: : : : (02) : (02) : : : : (02) : (02)

93 3 1 9312 31 93 3 1 9512 31 93-01-01 ( ) ( ) 93 12 31

: : : : (02) 2437-7666 : (02) 2437-7666 E-mail: chency@ems.cku.edu.tw : : : : (02)86625934 : (02)8662-5936 E-mail:julianlin@mail.tnit.edu.tw 93 3 1 93 12 31 93 3 1 95 12 31 93 94 0 0 0 0 400,000 0 0 400,000 0 50000 0 50000 95 (02) 2437-7666 (02) 2437-7666 (203) 336 E-mailsec@ems.cku.edu.tw

...1...1 1.1... 1 1.2... 2...6 2.1... 6 2.2... 8 2.3... 8...10 3.1... 10 3.2... 11 3.3... 11...13...13 1.1... 13 1.1.3... 15 1.1.4... 17 1.2... 22 1.2.1... 22 1.2.2... 25 1.2.3... 25 1.2.4... 26 1.2.5... 26 1.2.6... 26 1.3... 27 1.4... 29

1.4.1... 30 1.4.2... 32 1.4.3... 33...44 2.1... 45 2.1.1... 45 2.1.2... 45 2.1.3... 47 2.2... 48 2.2.1... 49 2.2.2... 50 2.3... 53 2.4... 54 2.4.1... 54 2.4.2... 54...57 3.1... 57 3.1.1... 57 3.1.2... 58 3.2... 59...63...64...79

88 10 1

- ( 74.8 32.7 ) 7 ( 32.5 ) ( ) 32.8 ( 2.5) ( ) () 27 12.9 12.2 () () ( 2.42.6 2.7 ) - 88 57% 90 41% 88 63% 90 54% 16.5% 5.7% - 154 40.9% 29.2% 26.0% 0.4 0.72 0.12 134 () 61.9% () 20.1% 0.11 () 0.33 ( ) 3 2

(71%) (17.5%) ( 4350 58%) ( 2017 27%) ( 87.3%) 91.692.8100 70% ( 49.3%) 71.440.050.0 35.6% ( 41.8%) (17.2%) (11.2%) 43.445.5 55.6% / ( 10 ) 57.155.0 83.3 40.0%( 58.9%) 20.637.516.7 40.0% ( 28.7%) ( 70.1%) 27.6% () 65.0% () 22 0.49 0.35 0.048 67 ( 64 2 1 ) 0.81 0.63 3

(24.0%) / (20.1%) (12.3%) (11.7%) (6.5%) (81.8%) (18.7%) / (14.2%) (9.0%) (8.2%) (7.5%) 11.2% (16.2%) (14.3%) (12.3%) (9.1%) (8.4%) 17.5% (32.4%) (40.3%) (20.1%) (10.4%) (8.2%) (3.0%) 5.2% (20.8%) (14.3%) / (11.7%) (10.4%) (9.1%) 88 921 1024 (77.8%) (48.5%) (9.0%) (6.7%) (6.0%) (5.2%) (16.4%) (7.8%) (3.9%) (3.9%) (3.2%) 25 17 (68%) (38.8%) (21.6%) (6.0%) (4.5%) (3.7%) (33.1%) 4

( )30.5% 5.2% 17.5% ( )49.3% (20.1%) 17.2% 12.7%( ) 59.7% 35.7% 67.9% 5

6

7

8

9

( ) 10

11

12

: a. b. c. 1.1.1 MSDS 13

14 1.1.2

1.1.3 1.1.3.1 15

1.1.3.2 3 1 2 4 1. 2. (1) (2) (3) ( ) 16

5 mm 100, 1.1.3.3 1.1.4 1.1.4.1 1.1.4.2 / (CAS.NO) 17

: ph / (UN.NO.) 1.1.4.3 1.1.4.4 18

19

MSDS ( ) (ml) MSDS MSDS MSDS MSDS MSDS MSDS MSDS MSDS MSDS MSDS 20

MSDS MSDS () ( ) 21

1.2.1 22

23

24

1.2.2 1.2.3 25

1.2.4 1.2.5 1.2.6 26

( http://www.lisc.edu.tw/center/) 27

28

3 29

30 1.4.1 ( )

