Ionics for sustainable world : proceedings of the 13th Asian Conference on Solid State Ionics, Sendai, Japan, July 2012

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1 TAIPEI Proceedings of the 13th Asian Conference on SOLID TATE IONICS IONICS FOR SUSTAINABLE WORLD Sendai, Japan July 2012 Editor* BVR Chowdari National University of Singapore, Singapore J Kawamura J Mizusaki K Amezawa Tohoku University, Japan Asian Society for Solid State Ionics Y p World Scientific NEW JERSEY LONDON SINGAPORE BEIJING SHANGHAI HONG KONG CHENNAI

2 LiSALT LiSALT SILICA xviii CONTENTS Preface '» Organization >v Sponsors vi Conference Programme vii Part 1: Batteries 1 ELECTROSPUN LiMn204 NANOFIBERS AS CATHODE FOR LITHIUM 3 ION BATTERIES XuanZhao, M.V. Redely, S. Ramakrishna, S. Mahishalkar, B.V.R. Chowdari 2 FABRICATION AND PROPERTIES OF MANGANESE MONOXIDE 10 NANOPARTICLES AS ANODE MATERIALS FOR LITHIUMION BATTERY Yingying Hu, Zhaoyin Wen, Jun Jin, Meifen Wu, Xiangwei Wu 3 VARIATION OF IONIC CODUCTIVITY WITH ANNEALING 18 TEMPERATURE IN ARGYRODITE SOLID ELECTROLYTES R. Prasada Rao, Maohua Chen, Stefan Adams 4 STRUCTURAL AND CONDUCTIVITY STUDIES ON LANTHANUM 27 DOPED LiNiP04 PREPARED BY POLYOL METHOD S. Karthickprabhu, G. Hirankumar, A. Maheswaran, R.S. Dciries Bella, C, Sanjeeviraja 5 SYNTHESIS AND ELECTROCHEMICAL STUDIES OF LiNio.jCoo.sVO,, 37 CATHODE MATERIAL BY SOLGEL METHOD D. Prakash, C. Sanjeeviraja 6 A NOVEL CONCEPT FOR ALLSOLIDSTATE LITHIUMSULFUR 44 BATTERY USING RTIL ELECTROLYTES QUASISOLIDIFIED Hideyuki Ogawa, Atsushi Unemoto, ham Honma 7 DEVELOPMENT OF ALLSOLIDSTATE LITHIUM BATTERY USING 55 QUASISOLIDSTATE RTIL ELECTROLYTES NANOCOMPOSITE Atsushi Unemoto, Hideyuki Ogawa, Yoshiyuki Gambe, Seitaro Ito, Irani Honma

