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2017 第9期獨家發行 CHEMISTRY 專刊電子檔索取QR http://www.facebook.

gl/6js7dx ፓ ᒙᡡ ᾦ ፍᚯ 員林高中陳品誌老師一前言依據 99 學年度實施之普通高級中學課程綱要簡稱 99 課綱

今年學測試題難易度為中等偏易沒有繁雜的計算應考時若能冷靜思考善用課堂上所學的基本知識靈活應用日常生活的常識便可獲取高分

筆者在解題時也附加了出處教戰重點難易度解析以便各位教師可以更清楚看到課程重點與關鍵之處期盼本文對教師在協助同學複習時有

1 2017 第9期獨家發行 CHEMISTRY 專刊電子檔索取QR ፓ ᒙᡡ ᾦ ፍᚯ 員林高中陳品誌老師一前言依據 99 學年度實施之普通高級中學課程綱要簡稱 99 課綱自民國 102 年開始命題迄今為止共 5 年且今年 106 年為 103 年課綱微調後的第一年基本上試題內容與題型大致不變今年學測試題難易度為中等偏易沒有繁雜的計算應考時若能冷靜思考善用課堂上所學的基本知識靈活應用日常生活的常識便可獲取高分本文試著將 102 年學測以來的歷屆試題作一些多元化的統計讓教師在協助同學複習時可在知己知彼的前提下更有效率的準備同時筆者在解題時也附加了出處教戰重點難易度解析以便各位教師可以更清楚看到課程重點與關鍵之處期盼本文對教師在協助同學複習時有所幫助註 103 年課綱微調係將原基礎化學灱常見的化學反應章節與基礎化學牞化學與能源章節對調並在基礎化學牞希望各家教材多著墨些關於環境中的化學反應的內容 2017第10期化學指考期刊.indd /3/16 下午 02:40:44

2 Ch Ch ( ) Ch Ch Ch Ch ( ) Ch Ch 灱 Ch3 Ch4 牞 Ch % 灱 Ch1 Ch2 牞 Ch % 牞 Ch3 Ch4 10% 10% 灱 Ch (8)(48) 1-4 (49) 2

3 CHEMISTRY Ch2 2-2 (26) Ch Ch Ch Ch 牞 Ch (7) Ch ( ) 3

4 % % 8 10% 4 10%

5 CHEMISTRY 杕杌杈 103 5

6 106 杋酎酏釕釢釚 B 牞 1-1 Ch4 酎 H 2 O 2(aq) MnO 2 MnO 2 Δ 2 H 2 O 2(aq) 2 H 2 O (l) O 2(g) 酏 KClO 3 MnO 2 90 C 2 KClO 3(s) MnO 2 Δ 2 KCl (s) 3 O 2(g) 釕 CaCO 3 Ca(HCO 3 ) 2 CaCO 3(s) Δ CaO (s) CO 2(g) 釢 K 2 SO 4 釚 NaHCO 3 50 C Δ 2 NaHCO 3(s) Na 2 CO 3(s) CO 2(g) H 2 O (g) 毐 g/mol 酎 28 酏 29 釕 31 釢 58 釚 62 E 牞 1-1 灱 1-3 牞 Ch3 6

7 CHEMISTRY CO 2 CS 2 NaHCO 3 CaCO 3 CaC 2 Mg 2 C 3 KCN KSCN KOCN HCO 3 CO 2 3 H 2 CO 3(aq) Δ H 2 O (l) CO 2(g) H 2 CO g/mol 釚氙 NH 4 NO C 40.0 酎 1.75 酏 3.50 釕 5.25 釢 7.00 釚 8.75 A 灱 NH 4 NO 3 2 NH 4 NO 3(s) Δ 4 H 2 O (g) 2 N 2(g) O 2(g) 坽坽 1 NH 4 NO 3(s) 2 H 2 O (g) 1 N 2(g) 0.5 O 2(g) 40.0 NH 4 NO ( ) 1.75mol 80 /mol 酎氚酎酏釕釢釚 D 灱 2-1 7

8 ( ) ( ) 1 1H 1 1H 100 ( ) 1 1H ( ) ( )( ) 釢汸 MgC 2 O 4 nh 2 O n MgC 2 O g/mol 酎 1 酏 2 釕 3 釢 4 釚 5 B 灱 MgC 2 O 4 nh 2 O MgC 2O n n 2 酏 MgC 2 O 4 nh 2 O (s) Δ MgC 2 O 4(s) nh 2 O (l) MgC 2 O 4 H 2 O MgC 2O 4 H 2 O 1 n /mol /mol n 2 酏 8

