Table of Content Preface Scope Normative reference Terms and definitions Residue definition Maximum residue l

Transcription

1 ICS G 25 GB 中华人民共和国国家标准 GB Replacing GB National food safety standard-- Maximum Residue Limits for Pesticides in Food Issued on Implement on Released by: Naitional Health and Family Planning Commission Ministry of Agriculture

2 Table of Content Preface Scope Normative reference Terms and definitions Residue definition Maximum residue limit (MRL) Extraneous maximum residue limit (EMRL) Acceptable daily intake (ADI) Technical requirements , 4-D and 2, 4-D Na , 4-D butylate MCPA (sodium) Abamectin Chlormequat Ethametsulfuron Diethyl aminoethyl hexanoate Picloram Paraquat Chlorothalonil Azinphos-methyl Fenthion Fenbutatin oxide Dichlofluanid Tribenuron-methyl Benomyl Fenothiocarb Benzoximate Difenoconazole Mefenacet Benalaxyl Zoxamide Fenamiphos Fenpropidin Pyriproxyfen Pyraflufen-ethyl Imidacloprid Diflufenican Fluazifop and fluazifop-p-butyl I

3 4.30 Pyrazosulfuron-ethyl Pymetrozine Pyraclostrobin Bensulfuron-methyl Pretilachlor Propiconazol Prothioconazole Benfuracarb Oxadiargyl Flumioxazin Propineb Profenofos Glufosinate-ammonium Benazolin-ethyl Glyphosate Chlorfenapyr Tebufenozide Diflubenzuron Kasugamycin Pyridaben Amobam Metriam Mancozeb Zineb Semiamitraz and semiamitraz chloride Canamide Monosulfuron Phenthoate Isoprothiolane Fenoxanil Trichlorfon Propanil Diquat Diuron Dichlorvos Fenaminosulf Anilazine Dinocap Edifenphos Fonofos Butachlor Fenpropimorph Carbosulfan Diafenthiuron II

4 4.74 Flufiprole Coumoxystrobin Acetamiprid Boscalid Picoxystrobin Chlorpyrifos Parathion Dodine Carbendazim Spinosad Paclobutrazol Oxadiazon Hymexazol Oxaziclomefone Oxadixyl Famoxadone Diphenylamine Pendimethalin Clopyralid Quinclorac Diazinon Dithianon Flutriafol Rimsulfuron Phosalone Tau-fluvalinate Flubendiamide Teflubenzuron Haloxyfop Flucetosulfuron Haloxyfop-methyl and haloxyfop-p-methyl Fluopicolide Fipronil Flufenoxuron Fluazinam Sulfoxaflor Flonicamid Chlorfluazuron Flusilazole Epoxiconazole Fomesafen Ttriflumizole Trifluralin Hexaflumuron III

5 4.118 Cyfluthrin and beta-cyfluthrin Flumorph Flucythrinate Flumiclorac Flutolanil Novaluron Flucarbazone-sodium Procymidone Thiram Ziram Fludioxonil Thiobencarb Molinate Diclofop-methyl Cyclosulfamuron Cyproconazole Hexazinone Fenhexamid Pyriftalid Sulcotrione Hexaconazole Emamectin benzoate Methamidophos Phorate Tolylfluanid Alachlor Metsulfuron-methyl Iodosulfuron-methyl-sodium Chlorpyrifos-methyl Parathion-methyl Mesosulfuron-methyl Tolclofos-methyl Phosfolan-methyl Thiophanate-methyl Pirimiphos-methyl Isofenphos-methyl Methiocarb Imazapic Carbaryl Fenpropathrin Metalaxyl and metalaxyl-m Bifenox Methoxyfenozide Imazamox IV

6 4.162 Fenbuconazole Myclobutanil Fenoxaprop-P-ethyl Dimethenamid-P Monocrotophos Pirimicarb Carbofuran Captan Quizalofop and quizalofop-p-ethyl Oxine-copper Quinalphos Fenazaquin Quinoxyfen Dimethoate Bifenazate Bifenthrin Bitertanol Phosphamidon Aluminium phosphide Megnesium phosphide Hydrogen phosphide phenylphenol Endosulfan Phosfolan Thiodicarb Sulfuryl fluoride Cadusafos Spirotetramat Spirodiclofen Chlortoluron Aminopyralid Chlorpropham Fenarimol Halosulfuron-methyl Forchlorfenuron Chlorantraniliprole Lvdingjunzhi Fluroxypyr and fluroxypyr-mepthyl) Cyhalothrin and lambda-cyhalothrin) Chloropicrin Chlorsulfuron Permethrin Chlorimuron-ethyl Cypermethrin and beta-cypermethrin V

7 4.206 Imidaclothiz Dicloran Isazofos Malathion Dicamba Prochloraz and prochloraz-manganese chloride complex) Imazaquin Imazethapyr Cinosulfuron Etofenprox Kresoxim-methyl Orthosulfamuron Azoxystrobin Cyprodinil Pyrimethanil Bentazone Methomyl Folpet Blasticidin-S Ethoprophos Mepronil Cyromazine Chlorbenzuron naphthylacetic acid and sodium 1-naphthalacitic acid Ningnanmycin Demeton Dimepiperate Triforine Metribuzin Cyanazine Cyhalofop-butyl Cyazofamid Fenvalerate and esfenvalerate Clodinafop-propargyl Propargite Lactofen Thidiazuron Thiacloprid Thiamethoxam Thifensulfuron-methyl Thifluzamide Dimethipin Thiabendazole Hexythiazox VI

8 4.250 Henziothiazolinone Buprofezin Fosthiazate Zinc-thiazole Fentin hydroxide Acifluorfen Tricyclazole Dicofol Tetradifon Fosetyl-aluminium Cyhexatin Triadimenol Triazophos Triadimefon Azocyclotin Amitrole Thiosultap-monosodium Thiocyclam Chlordimeform Bisultap thiosultap-disodium Triflumuron Cartap Fenitrothion Methidathion Oxamyl Bioresmethrin Florasulam [iminoctadinetris (albesilate)] Amitraz Mandipropamid Propamocarband propamocarb hydrochloride Cymoxanil Isocarbophos Metaldehyde Fthalide phthalide Tecnazene Clofentezine Terbufos Aldicarb Desmedipham Phenmedipham Metam-sodium Carboxin Trifloxystrobin VII