3 xix 8 LITHIUM ION POLYMER ELECTROLYTE BASED ON PVAPAN 63 F. Kingslin Mary Genova, S. Selvasekarapandian, N. Rajeswari, S. Siva Devi, S. Karthikeyan, C. Sanjeeviraja 9 ELECTROCHEMICAL EVALUATION OF Li3Mn04 USED AS 72 CATHODE MATERIALS FOR LITHIUM ION BATTERIES Zhiyong Yu, Shujing Xie, Xiaojun Liu, Yunjiang Cui, Hanxing Liu 10 DEVELOPMENT OF FERRITE BASED POLYMER ELECTROLYTE 79 SOLID STATE RECHARGEABLE BATTERY Markandey Singh, Nidhi Asthana, Kamlesh Pandey, Mrigank Mauli Dwivedi, S.L Agrawal 11 FAST HYDROTHERMAL SYNTHESIS AND ELECTROCHEMICAL 89 PROPERTY OF LiFeP04 Jun Qian, Zhiyong Yu, Lan Yao, Hanxing Liu 12 SYNTHESIS OF NANOSIZED Li2Mn03 POWDERS BY CITRATE 96 NITRATE GEL COMBUSTION PROCESS AND THEIR ELECTROCHEMICAL PROPERTIES Lan Yao, Zhiyong Yu, Jun Qian, Hanxing Liu 13 SIZE CONTROL OF LiFeP04/C CATHODE MATERIAL BY SURFACE f 02 TREATED FeP04 WITH CITRIC ACID Jianhe Hong, Lu LV, Yanfen Wang, Mingzhong He, Gang He 14 CRYSTAL AND LOCAL STRUCTURE OF LITHIUM COBALT OXIDE I 10 STUDIED BY NEUTRON DIFFRACTION Dyah S. Adipranoto, Tom Ishigaki, Akinori Hoshikawa, Kenji Iwase, Hidetoshi Oguro, Masao Yonemura, Kazuhiro Mori, Takashi Kamiyama 15 PYRROLELijN COCOATED LITHIUM ANODE FOR 122 RECHARGEABLE LITHIUM BATTERIES Meifen Wu, Zhaoyin Wen, Jun Jin 16 SYNTHESIS AND ELECTROCHEMICAL PROPERTY OF LiMn THIN FILM BY ELECTRODEPOSITION METHOD Zhen Quan, Shouya Ohguchi, Masayasu Kawa.se, Noriyuki Sonoyama 17 DETECTION OF DEGRADATION IN LiCoO, THIN FILMS BY IN SITU 138 MICRO RAMAN MICROSCOPY Naoaki Kuwata, Kazuki he, Yasutaka Matsuda, Junichi Kawamura, Takao Tsurui, Osamu Kami.shima

4 XX 18 ELECTRICAL AND ELECTROCHEMICAL PROPERTIES OF NEW 144 Mg2+ ION CONDUCTING POLYMER ELECTROLYTE MEMBRANES R.C, Agrawal, Dinesh K. Sahu, Y.K. Mahipal, Rehana Ashrafi 19 IMPROVEMENT OF SEALING PERFORMANCE FOR NAS BATTERY 152 BY A SURFACE MODIFICATION PROCESS Gaoxiao Zhang, Zhaoyin Wen, Xiangwei Wu, Guoqiang Ma 20 ION TRANSPORT AND ALLSOLIDSTATE BATTERY 160 CHARACTERIZATION STUDIES ON Mg2+ION CONDUCTING NANOCOMPOSITE POLYMER ELECTROLYTE (NCPEs): (75PEO:25MgS04) + x MgO R.C. Agrawal, Y.K. Mahipal, Dinesh Sahu, Priyanka Keshrawani Part 2: Fuel Cells 21 HIGH POWER DENSITY SOLID OXIDE FUEL CELLS USING LaGa PEROSKITE OXIDE THIN FILM PREPARED BY PLD METHOD Young Wan Ju, Tatsuini Ishihara 22 MATERIALS SCIENCE VIEWPOINT FOR RECENT DEVELOPMENT 180 OF SOLID OXIDE FUEL CELLS Harumi Yokokawa 23 PREPARATION AND MIXED CONDUCTIVITY OF MnDOPED BiSr 192 FeBASED PEROVSKITE TYPE OXIDES Doohyun Baek, Hitoshi Takamura 24 EFFECT OF LANTHANUMSTRONTIUMCOBALTITE CATHODE 198 CURRENTCOLLECTING LAYER ON THE PERFORMANCE OF ANODE SUPPORTED TYPE PLANAR SOLID OXIDE FUEL CELLS SunYoung Park, HoIIJi, HaeRyoung Kim, Kyung Joong Yoon, Ji Won Son, HaeWeon Lee, JongHo Lee 5 AN ELECTRICAL ENERGY STORAGE SYSTEM BASED ON SOLID 204 OXIDE FUEL CELLS T. Luo, L. Shao, J.Q. Qian, S.R. Wang, Z.L. Zhan 26 CHARACTERISATION OF PROTON CONDUCTING POLYMER 212 ELECTROLYTE BASED ON PAN S. Nithya, S. Selvasekarapandian, N. Rajeswari, S. Sikkanthar, S. Karthikeyan, C. Sanjeeviraja 27 MICROSTRUCTURE DEPENDENCE OF OXYGENION 221 CONDUCTIVITY OF SAMARIUMDOPED CERIA CERAMICS DuanPing Huang, Qing Xu, HanXing Liu, Wen Chen, Kai Zhao, BokHee Kim