(,,,,,, ),, ) 31

32 1.4.2 ( ) () () () () () () () () () ()

33 1.4.3, ( ) ( )

34 () ( ) () ( ) () () ( ) () ( )

1 2 3 4 56 7 8 91 11 1 1 1 1 1 1 1 1 2 2 2 2 2 2 2 2 2 2 3 0 2 3 4 5 6 7 8 9 0 1 2 3 4 5 6 7 8 9 0 1. 2. 3.( ) 4. 5. 6. 7. 8. 9. 10. 3 1 1. 15 1.3 2. 3. 35

1 2 3 4 56 7 8 91 11 1 1 1 1 1 1 1 1 2 2 2 2 2 2 2 2 2 2 3 0 2 3 4 5 6 7 8 9 0 1 2 3 4 5 6 7 8 9 0 1. 2. 3. 4. 5. 6.( ) 7. 8. 9. 10. 11. 3 1 1. 64 2. 3. 36

() () 1. 2. () () () () () () 1. 4045 2. 3. 4. 37

1. 2. 3. 4. 5. 6. 7. 8. 1. 37 2 2. 3. 38

12 3 45 6 78 9 10 11 1213141516171819202122232425262728293031 1. 2. 3. 4. 5. 6. 7. 8. 1. 37 2 2. 3. 39

40 () (1) (2) (3) () (1) (2) (3) (4) () (1) (2) (3) (4) (5) (6) () (1) (2) () (1) (2) (3) (4)

() (1) (2) (3) (4) () (1) (2) (3) () (1) (2) (3) (4) (5) () (1) (2) (3) (4) (5) (6) () (1) (2) (3) A. B. C. D. E. (4) 41

( ) (1) (2) (3) ( ) (1) (2) (3) ( ) (1) (2) (3) A. B. C. 1. 32 2. 3. 42

( ) ( ) ( ) ( ) ( ) ( ) (1) (2) (3) (4) (1) (2) (3) (1) (2) (1) (2) (1) (2) (3) (4) 1. 2. 3. 43

44

2.1 基本資料 2.1.1 校園相關位置圖 校園緊急應變計畫中應備有校園相關的位置圖(本計畫以東南技術學院 為例) 圖十 校園相關位置圖 2.1.2 緊急應變組織 建立應變組織之主要功用為當意外事故發生時 搶救人員各司其責 以縱 向上下溝通 統籌行政支援力量防救及處理 將混亂的災害現場條理化 俾使 災害損失減低至最小 並及早完成善後復原工作 當事故現場人力不足或規模 較小時 其任務分組可依現況作適當的調整 當重大災害發生時校長為緊急應變小組召集人及應變總指揮 總務長為副 召集人兼業務執行督導 學務處 人事室 會計室 學校一級單位及附設單位 之主管共同組成小組成員 為爭取時效 對於災害之防救與處理 校內各系所 應比照本計畫書成立緊急應變小組 45

46 1. 2. 3. ( ) 1. 2. 3. ( ) 1. 2. 3.

2.1.3 47

48

2.2.1 49

2.2.2 2.2.2.1 50

2.2.2.2 ( ) Y Y ( ) 51

2.2.2.3 ( ) ( ) : 52

2.3.1 2.3.2. 53

2.4.1 2.4.2 2.4.2.1 CPR 119 2.4.2.2 54

55 MSDS YES NO EMS( ) --ABC EMS ABCs EMS EMS ABCs EMS ABCs EMS EMS CPR EMS EMS ABCs EMS ABCs

56

3.1.1 57

3.1.2 58

59

60

61

62

[1] 88 2 [2] 91 10 [3] http://www.safelab.ncu.edu.tw/lab2004/93 8 [4] http://www.lisc.edu.tw/center/index.asp 93 9 [5] http://ccms.ntu.edu.tw/~epc/ 93 8 [6] 93 8 [7] http://www.ncu.edu.tw/~ncu7307/ 93 8 [8] 92 92 10 [9] IOSH91-H342 11 [10] 92 11 63