9 4.294 Quintozene Penconazole Tebuconazole Simetryn Simazine Clethodim Nitenpyram Sethoxydim Xiwojunan Dimethomorph Diniconazole Amidosulfuron Mesotrione Phoxim Bromoxynil Methyl bromide Bromothalonil Bromopropylate Deltamethrin Vamidothion Phosmet Ooxydemeton-methyl Imibenconazole Nicotine Nicosulfuron Omethoate Triallate Difenzoquat Ivermectin Acetochlor Ethiprole Spinetoram Ethion Etoxazole Diethofencarb Ethirimol Fluoroglycofen-ethyl Ethylicin Vinclozolin Ethephon Acephate Ethoxyquin Oxyfluorfen Ethoxysulfuron VIII

10 4.338 Propisochlor Metolachlor and s-metolachlor) Isoproturon Isoprocarb Iprobenfos Clomazone Iprodione Imazalil Maleic hydrazide Azadirachtin Indoxacarb Coumaphos Ametryn Atrazine Rotenone Piperonyl butoxide Sulfotep Butralin Fenobucarb Carfentrazone-ethyl Tolfenpyrad Fenpyroximate Flumetsulam Pyraoxystrobin Aldrin DDT Dieldrin Camphechlor Lindane HCB Chlordane Mirex Heptachlor Endrin Informative Appendix A Informative Appendix B Informative Appendix C IX

11 Preface This standard is formulated pursuant to rules provided in the GB/T 1.1 (Directives for standardization) This standard replaces the GB *, and differ from the GB in the following sapects: Verified and changed the definition of three pesticides (benomyl, fipronil, and nitenpyram), and ADI of nine pesticides, including MCPA (sodium); Added 65 pesticide nmaes; Added 1,357 MRL of pesticdes; Added 15 testing method standards, and removed one testing method standard; Amended the Informative Annex A; specified food categories and parts to be tested; added 66 food names, including Triticale; * Note: implementation of the GB annulled the following standards: GB Maximum Residue Limits for Pesticides in Food; GB Maximum Residue Limits for Pesticides in Food First Modification; Section (MRL of Pesticides) in GB Hygienic Standard of Cereals; GB MRL of 12 Pesticides (Including Chlorothalonil) in Foods; GB MRL of 54 Pesticides (including paraquat) in Foods; GB MRL of 85 Pesticides (including abamectin) in Foods; NY Maximum Residue Limits Of Carbaryl, Carbosulfan,Carbendazim,Propoxur and Pirimicarb in Tea; NY MRL of Cyfluthrin and Flucythrinate in Tea; NY Maxiumum Residue Limits Of Alachlor,Carbonfuran,Chlorothalonil, Fenamiphos and Metolachlor in Peanuts; NY Maximum Residue Limits for Acetamiprid in Fruits; NY Maximum Residue Limits for Pesticides in Leafy Vegetable; NY Maximum Residue Limits for Pesticides in Corn; NY MRL of Benzoximate, Buprofezin, Cypermethrin, Fenothiocarb, Fenpropathrin, Fenpyroximate, and Teflubenzuron in Citrus; 1

12 NY MRl of Pesticides in Agricultural Products; NY MRL of 20 Pesticides (including methamidophos) in Vegetables and Fruits; NY MRl of Pesticides in Agricultural Products. 2

13 Maximum Residue Limits of Pesticides in Foods 1 Scope This standard regulates the 3,650 maximum residue limits of 387 pesticides including 2,4-D, etc. in food. The standard applies to the food related to residue limits. The food categories and evaluation parts (Appendix A) is used to define the application scope of the pesticides maximum residue limits, which applies only to this standard. For instance, the maximum residue limit of a pesticide is applicable for a certain food category, all the food in this category will be applicable to this MRL, except special provisions 2 Normative reference The reference files in this standard is essential to the application of the standard. For dated references, only the dated versions apply to this standard. For not dated references, the latest version (including all amendments) applies in this standard. GB/T Determination of organochlorine pesticide multiresidues in foods GB/T Determination of organophosphorous pesticide residues in foods GB/T Determination of carbaryl residues in cereals, oils and vegetables GB/T Analytical methods for hygienic standard of grain GB/T Determination of phoxim pesticide residues in vegetable foods GB/T Determination of methamidophos and acephate pesticide residues in vegetable foods GB/T Determination of carbamate pesticide residues in vegetable foods GB/T Determination of chlorothalonil residues in cucumber GB/T Determination of diazinon residues in vegetable foods GB/T Determination of cypermethrin,fenvalerate and deltamethrin residues in vegetable foods GB/T Determination of thiocyclam residues in rice GB/T Determination of bisultap residues in rice 3

14 GB/T Determination of tricyclazole residues in rice GB/T Determination of triadmefon residues in vegetable foods GB/T Determination of ethoxyquin residues in fruits GB/T Determination of fomesafen residues in soybeans and cereals GB/T Determination of phosmet residues in vegetable foods GB/T Determination of atrazine residues in foods GB/T Determination of chlorotoluron residues in grains GB/T Determination of molinate residues in rice GB/T Determination of chlorbenzuron residues in vegetable foods GB/T Determination of quintozene residues in vegetable foods GB/T Determination of fluazifop-butyl and its acid residues in vegetable food GB/T Determination of amitraz residues in vegetables,fruits,edible oil GB/T Determination of isofenphos-methyl residues in vegetable foods GB/T Determination of organophosphorus and carbamate pesticide multiresidues in vegetable foods GB/T Determination of organochlorines and pyrethroid pesticide multiresidues in vegetable foods GB/T Determination of diflubenzuron residues in vegetable foods GB/T Determination of isoprothiolane residues in rice GB/T Determination of semianitraz residues in fruits GB/T Determination of organochlorine pesticide and pyrethroid pesticide multiresidues in animal original foods GB/T Determination of butachlor residues in rice GB/T Determination of 2, 4-D butylate residues in grains GB/T Determination of trifluralin residues in soybean, peanut, soybean oil, peanut oil GB/T Determination of metolachlor residues in peanut and soybean GB/T Determination of 2, 4-D in grains and vegetables GB/T Determination of dicofol residues in tea, fruits, edible evgetable oils GB/T Determination of propanil residues in rice 4