9 CHEMISTRY 汧 25 C 1 H 2(g) 1 2 O 2(g) H 2 O (l) ΔH kj H 2(g) 1 2 O 2(g) H 2 O (g) ΔH kj 1.0 kj 酎酏 44.0 釕 24.4 釢 2.4 釚 0.3 D 灱 ΔH H 2 O (l) H 2 O (g) H 2 O (l) H 2 O (g) ΔH 44.0 kj 1 H2( g) O2( g) H 2 O 18 44kJ/mol 2 2.4kJ/ 18 /mol kj H 2(g) 1 2 O kj 2(g) H 2 O (l) ΔH kj 坽 H 2 O (g) H 2(g) 1 2 O 2(g) H 2 O (g) ΔH kj 夌夌坽 H 2 O (l) H 2 O (g) ΔH 44.0 kj H 2 O 18 44kJ/mol 2.4kJ/ 18 /mol H 2 O ()44.0 kj 汫 Cu (s) 4 HNO 3(aq) Cu(NO 3 ) 2(aq) 2 NO 2(g) 2 H 2 O (l) M 酎 50 酏 100 釕 150 釢 200 釚 300 D 灱

10 mol/l L /mol 2.00 M V ml 6.35 Cu HNO 3 Cu HNO V 1000 V 200mL 釢汳 XYZW X Z 10 Y X 9 W Z 7 3 酎 Z 酏 X L 釕 Y Z YZ 2 釢 Y W YW 2 釚 X W X 2 W ACE 灱牞 2-1 X 10 e 11 X281 X A Na Y20 e 20 Y2882 Y A Ca Z 10 e 9 Z27 Z A F W16 e 16 W286 X A S A n B m A m B n mn Hg 2 2 Cl Hg 2 Cl 2 HgCl 酎 Z F 酏 K L M N O X M 10

11 CHEMISTRY 釕 Y A 2 Y 2 Z A 1 Z Y 2 Z YZ 2 釢 W A 2 W 2 Y 2 W 2 YW 釚 X A 1 X X W 2 X 2 W 酎釕釚汥 2 酎酏釕釢釚 Zn ZnSO 4(aq) V CuSO 4(aq) Cu AC 灱 Zn Cu Zn Zn (s) Zn 2 (aq) 2 e Cu Cu 2 (aq) 2 e Cu (s) Zn Cu Cu Zn Cu 酎酏釕釢釚酎釕 11

12 牣 α 2 酎 α 酏 α 釕釢 α 釚 α CE 灱 α 酎 α 4 2He 2 酏 α 4 2He 2 釕釢 α α 釚釢釕釚 W/m

13 CHEMISTRY 犺酎 CaCO 3(s) CaO (s) CO 2(g) 酏 C 6 H 12 O 6(aq) 2 C 2 H 5 OH (aq) 2 CO 2(g) 釕 C 6 H 12 O 6(aq) 6 O 2(g) 6 CO 2(g) 6 H 2 O (l) 釢 CH 4(g) 2 O 2(g) CO 2(g) 2 H 2 O (l) 釚 Fe 2 O 3(s) 3 CO (g) 2 Fe (s) 3 CO 2(g) E 牞 4-1 酎 CaCO 3(s) CaO (s) CO 2(g) 酏 C 6 H 12 O 6(aq) 2 C 2 H 5 OH (aq) 2 CO 2(g) 釕 C 6 H 12 O 6(aq) 6 O 2(g) 6 CO 2(g) 6 H 2 O (l) 釢 CH 4(g) 2 O 2(g) CO 2(g) 2 H 2 O (l) 釚 Fe 2 O 3(s) 3 CO (g) 2 Fe (s) 3 CO 2(g) 釚玕 2 酎酏釕釢釚 CD 牞 4-1 酎 ENSO 酏釕釢 H 2 O (g) CO 2 O 3 CH 4 N 2 OCFCs PECsHFCsHCFCsSF 6 釚釕釢 13