5 xxi 28 CHEMICAL STABILITY OF Bao.5Sr0.sCoo.8Feo.203.(>UNDER DIFFERENT 228 OXYGEN PARTIAL PRESSURE Fang Wang, Keiji Yashiro, Koji Amezawa, Junichiro Mizusaki 29 EFFECTS OF A PHASE TRANSITION AND OXYGEN 235 NONSTOICHIOMETRY ON ELASTIC MODULUS OF Lao.6Sro.4Co,.yFev03.,s Yuta Kimura, Takitto Kushi, Tatsuya Kawada, Shinichi Hashimoto, Koji Amezawa, Keiji Yashiro, Junichiro Mizusaki 30 Sr2MgMoOw: THERMAL, STRUCTURAL AND ELECTRICAL 246 ANALYSIS A run Kumar Dorai, SunDong Kim, JiHaeng Yu, InSub Han, Doo Won Seo, SangKuk Woo, Kim Seyoung 31 PROTON CONDUCTING POLYMER ELECTROLYTE BASED ON 253 PVAPAN S. Siva Devi, S. Selvasekarapandian, N. Rajeswari, F. Kingslin Mary Genova, S. Karthikeyan, C. Sanjeevi Raja Part 3: Material Properties, Processing 32 PREPARATION OF BINARY AND TERNARY OXIDES BY MOLTEN 265 SALT METHOD AND ITS ELECTROCHEMICAL PROPERTIES M. V. Reddy, L. Pei Theng, Hulbert Soh, Z. Beichen, F. Jiahuan, C. Yu, A. Yen Ling, L.Y. Andreea, C.H. Justin Ng, T.J.L. Galen Liang, M.F. Ian, H.V.T. An, K. Ramanathan, C.W.J. Kevin, T.Y.W. Daryl, T. YiHao, K.P. Loh, B.V.R. Chowdari 33 CORRELATION BETWEEN ELECTRICAL CONDUCTIVITY AND 281 GLASS TRANSITION TEMPERATURE OF Li,O:B20,:SiO2:TiO2:Li2SO4 GLASSES A.V. Deshpande, N.S. Satpute 34 MILLING EFFECTS ON LOCAL STRUCTURE AND ELECTRICAL 289 CONDUCTION IN ALUMINUM DOPED LITHIUM MANGANESE OXIDES Koichi Nakamura, Kosuke Shimokita, Yoichi Sakamoto, Yoshitaka Michihiro, Toshihiro Moriga, Naoaki Kuwata, Yoshiki Iwai, Junichi Kawamura 35 INELASTIC NEUTRON SCATTERING ON SOLID ELECTROLYTE 299 LiILiP03 Evvy Kartini, Masatoshi Aral, Mitsutaka Nakamura, Kenji Nakajima, Wagiyo Honggowiranto, Toha Maksim, Heri Jodi