15 GB/T Determination of oxadiazon residues in cereals and peanuts GB/T Determination of buprofezin in cereals and vegetables GB/T Determination of difenzoquat residues in wheat GB/T Determination of diniconazole residues in pear GB/T Determination of multi pesticide residues in fruits and vegetables GB/T Determination of the residues of chlorcholine chloride in cereals GB/T Determination of the residues of anilazine in cereals GB/T Determination of the residues of diquat in cereals GB/T Cereal, fruit and vegetable quality - Determination of Organophosphorus pesticides -Gas chromatography GB/T Method for determination of aldicarb residues in peanut cottonseed oil and peanut oil GB/T Tobacco and tobacco products - Determination of maleic hydrazide residues - UV Spectrophotometer Method GB/T Method for determination of 500 pesticides and related chemicals residues in fruits and vegetables - GC-MS method GB/T Method for determination of 475 pesticides and related chemicals residues in grains - GC-MS method GB/T Determination of 450 pesticides and related chemicals residues in fruits and vegetables - LC-MS-MS method GB/T Determination of 372 pesticides and related chemicals residues in grains - LC-MS-MS method GB/T Determination of residue limits of fluroxypyr in rice, vegetable and fruit GB/T Determination of ivermectin,abamectin,doramectin and eprinomectin residues in milk and milk powder - LC-MS-MS method GB/T Determination of 519 pesticides and related chemicals residues in tea. GC-MS method GB/T Determination of 448 pesticides and related chemicals residues in tea - LC-MS-MS method GB/T Determination of 512 pesticides and related chemicals residues in fruit juice vegetable juice and fruit wine - LC-MS-MS method 5

16 GB/T rmination of 511 pesticides and related chemicals residues in milk and milk powder -GC-MS GB/T Determination of 503 pesticides and related chemicals residues in mushrooms - GC-MS GB/T Determination of pesticides residues in tea - GC/MS method GB/T Determination of imidacloprid residues in fruits,vegetables and teas - HPLCHPLC GB/T Determination of carbendazim residues in fruits and vegetables HPLC GB/T Determination of acetamiprid residue in fruits and vegetables Liquid chromatography-tandem mass spectrometry GB/T Determination of Glyphosate residues in plant products-gc-ms method GB/T Method for determination of triazine herbicide residues in soybean GB/T Determination of imidazolinone herbicide residues in soybean GB/T Inspection of grain and oils - Determination of phosphide residues in grain - Spectrophotometric method NY/T 761 Pesticide multiresidue sceen methods for determination of organophosphorus pesticides, organochlorine pesticides, pyrethroid pesticides and carbamate pesticedes in vegetables and fruits NY/T 1016 Determination of ethephon residues in fruits and vegetables - gas chromatogram method NY/T 1096 Determination of glyphosate residues in food NY/T 1275 Determination of Imidacloprid Residual in Vegetables and Fruits NY/T 1277 Determination of Iprodione Residues in Vegetables by HPLC NY/T 1379 Multi-residue Determination of 334 Pesticides in Vegetable by GC/MS and LC/MS NY/T 1434 Multi-residue Determination of D and Other 12 Herbicides in Vegetable by LC/MS NY/T 1453 Determination of 16 pesticide residues in fruits and vegetables by LC - MS/MS NY/T 1455 Determination of myclobutanil residue in fruits by gas chromatogram NY/T 1456 Determination of prochloraz residue in fruits by gas chromatography NY/T 1616 Determination of Nine sulfonylurea herbicides residues in soils by LC-MS NY/T 1652 Determination of propargite residues in vegetables and fruits - GC NY/T 1679 Determination of carbamate pesticide residues in vegetable foods by LC - MS/MS NY/T 1680 Determination of carbendazim and other 3 benzimidazoles in vegetable and fruit by HPLC 6

17 NY/T 1720 Determination of seven benzoylurea pesticides residues in fruits and vegetables by HPLC NY/T 1722 Determination of anilazine residue in vegetables by HPLC NY/T 1725 Determination of cyromazine residue in vegetables by HPLC SN 0139 Method for determination of dithiocarbamate residues in grain for export SN 0150 Method for determination of axocyclotinresidue in fruit for export SN 0157 Method for determination of dithiocarbamate residue in fruit for export SN 0192 Method for determination of bromopropylateresidues in fruits for export SN 0209 Method for determination of phoxim residues in grains for export SN 0279 Method for the determination of amitrazresidues in fruits for export SN 0287 Method for the determination of ethoxyquinresidues in fruits for Export - Liquid chromatography SN 0340 Method for the determination of paraquat residues in cereals vegetables for export - UV-spectrophotometric method SN 0345 Method for the determination of dimehyporesidues in vegetables for export SN 0346 Method for the determination of α-naphthylacetic acid residues in vegetables for export: SN 0492 Method for the determination of thiobencarb residues in cereals for export SN 0499 Method for the determination of chlorothalonil residues in fruits and vegetables for export SN 0500 Method for the determination of dodine residues in fruits for export SN 0522 Method for the determination of terbufos residues in cereals for export SN 0584 Method for the determination of vinclozolin residues in cereals and oil seeds for export SN 0585 Method for the determination of acephate residues in cereals and oil seeds for export SN 0592 Method for the determination of fenbutatin oxide residues in cereals and oil seeds for export SN 0597 Method for the determination of o-phenylphenol and its sodium salt residues in fruits for export SN 0649 Method for the determination of methyl bromide residues in cereals for export SN 0654 Method for the determination of captan residues in fruits for export SN 0685 Method for the determination of propamocarb residues inf cereals for export 7