14 疕 E 酎 CH 3 COOCH 3 酏 CH 3 CH 2 COCH 3 釕 CH 3 CH 2 OCH 2 CH 3 釢 HOCH 2 CH 2 CH 2 OH 釚 CH 3 CH 2 CH 2 CH 2 OH 灱 1-3 牞 H mol 74 /mol H mol 2 /mol H H R OHR R O R'RR' R CHOR H R CO R'RR' R COO R'R H R' R COOHR H 酎 CH 3 COOCH 3 R COO R' 74 酏 CH 3 CH 2 COCH 3 R CO R' 72 釕 CH 3 CH 2 CH 2 CH 3 58 釢 HOCH 2 CH 2 CH 2 OH 1,3-76 釚 CH 3 CH 2 CH 2 CH 2 OH 74 釚 14

15 CHEMISTRY 皁 10 ml 10 ml 1 ml 3 酎酏釕釢 1 ml 釚 ABC 灱牞 - Br 2 I 2 酎酏釕釢酎釚 Ca 2 酎酏釕 15

16 礽酎酏釕釢釚 BC 灱牞 - Br 2 I 2 4 酏釕耴 40.0% 6.7% 酎酏釕釢釚 C 6 H 12 O 6 AD 灱 3-1 牞

17 CHEMISTRY A a B b ab a b A B A B ( ) n n A A B B CHO HO H 2 O 21 C m (H 2 O) n C 12H 1O 16 CHO 40% 12 CH 2 O % 1 40% 6.7% (CH 2 O) n nn 6 C 6 H 12 O 6 (CH 2 O) n nn 5 C 5 H 10 O 5 酎 C 6 H 12 O 6 酏酎釕 C 5 H 10 O 5 C 6 H 12 O 6 釢 CH 2 O 釚 C 6 H 12 O 6 C 5 H 10 O 5 酎釢肕 ph 7.0 A 酎 NO 2 酏 CaO 釕 NaHCO 3 釢 CaCl 2 釚 Na 2 CO 3 牞酎 NO 2 CO 2 SO 2 SO 3 ph NO 2(g) H 2 O (l) 2 HNO 3(aq) NO (g) HNO 3(aq) H (aq) NO 3(aq) 酏 CaO Na 2 O ph 7.0 CaO (s) H 2 O (l) Ca(OH) 2(aq) Ca(OH) 2(aq) Ca 2 (aq) 2 OH (aq) 17

18 釕 NaHCO 3 NaHCO 3(aq) Na (aq) HCO 3(aq) HCO 3(aq)HCO 3(aq) H 2 O (l)? H 2 CO 3(aq) OH (aq) ph 7.0 釢 CaCl 2 HCl (aq) Ca(OH) 2 2 HCl (aq) Ca(OH) 2(aq) CaCl 2(aq) 2 H 2 O (l) CaCl 2(aq) Ca 2 (aq) 2 Cl (aq) Ca 2 (aq) Cl (aq) ph 7.0 釚 Na 2 CO 3 Na 2 CO 3(aq) 2 Na (aq) CO 2 3(aq) CO 2 3(aq)CO 2 3(aq) H 2 O HCO 3(aq) OH (aq) ph 7.0 酎釕釢釚肙 3 酎酏釕釢釚 ABC 牞 C C π 坽 3 π 3 18

19 CHEMISTRY 夌 C C 4 3 酎酏釕肐酎酏釕釢釚 D 牞坽夌 0 奅奅坽夌酎 C Fe 2 O 3(s) 3 C (s) 2 Fe (s) 3 CO (g) 酏 Al 2 Al (s) 6 HCl (aq) 2 AlCl 3(aq) 3 H 2(g) 釕 O 2 Fe 2 Fe 3 19

CHEMISTRY 釢 AgNO 3(aq) NaCl (aq) AgCl (s) AgNO 3(aq) 釚 CuO 2 2 Cu (s) O 2(g) Δ 2 CuO (s) 釢 1 2 3 230 250

20 CHEMISTRY 釢 AgNO 3(aq) NaCl (aq) AgCl (s) AgNO 3(aq) 釚 CuO 2 2 Cu (s) O 2(g) Δ 2 CuO (s) 釢 we04@chwa.com.tw

cm CO Na CO HC NaO H CO SO

cm CO Na CO HC NaO H CO SO C H Na CO CaCO Na CO CaCO ml mm mm cm cm b a b c d K CO A B C D E F G H F C A D B H G C F A KC O MnO MnO KC O MnO KClO MH NO H SO N H N O H SO NaO H Na O ml Na O O NaO