(CNS 6864 Z5071) ( 1) 45 ( ) 100 5 1 a. b. 2.1 CNS 11295( ) 1997 (ST/SG/AC.10/ 1/REV.10) ( ) (2.1) (1) a. 64

(Non-detonative self-sustaining exothermic chemical reactions) 2 3 a. ( ) b. c. a b (2) (2.1) 11.1 (mass explosive hazard) ( ) 21.2 31.3 a. b. 41.4 S(in Compatibility Group S) 51.5 61.6 65

66

4.8 ( (CNS 6864 Z5071)) (Explosives) 1.1 1.2 1.3 1.4 1.5 1.6 1 1.1 1.2 1.3 1.4 1.5 1.6 (Gases) 2 2.1 Flammable gases 2.1 2.2 Non-flammable,non-toxic gases 2.2 2.3 2.3 Toxic gases (Flammable liquids) 3 (Flammable solids; 4 Substances liable to spontaneous combustion; Substances which in contact with water emit flammable gases) 4.1 4.1 4.2 4.2 4.3 4.3 (Oxidizing substances; Organic 5 peroxides) 5.1 5.1 5.2 5.2 (Toxic and infectious substances) 6 6.1 6.1 6.2 6.2 Radioactive material Radioactive I 7A Radioactive II 7B Radioactive III 7C Fissile material (Corrosive substances) 8 (Miscellaneous dangerous substances) 9 1. IAEA(International Atomic Energy Agency) 2. 1997 ( ST/SG/AC.10/1/REV.10) 3. 67

(3) 1.1 1.2 1.3 "1" "**""*" 1.4 1.5 1.6 "*" "1" (4) 0129 1.1A 0004 1.1D 0340 1.1D 0283 1.2D (1) 1 50 300 kpa 20 101.3 kpa 2 a. ( ) 20 b. 20 c. d. (2) 1 2.1 20 101.3 kpa 13 12 22.2 20 280 kpa 68

a. b. c. 32.3 (LC 50 ) 5,000 ml m 3 (ppm) (3) (4) 2.1 2 2.2 2 2.3 2 (5) 1075 2.1 1013 2.2 1017 2.38 1072 2.25.1 1076 2.38 2199 2.32.1 69

1749 2.35.18 1066 2.2 1070 2.25.1 1005 2.38 1049 2.1 (1) ( ) 60.5 65.6 4.9 4.9 ( ) I II III 23 23 60.5 35 35 35 (2) (3) 3 (4) 1090 3 1230 36.1 1294 3 1173 3 1093 36.1 1131 36.1 1203 3 70

(1) 1 4.1 4.1 24.2 34.3 (2), (3) 4.1 4 4.2 4 4.3 4 (4) 1869 4.1 1350 4.1 ( 30) 1354 4.1 1381 4.26.1 71

1362 4.2 2257 4.3 1418 4.34.2 1295 4.338 (1) 1 5.1 25.2-0-0- a. b. c. d. e. (2), (3) 5.1 5.1 5.2 5.2 (4) 1486 5.1 1495 5.1 1491 5.1 2032 85.16.1 72

3101 5.2 ( ) (1) 1 6.1 6.1 2.4 6.1 LD 50 / 200 500 LD 50 ( / ) V LC 50 ( /) LC 50 ( /3 ) 1000 10 V1/5LC 50 LC 50 5000 V 20 / 3 2 6.2 (2) 50200ppm 2,000ppm (3) 6.1 "6" " " 6.2 "6" " " 73

(4) 1689 6.1 2480 6.13 1649 6.1 1846 6.1 1888 6.1 1567 6.14.1 (1) (Specific activity) 70 KBq/kg(0.002ci/g) (1) (2) (3) 8 (4) 74

1831 86.1 2032 85.16.1 1789 8 1790 86.1 1823 8 (3050) 2672 8 (1) 100 240 (2) (3) 9 (4) 3151 9 2590 9 1941 9 3090 9 ( ) 1845 9 4.3.3 75