18 SN 0687 Method for the determination of diclofop-methyl residues in cereals and oil seeds for export SN 0695 Method for the determination of triforine residues in cereals for export SN 0701 Method for the determination of phosphamidon residues in cereals for export SN/T 0134 Determination of pesticide residues of 12 kinds carbamates including oxamyl in foods for import and export LC-MS/MS method SN/T 0292 Determination of bentazon residues in cereals for import and export SN/T 0351 Determination of ethoprophos residues in foods for import and export SN/T 0519 Determination of propiconazole residue in food for import and export SN/T 0711 Method for the determination of total residues of ethylene bisdithiocarbamate pesticides in tea for export SN/T 0712 Determination of 11 herbicide resdues in cereals and soybean for import and export. GC-MS method SN/T Method for the determination of quinclorac residues in cereals and oil seeds for export SN/T Determination of imidacloprid residues in cereals for import and export SN/T 1114 Determination of diniconazole residues in fruits for import and export: SN/T Determination of diniconazole residues in fruits for import and export SN/T 1117 Determination of multiple pyrethroid residues in food for import and export - Gas chromatography method SN/T 1477 Inspection of paclobutrazol residues in food for import and export SN/T 1541 Inspection of the total residues of dithiocarbamate pesticides in tea for export SN/T 1605 Inspection of cyanazin fluometuron atrazine propanil and linuron residues in products of plant origin for import and export - HPLC SN/T 1606 Inspection of phenoxy acid herbicides residues in products of plant origin for import and export - gc SN/T Determination of herbicides residues-part 2:Determination of diphenyl ether herbicides residues in cereal and oilseed by GC/MS method SN/T 1739 Determination of organophosphrous pesticides residues in cereals and oil seeds for import and export-gas chromatography mass spectrometry method 8

19 SN/T 1740 Determination of clofentezine residues in foods for import and export-gc/ms SN/T 1741 Determination of alachlor residues in foods for import and export GC/MS SN/T 1923 Determination of glyphosate residues in food for import and export - HPLC-MS/MS method SN/T 1967 Determination of iprobenfos residues in food for import and export SN/T 1969 Determination of bifenthrin residue in food for import and export-gc-ms method SN/T 1973 Determination of abamectin residues in food for import and export-hplc-ms/ms method SN/T 1975 Determinaiton of difenoconazole residue in food for import and export-gc-ms method SN/T 1976 Determination of azoxystrobin residues in fruit and vegetable for import and export-gc method SN/T 1977 Determination of fenpyroximate residues in fruit and vegetable for import and export-hplc method SN/T 1982 Determination of fipronil residues in food for import and export-gc-ms method SN/T 1983 Determination of flumioxazin residues in food for import and export-gc-ms method SN/T 1986 Determination of chlorfenapyr residues in food for import and export SN/T 1990 Determination of azocyclotin and cyhexatin residues in food for import and export-gc-ms method SN/T 2095 Determination of chlorfluazuron residues in vegetables for import and export - HPLC SN/T 2114 Determination of abamectin residues in fruit and vegetable for import and export - LC method SN/T 2147 Determination of cadusafos residues in food for import and export SN/T 2149 Determination of benoxacor, anilofos, allidochlor 110 pesticides residues in foodstuffs for import and export - GC-MS Method SN/T 2150 Determination of residues of aldoxycarb, pyraclostrobin, azoxystrobin 65 pesticides in foodstuffs for import and export - LC-MS/MS method SN/T 2151 Determination of pesticides residue of 28 kinds of including bioresmethrin, acinathrin, bifenthrin in food import and export - GC-MS method SN/T 2152 Determination of hexaflumuron residue in food for import and export - HPLC-MS/MS 9

20 method SN/T 2158 Determination of chlorpyrifos residue in foods for import and export SN/T 2212 Determination of bensulfuron methyl residues in cereals for import and export - Liquid chromatography SN/T 2228 Determination of 31 acid pesticide residues in foods for import and export - GC-MS method SN/T 2232 Determination of triadimenol residue in foods for import and export - GC-MS method SN/T 2233 Determination of fenpropathrin residue in food for import and export SN/T 2234 Determination of profenofos residue in food for import and export - GC and GC-MS method SN/T 2236 Determination of flusilazole residues in food for import and export - GC-MS method SN/T 2320 Determination of chlorthalonil, dichlofluanid, tolylfluanid, captan, folpet, captafol and deltamethrin residues in food for import and export GC-MS method SN/T 2322 of cetochlor residue in foods for import and export SN/T 2324 Determination of 33 organophosphrous pesticides residues (butamifos, chlorpyrifos, chlorpyrifos-methyl et al infoodstuffs) for import and export SN/T 2325 Determination of 45 pesticides residues including azimsulfron, bensulfron-methyl, cinousulfron et al in foods for import and export - HPLC-MS/MS method SN/T 2397 Method for determination of Nicotine in foods for import and export SN/T 2432 Determination of pyridaben residues in food for import and export SN/T 2433 Determination of clodinafop propargyl residues in food for import and export SN/T 2459 Determination of flumiclorac-pentyl residues in food for import and export. GC-MS method SN/T 2560 Determination of carbamate pesticide residues in food for import and export - LC-MS method YC/T 180 Tobacco and tobacco products-determination of camphechlor residues-gc method 3 Terms and definitions The terms and definitions below apply to this standard. 3.1 Residue definition 10