6 Sm0.2Ce().8Oi.9 xxii 36 IONMOBILITYINA3Fe2(P04)3(A = LiandNa)SYNTHESISEDBY 307 SOLUTION COMBUSTION TECHNIQUE Lakshmi Vijayan, Rajesh Cheruku, G. Covindaraj 37 THERMAL DECOMPOSITION AND PHASE FORMATION OF 317 CERATEZIRCONATE CERAMICS PREPARED WITH DIFFERENT CHELATING AGENTS Nafisah Osman, Nur Athirah Abdullah, Sharizal Hasan 38 CONDUCTIVITY AND 1H NMR STUDIES ON PVP: NH4Br POLYMER 324 ELECTROLYTE N. Vijaya, S. Selvasekarapandian, J. Malathi, Y. Iwai, H. Nithya, J. Kawamura 39 PROTON CONDUCTION AND IMPEDANCE ANALYSIS IN 334 SUBMUCOSA MEMBRANE Yasumitsu Matsuo, Junko Hatori, Hiroshi Oyama 40 IMPROVED OXIDE IONIC CONDUCTIVITY IN PrjNio.xsCuo.jjGaaosCW 340 (PNCGSDC) LAYER BY LAYER FILM Junji Hyodo, Hidehisa Hagiwara, Tatsumi hhihara 41 STRUCTURAL AND ELECTROCHEMICAL PROPERTIES OF 350 LAYERED STRUCTURE La2LiZt(CO)i..A Muhammad Iqbal, Genki Kobayashi, Hirayama Masaaki, Ryoji Kanno 42 PHASEINVERSION TAPE CASTING AND OXYGEN PERMEATION 359 PROPERTIES OF Zro.84Y0.i601.,2Lao.8Sro.2Mn03.,; DUALPHASE MIXED CONDUCTING COMPOSITE MEMBRANES Wei He, Zhaoze Chu, Tong Liu, Chusheng Chen 43 STUDY OF STRUCTURAL AND DIELECTRIC BEHAVIOUR ON 366 CARBON NANOTUBE (CNT) DISPERSED (XPVF: (lx) CH,COONH4} ELECTROLYTE S.L Agrawal, Markandey Singh, Shuchi Pandey, Kamlesh Pandey, Mrigank Mauli Dwivedi 44 PREPARATION AND PROPERTIES OF CHITOSANGRAFT 375 POLY(ACRYLIC AC1D)/GRAPHENE OXIDE NANOCOMPOSTIE HYDROGELS Yiwan Huang, Ming Zeng, Qingyu Xu, Liren Fan 45 STRUCTURAL AND ELECTRICAL RELAXATION STUDIES OF 386 NANOCRYSTALLINE Li2MgTi04 MATERIAL Rajesh Cheruku, Lakshmi Vijayan, G. Govindaraj

7 xxiii 46 CONDUCTION OF Li ION AND APPLICATION TO Li BATTERIES OF 395 Li ION CONDUCTORS Naoto Ojima, Shinji Ono, Masashi Kotobuki 41 FAST ION CONDUCTION IN Li7.tLa3(Zr2_tM.r)0,2 401 (M Ta5+, Nb5+, = x = 0, 0.25) GARNETS Stefan Adams, Gu Wenyi, R. Prasada Rao 48 COMPOSITION OPTIMIZATION OF AlDOPING LITHIUM 41 I MANGANESE OXIDE FROM Al203Li2CO3MnO2 TERNARY SYSTEM Gang He, Xinyan Sun, Jianhe Hong, Mingzhong He 49 STUDY OF ION TRANSPORT BEHAVIOUR IN (PVANH4I):Si NANO COMPOSITE POLYMER ELECTROLYTE Mridula Tripathi, Shivangi Trivedi, Ruby Upadhyay, Markandey Singh, N.D. Pandey, Kamlesh Pandey 50 STUDY OF THE EFFECT ON IONIC CONDUCTIVITY AND 424 STRUCTRAL MORPHOLOGY OF THE Sr DOPED LANTHANUM GALLATE SOLID ELECTROLYTE Kapil Sood, K. Singh, O.P. Pandey 51 STRUCTURAL PREREQUISITES FOR FAST Li+ ION MIGRATION IN 432 Lil0GeP2S12 Stefan Adams 52 PREPARATION, STRUCTURAL CHARACTERIZATION AND IONIC 442 CONDUCTIVITY STUDIES OF CALCIUM DOPED LiZr2(P04)3 M. Prabu, M. V. Reddy, S. Selvasekarapandian, G. V. Subba Rao, B.V.R. Chowdari 53 SYNTHESIS AND CHARACTERIZATION OF LTIHIUM NICKEL 450 VANADATE NANOCRYSTALLITES A, Sakunthala, S. Selvasekarapandian, M.V. Reddy, C. Sanjeevirqja 54 EFFECT OF NbDOPING ON THE IONIC CONDUCTIVITY OF 456 LITHIUM ORTHOSILICATE Xiangwei Wu, Zhaoyin Wen, Jun Jin, Yingying Hu, Jingchao Zhang, Meifen Wu 55 SYNTHESIS AND CHARACTERIZATION OF Bio.oDyojFeOaCoFeA, 462 MULTIFERROIC COMPOSITES Gonglan Ye, Jianmei Xu, Zhenmin Jin, Xiangwen Liu, Zhuang Ma

