研究室紹介2019年版大学院紹介

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1 2019 Scientists should provide solutions to social problems and dreams for people 1

2 2

3 hemical & Engineering ews Dec 23, 2013 Quotes

(2019 4 1 Dominik Lungerich Junfei Xing Lu Hua obu Yasuda 3 (D3) (D2) MERIT ALPS MERIT (D1) MERIT

4 ( Dominik Lungerich Junfei Xing Lu Hua obu Yasuda 3 (D3) (D2) MERIT ALPS MERIT (D1) MERIT (M2) Ziyue Qiang MERIT XPS ALPS, 1 (M1) Olivier hevalier (XPS Mengqing hen Keyi Sun 川嶋愛 Hlib Razumkov 4

5 5

6 [ ] Sung hul SHI Sang Gyeong LEE Shou-Fei ZHU Xiaozhang ZHU Yu-Wu ZHOG Yunlong GUO Xiaoming ZEG hang-zhi LI Biotech, Thailand University of Zurich ristina EVADO [ ] Laurean ILIES Rui Shang anyang Technological University anyang Technological University Ecole ationale Superieure de himie de Rennes Loic LEMIEGRE Yonggang ZHE Zuo XIAO Baolin LI Qifan YA Mahidol University opporn RUAGSUPAPIHAT Linkoping University iclassoli Polish Acad. of Sci. Adam Mieczkowski Visva-Bharati University Alakananda HAJRA [ ] MPI for Polymer Science 8 6

7 0.1 nm 10 nm 100 nm 1 µm 1 mm PhPh O Si Si O PhPh PhPh PhPh X Fe F e

8 493. Direct Microscopic Analysis of Individual 60 Dimerization Events: Kinetics and Mechanisms, J. Am. hem. Soc., (2018). 9

9 With Drs. Sawamura, Matsuo and Prof. Takashi Kato ature, 419, (2002) 15

onfined in a Watertight Bilayer Vesicle,

10 (2000-) With Drs. Sawamura, Isobe and Harano and Prof. Ben hu Heidelberg) R R K nm Science 2001, 291, PAS 2007, 104, R _ R R Ph 5 60 K (PhK) eutron Scattering Reveals Water onfined in a Watertight Bilayer Vesicle, W. Abuillan, A. S. Becker, B. Demé, T. Homma, H. Isobe, K. Harano, E. akamura, M. Tanaka, J. Am. hem. Soc., 140, (2018). 16

11 Univ of Tokyo ( ) R Si R Si Mitsubishi hemical's window solar cells (2017) 7 R = Me, Ph H H BP akamura, JAS (2009) 17

abon-bridged Oligo(phenylenevinylene) (OPVs) arbon-bridged

OPV-2 OPV-3 OPV-4 OPV-5 OPV-6 H Ph Ph DFB emission Ph Ph

Ph Ph Ph Ph Ph detector Distributed Feedbck Laser H Intense

12 abon-bridged Oligo(phenylenevinylene) (OPVs) arbon-bridged oligo(phenylenevinylene)s (OPVs) OPV-1 Ar Ar Sample Pump beam OPV-2 OPV-3 OPV-4 OPV-5 OPV-6 H Ph Ph DFB emission Ph Ph reflected light Ph Ph Ph Ph Ph Ph Ph Ph Ph Ph Ph Ph Ph Ph Ph Ph Ph Ph Ph Ph detector Distributed Feedbck Laser H Intense abs / olor tuning High quantum yield (Φ 1) n = 1 n = 6 n = 1 n = 6 18

13 akamura and Sato, ature Materials, March Issue, "Element Strategy Initiative" Proposed in 2004 for the Japanese Government 19

14 Pd) - - H 3 O H 3 HR H + (pin)b Fe catalyst R = H 3 O H 3 HR Pd Rh Iron-catalyzed ortho -H Methylation of Aromatics Bearing a Simple arbonyl Group with Methylaluminum and Tridentate Phosphine Ligand, J. Am. hem. Soc., 138, (2016). 20

15 S H R H O H Q H + H R Fe III S P O P cat. Fe(acac) 3 /dppen (Me 3 SiH 2 ) 2 Zn 2Mgl 2 DP THF, 70, 18 h O H Q O H S R H R Fe III P P S Ph 2 P PPh 2 dppen l DP Q l Transient connection of reactants ü ü ü 99% ü ature atalysis (2019)

16 Enantioselective Iron atalysis on 10 kg scale H 3 O H 3 O H S ( kg g) H 3 OH 3 H 3 Fe(acac) 3 (8 mol %) ligand (9 mol %) additive (10 mol %) H 2 O 2 (2.1 equiv) EtOAc, 15 to 6 H S O H 3 OH 3 H 3 (S)-esomeprazole O 2 Li t-bu additive = ligand = l OH OH HPL: 87%, 99.4% ee; Sulfone: 12% Isolated as K salt: 77%, > 99.9% ee Me 2 l AS atal., 8, (2018). Iron-catalyzed enantioselective sulfoxidation:. Bolm, AIE 2003, 115, 5645; AIE 2004, 43, 4225; hem. Eur. J. 2005, 11, 1086.