21 Any particular substance in food, agricultural products and animal feed due to the use of pesticides, including the pesticide derivatives which is considered to have toxicological significance, such as pesticide conversion products, metabolites, reaction products and impurities, etc. 3.2 Maximum residue limit (MRL) The statutory maximum concentration of pesticide residues that allowed in the internal or surface of food or agricultural products, expressed as the milligrams of pesticide residues per kilogram of food or agricultural products (mg/kg). 3.3 Extraneous maximum residue limit (EMRL) Although some persistent residual pesticides have been prohibited, they ll presence in the environment for a long time, which is in the formation of residues in food once again. Develop the residue limits in food in order to control contamination of these kinds of pesticide residues on food. Expressed as the milligrams of pesticide residues per kilogram of food or agricultural products (mg/kg). 3.4 Acceptable daily intake (ADI) The estimated amount that human lifetime daily intake of a substance but without creating detected health hazards. Expressed by the amount of intake per kilogram of body weight (mg/kg). 4 Technical requirements 4.1 2, 4-D and 2, 4-D Na Major purpose of use: Herbicide ADI: 0.01 mg/kg bw Residue definition: 2, 4-D Maximum residue limit: Shall comply with provisions in the Table 1. Table 1 Cereals Oil seed and oil Vegetables Wheat 2 Rye 2 Corn 0.05 Fresh maize 0.1 Sorghum 0.01 Soybean 0.01 Celery cabbage 0.2 Tomato

22 Fruit Eggplant 0.1 Chili 0.1 Potato 0.2 Cactus 0.05 Citrus fruit 1 Pome fruit 0.01 Stone fruit 0.05 Berries and other small fruits 0.1 Nuts 0.2 Sugar crop Sugarcane 0.05 Edible fungi Mushroom (fresh) 0.1 GB Testing method: Cereals (with the exception of sorghum), vegetables, and edible fungi shall be tested by methods provided in tested by methods provided in GB/T ; testing of sorghum, oil seed and oil, fruits, nuts, and sugar crops shall refer to methods provided in NY/T , 4-D butylate Major purpose of use: Herbicide ADI: 0.01 mg/kg bw Residue definition: 2, 4-D butylate Maximum residue limit: Shall comply with provisions in the Table 2. Table 2 Cereals Corn Testing method: Cereals shall be tested by methods provided in GB/T , GB/T MCPA (sodium) Major purpose of use: Herbicide ADI: 0.1 mg/kg bw Residue definition: MCPA Maximum residue limit: Shall comply with provisions in the Table 3. Table 3 Cereals Fruit Sugar crop Brown rice 0.05 Corn 0.05 Citrus 0.1 Sugarcane

23 4.3.5 Testing method: testing of grain, sugar crops shall refer to methods provided in SN/T 2228; fruits shall be tested by methods provided in by methods provided in GB/T Abamectin Major purpose of use: pesticide ADI: mg/kg bw Residue definition: (total of B1a and B1b) Maximum residue limit: Shall comply with provisions in the Table 4. Table 4 Cereals Brown rice 0.02 Oil seed and oil Cotton seed 0.01 Vegetables Leek 0.05 Head cabbage 0.05 Broccoli 0.5 Spinach 0.05 Ordinary cabbage 0.05 Lettuce 0.05 Celery 0.05 Celery cabbage 0.05 Tomato 0.02 Sweet pepper 0.02 Cucumber 0.02 Squash 0.01 Cowpea 0.05 Kidney bean 0.1 Radish 0.01 Potato 0.01 Fruit Citrus fruit (with the exception of citrus) 0.01 Citrus 0.02 Apple 0.02 Pear 0.02 Strawberry 0.02 Melons 0.01 Nuts Beverages Almond 0.01 Walnut 0.01 Hop

24 Condiment Dried chilli 0.2 Pepper 0.05 GB Testing method: Cereals shall be tested by methods provided in SN/T 1973; Oil seed and oil shall be tested by methods provided in SN/T 1973; Vegetables, fruits shall be tested by methods provided in by methods provided in SN/T 1973, SN/T 2114; testing of nuts, beverages, and condiment shall refer to methods provided in SN/T Chlormequat Major purpose of use: plant growth regulator ADI: 0.05 mg/kg bw Residue definition: Chlormequat cation, expressed as chloride compound Maximum residue limit: Shall comply with provisions in the Table 5. Table 5 Cereals Wheat 5 Barley 2 Oats 10 Rye 3 Triticale 3 Corn 5 Rye flour 3 Whole rye flour 4 Oil seed and oil Rapeseed 5 Crude rapeseed oil 0.1 Cotton seed Testing method: Cereals shall be tested by methods provided in GB/T ; Oil seed and oil shall be tested by methods provided in GB/T Ethametsulfuron Major purpose of use: Herbicide ADI: 0.2 mg/kg bw Residue definition: Ethametsulfuron Maximum residue limit: Shall comply with provisions in the Table 6. Table 6 Oil seed and oil Rape seed Testing method: Oil seed and oil shall be tested by methods provided in NY/T

25 4.7 Diethyl aminoethyl hexanoate Major purpose of use: plant growth regulator ADI: mg/kg bw Residue definition: Diethyl aminoethyl hexanoate Maximum residue limit: Shall comply with provisions in the Table 7. Table Picloram Cereals Vegetables Corn 0.2 * Ordinary cabbage 0.05 * Celery cabbage 0.2 * *The MRL is the temporary limit Major purpose of use: Herbicide ADI: 0.3 mg/kg bw Residue definition: Picloram Maximum residue limit: Shall comply with provisions in the Table 8. Table Paraquat Oil seed and oil Rape seed 0.1 * *The MRL is the temporary limit Major purpose of use: Herbicide ADI: mg/kg bw Residue definition: Paraquat cation, expressed as dichloro paraquat Maximum residue limit: Shall comply with provisions in the Table 9. Table 9 Cereals Corn 0.1 Sorghum 0.03 Coarse cereals 0.5 Wheat flour 0.5 Oil seed and oil Rapeseed oil 0.05 Cotton seed 0.2 Soybean 0.5 Sunflower seed 2 Vegetables 15