8 xxiv 56 SYNTHESIS AND VITRIFICATION OF NASICON TYPE LITHIUM 469 BOROPHOSPHATE GLASSES H. Nithya, Junichi Kawamura, Yoshiki Iwai. Reiji Takekawa, Naoaki Kuwaia, Yasutaka Matsuda 57 ELECTRICAL RELAXATION STUDIES OF Lio.5Fe2.5O4 PREPARED BY 479 TWO DIFFERENT TECHNIQUES Viswarupa Mohanty, Rajesh Cheruku, Lakshmi Vijayan, C. Govindaraj 58 SYNTHESIS OFyMnOOH NANORODS BY HYDROTHERMAL 490 METHODS A.K. Jahja, W. Honggowiranto, E. Kartini 59 SYNTHESIS AND CHARACTERIZATION OF LiMn NANOPARTICLES W. Honggowiranto, A.K. Jahja, E. Kartini 60 ELECTROCHEMICAL BEHAVIOUR OF POLYPYRROLE FILMS IN 505 HIGH CONCENTRATED AQUEOUS ELECTROLYTES M.JM. Jafeen, M.A. Careem 61 LASER RAMAN, XRD, DSC AND ACIMPEDANCE ANALYSIS OF 515 POLYMER BLEND ELECTROLYTE BASED ON ECOFRIENDLY PVAPVP BLEND WITH NH4NO3 N. Rajeswari, S. Selvasekarapandian, S.R.S. Prabaharan, J. Kawamura, Y. Iwai, S. Karthikeyan 62 INVESTIGATIONS ON PVA: NH4F:Zr02 COMPOSITE POLYMER 523 ELECTROLYTES K.P. Radha, S. Selvasekarapandian, S. Karthikeyan, C. Sanjeeviraja 63 STUDIES ON PROTON CONDUCTING POLYMER ELECTROLYTES 534 BASED ON PVDFPVA WITH NH4NO3 M. Muthuvinayagam, C. Gopinathan, N. Rajeswari, S. Selvasekarapandian, C. Sanjeeviraja PREPARATION AND CHARACTERISATION OF PVA DOPED WITH 543 BETA ALANINE R. Bhuvaneshwari, S. Karthikeyan, N. Rajeswari, S. Selvasekarapandian, C. Sanjeeviraja.5 PROTON ION CONDUCTING POLYMER ELECTROLYTE PAN: 550 NH4PF6 S. Sikkanthar, S. Karthikeyan, N. Rajeswari, S. Selvasekarapandian, C. Sanjeeviraja

