2019 Scientists should provide solutions to social problems and dreams for people 1 http://www.chem.s.u-tokyo.ac.jp/users/common/akamuralab.html
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hemical & Engineering ews Dec 23, 2013 Quotes
(2019 4 1 Dominik Lungerich Junfei Xing Lu Hua obu Yasuda 3 (D3) (D2) MERIT ALPS MERIT (D1) MERIT (M2) Ziyue Qiang MERIT XPS ALPS, 1 (M1) Olivier hevalier (XPS Mengqing hen Keyi Sun 川嶋愛 Hlib Razumkov 4
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[ ] Sung hul SHI Sang Gyeong LEE Shou-Fei ZHU Xiaozhang ZHU Yu-Wu ZHOG Yunlong GUO Xiaoming ZEG hang-zhi LI Biotech, Thailand University of Zurich ristina EVADO [ ] Laurean ILIES Rui Shang anyang Technological University anyang Technological University Ecole ationale Superieure de himie de Rennes Loic LEMIEGRE Yonggang ZHE Zuo XIAO Baolin LI Qifan YA Mahidol University opporn RUAGSUPAPIHAT Linkoping University iclassoli Polish Acad. of Sci. Adam Mieczkowski Visva-Bharati University Alakananda HAJRA [ ] MPI for Polymer Science 8 6
0.1 nm 10 nm 100 nm 1 µm 1 mm PhPh O Si Si O PhPh PhPh PhPh X Fe F e
493. Direct Microscopic Analysis of Individual 60 Dimerization Events: Kinetics and Mechanisms, J. Am. hem. Soc., (2018). 9
With Drs. Sawamura, Matsuo and Prof. Takashi Kato ature, 419, 702-705 (2002) 15
(2000-) With Drs. Sawamura, Isobe and Harano and Prof. Ben hu Heidelberg) 4.48 2.38 2.99 R R K + 4.29 30 nm Science 2001, 291, 1143 1146. PAS 2007, 104, 14895 14898. R _ R R Ph 5 60 K (PhK) 14.14 eutron Scattering Reveals Water onfined in a Watertight Bilayer Vesicle, W. Abuillan, A. S. Becker, B. Demé, T. Homma, H. Isobe, K. Harano, E. akamura, M. Tanaka, J. Am. hem. Soc., 140, 11261 11266 (2018). 16
Univ of Tokyo (2004-10) R Si R Si Mitsubishi hemical's window solar cells (2017) 7 R = Me, Ph H H BP akamura, JAS (2009) 17
abon-bridged Oligo(phenylenevinylene) (OPVs) arbon-bridged oligo(phenylenevinylene)s (OPVs) OPV-1 Ar Ar Sample Pump beam OPV-2 OPV-3 OPV-4 OPV-5 OPV-6 H Ph Ph DFB emission Ph Ph reflected light Ph Ph Ph Ph Ph Ph Ph Ph Ph Ph Ph Ph Ph Ph Ph Ph Ph Ph Ph Ph detector Distributed Feedbck Laser H Intense abs / olor tuning High quantum yield (Φ 1) n = 1 n = 6 n = 1 n = 6 18
akamura and Sato, ature Materials, March Issue, 2011. "Element Strategy Initiative" Proposed in 2004 for the Japanese Government 19
Pd) - - H 3 O H 3 HR H + (pin)b Fe catalyst R = H 3 O H 3 HR Pd Rh Iron-catalyzed ortho -H Methylation of Aromatics Bearing a Simple arbonyl Group with Methylaluminum and Tridentate Phosphine Ligand, J. Am. hem. Soc., 138, 10132-10135 (2016). 20
S H R H O H Q H + H R Fe III S P O P cat. Fe(acac) 3 /dppen (Me 3 SiH 2 ) 2 Zn 2Mgl 2 DP THF, 70, 18 h O H Q O H S R H R Fe III P P S Ph 2 P PPh 2 dppen l DP Q l Transient connection of reactants ü ü ü 99% ü ature atalysis (2019)
Enantioselective Iron atalysis on 10 kg scale H 3 O H 3 O H S (1000 4.6 kg g) H 3 OH 3 H 3 Fe(acac) 3 (8 mol %) ligand (9 mol %) additive (10 mol %) H 2 O 2 (2.1 equiv) EtOAc, 15 to 6 H S O H 3 OH 3 H 3 (S)-esomeprazole O 2 Li t-bu additive = ligand = l OH OH HPL: 87%, 99.4% ee; Sulfone: 12% Isolated as K salt: 77%, > 99.9% ee Me 2 l AS atal., 8, 9738 9743 (2018). Iron-catalyzed enantioselective sulfoxidation:. Bolm, AIE 2003, 115, 5645; AIE 2004, 43, 4225; hem. Eur. J. 2005, 11, 1086.
