Microsoft Word - 3--丁昌璞校后_new_.doc

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1 土壤 (Soils), 2013, 45(5): 中国土壤电化学的发展历程 ( ) 50 ( ) S [1] [2] 14 [3] [4] 59 ( ) () ( ) ( Eh ) () (1931 ) (International Foundation for Science Sweden) liliangmob@163.com

2 1 20 60 70 50 [1] 2 1953 60 [2] 14 [3] [4] 59 ( ) () (

2 5 781 ( ) ( )( )( ) [5-6] ( ) [7-11] [12] (CNR) P. Sequi 1981 P. Sequi Udine 10 [13-17] J. Plant Nutri. and Soil Sci. J. Soil Sci. Soil Sci. Geoderma J. Colloid Interface Sci. Pedosphere 1990 () [18] Advances in Agronomy Ion-Selective Electrode Reviews Future Prospects of Soil Chemistry (1999) 1980 (Yu 1997) [19] [20-22] [23] 1990 [24] [25-27] 2011 [28]

3 [28-30] [31-40] Eh [41-42] [30] [30] [43-44] 2013 [45] ( ) [46-48] [49-51] [52-56] [51] [54-56] [1] Yu TR, Li SH. Study on oxidation reduction processes in paddy soil[r] // 6 th International Congress of Soil Science. Vol. A, 1956: [2]. [M]. :, 1992 [3]. [J]., 1982, 14(2): [4]. [J]., 1984, 15(6): [5],. [M]. :, 1991 [6],,. [M]. :, 1996 [7]. ( )[M]. :, 1978 [8]. [M]. :, 1987 [9] Yu TR. Physical Chemistry of Paddy Soils[M]. Beijing- Belin: Science Press-Springer Verlag, 1985 [10] Yu TR, Ji GL. Electrochemical Methods in Soil and Water Research[M]. Oxford: Pergamon Press, 1993 [11] Yu TR. Chemistry of Variable Charge Soils[M]. New York: Oxford University Press, 1997 [12] Institute of Soil Science, Academia Sinica. Proceedings of Symposium on Paddy Soils[M]. Beijing: Science Press, 1981 [13], Ceccanti B. [J]., 1987, 24(3): [14], De Nobili M, Ceccanti B. [J]., 1989, 26(4): [15] Ding CP, Ceccanti B. Anaerobic decomposition of green manures in flooded soils, in the presence of Cr(VI): I. Redox processes and Cr, Fe, Mn solubility[j]. Agrochimica, 1984, 28(5/6): [16] Ceccanti B, Ding CP. Anaerobic decomposition of green manures in flooded soils, in the presence of Cr (VI): II, Charge and size characterization of decaying products and their metal complexes[j]. Agrochimica, 1985, 29(1): [17] De Nobili M, Ding CP, Leita L. Voltammetric behavior of water-soluble reducing substances from anaerobic decomposition of green manure and rice straw[a]//proceedings of