1.1D 1. 2. 3. 4. 1. 2. 3. 4. 1. 2. 3. 76

2.2 ( ) 1. 1. 2. 3. 1. 2. 3. 77

2.38 ( ) 1. 2. 3. 4. 1. 2. 3. 1. 2. 3. 78

2.1 ISO MSDS / / MSDS (1) (2) (3) MSDS (4) MSDS / 79

2.2 (1) (2) () Isomyl Acetate (3) (CAS.NO.) (Chemical Abstracts Service) (CA) (CAS. NO.) 1969 71 CA CAS. NO. (4) CAS No. CAS NO. (5) 1 CAS No. 2.3 80

(1) (2) (3) 5.1 --- 5.2 81

2.4 (1) 20 (2) (3) 2.5 (1) ( ) 4.3 4.4 82

(2) (3) (4) (5) MSDS (6) 83

4.3 (A) (B) (C) (D) 4.4 ABCBCD A B C D 1. 2. BC 3. BC ABC 4.D G-powder 84

85 2.6 (1) (2) (3) À (secure the area) Á (placard) MSDS Â Ã Ä

86 ( ) ( ) 2.7 (1) (2) À (2) (3) 2.8

(1) a. ( ) ( ) b. (2) a. ppmmg/m 3 ppm mg/m 3 (a) (TWA) TWA(Time-Weighted Average) (b) (STEL) STEL(Short-Term Exposure Limit) 87

(c) (CELING) CELING b. American Conference of governmental Industrial Hygiensts;ACGIH Biological Exposure Indices,BEIs BEI (3) (Personal Protection Equipment) PPE a. ( 19.5) b. c. 88

89 (4) (5) (6) / /

90 2.9 (1) ( ) (2) ( ) ( ) ( ) ( ) (3) ( ) ( ) ( ) (4)pH 014 ph ph ph 03 ph 11140 (5) / () ( F) (760mmHg) (6) (7) ( ) F (

closed-cup ) ( open-cup ) ASTM(American Standard Test Method) ( ) (8) (Lower Explosion LimitLEL) (Upper Explosion LimitUEL) (propagation) g/m 3 UEL LEL ( ) UEL LEL LEL30 10 (9) (10) 20 ( ) (mmhg)psi 14.7psi atm760mmhg (ppm) (mmhg) 760 10 6 (11) ( ) 91

28.8 (12) ( ) 4 1 ( 0.7) (13) 20 100 4.5 (20) 0.1 0.11 110 10 WHMIS CORE MATERIAL(Aug.1988) ph / 92

93 2.10 (1) (2) 340 (3) (4) ( ) (5) (6) (azides) (7)

94 2.11 (1) 24 (2) (3) (4) (5)

IARC Group 12A2B 4 (6) (LD 50 (mg/) 14 (50) LD (Median Lethal Dose) mg/kg LD 50 ( ) (7) (LC 50 ) ( 14 ), 14 (50), Median Lethal Concentration ppm LC 50 (8) LD 50 LC 50 LD 50 LC 50 95

4.6 IARC Group 1 - Group 2A - Group 2B - Group 3 - Group 4-4.7 LC50 LD50 LD50 6 4 2~4 (g/kg) (g/kg) (ppm) (1) 0.001 10 0.005 (Extremely toxic) 0.0648 0.001~0.05 10~100 0.005~0.043 1 (4cc) (Highly toxic) 1 0.001~0.05 100~1,000 0.044~0.340 (Highly toxic) (30gm) 1 0.05~0.5 1,000~10,000 0.35~2.81 (Slightly toxic) (250gm) 1 (1/4 0.5~5.0 10,000~100,000 2.82~22.6 (Practically toxic) ) 15.00 100,000 22.6 1 (Relatively toxic) Spector, S.W., ed. Handbook of Toxicology, Vol.1, Acute Toxicities, Philade phia, PA: W.B. Saunders Co. 1956. 96

97 2.12 (1) / (2) (3) (4) / 2.13 (1)

( ) (2) ( ) 98

2.14 (1) DOT IMO IATA (2) (UN.NO) UN UN 99

UN 1457 1504 1483 (UN.NO) Emergncy Response Cuidebook 62 (111172) (3) 84 100

2.15 (1) (2) 2.16 (1) (2) / 101

102 2.1 / CAS No. / /

103 ph / / /