Academic English in hemistry 1 4 3 ERATO Our challenges may be new....but those values upon which our success depends - hard work and honesty, courage and fair play, tolerance and curiosity, loyalty and patriotism 23 - these things are old. These things are true.
*1 Electron Microscopic Imaging of a Single Group 8 Metal Atom atalyzing - Bond Reorganization of Fullerenes, E. akamura, et al., J. Am. hem. Soc., 133, 14151-14153 (2011). *2 Imaging Single Molecules in Motion, Science, 316, 853 (2007). *3 Phenanthrene Synthesis by Iron-atalyzed [4 + 2] Benzannulation between Alkyne and Biaryl or 2-Alkenylphenyl Grignard Reagent, J. Am. hem. Soc., 133, 6557-6559 (2011). *4 Synthesis of hiral a-fluoroketones via atalytic Enantioselective Decarboxylation, Angew. hem. Int. Ed. (2006) *5 *6 Homocoupling-free Iron-catalysed Twofold H Activation/ross-couplings of Aromatics via Transient onnection of Reactants, T. Doba, T. Matsubara, L. Ilies, R. Shang, E. akamura, at. atal., in press *6. eutron Scattering Reveals Water onfined in a Watertight Bilayer Vesicle, W. Abuillan, A. S. Becker, B. Demé, T. Homma, H. Isobe, K. Harano, E. akamura, M. Tanaka, J. Am. hem. Soc., 140, 11261 11266 (2018). *7 Acid-Responsive onductive anofiber of Tetrabenzoporphyrin Made by Solution Processing, Y. Zhen, K. Inoue, Z. Wang, T. Kusamoto, K. akabayashi, S. Ohkoshi, W. Hu, Y. Guo, K. Harano, E. akamura, J. Am. hem. Soc., 140, 62-65 (2018). *8 Electron transfer through rigid organic molecular wires enhanced by electronic and electron vibration coupling, J. Sukegawa,. Schubert, X. Zhu, H. Tsuji, D. M. Guldi, E. akamura, at. hem., 6, 899 905 (2014). 9 Disodium Benzodipyrrole Sulfonate as eutral Hole-Transporting Materials for Perovskite Solar ells, R. Shang, Z. Zhou, H. ishioka, H. Halim, S. Furukawa, I. Takei,. inomiya, E. akamura, J. Am. hem. Soc., 140, 5018-5022 (2018). 10 In vivo gene delivery by cationic tetraamino fullerene, R. Maeda-Mamiya, E. oiri, H. Isobe, W. akanishi, K. Doi, T. Sugaya, T. Homma, and E. akamura, Proc. at. Acad. Sci., U.S.A., (2010) ature 2002, JAS 2006, 7, 10 K + Science 2001 PAS 2007 JAS 2018 JAS 2009 Science 2007 at. anotech 2008 JAS 2008 at. hemistry 2010 at Materials 2012 JAS 2008 2017, at atalysis (2018) at hem 2014 24 2014