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4 5 783 International Symposium on Paddy Soil Fertility[C]. Chiangmai, Thailand, 1988 [18] Yu TR. Introduction to Symposium on Surface Chemistry Under Varying Redox Conditions[A]// Transactions of 14 th International Congress of Soil Science[C]. 1990, II: 37 [19]. [M]. :, 1983 [20]. [J]., 1987, 19(4): [21],. [A]//. [M]. :, 1989 [22],,. [J]., 1994, 31(4): [23],. IV. [J]., 1958, 6(2): [24],. [M]. :, 1990 [25],. (I): [J]., 2002, 39(4): [26],. (II): [J]., 2003, 40(4): [27],,. (V): [J]., 2006, 43(1): [28],. [M]. :, 2011 [29],. [J]., 2006, 23(4): [30]. [J]., 45(1): [31]. [A]//,. [M]. :, 2011: 1 30 [32],,. [A]//,. [M]. :, 2011: [33],,. - [A]//,. [M]. :, 2011: [34],. [A]//,. [M]. :, 2011: [35],. [A]//,. [M]. :, 2011: [36],. [A]//,. [M]. :, 2011: [37]. [A]//,. [M]. :, 2011, [38],,. [A]//,. [M]. :, 2011: [39]. (I): [J]., 2010, 47(3): [40]. (II): [J]., 2011, 48(5): [41]. [J]., 1992, 24(5): [42] Ding CP, Liu ZG, Yu TR. Determination of reducing substances by votammetric method[j]. Soil Science, 1982, 134(4): [43],. ph [J]., 1998, 35(2): [44],,. 2 [J]., 2009, 25(3): [45]. [M]. :, 2013 [46],,. [J]., 2009, 41(6): [47],. ph [J]., 2005, 24(3): [48],. [J]., 2011, 20(4): [49] Hou T, Xu RK, Tiwari D, Zhao AZ. Interaction between electric double layers of soil colloids and Fe/Al oxides in suspensions[j]. Journal of Colloid and Interface Science, 2007, 310: [50] Li SZ, Xu RK. Electrical double layers interaction between oppositely charged particles as related to surface charge density and ionic strength[j]. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2008, 326: [51] Li SZ, Xu RK, Li JY. Electrical-double layer interaction between oppositely charged particles in variable charge soils as related to salt adsorption[j]. Soil Science, 2009, 134: [52] Xu RK, Xiao SC, Jiang J, Wang YP. Effect of amorphous Al(OH) 3 on desorption of Ca 2+, Mg 2+ and Na + from soils and minerals as related to diffuse layer overlapping[j]. Journal of Chemical and Engineering Data, 2011, 56: [53] Wang YP, Xu RK, Li JY. Effect of Fe/Al oxides on desorption of K + and NH 4 + from soils and kaolinite[j]. Pedosphere, 2013, 23: [54] Li JY, Xu RK, Zhang H. Iron oxides serve as natural anti-acidification agents in highly weathered soils[j]. Journal of Soils and Sediments, 2012, 12: [55] Li JY, Xu RK. Inhibition of the acidification of kaolinite and alfisol by iron oxides through electrical double-layer interaction[j]. Soil Science, 2013, 178: [56] Li JY, Xu RK. Inhibition of acidification of kaolinite and alfisol by aluminum oxides through electrical double-layer interaction and coating[j]. European Journal of Soil Science, 2013, 64:

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5 Developmental Course of Soil Electrochemistry in China DING Chang-pu (Institute of Soil Science, Chinese Academy of Sciences, Nanjing , China) Abstract: The paper introduced the systematical achievements of soil electrochemistry in chemical behaviors of charged particles, electrode operation, subject infiltration, research successes, influence and evaluation, which formed the scientific system of soil electrochemistry by merging basic principles, practical uses and research methods. Chief points of the system included nonequivalent-nonelectrostatic exchange-adsorption, spatial zonal pattern of oxidation-reduction regimes from humid to arid area, interaction between organic reducing substances and soils, contribution of redox processes as a driving force to soil substances cycle, soil acidification theory, amelioration measures, industrial and agricultural waste uses for environment protection, interaction of oppositely charged particles, diffuse layer overlapping mechanism, effect of electric double layers on soil surface and acidification. Key words: Soil electrochemistry system, Redox processes, Organic reducing substances, Nonequivalent-nonelectrostatic exchange-adsorption, Acidified red soil, Amelioration measures, Interaction of electric double layers

the scientific system of soil electrochemistry by merging basic principles, practical uses and research methods.

Microsoft Word 姜军_new_.doc

Microsoft Word 姜军_new_.doc 土壤 (Soils), 2015, 47(2): 422 426 DOI: 10.13758/j.cnki.tr.2015.02.034 1 离子强度对三种可变电荷土壤表面电荷和 Zeta 电位的影响 * ( () 210008) Zeta ph (PZSE) ( ) Zeta ph PZSE ( ) Zeta K + Na + K + Na + KNO 3 Zeta NaNO 3 Zeta PZSE