9 XXV 66 STRUCTURAL VARIATION OF LaMn03+(, BY OXYGEN 557 NONSTOICHIOMETRY Eiki Niwa, Hiroki Maeda, Takuya Hashimoto, Junichiro Mizusaki 67 PRESSURE DEPENDENCE OF CRYSTAL STRUCTURE OF AG20 BY 563 XRAY DIFFRACTION MEASUREMENT T. Wada, R. Sakai, M. Itakura, Y. Hayashi, M. Watanabe, Makhsun, T. Sakuma, H. Takahashi, S.A. Danilkin 68 MILLIMETER WAVE ABSORPTION BANDS OF SILVER/COPPER 569 IODIDESPHOSPHATE GLASSES TeruyoshiAwa.no, Toshiharu Takahashi 69 ELECTRICAL RELAXATION STUDIES OF LiNaS04 USING A NEW 577 ANOMALOUS RELAXATION FUNCTION N. S. Krishna Kumar, K. N. Ganesha, G. Govindaraj 70 CONDUCTION CHARACTERISTICS OF SOME LITHIUM FLUORIDE 586 BASED SYSTEMS Dipak Kumar Khatua, Prashant Dabas, K. Hariharan 71 PREPARATION AND CHARACTERIZATION OF NANOTHICKNESS 596 POLYPYRROLE FILMS M.J.M. Jafeen, M.A. Careem, S. Skaarup 72 STUDY OF GLASS AND GLASS CERAMICS IN THE 45PbO: TiO2:22.5B2O3:2.5SiO2 SYSTEM V.K. Deshpande, V.U. Rahangdale 73 FAST ION CONDUCTION OF COPPER IODIDE DOPED 613 CHALCOGENIDE GLASSES T. Usuki, T. Furukawa, K. Kanai, T. Nasu 74 XAFS STUDY OF PLATINUM GROUP METALS OCCLUDED IN 621 LaSc03BASED PEROVSKITE OXIDE BY SOLIDPHASE REACTION AT HIGH TEMPERATURES Hiroyuki Kageyama, Katsuhiro Nomura, Kentaro Ohmi, Mitsuharu Fujita, Tetsuya Veda Part 4: Fundamental, Theories 75 QUASI SOLIDPOLYMER ELECTROLYTES FOR DYE SENSITIZED 631 SOLAR CELLS M.A.K. Lakshman Dissanayake

10 xxvi 76 STRUCTURE MATERIALS Stefan Adams CONDUCTIVITY CORRELATIONS IN BATTERY EFFECTS OF THE INDIRECT IONIC INTERACTION ON THE 651 DIFFUSION OF THE CATION JN THE SILVER HALIDE CRYSTALS WITH THE ROCKSALT STRUCTURE Yoshitaka Michihiro, Kazuya Itsuki, Shigeki Endou, Masaya Isono, Koichi Nakamura, Takashi Ohno 78 COMPLEX HOPPING ION DYNAMICS IN ION CONDUCTING 661 SOLIDS G, Govindaraj 79 ANALYSIS OF ELASTIC PROPERTIES OF METAL BOROHYDR1DES 671 Yutaro Noguchi, Masant Aniya 80 MECHANICAL, THERMAL AND CONDUCTION CHARACTERISTICS 679 OF BINARY PHOSPHATE GLASSES Prashant Dabas, K. Hariharan 81 SIMULATION AND PERFORMANCE ANALYSIS OF LITHIUM 689 BATTERY BANK MOUNTED ON THE HYBRID POWER SYSTEM FOR MOBILE PUBLIC HEALTH CENTER Pratonda Busona, Evvy Kartini 82 INVESTIGATION ON VO.^CNTS NANOCOMPOSITES ACT AS 698 ELECTRODE OF SUPERCAPACITORS Quanyao Zhu, lhaolong Li, Xiaoyan Zhang, Shengnan Huang, Yue Yit, Wen Chen, Galina S. Zakharova 83 TEMPERATURE DEPENDENCE OF ELASTIC PARAMETERS OF 705 IONIC CONDUCTORS Haruhito Sadakuni, Maseru Aniya 84 A THEORETICAL ANALYSIS OF PHYSICAL PROPERTIES OF 714 AQUEOUS TREHALOSE WITH BORAX Sahara, Masaru Aniya 85 VIBRATIONAL STUDY ON FAST PROTON CONDUCTION OF 723 SINGLE CRYSTAL Rb3H(S04)2 0. Kamishima, S. Kamei, Y. Matsuo, N. Kuwata, J. Kawamura 86 STRUCTURE AND ATOMIC DYNAMICS IN MOLTEN RbAg4I5 BY 730 MOLECULAR DYNAMICS SIMULATION Shigeki Matsunaga

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24-2_cover_OK 2 08 Flexible All Solid State Thin Film Li-ion Battery 1 1 2 1 1 2 ( 300Wh/kg) (3.4~3.8 V) ( 1000 cycles) (LiCoO 2 ) (LiPON) (Mica) 26mAhcm -2 mm -1 30 85% LED Abstract With the ever-changing technology,