *2 14 (1020703) CNS15030 1 CNS15030 2 15 / 1 2 3 16 / / 17 / - - - - ** ( ) 2 18 1 2 3 4 5 6 ( 1 2 3 4 3 ) 4 19 20 29-1-3 30-1-5 / 5 / / 1 2 15 *1 ( ) 3 / *2 16 *1 6 6 *1 22 23 24 18 *1 2 *3 (4) 25 30% *2 (9) (10) (11) 3 26 9 19 *1 20 *1 10 / / *2 11 *6 21 *1 10 *1 (14) 1 2 3 4 *2 1 2 11 *1 1 2 3 4 5 *2 12 *1 1 2 *3 1 2 22 *1 50 3 2 23 *4 1 2 3 ( ) 27 13 *1 1 2 3 1 () 2014 2 () 2014
/ / / / 42 / / / / 43 36 *1 *28 ( ( ) ( ) 37 *1 29 20-1 *2 30 / / / / *23 1 2 3 4 5 6 *24 31 *4 47 48 32 / / / / / 33 / / 40 1 6-116-1 37-2-1 3 / // 30 2 34 / 41 1 1 18 35 / / / / / 6-116-1 37-2-2 *29 18-129-130-130-237-4 36-1 2 42 1 15-115-2 37-2 30-300 2 12-4 30-100 43 1 3-30 10-111-123-2 *30 1 6-112-112-314-216-119-12431-131-237-137-2 6-2 15-115-2 44 1 7-3 10-2 3-15 2 7-18-113-114-1 20-200 3 7-3 9-1 3-30 4 10-100 5 7-18-19-1 14-1 *2 45 3-15 6-212-420-120-221-121-222-123-132-134-138 31 *1 1718-326-2829-33339-4 36-1 *2 46 20-632-334-2 3000 47 6-30 39 CNS15030 / / 48 6-30 1 8-52 12-53 20-44 32-25 36-3 49 *32 37-2 40-454748 *33 *34 40 / / / / / / 41 3 () 2014 4 () 2014