26 Bulb vegetables 0.05 Brassica vegetables 0.05 Leaf vegetables 0.05 Solanaceous vegetables 0.05 Gourd vegetables 0.05 Leguminous vegetables 0.05 Stem vegetable 0.05 Root, tuber and tuberous rooted vegetables 0.05 Aquatic vegetables 0.05 Sprout vegetables 0.05 Other vegetables 0.05 Fruit Citrus fruit (with the exception of citrus) 0.02 Citrus 0.2 Pome fruit (with the exception of apples) 0.01 Apple 0.05 Stone fruit 0.01 Berries and other small fruits 0.01 Olive 0.1 Tropical and sub-tropical fruits inedible peel (with the exception of bananas) 0.01 Banana 0.02 Melons 0.02 Nuts 0.05 Beverages Hop 0.1 GB Testing method: Cereals, vegetables, fruits shall be tested by methods provided in SN 0340; Oil seed and oil shall be tested by methods provided in SN 0340; Nuts, beverages shall be tested by methods provided in SN Chlorothalonil Major purpose of use: fungicide ADI: 0.02 mg/kg bw Residue definition: Chlorothalonil Maximum residue limit: Shall comply with provisions in the Table 10. Table 10 Cereals Rice 0.2 Wheat 0.1 Fresh maize 5 Mung bean

27 Oil seed and oil Vegetables Fruit Adsuki bean 0.2 Soybean 0.2 Peanut 0.05 Spinach 5 Ordinary cabbage 5 Lettuce 5 Celery cabbage 5 Tomato 5 Eggplant 5 Chili 5 Cucumber 5 Squash 5 Loofah 5 Pumpkin 5 Citrus 1 Apple 1 Pear 1 Grape 0.5 Water melon 5 Sweet melon 5 Edible fungi Mushroom (fresh) 5 GB Testing method: Cereals shall be tested by methods provided in SN/T 2320; Oil seed and oil shall be tested by methods provided in SN/T 2320; Vegetables, fruit, edible fungi shall be tested by methods provided in NY/T 761, SN 0499, GB/T Azinphos-methyl Major purpose of use: pesticide ADI: 0.03 mg/kg bw Residue definition: Azinphos-methyl Maximum residue limit: Shall comply with provisions in the Table 11. Table 11 Oil seed and oil Soybean 0.05 Cotton seed 0.2 Vegetables Vegetables (with the exception of the separately listed) 0.5 Broccoli 1 17

28 Tomato 1 Sweet pepper 1 Cucumber 0.2 Potato 0.05 Fruit Fruit (with the exception of the separately listed) 1 Apple 2 Pear 2 Peach 2 Cherry 2 Nectarine 2 Prune 2 Dried prune 2 Blueberry 5 Cranberry 0.1 Water melon 0.2 Sweet melons 0.2 Nuts Sugar crop Almond 0.05 Carya cathayensis 0.3 Sugarcane 0.2 Condiment Condiment (with the exception of the separately listed) 0.5 Dried chilli 10 GB Testing method: testing of oil seed and oil, Potato, nuts, sugar crops, and condiment shall refer to methods provided in SN/T 1739; Vegetables (with the exception of potatos), fruits shall be tested by methods provided in by methods provided in NY/T Fenthion Major purpose of use: pesticide ADI: mg/kg bw Residue definition: The sum of fenthion and its oxygen analogues (sulfoxide, sulfone compound), expressed as fenthion Maximum residue limit: Shall comply with provisions in the Table 12. Table 12 Cereals Oil seed and oil Rice 0.05 Wheat

29 Edible vegetable oil 0.01 Virgin olive oil 1 Vegetables Bulb vegetables 0.05 Brassica vegetables 0.05 Leaf vegetables 0.05 Solanaceous vegetables 0.05 Gourd vegetables 0.05 Leguminous vegetables 0.05 Stem vegetable 0.05 Root, tuber and tuberous rooted vegetables 0.05 Aquatic vegetables 0.05 Sprout vegetables 0.05 Other vegetables 0.05 Fruit Citrus fruit 0.05 Pome fruit 0.05 Stone fruit (with the exception of cherry) 0.05 Cherry 2 Berries and other small fruits 0.05 Tropical and sub-tropical fruits (with the exception of olive) 0.05 Olive 1 Melons 0.05 GB Testing method: Cereals shall be tested by methods provided in GB/T ; Oil seed and oil shall be tested by methods provided in GB/T ; Vegetables, fruits shall be tested by methods provided in NY/T 761, GB/T Fenbutatin oxide Major purpose of use: Acaricide ADI: 0.03 mg/kg bw Residue definition: Fenbutatin oxide Maximum residue limit: Shall comply with provisions in the Table 13. Table 13 Vegetables Fruit Tomato 1 Cucumber 0.5 Citrus 1 Preserved citrus 25 Lemon 5 19

30 Pummelo 5 Orange 5 Pome fruits (with the exception of apple and pear) 5 Apple 5 Pear 5 Cherry 10 Peach 7 Prune 3 Dried prune 10 Grape 5 Raisin 20 Strawberry 10 Banana 10 Nuts Almond 0.5 Carya cathayensis 0.5 Walnut 0.5 GB Testing method: testing of Vegetables, fruit, and nuts shall refer to methods provided in SN Dichlofluanid Major purpose of use: fungicide ADI: 0.3 mg/kg bw Residue definition: Dichlofluanid Maximum residue limit: Shall comply with provisions in the Table 14. Table 14 Vegetables Fruit Onion 0.1 Lettuce 10 Tomato 2 Chili 2 Cucumber 5 Potato 0.1 Apple 5 Pear 5 Peach 5 Current (black, red, white) 15 Raspberry 7 Gooseberry (red, black) 15 Grape 15 Strawberry 10 20

31 Condiment Dried chilli Testing method: testing of Vegetables, fruits, and condiment shall refer to methods provided in SN/T Tribenuron-methyl Major purpose of use: Herbicide ADI: 0.01 mg/kg bw Residue definition: Tribenuron-methyl Maximum residue limit: Shall comply with provisions in the Table 15. Table 15 Cereals Wheat Testing method: Cereals shall be tested by methods provided in SN/T Benomyl Major purpose of use: fungicide ADI: 0.1 mg/kg bw Residue definition: The sum of Benomyl and carbendazim, expressed as carbendazim Maximum residue limit: Shall comply with provisions in the Table 16. Table 16 Fruit *The MRL is the temporary limit. Citrus 5 * Pear 3 * Testing method: fruits shall be tested by methods provided in GB/T 23380, NY/T Fenothiocarb Major purpose of use: Acaricide ADI: mg/kg bw Residue definition: Fenothiocarb Maximum residue limit: Shall comply with provisions in the Table 17. Table 17 Fruit *The MRL is the temporary limit. Citrus 0.5 * Testing method: fruits shall be tested by methods provided in GB/T Benzoximate Major purpose of use: Acaricide. 21