17 Academic English in hemistry ERATO Our challenges may be new....but those values upon which our success depends - hard work and honesty, courage and fair play, tolerance and curiosity, loyalty and patriotism 23 - these things are old. These things are true.

*1 Electron Microscopic Imaging of a Single Group 8 Metal Atom atalyzing - Bond Reorganization of Fullerenes, E. akamura, et al., J. Am. hem.

*3 Phenanthrene Synthesis by Iron-atalyzed [4 + 2] Benzannulation between Alkyne and Biaryl or 2-Alkenylphenyl Grignard Reagent, J. Am. hem.

(2006) *5 *6 Homocoupling-free Iron-catalysed Twofold H Activation/ross-couplings of Aromatics via Transient onnection of Reactants, T.

eutron Scattering Reveals Water onfined in a Watertight Bilayer Vesicle, W. Abuillan, A. S. Becker, B. Demé, T. Homma, H. Isobe, K. Harano, E.

*7 Acid-Responsive onductive anofiber of Tetrabenzoporphyrin Made by Solution Processing, Y. Zhen, K. Inoue, Z. Wang, T. Kusamoto, K.

*8 Electron transfer through rigid organic molecular wires enhanced by electronic and electron vibration coupling, J. Sukegawa,. Schubert, X.

9 Disodium Benzodipyrrole Sulfonate as eutral Hole-Transporting Materials for Perovskite Solar ells, R. Shang, Z. Zhou, H. ishioka, H.

18 *1 Electron Microscopic Imaging of a Single Group 8 Metal Atom atalyzing - Bond Reorganization of Fullerenes, E. akamura, et al., J. Am. hem. Soc., 133, (2011). *2 Imaging Single Molecules in Motion, Science, 316, 853 (2007). *3 Phenanthrene Synthesis by Iron-atalyzed [4 + 2] Benzannulation between Alkyne and Biaryl or 2-Alkenylphenyl Grignard Reagent, J. Am. hem. Soc., 133, (2011). *4 Synthesis of hiral a-fluoroketones via atalytic Enantioselective Decarboxylation, Angew. hem. Int. Ed. (2006) *5 *6 Homocoupling-free Iron-catalysed Twofold H Activation/ross-couplings of Aromatics via Transient onnection of Reactants, T. Doba, T. Matsubara, L. Ilies, R. Shang, E. akamura, at. atal., in press *6. eutron Scattering Reveals Water onfined in a Watertight Bilayer Vesicle, W. Abuillan, A. S. Becker, B. Demé, T. Homma, H. Isobe, K. Harano, E. akamura, M. Tanaka, J. Am. hem. Soc., 140, (2018). *7 Acid-Responsive onductive anofiber of Tetrabenzoporphyrin Made by Solution Processing, Y. Zhen, K. Inoue, Z. Wang, T. Kusamoto, K. akabayashi, S. Ohkoshi, W. Hu, Y. Guo, K. Harano, E. akamura, J. Am. hem. Soc., 140, (2018). *8 Electron transfer through rigid organic molecular wires enhanced by electronic and electron vibration coupling, J. Sukegawa,. Schubert, X. Zhu, H. Tsuji, D. M. Guldi, E. akamura, at. hem., 6, (2014). 9 Disodium Benzodipyrrole Sulfonate as eutral Hole-Transporting Materials for Perovskite Solar ells, R. Shang, Z. Zhou, H. ishioka, H. Halim, S. Furukawa, I. Takei,. inomiya, E. akamura, J. Am. hem. Soc., 140, (2018). 10 In vivo gene delivery by cationic tetraamino fullerene, R. Maeda-Mamiya, E. oiri, H. Isobe, W. akanishi, K. Doi, T. Sugaya, T. Homma, and E. akamura, Proc. at. Acad. Sci., U.S.A., (2010) ature 2002, JAS 2006, 7, 10 K + Science 2001 PAS 2007 JAS 2018 JAS 2009 Science 2007 at. anotech 2008 JAS 2008 at. hemistry 2010 at Materials 2012 JAS , at atalysis (2018) at hem

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