32 ADI: 0.15 mg/kg bw Residue definition: Benzoximate Maximum residue limit: Shall comply with provisions in the Table 18. Table 18 Fruit *The MRL is the temporary limit. Citrus 0.3 * Testing method: fruits shall be tested by methods provided in GB/T Difenoconazole Major purpose of use: fungicide ADI: 0.01 mg/kg bw Residue definition: Difenoconazole Maximum residue limit: Shall comply with provisions in the Table 19. Table 19 Cereals Brown rice 0.5 Wheat 0.1 Oil seed and oil Rape seed 0.05 Soybean 0.05 Peanut 0.2 Sunflower seed 0.02 Vegetables Garlic 0.2 Scallion 0.3 Head cabbage 0.2 Brussels sprouts 0.2 Sprouting broccoli 0.5 Broccoli 0.2 Stem and leaf lettuce 2 Cabbage lettuce 2 Celery cabbage 1 Tomato 0.5 Cucumber 1 Edible podded pea 0.7 Asparagus 0.03 Carrot 0.2 Celeriac 0.5 Potato 0.02 Fruit GB

33 Citrus 0.2 Pome fruits (with the exceptance of apple and pear) 0.5 Apple 0.5 Pear 0.5 Prune 0.2 Dried prune 0.2 Peach 0.5 Nectarine 0.5 Cherry 0.2 Passion fruit 0.05 Olive 2 Litchi 0.5 Mango 0.07 Banana 1 Papaya 0.2 Water melon 0.1 Nuts 0.03 Sugar crop Beverages Medicinal plant Sugar beet 0.2 Tea 10 Ginseng 0.5 GB Testing method: Cereals shall be tested by methods provided in GB/T 19649; Oil seed and oil shall be tested by methods provided in SN/T 1975; Vegetables, fruits shall be tested by methods provided in SN/T 1975, GB/T , GB/T 19648; testing of tea shall refer to methods provided in SN/T 1975, GB/T , GB/T 19648; testing of nuts, sugar crops, and medicinal plant shall refer to methods provided in SN/T 1975, GB/T , GB/T Mefenacet Major purpose of use: Herbicide ADI: 0.007mg/kg bw Residue definition: Mefenacet Maximum residue limit: Shall comply with provisions in the Table 20. Table 20 Cereals Brown rice 0.05 * *The MRL is the temporary limit Testing method: Cereals shall be tested by methods provided in GB/T 19649, GB/T 20770, SN/T

34 4.21 Benalaxyl Major purpose of use: fungicide ADI: 0.07 mg/kg bw Residue definition: Benalaxyl Maximum residue limit: Shall comply with provisions in the Table 21. Table 21 Vegetables Fruit Onion 0.02 Cabbage lettuce 1 Tomato 0.2 Potato 0.02 Grape 0.3 Water melon 0.1 Sweet melons Testing method: vegetables, fruits shall be tested by methods provided in GB/T 19648, GB/T Zoxamide Major purpose of use: fungicide ADI: 0.5 mg/kg bw Residue definition: Zoxamide Maximum residue limit: Shall comply with provisions in the Table 22. Table 22 Vegetables Fruit Tomato 2 Gourd vegetables 2 Potato 0.02 Grape 5 Raisin 15 Melons Testing method: Vegetables, fruits shall be tested by methods provided in GB/T 19648, GB/T Fenamiphos Major purpose of use: pesticide ADI: mg/kg bw Residue definition: The sum of Fenamiphos and its oxygen analogue (sulfoxide, sulphone), expressed as Fenamiphos. 24

35 Maximum residue limit: Shall comply with provisions in the Table 23. Table 23 Oil seed and oil Peanut 0.05 Peanut oil 0.05 Vegetables Bulb vegetables 0.02 Brassica vegetables 0.02 Leaf vegetables 0.02 Solanaceous vegetables 0.02 Gourd vegetables 0.02 Leguminous vegetables 0.02 Stem vegetable 0.02 Root, tuber and tuberous rooted vegetables 0.02 Aquatic vegetables 0.02 Sprout vegetables 0.02 Other vegetables 0.02 Fruit Pome fruit 0.02 Citrus fruit 0.02 Stone fruit 0.02 Berries and other small fruits 0.02 Tropical and sub-tropical fruits 0.02 Melons 0.02 GB Testing method: Oil seed and oil shall be tested by methods provided in GB/T 20770; Vegetables, fruits shall be tested by methods provided in GB/T , GB/T Fenpropidin Major purpose of use: fungicide ADI: 0.02mg/kg bw Residue definition: Fenpropidin Maximum residue limit: Shall comply with provisions in the Table 24. Table 24 Cereals Wheat Testing method: Cereals shall be tested by methods provided in GB/T Pyriproxyfen Major purpose of use: pesticide ADI: 0.1 mg/kg bw. 25

36 Residue definition: Pyriproxyfen Maximum residue limit: Shall comply with provisions in the Table 25. Table 25 Oil seed and oil and oil Vegetables Fruit Cotton seed 0.05 Crude cotton seed oil 0.01 Cotton seed oil 0.01 Tomato 1 Citrus fruit 0.5 GB Testing method: Oil seed and oil shall be tested by methods provided in GB/T 19648; Vegetables, fruits shall be tested by methods provided in GB/T Pyraflufen-ethyl Major purpose of use: Herbicide ADI: 0.2 mg/kg bw Residue definition: Pyraflufen-ethyl Maximum residue limit: Shall comply with provisions in the Table 26. Table 26 Cereals Fruit Wheat 0.03 Apple Testing method: Cereals shall be tested by methods provided in GB/T 19649; fruits shall be tested by methods provided in GB/T 19648, NY/T Imidacloprid Major purpose of use: pesticide ADI: 0.06 mg/kg bw Residue definition: Imidacloprid Maximum residue limit: Shall comply with provisions in the Table 27. Table 27 Cereals Brown rice 0.05 Wheat 0.05 Corn 0.05 Fresh maize 0.05 Oil seed and oil Cotton seed

37 Vegetables Fruit Sugar crop Beverages Leek 1 Head cabbage 1 Celery 5 Celery cabbage 0.2 Tomato 1 Eggplant 1 Cucumber 1 Zucchini 0.5 Radish 0.5 Citrus 1 Apple 0.5 Pear 0.5 Sugarcane 0.2 Tea 0.5 GB Testing method: Cereals shall be tested by methods provided in SN/T , GB/T 20770; Oil seed and oil shall be tested by methods provided in SN/T , GB/T 20770; Vegetables, fruits shall be tested by methods provided in GB/T 23379, GB/T 20769, NY/T 1275; testing of sugar crops and tea shall refer to methods provided in GB/T Diflufenican Major purpose of use: Herbicide ADI: 0.2 mg/kg bw Residue definition: Diflufenican Maximum residue limit: Shall comply with provisions in the Table 28. Table 28 Cereals Wheat Testing method: Cereals shall be tested by methods provided in SN/T Fluazifop and fluazifop-p-butyl Major purpose of use: Herbicide ADI: mg/kg bw Residue definition: The sum of Fluazifop and Fluazifop acid (its metabolite), expressed as Fluazifop Maximum residue limit: Shall comply with provisions in the Table 29. Table 29 Oil seed and oil 27

38 Sugar crop Cotton seed 0.1 Soybean 0.5 Peanut 0.1 Sugar beet 0.5 GB Testing method: Oil seed and oil, sugar crops shall be tested by methods provided in GB/T Pyrazosulfuron-ethyl Major purpose of use: Herbicide ADI: mg/kg bw Residue definition: Pyrazosulfuron-ethyl Maximum residue limit: Shall comply with provisions in the Table 30. Table 30 Cereals Brown rice Testing method: Cereals shall be tested by methods provided in SN/T Pymetrozine Major purpose of use: pesticide ADI: 0.03 mg/kg bw Residue definition: pymetrozine Maximum residue limit: Shall comply with provisions in the Table 31. Table 31 Cereals Brown rice 0.1 Wheat 0.02 Oil seed and oil Cotton seed 0.1 Vegetables Head cabbage Testing method: Cereals shall be tested by methods provided in GB/T 20770; Oil seed and oil, vegetables shall be tested by methods provided in GB/T Pyraclostrobin Major purpose of use: fungicide ADI: 0.03mg/kg bw Residue definition: Pyraclostrobin Maximum residue limit: Shall comply with provisions in the Table 32. Table 32 28

39 Oil seed and oil Vegetables Fruit Peanut 0.05 Head cabbage 0.5 Celery cabbage 5 Cucumber 0.5 Chili 0.5 Potato 0.02 Apple 0.5 Grape 2 Litchi 0.05 Mango 0.05 Banana 0.02 Water melon 0.5 Sweet melon 0.5 GB Testing method: Vegetables, fruits shall be tested by methods provided in GB/T 19648, GB/T 20769; Oil seed and oil shall be tested by methods provided in GB/T Bensulfuron-methyl Major purpose of use: Herbicide ADI: 0.2 mg/kg bw Residue definition: Bensulfuron-methyl Maximum residue limit: Shall comply with provisions in the Table 33. Table 33 Cereals Rice 0.05 Brown rice 0.05 Wheat Testing method: Cereals shall be tested by methods provided in SN/T 2212, SN/T Pretilachlor Major purpose of use: Herbicide ADI: mg/kg bw Residue definition: Pretilachlor Maximum residue limit: Shall comply with provisions in the Table 34. Table 34 Cereals Rice 0.1 Wheat Testing method: Cereals shall be tested by methods provided in SN/T

40 4.35 Propiconazol Major purpose of use: fungicide ADI: 0.07 mg/kg bw Residue definition: Propiconazol Maximum residue limit: Shall comply with provisions in the Table 35. Table 35 Cereals Brown rice 0.1 Wheat 0.05 Barley 0.2 Rye 0.02 Triticale 0.02 Oil seed and oil Rape seed 0.02 Soybean 0.2 Peanut 0.1 Vegetables Fruit Sugar crop Nuts Beverages Cactus 0.05 Apple 0.1 Cranberry 0.3 Banana 1 Pineapple 0.02 Sugarcane 0.02 Sugar beet 0.02 Carya cathayensis 0.02 Coffee bean Testing method: Cereals shall be tested by methods provided in GB/T 20770, GB/T 19649; testing of oil seed and oil, sugar crops, beverages, and nuts shall refer to methods provided in SN/T 0519; vegetables and fruits shall be tested by methods provided in GB/T 20769, GB/T Prothioconazole Major purpose of use: fungicide ADI: 0.05 mg/kg bw Residue definition: desulfurized metabolite of prothioconazole, expressed as prothioconazole Maximum residue limit: Shall comply with provisions in the Table 36. Table 36 Cereals 30

41 Oil seed and oil Sugar crop 4.37 Benfuracarb Wheat 0.1 * Barley 0.2 * Oats 0.05 * Rye 0.05 * Triticale 0.05 * Coarse cereals 1 * Rape seed 0.1 * Soybean 1 * Peanut 0.02 * Sugar beet 0.3 * *The MRL is the temporary limit Major purpose of use: pesticide ADI: 0.01 mg/kg bw Residue definition: Benfuracarb Maximum residue limit: Shall comply with provisions in the Table 37. Table 37 Cereals 4.38 Oxadiargyl Rice 0.2 * Brown rice 0.2 * Oil seed and oil Cotton seed 0.5 * Cotton seed oil 0.05 * *The MRL is the temporary limit Major purpose of use: Herbicide ADI: mg/kg bw Residue definition: Oxadiargyl Maximum residue limit: Shall comply with provisions in the Table 38. Table 38 Cereals Vegetables Brown rice 0.02 * *The MRL is the temporary limit. Potato 0.02 * 31